硅橡胶与氟硅橡胶在汽车中的应用

1、MOMENTIVEperformanee materialsThe scienee behind the solutions.迈图高新材料集团第四届橡塑技术在汽车部件生产中的应用论坛2009年08月0607口 上海硅橡胶与氟硅橡胶在汽车工业中的应用与发展武玉斌 弹性体汽车应用市场经理/边图中国 刘增君 研发及应用工程师/迈图中国MOMENTIVEperformance materialsPresentation Agenda报告内容迈图高新材料集团汽车行业的发展全球专业有机硅公司对有机硅应用的影响硅橡胶/氟硅橡胶的发展及在汽车零部件中的应用 LSR液体硅橡胶在汽车零部件中的应用4- MOMEN

2、TIVE performance materialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.The science behind the solutions.迈图高新材料集团Momentive Performanee Materials今前身为GE Advanced Materials GE高新材料寸 GE SiliconesGE有机硅GEBayer Silicones GE拜耳有机硅GE Toshiba Silicones GE东芝有机硅The science behind the sol

3、utions.The science behind the solutions.The science behind the solutions.4- MOMENTIVE performance materials迈图高新材料集团Momentive Performance Materials全球领先的一系列高科技材料的解决方案的提供者A global leader in a range of high-technology materials solutionsThe science behind the solutions.The science behind the solutions.S

4、ilicones有机硅QuartzAdvaneed Ceramics密封胶与粘合剂石英先进陶瓷Sealant & AdhesivesElastomer, RTV弹性体,RTVHigh-purityfused quartzCeramic materialsSilicone and acrylic sealantsSilanes, Resinsand Specialties硅烷，硅树脂Specialty Fluids特种硅油Urethane Additives聚氨酯添加剂MOMENTIVEperformanee materialsThe science behind the solutio

5、ns.Sealants & Adhesives密封胶与粘合剂4-MOMENTIVEperformance materialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.The science behind the solutions.中国车产量20032008一数据来源:Marklines Co.The science behind the solutions.The science behind the solutions.1O5OOO5OOOChina Vehicle Output2

6、0032004200520062007200 Cars Trucks Buses Total6,000,0005,000,0004,000,0003,000,0002,000,000 1,000,0000The science behind the solutions.YearThe science behind the solutions.The science behind the solutions.The science behind the solutions.MOMENTIVEperformance materialsCopyright 2009 Momentive Perform

7、ance Materials Inc. All rights reserved.The science behind the solutions.中国车产量2009 1 -4一数据来源:Marklines Co.China Auto Output 2009 VS 20084,000,00G 吕 3,500,000 W 3,000,0002,500,0002,000,000 2009 Output 2008 Outputo n uQ)IE1,500,0001,000,000500,000JanFebMarMonthApr Jan to Apr4-MOMENTIVEperformance mate

8、rialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.9The science behind the solutions.全球研发平台更多保证与更长使用寿命 更高的引擎效率更多电子控降低噪音新能源更严格的排放法规Automotive Trends汽车行业发展趋势Global platformsHigher warranty/longer lifecycl

9、eBetter engine efficiencyMore electronicsNoise reductionNew engergyTighter Emission regulationsAll points accelerate growth of Silicones所有这些要求都促进有机硅的应用发展Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the solutions.Copyright 2009 Momentive Performance Mate

10、rials Inc. All rights reserved.11The science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the solutions.MOMENTIVEperformance materialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the so

11、lutions.汽车用硅橡胶/氟硅橡胶发展趋势汽车工业的发展促进了对有机硅弹性体材料的需求部分传统的橡胶(NR, EPDM.ACM.FKM.) 9硅橡胶VMQ固体硅橡胶HCE今液体硅橡胶LSR固体氟硅橡胶FSE 9全氟液体氟硅橡胶FFSLMOMENTIVECopyright 2009 Momentive Performance Materials Inc. All rights reservedperformance materialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.13The sc

12、ience behind the solutions.MOMENTIVEperformance materialsThe science behind the solutions.硅橡胶=VMQHCE / HCRLSR氟硅橡胶材料=FVMQFSE / FQE FSL / FFSL4- MOMENTIVE performance materialsWhy use silicone elastomers?为何使用硅橡胶?Easy and flexible in processing and production!加工工艺与生产简便灵活Gen erally stable at high temper

13、ature通常高温下稳定Gen erally flexible at low temperature通常低温下柔软Little change of properties over a broad temperature range 在宽广温度范围内性能变化较小Heat CuredElastomer固体硅橡胶HCE HCR- HTVFVMQ- FSE- FQEResistant to many fluids耐多种液体Outstanding sealing properties 优异的密封性Long service life 使用寿命长Excellent weatherability优异的耐候性L

