三氯化铁安全数据单.doc

附件1：安全数据单样本（中文） 报验号：272302012000483第5页，共6页化学品安全数据单一、标识物品名称：三氯化铁/ Ferric Trichloride。其它名称：无水氯化铁使用建议及使用限制： 工业级产品主要用于工业废水水处理.制造商或供货商名称、地址及电话：济南高孚工贸有限责任公司山东省济南市历城区王舍人镇路家庄 053188682542紧急联络电话/传真电话：053188882448/ 053188682554二、危险标识物质或混合物的分类：急性毒性（口服）第4类金属腐蚀物第1类皮肤腐蚀/刺激第1C类严重眼损伤/眼刺激第1类危害水生环境（长期）第3类。全球统一制度标签要素，包括防范说明：信号词：危险。危险说明：吞咽有害。可能腐蚀金属。造成严重皮肤灼伤和眼损伤。对水生生物有害并具有长期持续影响。防范说明：预防：作业后彻底清洗。使用本产品时不要进食、饮水或吸烟。只能在原容器中存放。不要吸入粉尘/烟/气体/烟雾/蒸气/喷雾。戴防护手套/穿防护服/戴防护眼罩/戴防护面具。避免释放到环境中。反应：如误吞咽：漱口。不得诱导呕吐。如感觉不适，呼叫解毒中心或医生。吸收溢出物，防止材料损坏。如皮肤（或头发）沾染：立即去除/脱掉所有沾染的衣服。用水清洗皮肤/淋浴。沾染的衣服清洗后方可重新使用。如误吸入：将受害人转移到空气新鲜处，保持呼吸舒适的休息姿势。立即呼叫解毒中心或医生。如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫解毒中心或医生。贮存：贮存于抗腐蚀/带抗腐蚀衬里的容器中。存放处须加锁。处置：按照相关规章处置内装物和容器。不导致分类的其他危险（例如尘爆危险）或不为全球统一制度覆盖的其他危险：/三、组成/成分信息化学名称化学文摘社登记号码（CAS No.）含量%三氯化铁7705-08-097.21%四、急救措施必要的急救措施吸入：如果吸入,请将患者移到新鲜空气处。如果停止了呼吸,给予人工呼吸。求医。皮肤接触：用肥皂和大量的水冲洗。求医。眼睛接触：用大量水彻底冲洗至少15分钟。就医。食入：禁止催吐。切勿给失去知觉者从嘴里喂食任何东西。用水漱口。就医。最重要的急性和延迟症状/效应：/必要时注明立即就医及所需的特殊治疗：/五、消防措施适用和不适用的灭火剂：用雾状水、抗醇泡沫、干粉或二氧化碳灭火。化学品产生的具体危险：不可燃。无明显的着火危险。酸与金属反应产生一种极易燃并且具有爆炸性的氢气。受热可引起膨胀或分解，会导致容器剧烈破损。可以放出腐蚀性、有毒烟雾。可释放辛辣刺激的烟雾。消防人员的特殊防护行为：如必要,戴自给式呼吸器去救火。用雾状水冷却未打开的容器。六、意外释放措施人身防范、保护设备和应急程序：避免与皮肤和眼睛接触。采用防护设备来防止与身体直接接触。疏散所有人员，向上风向撤离。环境防范措施：在确保安全的条件下,采取措施防止进一步的泄漏或溢出。不要让产物进入下水道。抑制和清理的方法和材料：对残留物进行中和/去污。收集固体残留物，密封于贴有标签的桶中，以便废弃处理。冲洗沾染区域，防止废液流入阴沟。完成清理工作后，对所有防护服和设备，在存放和再使用前，应进行去污和清洗。七、操作与储存安全操作的防范措施：避免所有的个体接触，包括吸入。当有接触危险时，穿戴防护服。在通风良好的区域使用本物质。安全存储的条件，包括任何不相容性：贮存在阴凉处。容器保持紧闭，储存在干燥通风处。打开了的容器必须仔细重新封口并保持竖放位置以防止泄漏。八、接触控制/人身保护控制参数：来源物质TWAppmTWAmg/mSTELppmSTELmg/mSingapore Permissible Exposure Limits of Toxic Substancesferric chloride1Australia Exposure Standardsferric chloride1New Zealand Workplace Exposure Standards (WES)ferric chloride1工程控制：搬运粉状或晶体状固体物质时，需要局部通风系统。如果即使有局部通风系统，空气中物质的浓度仍然达到了有害的程度，应考虑使用呼吸保护设备。个人防护设备眼睛防护：化学护目镜。全面脸部防护可以被用作眼部的辅助防护但不能做主要防护。手部防护：戴化学防护手套(如聚氯乙烯 PVC)。穿安全鞋或安全靴(如橡胶材料)。手套类型的适用性和耐用性取决于使用方法。呼吸防护：呼吸器种类和型号的选择取决于呼吸区域污染物的等级以及污染物的化学性质。九、物理及化学性质外观（物理状态、颜色等）气味气味阙值pH值熔点/凝固点初始沸点和沸腾范围闪点蒸发速率易燃性（固态、气态）上下易燃极限或爆炸极限蒸气压力蒸气密度相对密度可溶性分配系数：n-辛醇/水自动点火温度分解温度粘度粉末状固体/300C315319C/0.13 kPa (194)。/2.90（水=1）。可溶的/十、稳定及反应性反应性：/化学稳定性：与碱性物质接触会释放出热量。危险反应的可能性：/应避免的条件：防潮 。不相容的物质和材料：危险的分解产物：/十一、毒理学信息急性毒性效应：吸入：不认为吸入该物质能产生有害健康的影响。接触高浓度会引起气道发炎和肺水肿。食入：如服入是有害的。食入本物质可对口腔和胃肠道造成化学烧伤。皮肤：皮肤直接接触本品可造成化学烧伤。眼睛：眼睛直接接触该物质可产生化学烧伤。蒸气和气雾具有极度刺激性。慢性毒性或长期毒性效应：反复或长期接触腐蚀性物质，可导致牙齿受腐蚀、口腔炎症和溃疡以及颌骨坏死(少见)。支气管刺激症状会伴有咳嗽，经常发作会使支气管肺炎得到恶化。也可发生胃肠功能失衡。长期接触可引起皮炎或结膜炎。毒性的数值度量（如急性毒性估计值）：LD50：450 mg/kg(大鼠经口)。十二、生态信息生态毒性：/持久性及降解性：/生物蓄积性：/在土壤中的流动性：/其它不利效应：对水生生物有害并具有长期持续影响。十三、处置考虑处置方法：容器清空后仍可能有化学品危害或危险存在。如有可能，请将容器返还给供应商循环使用。十四、运输信息联合国编号：1773联合国运输名称：无水氯化铁运输危险种类：8包装类别：III海洋污染物（是/否）：是使用者的特殊防范措施：/十五、管理信息国内化学品安全管理法规：三氯化铁出现在以下法规中：中国现有化学物质名录，危险化学品名录。本化学品安全技术说明书遵照了以下相关国家标准：GB16483-2000、GB13690-1992、GB6944-1986、GB/T15098-1994、GB18218-2000、GB15258-2000、GB6944-86、GB190-90、GB191-90,、GB12268-90、GA57-93、GB/T 15098-94,、GBZ 2-2002以及相关法规：危险货物运输管理规则 （铁道部1995年颁布）、危险化学品安全管理条例（国务院2002年颁布）、联合国关于危险货物运输的建议书（简称 UN RTDG）。十六、其它信息參考文献联合国关于危险货物运输的建议书.规章范本联合国全球化学品统一分类和标签制度制表日期2012年03月01日注1：当产品为含有两种以上危险物质的混合物时，应依据其混合后的危险性，制作安全数据单。注2：制造商/供应商应根据实际情况确保安全数据单所含信息的正确性，并适时更新。注3：如由于产品特性而不可得或不存在某些信息时（如固体不存在沸点），应在表格中以“/”标识。