试题库三完成反应式题及解答

1、试题库三一一完成反应式题及解答 1. 2CH3OCH=CH2+ HBr 3. CH3CH2CH=CH2 CH3CH2CH2CH2OH 4. CH3CH=CH2氐戈- H2O2 5. (CH3)2C=CHCH2CH3 6. CH2=CHCH2OH CICH2CHCH2OH 7. CH3CH2CH2C三CH + HClO过量) 8. CH3CH2C三CH + HBr (过量) 9. CH3CH2C三CCH3+ KMnO4 10. CH3CH2C三CCH3 + H2O H2SO4 - 11. CH2=CHCH= CH2+ ch2=cjHcHio 12. 13. 12. j #+ C|2 13. 16

2、. 17. 18. 19. 20. 21. 22. 0AICI3 + CH2CI2 23. 24. 25. 26. 27. 28. H+ CH2=CHCH 2Br + NaOC 2H5 29. 30. 31. 32. 33. OH- SN 2历程 34. 35. 36. CH2=CHCH2ClCH2=CHCH2CN 37. (CH3)3CCl + NaOH f 38. (CH3)2CHCH2CH2OH + HBr ” 39. .： -OH + HCl 无水ZnCl 2. 40. 0HC 41. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55

3、. 56. 57. 58. 59. 60. 61. 62. 63. 64. 65. 66. 67. 68. 69. 70. 71. 72. 73. 74. 75. 76. 77. 78. 79. 80. 81. 82. 83. 84. 85. 86. (CH3)2CHBr + NaOC2H5 CH3CH2CH2CH2CHCH KMn4 J OH CH3 C CH HI04CH3COOH + CH3CH2CHO HJO4 CH3COCH2CH2CH2CHO 浓 H 2SO 4 h2CHCh 2CH3 CHOCH3 + H2分-OH水 CI3CCHO + H2O CH3CH2CHO稀 NaOH 厂

4、 C6H5COCH3 + C6H5MgBr (CH3)3CCHO浓 NaOH CH2=CHCH2CH2COCH3+ HCI C6H5CHO + CH3COCH3 CH3COCHCO 2C2H5 稀_H， CH3COCHCO cCH3 浓 Na(H2O 丨 ch scfcCCOOH3 - r OH CH3 般CCCOCC蹲a2. L3 Cl 稀 H2SO4 CH3CHcCO咒hh=* QOOH hOOh . COOH CH3CH2COOH + Cl 2 P* HOCH2CH2COOH 山耐 4. NCCH 2CH 2CN + H 20 NaOH* CH3C0CI + NaOE CH3CH2COO

5、 C2H5 CH3COOC2H5 + CH3CH2CH2OH H2O CH3CH(COOH)2 COOH + HCl 87. 88. 89. 90. 91. 92. 93. 94. 95. 96. 97. 98. 99. 100. 101. 102. 103. 104. 105. 106. 107. 108. 109. 110. 111. 112. 113. 114. 115. 116. 117. 118. 119. 120. 121. 122. 123. 124. 125. 126. 127. 128. 129. 130. HCOOH +、OH CH2CH2COOGH5 NaOEt CH2C

6、H2COOC 2H5 (C2H5)3N + CH3CHBrCH3 (CH3)3NCH2CH2CH2CH3+C+ NaOH CH3CH2COCI + CH2CH2COOC2H5 ch2chchocH2ch2cn I H3C H2O2 ? 30%HAc ? CHO? NaOC2H 5 H+ / H2O CH3CH2Br ch3ch2cho oh NaBH4 C6H5CHO H2S + a+NaBS(C 冃2Osh + 知2HO HCl OH- _ h2O CH3CHO NazCgO? HOCH2CH2OH ch3ch2ch2cho + (CH 3)2CHCH 2COOH J Na?CO 3 CH3

7、CH2CH2CHO + NaHSO3? CH3CHO + CH3CH2OH 无水 HCI】 Zn-Hg HCl C6H5COCH3 h2nnhconh 131. 132. 133. 134. 135. 136. 137. 138. 139. 140. 141. 142. 143. 144. 145. 146. 147. 148. 149. 150. 151. 152. 153. 154. 155. 156. 157. 158. 159. 160. 161. 162. 163. ch3ch-chch 3 0? ? 164. CHCH=CH-CH=C乙醇 + CF3-CF=CF 2 18 165

8、ch2=ch-ch=ch 2 + CH=CHCN 166. CH3CH2=CH-CH=CH 2+ CH=CHCHO 167. 168. 169. ch3 170 CH 3CH 2OCCHH 171 . 172 . 173 . 174 . C6H5CH2CI 干醚 6 52 干醚 (CH3)2CHCHCH 30H + N(CH 3)3 CH3(CH2)4COCl NH3 CH2CI I C. nh2+ ch3 CCOH2CI Ii ICH2CHO4 HCN hno3 COOH pci5 + phCH2CH-NMe2 CH3O- CO2 H2O Na OH + Cl2 h2o NaCNNaOH ?

