2019污染源源强核算技术指南 石油炼制工业

ii

1 1

2 1

3 2

4 3

5 7

6 14

7 17

8 22

9 23

10 24

A25

B28

C29

D33

i

PAGE

11

PAGE

10

1

GB13223HJ888 GB13271

2

GB12348

GB13223

GB13271

GB14554

GB31570

GB50015

GB/T16157

HJ2.1

HJ2.2

HJ2.3

HJ2.4

HJ/T55

HJ75 SO2NOx

HJ76 SO2NOx

HJ/T91

HJ/T92

HJ/T353

HJ/T354

HJ/T355

HJ/T356

HJ/T373

HJ/T397

HJ/T405

HJ630

HJ853

HJ880

HJ884

HJ888

HJ2045

VOCs

3

3.1

3.2

sourwater

pollutedrainwater

50mg/L100mg/L

GB31570

3.3

volatileorganiccompounds

3.4

non-methanehydrocarbon

3.5

abnormaldischarge

3.6

standardcondition

273.15K101325Pa

3.7

hydrargyratecrudeoil

5g/g

4

4.1

HJ884

4.2

4.3

HJ2.1HJ2.2HJ2.3HJ2.4

GB31570

GB31570GB145541

4.4

4.4.1

1

1

c

d

1.

2.

1.

2.

3.

1.

2.

3.

1.

2.

c

1.

2.

1.

2. d

a

b

1.

2.

1.

2.

1.

1.

2.

2.

1.

1.

2.

2.

1.

1.

2.

2.

3.

3.

a a

d

d

d

(a)

d

d

e e

d

(a) 1.

2.

1.

2.

3.

1. —

2.

f

1.

2. d

3.

c

1..

2.

d

d

1.

2.

3.

1.

2.

abc

d

ef

4.4.2

4.4.2.1

(a)