附件2：安全数据单样本（英文） 报验号：272302012000483第6页，共7页Chemical Safety Data SheetSECTION 1 IDENTIFICATIONProduct Name: Ferric TrichlorideOther Name: iron trichloride, anhydrousRecommended use of the chemical and restrictions on use: /Industrial products used for treating industrial dirty water.Suppliers details: /Jinan Gaofu Industry Trading Co., Ltd. Lujiazhuang village Wangsheren town Licheng District, Ji Nan, Shan Dong province of ChinaEmergency phone number: /053188882448/ 053188682554SECTION 2 HAZARDS IDENTIFICATIONClassification of the substance or mixtureAcute Toxicity (Oral) Category 4Metal Corrosion Category 1Skin Corrosion/Irritation Category 1Cerious Eye Damage Category 1Chronic Aquatic Hazard Category 3GHS Label elements, including precautionary statementsSignal word: DangerHazard statement(s): Harmful if swallowed. May be corrosive to metals. Causes severe skin burns and eye damage. Harmful to aquatic life with long lasting effects.Precautionary statement(s):Prevention: Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Keep only in original container. Do not breathe dusts or mists. Avoid release to the environment.Response: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. Do NOT induce vomiting. Absorb spillage to prevent material damage. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.Storage: Store in corrosive resistant/ container with a resistant inner liner. Store locked up.Disposal: Dispose of contents/container to in accordance with national regulations.Other hazards which do not result in classification: /SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTSChemical NameCAS No.Concentration%Ferric Trichloride7705-08-097.21%SECTION 4 FIRST AID MEASURESDescription of necessary first aid measuresIf inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.In case of skin contact: Wash off with soap and plenty of water. Consult a physician.In case of eye contact: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.If swallowed: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.Most important symptoms and effects, both acute and delayed: /Indication of immediate medical attention and special treatment needed：/SECTION 5 FIREFIGHTING MEASURESSuitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.Special hazards arising from the chemical: Non-combustible. Not considered to be a significant fire risk. Acids may react with metals to produce hydrogen, a highly flammable and explosive gas. Heating may cause expansion or decomposition leading to violent rupture of containers. May emit corrosive, poisonous fumes. May emit acrid smoke.Special protective actions for fire-fighters: Wear self-contained breathing apparatus for firefighting if necessary. Use water spray to cool unopened containers.SECTION 6 ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment and emergency procedures: Avoid contact with skin and eyes. Control personal contact by using protective equipment. Clear area of personnel and move upwind.Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains.Methods and materials for containment and cleaning up: Neutralise/decontaminate residue. Collect solid residues and seal in labelled drums for disposal. Wash area and prevent runoff into drains. After clean-up operations, decontaminate and launder all protective clothing and equipment before storing and re-using.SECTION 7 HANDLING AND STORAGEPrecautions for safe handling: Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area.Conditions for safe storage, including any incompatibilities: Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTIONControl parameters:SourceMaterialTWAppmTWAmg/mSTELppmSTELmg/mSingapore Permissible Exposure Limits of Toxic Substancesferric chloride1Australia Exposure Standardsferric chloride1New Zealand Workplace