9、 h2o | I CHsMgl” ?H 2SO4y CH3CHH2cH2Sh4 HOCH2CH2CHO HCN H3O+ O3 B2H6y H 2O2 CrO3 - HCHO HCl .- ? + H2O I CH3 Na OH 一 H2O H2SO4 3 + HI (过量)？+? HO CH2 - NBS cCTT 175. 176. 177. 178. Na CH3c6淀氨 CH3CH 2Br 液氨 H2 Pd / Basq 179. 180. H o H2C/CHCH 2CH3 H2O O HIO4 181. 182. 183. CH2C1 CH=CHBrKCN 184. 185. 18

10、6. OCH3 + HI OCH2CH3 HU 187. 188. 189. 190. 191. 192. 193. 194. -CH3 - + Cl2 二 + H2 CH3 HI FeCb 195. 196. 197. 198. O3Zn/学。 CH2+H2O B2H6 = ch2 CH=CHC HCH2OH2OH + KMnO 4 199. 200. 201 202. 203. 204. 205. 206. 207. 208. 209. CH CCH 2CH=CH2 + Br2(1mol) KMnO 4 H3C 二 CH(CH 3)2 211. 211. 212. | H2H2/Ni? _

11、 CH=CH； +常竺 213. 214. 215. Cl2 - 、 + CH2=CH-COOEt . + Br2 (CH3)2C=CH 2 + hCI KOH ； 乙醇 218.CH2CH2CH3 NBSr Me3COK KMnO4 - ? 219. 220. 221. 222. 223. 224. 225. 226. 227. 228. PhCH2CH2CH3 Cl2 -CH3竺坐? 冷稀KMnO? KOH T (BHJ H2O2 OKMinO 4 - + H CH3CH2C 毛H HOBr CH3CH=CH 2 + HOCl 060 C +浓卡=鍛？ 浓H2S4- Na CH3CH2C毛

12、CH 2CH3 + h2 CH3CH2CH=CH2 + Cl2 500 C 液氨 。3 229. 230. 231. 232. 233. 234. 235. 236. 237. 238. 239. 240. 241. 242. 243. 244. 245. 246CH 247.CH 248 CH3-C-CH2OH + HBr .CH3 试题库二：完成反应式答案 Zn ,20 CH 毛H + HCN 号2. 127 C CH3CH2CH2CH3+ Br2 - OH- CH3CHCH3 OH H2O H2O H2O CH3 + Br2 Cl Cl 2CI2a|c| CFe2C?2CHCR光7 Cl

13、 HNO3 no23_ 2 H2SO4 1. (CH3)2g-CH2CH3 B2H6_ B2O2. HBr 3. 5. 7. 9. 19. _* 或 HH2 OHH2O2 OH (CH3)2C=O + CH3CH2CHO CH3CH2CH2CCI2CH3 CH3CH2COOH + CH3COOH CH3 CH3 Br NaCN H3O + 2. 4. 6. B2H6 H2O2/OhA CH3OCHCH3 CH3CH2CH2OH CI2+H2O )3C-OH Cl 8. CH3CH2CH2CBr2CH3 10. CH3CH2CCH 2CH3 n OH 24. 36. CH3 38 . (CH3)

14、2CHCH2CH2Br 40 . + ch3ch2ch2cch 3 If O 43. (CH3)2CH- O-C2H5 44 CH3CH2CH2CH2CCH3 48. CH3CH2CH=CHCH2CH3 50. Cl3CCH(OH)2 55. (CH3) O 56. (CH3)3CCOOH + 63. = N-OH H2OH 58. HOOCCH2CH2CH2COOH 62. CH3CH(CI)CH 2CH2COCH3 CH2COCH3 79. H3CCOOCHMe 2 81. NaOOC 2CH2COONa HOOCCH 2CH2COOH 86.CH3COOCH2CH2CH3 + CH3CH

15、2OH 88. 90. 92. 94. (C2H5)3NCHMe2+Br- CI-+OH- 96. H3C 103. C 104. N CCH2CH3 2cHhCcho CH 3 108. HSCH2CH2OH 114. 126. 134. 136. 138. 140. 175. NHCOCH2CH3 C6H5C=NNHCONH2 1 CH3 C2N3(CH 2)CcONh 2 CH3CHO + HCOOH 179. 190. 192. 198. 208. 210. 212. 213. 215. 217. 80. HOCH2CH2CH2OH 87.CH3CH2COOH + CO2 89. 91

16、. 93. 95. (CH3)3NCH2CH2CH2CH3+Na+ 97. ch3ch2ch=cch 2oh Ch 3 109. 113. 127. 129. 135. 137. 139. O QOH OOV： CH3(CH2)4NH2 ClCH=CH2 (CH3)2CHC=CH 2 D。 CH3(CH2)4NH2 + CH 3-C-CH 3 IV 176. Cl3；反-2-戊烯 CH3CH2C 三 CNa; CH3CH2C 三 C CH3CH2CHOH CH2OH; CH3CH2CHO+HCHO CH3CHICH 2CH3 CH3CH2CH3 CH3 185. 189. 191. 193 1

17、97. OH + CH3I CICH 2CH2CH2CI CH3CHBrCH 2CH3 CH3COOH + HOOCH 2CH2COOH HOOC CMe3 H3C BCH2桝2觸 H3C d Cl C|CH2CH2CH2CH2C| BMe2CCH Br Cl H3CD D CH2Br 1205. 209. 211. D CH2MgBr Q 214. 216. 218. Br 2=CHCH 3 CH2O X- ；j CH-CH2Br Br Me2CCH3 CHCHCCH3 I Br CH=CHCH 3 COOH H=CHCHj OH Me2CICCMe3CH3 CH3CH-_Br I I O CH3CH2H = c CH3CCH3+ ohCChhochiHCho Crf2=CHCN CH3CHCH3 I (CH 3BfCHMgBr (CH 3)2CHCH 3 OMgBr CH3 CH3C = C-CH2CH3 J I CHCH3CH3( CH2C1 CH2C1 Cl Cl P