14、iquid siliconerubberI nert 一 non reactive with most materials惰性与大多数材料不反应Very good dielectric properties 很好的介电性能液体硅橡胶LSR- LIM* Easily pigmentable under most conditions大多数情况下易着色Favorable flammability characteristics良好的阻燃特性FSL FFSLLow hardness without plasticizers低硬度无增塑剂Copyright 2009 Momentive Perform

15、ance Materials Inc. All rights reserved.15The science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the solutions.Broad spectrum of properties具有诸多性能优点Momentive Technology / Service / Support 迈图集团技术/服务/支持MOMENTIVEperformance materials

16、Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the solutions.not 140Required不要求12010080604030Volume swell in I RM 903 oil % 在I RM 903油中体积溶胀率% Overview ASTM D2000 Silicones vs Organic Elastomers 材料的ASTM分类一有机硅弹性体与其他橡胶材料的性能比较FKMVMQFSLFVMQ=HCE, HCR=FSE/ FQE/

17、FEPDM/LSRAEM, ACM, HNBRHRCPE / CSMNBR, ECOSBRCRNR2010FFKM75o5o7521o20522752Good heat & oil resista nee brings silicone elastomers big pote ntial applicati onsin Automotive有机硅橡胶与氟硅橡胶的耐高温性和耐油性可满足汽车的很多应用Low Temperature Flexibility of Silicone Elastomer 有机硅弹性体的低温柔性LTflexibility 55° C,TR10 = 60

18、° CExample 1: General Purpose Grade Silopren® LSR 2650 (Hardness 50 Sh.A) 通用液体硅橡胶Silopren® LSR 2650Example 2: Fluorosilicone RubberFSE and FFSL series氟硅橡胶系列产品TR10(DMA) TR10 DSC° c ° c ° cFFSL 7040-5961七7FFSL 7050-59FFSL 7060-61FFSL 7070-64-64FSE 7560 black -60FSE 7570 b

19、lack -57Fig. 15: Logarithmic decrement and shear modulus of Silopren LSR 2650 as a function of temperatureI' 焜罄Temperature (rC)snaPOLUsnQsqa(i) lest data. Actual results may vary,实际结果对能仃丈Both general purpose LSR and Fluorosilicone Elatomer have good low temperature flexibility通用型LSR与氟硅橡胶都具有良好的低温

20、柔性The science behind the solutions.A动力系统/总成：发动机内部与周边A燃油系统：油箱与油路系统硅橡胶/氟硅橡胶在汽车橡胶零部件中的应用部位Copyright 2009 Momentive Performance Materials Inc. All rights reserved.19The science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the solutions.

21、调，雨刮A底盘：减震，管路A电器零部件：汽车电子防水包装连接器密封，点火系统，车灯系统等Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the solutions.MOMENTIVEperformance materialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the solutions.HCR/ LSR的部分应用实

22、例汽车工业火花塞护套点火电缆冷却器垫圈 发动机盖密封 传动系统密封Copyright 2009 Momentive Performance Materials Inc. All rights reserved.21The science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the solutions.O形密封Copyright 2009 Momentive Performance Materials Inc

23、. All rights reserved.#The science behind the solutions.接头密封套 插头垫圈胶管4- MOMENTIVE performance materialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the solutions.迈图有机硅一自润滑液体硅橡胶LSR自润滑LSR产品规格5ShoreA10ShoreA标准产品MOMENTIVEperformance materialsSilopren*LSR 348

24、6/：TP 3648超低压缩 变形产品低压缩变 形产品20ShoreA30ShoreA4050Shore ShoreAASilopren*口;R 3785/STr 7%Att=M75ttpilopre n*"T$R 3485/354% oilpren13596oililopren* R 3596/30 TPJ967 nilSilopre rTSR 3786/2 0.TP 394460ShoreA70ShoreA80ShoreAollOpren'" ItSR 3285/5C2 %叫Silopren*H)R 3485/ >0Silopren*1 SR 3186/5

25、TP 3651Silopren* | Silopren*SR 3286/4CSR 3286/!TP 3649 TP 4224Silopren* | Silopren*SR 3286/OflSR 3286/7TP 0125 I TP 36502%-otiSilopren* | Silopren* | Silopren*SR 3386/：TP 3616R 3386/，>R 3486/5 TP 42683%otFCopyright 2009 Momentive Performance Materials Inc. All rights reserved.23The science behind