Exposure Standards (WES)ferric chloride1Appropriate engineering controls: Local exhaust ventilation is required where solids are handled as powders or crystals; even when particulates are relatively large, a certain proportion will be powdered by mutual friction. If in spite of local exhaust an adverse concentration of the substance in air could occur, respiratory protection should be considered.Personal protective equipmentEye/face protection: Chemical goggles. Full face shield may be required for supplementary but never for primary protection of eyes.Skin protection: Wear chemical protective gloves, eg. PVC. Wear safety footwear or safety gumboots, eg. Rubber. Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves.Respiratory protection: Selection of the Class and Type of respirator will depend upon the level of breathing zone contaminant and the chemical nature of the contaminant.SECTION 9 PHYSICAL AND CHEMICAL PROPERTIESAppearanceOdourOdour ThresholdpHMelting point/freezing pointInitial boiling point and boiling rangeFlash pointEvaporation rateFlammability (solid, gas)Upper/lower flammability or explosive limitsVapour pressureVapour densityRelative densityWater solubilityPartition coefficient: noctanol/waterAutoignition temperatureDecomposition temperatureViscosityDivided solid/300C315319C/0.13 kPa (194)。/2.90（water=1）。miscible/SECTION 10 STABILITY AND REACTIVITYReactivity: /Chemical stability: Contact with alkaline material liberates heat.Possibility of hazardous reactions: /Conditions to avoid: /Incompatible materials: /Hazardous decomposition products: /SECTION 11 TOXICOLOGICAL INFORMATIONAcute health effectsInhalation: The material is not thought to produce adverse health effects following inhalation. High concentrations cause inflamed airways and watery swellingof the lungs with oedema.Ingestion: May be harmful if swallowed. The material can produce chemical burns within the oral cavity and gastrointestinal tract following ingestion.Skin: The material can produce chemical burns following direct contact with the skin.Eyes: The material can produce chemical burns to the eye following direct contact. Vapours or mists may be extremely irritating. If applied to the eyes, this material causes severe eye damage.Chronic health effects: Repeated or prolonged exposure to corrosives may result in the erosion of teeth, inflammatory and ulcerative changes in the mouth and necrosis (rarely) of the jaw. Bronchial irritation, with cough, and frequent attacks of bronchial pneumonia may ensue. Gastrointestinal disturbances may also occur. Chronic exposures may result in dermatitis and/or conjunctivitis.Numerical measures of toxicity(such as acute toxicity estimates): LD50 Oral - rat - 450 mg/kg, LD50 Oral - mouse 895 mg/kg.SECTION 12 ECOLOGICAL INFORMATIONToxicity:/Persistence and degradability: /Bioaccumulative potential: /Mobility in soil: /Other adverse effects: Harmful to aquatic life with long lasting effects.SECTION 13 DISPOSAL CONSIDERATIONSDisposal methods: Containers may still present a chemical hazard/ danger when empty. Return to supplier for reuse/ recycling if possible.SECTION 14 TRANSPORT INFORMATIONUN number: 1773UN proper shipping name: FERRIC CHLORIDE, ANHYDROUSTransport hazard class(es): 8Packaging group: IIIEnvironmental hazards: yesSpecial precautions for user: / SECTION 15 REGULATORY INFORMATIONRegulations：Ferric trichloride is found on the following regulatory list：China Dan