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ARTICLEINFOARTICLEHISTORYRECEIVED25OCTOBER2010RECEIVEDINREVISEDFORM12JANUARY2011ACCEPTED14JANUARY2011AVAILABLEONLINE21JANUARY2011KEYWORDSMICROCELLULARINJECTIONMOLDINGPLASTICFOAMINGSWIRLFREESURFACEABSTRACTMICROCELLULARINJECTIONMOLDINGISTHEMANUFACTURINGMETHODUSEDFORPRODUCINGFOAMEDPLASTICPARTSMICROCELLULARINJECTIONMOLDINGHASMANYADVANTAGESINCLUDINGMATERIAL,ENERGY,ANDCOSTSAVINGSASWELLASENHANCEDDIMENSIONALSTABILITYINSPITEOFTHESEADVANTAGES,THISTECHNIQUEHASBEENLIMITEDBYITSPROPENSITYTOCREATEPARTSWITHSURFACEDEFECTSSUCHASAROUGHSURFACEORGASFLOWMARKSMETHODSFORIMPROVINGTHESURFACEQUALITYOFMICROCELLULARPLASTICPARTSHAVEBEENINVESTIGATEDBYSEVERALRESEARCHERSTHISPAPERDESCRIBESANOVELMETHODFORACHIEVINGSWIRLFREEFOAMEDPLASTICPARTSUSINGTHEMICROCELLULARINJECTIONMOLDINGPROCESSBYCONTROLLINGTHECELLNUCLEATIONRATEOFTHEPOLYMER/GASSOLUTIONTHROUGHMATERIALFORMULATIONANDGASCONCENTRATION,MICROCELLULARINJECTIONMOLDEDPARTSFREEOFSURFACEDEFECTSWEREACHIEVEDTHISPAPERPRESENTSTHETHEORETICALBACKGROUNDOFTHISAPPROACHASWELLASTHEEXPERIMENTALRESULTSINTERMSOFSURFACEROUGHNESSANDPROFILE,MICROSTRUCTURES,MECHANICALPROPERTIES,ANDDIMENSIONALSTABILITYINTRODUCTIONTHECOMMERCIALLYAVAILABLEMICROCELLULARINJECTIONMOLDINGPROCESSAKATHEMUCELLPROCESSCONSISTSOFFOURDISTINCTIVESTEPS,NAMELY,GASDISSOLUTION,NUCLEATION,CELLGROWTH,ANDSHAPING1INTHEGASDISSOLUTIONSTAGE,POLYMERINTHEINJECTIONBARRELISMIXEDWITHSUPERCRITICALFLUIDSCFNITROGEN,CARBONDIOXIDE,ORANOTHERTYPEOFGASUSINGASPECIALSCREWWHICHISDESIGNEDTOMAXIMIZETHEMIXINGANDDISSOLVINGOFTHEGASINTHEPOLYMERMELTDURINGINJECTION,ALARGENUMBEROFNUCLEATIONSITESORDERSOFMAGNITUDEHIGHERTHANCONVENTIONALFOAMINGPROCESSESAREFORMEDBYARAPIDANDSUBSTANTIALPRESSUREDROPASTHEPOLYMER/GASSOLUTIONISINJECTEDINTOTHEMOLDCAVITY,THUSCAUSINGTHEFORMATIONOFCELLSBUBBLESDURINGTHERESTOFTHEINJECTIONMOLDINGCYCLE,CELLSCONTINUETOGROWTOFILLANDPACKOUTTHEMOLDANDSUBSEQUENTLYCOMPENSATEFORTHEPOLYMERSHRINKAGEASTHEMATERIALCOOLSINSIDETHEMOLDTHECELLGROWTHISDRIVENBYTHEAMOUNTANDSPATIALDISTRIBUTIONOFTHEDISSOLVEDGASTHECELLGROWTHISALSOCONTROLLEDBYPROCESSINGCONDITIONSSUCHASMELTPRESSUREANDTEMPERATUREASWELLASMATERIALPROPERTIESSUCHASMELTSTRENGTHANDGASSOLUBILITYFINALLY,THESHAPINGOFTHEPARTTAKESPLACEINSIDETHEMOLDUNTILTHEMOLDOPENSALLOWINGTHEPARTTOBEEJECTEDSINCETHEMICROCELLULARINJECTIONMOLDINGPROCESSWASINVENTED,THEREHAVEBEENNUMEROUSSTUDIESONPROCESS,MATERIAL,ANDTECHNICALDEVELOPMENTSAIMEDATMATERIALIZINGTHEFULLPROCESSPOTENTIALACCORDINGTOPREVIOUSSTUDIES15,MICROCELLULARINJECTIONMOLDINGOFFERSANUMBEROFADVANTAGESSUCHASCOSTSAVINGS,WEIGHTREDUCTION,EASEINPROCESSINGDUETOLOWVISCOSITY,ANDOUTSTANDINGDIMENSIONALACCURACYDUETOTHESEADVANTAGES,THEMICROCELLULARINJECTIONMOLDINGPROCESSHASBEENUSEDINMANYINDUSTRIESSUCHASAUTOMOTIVE,ELECTRICALGOODS,ANDHOMEAPPLIANCESUSINGABROADRANGEOFTHERMOPLASTICSDESPITETHESEADVANTAGES,HOWEVER,THESURFACEIMPERFECTIONSASSOCIATEDWITHMICROCELLULARINJECTIONMOLDEDPARTSDSUCHASUNIQUEGASFLOWMARKS,REFERREDTOASSWIRLMARKSTHROUGHOUTTHISPAPER,ANDALACKOFSMOOTHNESSDSTILLREMAINONEOFTHEMAINDRAWBACKSSURROUNDINGMICROCELLULARINJECTIONMOLDINGINORDERTOELIMINATEORREDUCETHESESURFACEIMPERFECTIONSTHEREHAVEBEENSEVERALSTUDIESATTEMPTED,ASREPORTEDINREFS614SOMERESEARCHERSHAVEFOCUSEDONTEMPERATUREMODIFICATIONOFTHEMOLDSURFACETOIMPROVETHESURFACEQUALITYOFMICROCELLULARINJECTIONMOLDEDPARTS68WITHPOLYMERICFOAM,ITWASFOUNDTHATBUBBLESFORMINGATTHEADVANCINGMELTFRONTAREFIRSTSTRETCHEDBYTHEFOUNTAINFLOWBEHAVIORTOWARDTHEMOLDSURFACEANDSUBSEQUENTLYDRAGGEDAGAINSTTHEMOLDWALLCAUSINGSWIRLMARKS9DURINGTHEFILLINGSTAGEOFPOLYMERMELTS,KEEPINGTHEMOLDWALLTEMPERATUREHIGHENOUGHFORBUBBLESATTHEMOLDSURFACETOBEELIMINATEDIMPROVESTHESURFACEQUALITYOFMICROCELLULARINJECTIONMOLDEDPARTSBYCONTROLLINGTHEMOLDTEMPERATURERAPIDLYANDPRECISELYUSINGMOLDTEMPERATURECONTROLUNITSOROTHERKINDSOFTHERMALORSURFACEHEATINGDEVICES,MICROCELLULARFOAMEDPLASTICSWITHGLOSSYANDSWIRLFREESURFACESCANBEPRODUCEDTHEREHAVEALSOBEENEFFORTSTOELIMINATETHESWIRLMARKSONMICROCELLULARINJECTIONMOLDEDPARTSWITHOUTANYMOLDTEMPERATURECONTROLLERINPARTICULAR,ITWASPROPOSEDTHATINSERTINGANINSULATORONTOTHEMOLDWALLMIGHTHELPKEEPINGTHEINTERFACETEMPERATUREBETWEENTHEMOLDANDTHEPOLYMERMELTHIGHTHISTECHNIQUEBASICALLYYIELDSTHESAMERESULTASTEMPERATUREMODIFICATIONOFTHEMOLD10THERMALANALYSISANDEXPERIMENTALRESULTSPROVETHATTHEADDITIONOFANINSULATORLAYERONTHEMOLDCANIMPROVETHESURFACEQUALITYOFMICROCELLULARINJECTIONPARTS11ANOTHERMETHODOFPRODUCINGPARTSWITHANIMPROVEDSURFACEQUALITYLEADSTOAMICROCELLULARCOINJECTIONMOLDINGPROCESS12INTHISTECHNIQUE,APROPERAMOUNTOFSOLIDSKINMATERIALISINJECTEDPRIORTOTHEINJECTIONOFAFOAMINGCOREMATERIALTHISCANYIELDASANDWICHEDSOLIDSKINEFOAMEDCOREESOLIDSKINSTRUCTUREWITHASURFACEFINISHSIMILARTOACONVENTIONALLYMOLDEDCOMPONENTWHILEPARTIALLYMAINTAININGTHEADVANTAGESOFMICROCELLULARINJECTIONMOLDINGANOTHERAPPROACHFORIMPROVINGTHESURFACEQUALITYOFMICROCELLULARINJECTIONMOLDEDPARTSISTHEGASCOUNTERPRESSUREPROCESS13,14INTHISPROCESS,AHIGHPRESSUREGASISINJECTEDINTOTHEMOLDPRIORTOTHEPOLYMER/GASSOLUTIONTOSUPPRESSCELLNUCLEATIONANDBUBBLEGROWTHWHILETHEPOLYMER/GASSOLUTIONISBEINGINJECTEDINTOTHEMOLDCAVITYTOWARDTHEENDOFINJECTION,COUNTERGASPRESSUREISRELEASEDANDBUB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CULARDENSITYOFTHEBULKLIQUID,ANDS1ISDEFINEDASTHEDEGREEOFSUPERSATURATIONTHUS,THEACTIVATIONENERGYEQUATIONCFEQUATION2FORNUCLEATIONINTHEMICROCELLULARINJECTIONMOLDINGPROCESSCANBEGIVENBY(8)16331LN2HENCEITCANBESTATEDTHATTHEACTIVATIONENERGYFORNUCLEATIONISINVERSELYPROPORTIONALTOTHESQUAREOFTHENATURALLOGARITHMOFTHESUPERSATURATIONDEGREEINTHEMICROCELLULARINJECTIONMOLDINGPROCESS,THEPOLYMER/GASSOLUTIONBECOMESAMETASTABLESUPERSATURATIONSOLUTIONWHENITISINJECTEDINTOTHEMOLDCAVITYTHISISBECAUSETHEAMOUNTOFGASABLETOBEDISSOLVEDINTHEPOLYMERINTHEPRESENCEOFARAPIDPRESSUREDROPISLESSTHANTHEGASAMOUNTORIGINALLYDISSOLVEDINPOLYMERMELTSINPARTICULAR,ASSUMINGTHEAIRINTHECAVITYISPROPERLYVENTED,THEPRESSUREATTHEADVANCINGMELTFRONTISATTHEATMOSPHERICPRESSURETHESOLUBILITYOFAGASINAPOLYMERATATMOSPHERICPRESSUREANDPROCESSINGTEMPERATURECANBEOBTAINEDBYANARRHENIUSTYPEEXPRESSIONWITHREGARDTOTEMPERATURE229111298WHEREISTHESOLUBILITYOFTHEGASINTHEPOLYMERATSTANDARDTEMPERATUREANDPRESSURECONDITIONS298KAND1ATMTHEPARAMETERDHSISTHEMOLARHEATOFSORPTION,ANDTMELTISTHEPOLYMERMELTTEMPERATURETHUS,THEDEGREEOFSUPERSATURATIONISGIVENBY1011298WHEREISTHEGASDOSAGEWHICHCANBECONTROLLEDBYTHESUPERCRITICALFLUIDSCFSUPPLYSYSTEMTHEHEATOFSORPTION,OFVARIOUSPOLYMER/GASSYSTEMSATSTANDARDTEMPERATUREHASBEENSTUDIEDANDSUMMARIZEDINMANYPREVIOUSLYPUBLISHEDSTUDIESINORDERTOOBTAINTHEDEGREEOFSUPERSATURATIONFORAPOLYMER/GASSOLUTIONINTHEMICROCELLULARINJECTIONMOLDINGPROCESS,ONEHASTOEITHERMEASURETHESOLUBILITYOFTHEGASINTHEPOLYMERATSTANDARDTEMPERATUREANDPRESSUREORCONSULTPUBLISHEDDATAONTHESOLUBILITYOFTHEGASINTHEPOLYMERTHEN,THEACTIVATIONENERGYBARRIERFORNUCLEATIONINEQUATION8,G,CANBEOBTAINEDBASEDONTHECALCULATEDDEGREEOFSUPERSATURATIONANDTHESURFACEENERGYOFTHEBUBBLEINTERFACE,GIVENTHEACTIVATIONENERGYBARRIERANDTHEFREQUENCYFACTOR,F,THENUCLEATIONRATEEXPRESSEDINEQUATION1CANTHENBECALCULATEDTHEESTIMATEOFTHESURFACEENERGYOFTHEBUBBLEINTERFACEANDTHEFREQUENCYFACTORISDISCUSSEDBELOWINMICROCELLULARINJECTIONMOLDING,THEPOLYMER/GASSOLUTIONCANBETREATEDASALIQUIDMIXTURETHUS,THESURFACEENERGYOFTHEBUBBLEINTERFACE,G,CANBEEXPRESSEDAS23,24(11)41WHEREISTHESURFACEENERGYOFTHEPOLYMER,ARETHEDENSITIES,ANDISTHEWEIGHTFRACTIONOFGASINADDITION,AFREQUENCYFACTORFORAGASMOLECULE,F,INEQ1CANBEEXPRESSEDAS24261242WHEREZISTHEZELDOVICHFACTOR,WHICHACCOUNTSFORTHEMANYCLUSTERSTHATHAVEREACHEDTHECRITICALSIZE,BUTARESTILLUNABLETOGROWTOSUSTAINABLEBUBBLESTHEPARAMETERBISTHEIMPINGEMENTRATEATWHICHGASMOLECULESCOLLIDEWITHTHEWALLOFACLUSTERTHEPARAMETERCANBEUSEDASACORRECTIONFACTORANDISDETERMINEDEXPERIMENTALLYONCETHENUCLEATIONRATEASAFUNCTIONOFTHEDEGREEOFSUPERSATURATIONISOBTAINED,ONECANCONTROLTHEGASSCFCONTENTINTHEPOLYMERMELTTOCONTROLORDELAYTHEONSETOFCELLNUCLEATIONSOTHATNOBUBBLEWILLFORMATTHEADVANCINGMELTFRONTDURINGTHEINJECTIONFILLINGSTAGE,THUS,ALLOWINGMICROCELLULARPARTSWITHSOLID,SWIRLFREESURFACETOBEINJECTIONMOLDED3EXPERIMENTAL31MATERIALSTHEMATERIALUSEDINTHISSTUDYWASANINJECTIONMOLDINGGRADELOWDENSITYPOLYETHYLENE,LDPECHEVRONPHILLIPSCHEMICALCOMPANY,TEXAS,USAITHASAMELTINDEXOF25G/10MINANDADENSITYOF0925G/3TOCONFIRMTHETHEORYFORIMPROVINGSURFACEQUALITYBYCONTROLLINGTHEDEGREEOFSUPERSATURATION,ARANDOMCOPOLYMERPOLYPROPYLENEPPWASALSOUSEDINTHISSTUDYTHEPPUSEDINTHISSTUDYWASTITANPROSM668TITANCHEMICALSCORP,MALAYSIA,WITHAMELTFLOWINDEXOF20G/10MINANDADENSITYOF09G/BOTH3MATERIALSWEREUSEDASRECEIVEDWITHOUTANYCOLORANT,FILLERS,ORADDITIVESCOMMERCIALGRADENITROGENWASUSEDASAPHYSICALBLOWINGAGENTFORTHEMICROCELLULARINJECTIONMOLDINGTRIALS32MICROCELLULARINJECTIONMOLDINGINTHISSTUDY,ANARBURG320SINJECTIONMOLDINGMACHINEARBURG,GERMANYWASUSEDFORBOTHTHESOLIDCONVENTIONALANDMICROCELLULARINJECTIONMOLDINGEXPERIMENTSTHESUPERCRITICALFLUIDSCFSUPPLYSYSTEMUSEDINTHISSTUDYWASTHES11TR3MODELTREXEL,WOBURN,MA,USATHETOTALGASDOSAGEWASCONTROLLEDBYADJUSTINGTHEGASINJECTIONTIME,T,ANDTHEGASINJECTIONFLOWRATE,M_GATENSILETESTMOLD,WHICHPRODUCESTENSILETESTSPECIMENSTHATMEETTHEASTMD638TYPEISTANDARDS,WASUSEDFORTHISEXPERIMENTFORINJECTIONMOLDINGOFBOTHLDPEANDPPTENSILETESTSPECIMENS,NOZZLEANDMOLDTEMPERATURESWERESETAT221AND25,RESPECTIVELYTHECYCLE。TIMEWAS40SANINJECTIONSPEEDOF80CM3/SWASEMPLOYEDINTHISSTUDY,SIXDIFFERENTGASDOSAGESCONCENTRATIONSWEREUSEDFORINJECTIONMOLDINGOFLDPEASSHOWNINTABLE1ALSO,FOURDIFFERENTGASDOSAGESWEREEMPLOYEDFORMICROCELLULARINJECTIONMOLDINGOFPPTHESUPERCRITICALFLUIDWASINJECTEDINTOTHEINJECTIONBARRELAT140BARPRESSURETOBEMIXEDWITHTHEPOLYMERMELTSINTHISEXPERIMENTTHEWEIGHTREDUCTIONOFFOAMEDVERSUSSOLIDPLASTICPARTSWASTARGETEDAT8_05FOREACHSPECIMENFORTHECONVENTIONALINJECTIONMOLDINGEXPERIMENT,THESHOTSIZEOF202ANDAPACKINGPRESSUREOF800BARSWEREEMPLOYEDFOR6SFORTHEMICROCELLULAR3INJECTIONMOLDINGEXPERIMENTS,THESHOTSIZEOFTHEPOLYMERMELTWAS192AND3THEPACKINGSTAGEWASELIMINATED33ANALYSISMETHODSTOANALYZETHESURFACEROUGHNESSOFTHEMOLDEDTENSILEBARSPECIMENS,AFEDERALSURFANALYZER4000FEDERALPRODUCTCORPORATION,RI,USAWASUSEDTHESURFACEROUGHNESSESOFCONVENTIONALANDMICROCELLULARINJECTIONMOLDEDPARTSWEREEVALUATEDATTHREELOCATIONSSHOWNINFIG1ANDTHEAVERAGEDSURFACEROUGHNESSBASEDONMEASUREMENTSDONEATALLTHREELOCATIONSWASRECORDEDANDREPORTEDTHECUTOFF,DRIVESPEED,ANDDRIVELENGTHFORTHETESTWERE075MM,25MM/S,AND25MM,RESPECTIVELYFOREACHPROCESSCONDITION,TENSPECIMENSANDTHREEPOINTSONEACHSPECIMENWERETESTEDINADDITIONTOTHESURFACEROUGHNESS,SWIRLMARKSCOMMONLYOBSERVEDINMICROCELLULARINJECTIONMOLDEDSAMPLESCANALSOBECLEARLYREVEALEDBYA3DSURFACEPROFILERZYGONEWVIEWZYGOCORPORATION,CT,USA,ANONCONTACT3DSURFACEPROFILER,WASEMPLOYEDTOEXAMINETHESURFACEPROFILEOFINJECTIONMOLDEDPARTSINTHISSTUDYUSINGASCANDISTANCEOF10MMAJEOLJSM6100SCANNINGELECTRONMICROSCOPEWITHANACCELERATINGVOLTAGEOF15KVWASEMPLOYEDFOROBSERVINGTHEMICROSTRUCTURESOFTHEFOAMEDPARTSTOOBSERVETHECROSSSECTIONOFTHEMICROCELLULARINJECTIONMOLDEDPARTS,TESTSPECIMENSWEREFROZENBYLIQUIDNITROGENANDSUBSEQUENTLYFRACTUREDREPRESENTATIVEIMAGESOFEACHPROCESSCONDITIONWERESELECTEDANDCELLSIZESANDDENSITIESWEREANALYZEDAUTHSCSAIMAGETOOLWASEMPLOYEDASTHEIMAGEANALYSISSOFTWARETOEVALUATECELLDENSITIESANDSIZESAMTSSINTECH10GLSCREWDRIVENMACHINEWASUSEDTOTESTTHEMECHANICALPROPERTIESOFTHEMOLDEDSPECIMENS,INCLUDINGTHEYIELDSTRESS,STRAINATBREAK,MODULUS,ANDULTIMATESTRESSTENSPECIMENSFOREACHCONDITIONWERETESTEDTHETENSILETESTSPEEDWAS508MM/MINTHESCHEMATICOFTHEASTMTENSILEBARANDLOCATIONSOFTHEVARIOUSANALYSESARESHOWNINFIG1TOTESTTHEDIMENSIONALSTABILITYOFTHEINJECTIONMOLDEDSPECIMENS,ADIALCALIPERMADEBYMITUTOYOWASUSEDDIMENSIONSOFTHEMOLDCAVITYWEREFIRSTMEASUREDANDTHENTHEINJECTIONMOLDEDPARTSWEREMEASUREDANDCOMPAREDWITHTHEACTUALDIMENSIONSOFTHEMOLDCAVITY4RESULTSANDDISCUSSION41SURFACEPROFILEANDROUGHNESSMEASUREMENTASAVISUALILLUSTRATION,FIG2SHOWSTHEREPRESENTATIVEINJECTIONMOLDEDLOWDENSITYPOLYETHYLENELDPEPARTSTOBETTERREVEALTHESURFACEQUALITYINTHEPHOTO,5WTCOLORANTWASADDEDTOTHEMATERIALALTHOUGHTHESAMESURFACEQUALITYWASOBTAINEDWITHOUTCOLORANTASANTICIPATED,THECONVENTIONALSOLIDINJECTIONMOLDEDPARTFIG2AHASAGLOSSYANDFLAWLESSSURFACEONTHEOTHERHAND,THETYPICALMICROCELLULARINJECTIONMOLDEDPARTFIG2BPRODUCEDWITHAMODERATEORHIGHGASCONCENTRATIONHASALUSTERLESSSURFACEDUETOSWIRLMARKSAMICROCELLULARPLASTICPARTFIG2CMOLDEDWITHACAREFULLYCONTROLLEDGASCONCENTRATIONOF0173WTORLESSHASAHIGHQUALITYSURFACEFINISHCOMPARABLETOTHECONVENTIONALSOLIDINJECTIONMOLDEDPARTNOSWIRLMARKSORDEFECTSAREOBSERVEDONTHESURFACEFORPOLYPROPYLENEPP,ITWASOBSERVEDTHATMICROCELLULARINJECTIONMOLDEDPARTSPRODUCEDWITHAGASAMOUNTOF0173WTORLESSALSOEXHIBITEDSWIRLFREEANDSHINYSURFACESFIG3SHOWSTHEREPRESENTATIVESURFACEPROFILESOFINJECTIONMOLDEDPARTSMADEFROMLDPEFORTHISMATERIAL,MICROCELLULARPLASTICPARTSMOLDEDWITHAGASAMOUNTOF0173WTORLESSDIE,MC1L,MC2LANDMC3LCFTABLE1DHAVEASURFACEQUALITYEQUIVALENTTOTHATOFCONVENTIONALINJECTIONMOLDEDPARTSFORTHOSEPARTS,ANYSWIRLMARKSONTHESURFACEWEREINVISIBLETOTHENAKEDEYECFFIG2ALSO,THELACKOFSMOOTHNESSANDBRIGHTNESSTYPICALLYFOUNDINM
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