26、 the solutions.应用一发动机IMTF.WXLEawwroRWiCTERPUM9/ITURBOCKAnGCHNTAKC VAMFOLDtOCCMTRIC WFTL PICKUP加伽 ql蚀辟Ufam CtyTCH硅橡胶/氟硅橡胶产品SE系列 高性能硅橡胶TSE系列耐热硅橡胶3.硅胶胶管 Rubber Hoses冷却液管 Coolant Hoses热风管 Hot Air Hoses涡轮增压管 Turbocharger Hoses生产工艺FSE系列氟硅橡胶-涡轮增压管硅胶帘线压延成型工艺，挤出缠绕工艺/热空气/蒸汽硫化編能2高温稳定性耐冷却液要求较好的胶料格林强度要求胶料良好的加工性，

27、粘合性MOMENTIVECopyright 2009 Momentive Performance Materials Inc. All rights reservedperformance materials0型圈 O-RingsThe science behind the solutions.The science behind the solutions.应用P3密封件硅橡胶产品固体胶硅橡胶TSE或SE系列氟硅橡胶FSE液体胶 LSR FSL/ FFSL模压/注压注射性能特点要求加工性耐介质性能（汕，燃油，OEM油等.）尽管都是VMQ或FVMQ,但不同厂家/规 格的硅胶/氟硅胶性能/稳定性

28、差异性往往很 大，要关注混炼胶的物性，也要关注其加工性和稳定性需要认真严格的系列试验评估。压缩变形威蠶稳定性MOMENTIVEperformance materials迈图公司为客户提供稳定的适合不同用途的系列产品Copyright 2009 Momentive Performance Materials Inc. All rights reserved17耐高低温性The science behind the solutions.生产工艺滤油器垫片HCELSR /LIM应用Anti Drain Back valve模压或注射成型性能特点1. 滤油器垫片 Oil filter element耐

29、油，耐热宽广使用稳定范围：综合了高温稳定性与低温柔性 低压缩永久变形Copyright 2009 Momentive Performance Materials Inc. All rights reserved.29MOMENTIVEperformance materialsThe science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#MOMENTIVEperformance materialsThe science behind the sol

30、utions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#MOMENTIVEperformance materialsThe science behind the solutions.4.发动机周边部件密封垫片进气岐阀密封垫片发动机盖密封垫片Copyright 2009 Momentive Performance Materials Inc. All rights reserved.31MOMENTIVEperformance materialsThe science behind the s

31、olutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.MOMENTIVEperformance materialsThe science behind the solutions.XE20- 53x系列XE20-C4xx 系列LSx85/zLSR3x86/zLSR3x96/z FSL7x86/z迈图提供“系列多规格LSR” 和客户定制产品Copyright 2009 Momentive Performance Materials Inc. All rights reserved20安装便

32、利，高安全和稳定性 宽广的使用温度（60+2009） 优异的耐热性能优异稳定的电性能抗外界电场干扰强 密封性能优异耐侯性，耐老化性优异LSR加工容易，高效 MOMENTIVEperformance materials汽车性能提高对汽车电子连接器密封提出新要求更多汽车电子控制 9使用更多连接器,单车达几百个更稳定的电子操控 9更好的密封硅橡胶/氟硅橡胶材料更简易的加工/安装9LSR注射成型自润滑密封件Copyright 2009 Momentive Performance Materials Inc. All rights reserved.MOMENTIVEperformance materi

33、alsThe science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.MOMENTIVEperformance materialsThe science behind the solutions.o环保与燃油的要求o汽车发动机的温度o对压缩永久变形的要求9耐介质9耐高低温9降低压缩永久变形Copyright 2009 Momentive Performance Materials Inc. All rights reserved.MOMENTIVEp

34、erformance materialsThe science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.MOMENTIVEperformance materialsThe science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.MOMENTIVEperformance materialsThe scienc

35、e behind the solutions.6.硅橡胶用于点火系统-火花塞护套不断发展的迈图有机硅弹性体产品满足新的应用要求TSE221 TSE2527SC0601 -608BAC161-SP高安全稳定性宽广的使用温度(60+200'C) 优异的耐热性能优异稳定的绝缘性能，耐电弧性 抗外界电场干扰强密封性能优异耐侯性，耐老化性优异加工容易LSR2660Z迈图舉供“即买即用的客户定制硅胶MOMENTIVEperformance materialsThe science behind the solutions.Car body chassis7.硅橡胶用于底盘减震-排气管吊耳 不断发展

36、的迈图有机硅弹性体产品满足新的应用要求硅橡胶取代传统的合成橡胶-降低噪音提高车的乘用舒适性 宽广的使用温度(60+20(TC) 耐侯性，耐老化性优异-耐高温优异-长期使用稳定性好-弹性好，耐油性迈图提供“即买即用的客户定制硅胶 4-Copyright 2009 Momentive Performance Materials Inc. All rights reserved.LSR23易加工9.氟硅在汽车中的应用Seals / Gaskets密封圈与密封垫2- comp. Molding 双射成型Umbrella-Valves 伞阀MOMENTIVEperformance materialsTh

37、e science behind the solutions.MOMENTIVEperformance materialsThe science behind the solutions.Flaps 薄垫片 I Fuel燃規Ives I O-Rings osyfflMOMENTIVEperformance materialsThe science behind the solutions.MOMENTIVEperformance materialsThe science behind the solutions.Conn ecto®连接器硬度（邵氏A） 40Membranes 隔膜M

38、OMENTIVEperformance materialsThe science behind the solutions.MOMENTIVEperformance materialsThe science behind the solutions. Ml urwfLx»amr rvwowwiisting FVMQ Applications 现有氟硅橡胶的应用MOMENTIVEperformance materialsThe science behind the solutions.8.燃油系统Fuel systemFluorosilicone Applicatio ns燃油管的连接

39、快速接头密封燃油箱一燃油密封阀一进入阀控制阀FVMQ are used in fuel system where needs good sealing & fuel resistance氟硅橡胶用于燃油系统需要密封和耐油的部件purrornTdnLCiTTdTerTdTbFluorosilicone Products Family Heat Cured Rubber 氟硅橡胶高温硫化固体氟硅橡胶Copyright 2009 Momentive Performance Materials Inc. All rights reserved.41MOMENTIVEperformance ma

40、terialsThe science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#MOMENTIVEperformance materialsThe science behind the solutions.Shore A硬度203040506070通用低压缩变形Standard Low C/SFSE7520FSE7540FSE7560FSE7570Copyright 2009 Momentive Performance Materials Inc.

41、All rights reserved.#MOMENTIVEperformance materialsThe science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#MOMENTIVEperformance materialsThe science behind the solutions.FSE7340FSE7360High Tear Strength高抗撕裂Copyright 2009 Momentive Performance Materia

42、ls Inc. All rights reserved.#MOMENTIVEperformance materialsThe science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#MOMENTIVEperformance materialsThe science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.

43、43MOMENTIVEperformance materialsThe science behind the solutions.硬度FSL液体氟硅橡胶产品系列30 Sh. A 40 Sh. A 50 Sh. A 60 Sh. ACopyright 2009 Momentive Performance Materials Inc. All rights reserved.#MOMENTIVEperformance materialsThe science behind the solutions.Copyright 2009 Momentive Performance Materials In

44、c. All rights reserved.#MOMENTIVEperformance materialsThe science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#MOMENTIVEperformance materialsThe science behind the solutions.FFSL全氟液体氟硅橡胶产品系列The science behind the solutions.The science behind the solut

45、ions.40 Sh. A50 Sh A60 Sh.A70 Sh.AThe science behind the solutions.4- MOMENTIVE performance materialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.28The science behind the solutions.9迈图超透明LSR在光学产品中的应用潜力The science behind the solutions.The science behind the solutions.The sc

46、ience behind the solutions.The science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.294- MOMENTIVE performance materials迈图新开发的Crystal Clear LSR超低硬度高透明液体硅橡胶Silopren® LSR 7005> Silopren® LSR 7005 新产品迈图公司新开发的高透明液体硅橡胶> Application应用基于照相技术的驾

47、驶辅助系统，集成了雨水和光传感器为一体。Ref: KOSTAL GmbH & Co. KG and Momentive Performance Materials GmbMOMENTIVEperformance materialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.30Ultra-Clear LSR超透明液体硅橡胶潜在的汽车光学应用The science behind the solutions.The science behind the solutions.LED镜片high

48、 heat resistance high UV resistance光学镜片high transparency no inner stress no birefringeneeThe science behind the solutions.The science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.314-MOMENTIVEperformance materialsEschenbachThe science behind the soluti

49、ons.硅橡胶/氟硅橡胶材料的发展高性能、易加工、功能提升、新应用更宣ouels-spw_丄Processability加工性优异的加工性、稳定的产品性能、合理的性/价比, 共同开发，协同双赢液体硅橡胶LSR注的优势MOMENTIVECopyright 2009 Momentive Performance Materials Inc. All rights reserved,performance materialsThe science behind the solutions.具有成本优势的液体硅橡胶LSR加工工艺A全自动化工艺，自动生产单元A生产周期短A流动性优异，可充满长模具流道单模可多达256模腔制品无废边冷流道技术，无注胶口胶或注胶损失A最低模具磨损，可达100万次单件成本可能低The science behind the solutions.The science behind the solutions.MOMENTIVEperformance materialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.34The science behind the solutions.2 Componets Injection Molding with