4.4.2.2

HJ880

HJ880

4.4.3

4.4.3.1

4.4.3.2

HJ880

HJ880

4.4.4

4.4.4.1

4.4.4.2

4.4.5

4.4.5.1

4.4.5.2

4.4.6

4.5

4.5.1

1

n

i i

D D D' 1

i1

D—t

Di—t

i

D’—t

n—

4.5.2

2

n

D Di 2

i1

D—t

Di—t

n—

4.6

A

5

5.1

5.1.1

5.1.2

5.1.2.1

B

B— kg/hm3/h

3

3.6105 Qe 3

Qd

Qe— kW

— %

Qd—kJ/kgkJ/m3

5.1.2.2

a 4

21

21

0.264

1000

V B Q+0.02+0.38+0.018Q 4

V—

B— m3/h

d

m3/h

1000 d

—%

Qd—kJ/m3

b 5

21

0.2

1000

V B Qd+2

+0.27 Q 5

1000 d

V— m3/h

B—kg/h

—%

Qd— kJ/kg

5.1.2.3

6

D 2B

WS 6

100

D—t

B—t

WS—%

5.1.3

5.1.3.1

7

V 2+

100

1.266

1

2

VA

1

7

V— m3/h

— 2

1— CO%

2 N2%

VA—m3/h 8

2

%

/

-30

-20

-10

0

10

20

30

40

10

0.00425

0.00733

20

0.00464

0.00844

0.01478

30

0.00355

0.00697

0.01272

0.02233

40

0.00242

0.00487

0.00932

0.01702

0.02999

50

0.00128

0.00302

0.00600

0.01168

0.02138

0.03778

60

0.00061

0.00154

0.00363

0.00712

0.01405

0.02576

0.04567

100

0.00038

0.00102

0.00257

0.00606

0.01826

0.02362

0.04370

0.07850

pT0

p0 T

VA Q 8

pT—

kPa

K

p0T0—

Q—

kPa

m3/h

K

5.1.3.2

D 2 B

2.03

9

WS

100

0.81

9

D—t

WS— %

B— t 10

100

V1—

m3/h V1

1

1—

CO2

%

2—

3—

t—

COO2

%

%

h

B V1

3.78 0.2421 0.3132

0.183

t10-3 10

1+2+3

VA VA 8

5.1.3.3

11

D 2.05 40+0.2W+1.25 +105W V

109 11

N Pt

D—t

WN—g/g

— %

WPt—Ptg/g 0.2~0.5

V— m3

5.1.3.4

D=D0 D1

12

100

D2 1 12

D—t

D0— t

D1—t

D2—t

— %

5.1.3.5

D=D0

13

13

100

D— t

D0— t

—%

5.1.4

D 2B

WS

100

1

100

14

14

D—t

B—t

WS—%

—%

5.1.5

D=36.5

35.5

142

166

D D

0 1

15

15

D—HCl t

D0— t

D1—t

5.1.6

5.1.6.1

D 2Q

y 32

100 22.4

1

100

16

16

D—SO2 kg

Q—m3

y—H2S%

—%

5.1.6.2

D

64

32

Q

y 32

100 22.4

1

100

a 17

17

D—

Q—

SO2

kg

y—

—SO2

H2S

SO3

%

%

b

m3

18

D

98

32

Q

y 32

100 22.4100

1

100

18

D—kg

Q— m3

y—H2S%

—SO2SO3 %

—SO3%

5.1.7

19

D D

D —t

D—t

—%

1 19

100

5.2

5.2.1

5.2.2

a

b c

d

10%

e

5.2.3

30%

19

5.3

5.3.1

5.3.2

HJ/T373HJ630HJ853HJ880

n

D=

i1

i qi

20

10-9

HJ75HJ76

20

D—t

i—i mg/m3

qi—i m3

n—

5.3.3

GB/T16157HJ/T397HJ/T373HJ

630HJ853HJ880

n

D i1

i qi

n

21

t109 21

Dt

n—

i—img/m3qi—i m3/ht—h

5.4

5.4.1

D

Q 1

100

22

103 22

D —t

—kg/t

B.1

Q—t

—%

5.4.2

5.4.2.1

n

D = Qi

i1

23

103 23

D — t

n—Qi—i m3

—i 3

3

/

>3500mg/L

kg/m3

0.6

880~3500mg/L

kg/m3

0.111

<880mg/L

kg/m3

0.0225

kg/m3

0.005

5.4.2.2

24

D

D

1

100 100

24

D — t

D — t

— %

— %

5.4.3

D

n

2 SiQiti

i1

n

Qiti

i1

25

25

D —kg

n—

Si— kg/m³

Qi—m³/h

ti—ih

—kg/m3 0.054

6

6.1

i1

j1

D D i D ,j 26

D —t

D ,i—i tn—

D ,j—j t

m—

6.2

6.2.1

6.2.2

6.2.2.1

n

i1

27

D eTOC,i

WFVOCs,i t 27

i

WFTOC,i

D —kg

—

n—B.3

eTOC,i—iTOC 10000 kg/h 4

WFVOCs,i—i %

WFTOC,i—iTOC %

ti—i h

4 TOCeTOC

/kg/h/

1

0.028

2

0.03

3

0.064

4

0.073

5

0.074

6

0.085

7

0.073

6.2.2.2

a 28

D =LL Q 28

1000

D —t/a

LL—kg/m3 / 0.215kg/m3

0.410kg/m3

Q—m³/a

LL 29

L=1.2010-4

S PT

Mvap 29

273.15T

L

S—0.6 0.5

PT—T Pa

Mvap— g/mol

T—

LL=LA

LL 30

LG 30

LA— 0.040kg/m3

1.02M

273.15T

LG— 31

LG=0.102 0.064P

0.42 31

P—TkPa

M— g/mol

T—

D

D

1

100 100

b 32

32

D — t/a

D — t/a

—%

—%

6.2.2.3

a

D =ES+EW

33~35

33

2

ES 3654 D

HS HL HROWVKEKS 34

W

E 5.614MPQKKK 35

RTLA

VVA N PB

36~40

D =ER+EWD EF ED 36

ER

EWD

KRa

nDP*MK

Kv

VC

Rb

37

0.943QCSWL

D

NCFCD

1 38

F F VC

39

E FP*MK

DD VC

D

40

E KSD2P*MK

VOCs

1

b

D =D

41

1 41

100

D —kg/h

D —kg/h

—%

6.2.3

D=DVOCs

42

42

100

D—t

DVOCs—t

—%

6.2.4

n

D=

i1

t

r

+

W

43

43

D—

n—

—

5

t—

h

r—

h/

—

5

W—

t

5

t

2.59×10-2t/ ·

1.63×10-4t/t

6.3

6.3.1

5.2.2

6.3.2

19

6.4

VOCs

7

7.1

7.1.1

7.1.2

7.1.2.1

44

d=d1+d2+d3 d4

d— m3

d5 d6 d7 d8 44

d1— m3

d2— m3

d3—m3

d4—m3

d5—m3

d6—m3

d7—m3

Fs

1000

n

i1

d8— m3 45

d8= HSi 45

Fs—m2

Hs—imm 15mm~30mmn—

46

d =d d 46

d — m3

d—m3

d — m3

7.1.2.2

d=

+

W

47

47

100

d—m3

—% 0.5%

— % 5%~8% 10%

W—t

7.1.2.3

48

d=

+

100

W+

1

100

W

2

100

W

3

a

d—t

—%

W4 W5

W 48

100 6

—% 1%~2%

W1— t

— % 2%

W2— t

— % 1%

W3— t

W4— t 8kg/t 11kg/t ~12kg/t

W5—

—

t;

%

2%

W6—

b

t

49

d=W1+100W2

100

W3 W4

W5+W6+W7 W8 49

d—t

W1—t 3%

5%2%~4%

—% 0.3%

W2—t

—% 2%~3%

W3— t

W4—t

W5— t

W6—t

W7— t

W8—t

c 50

d=W1+100

d—t

W1— t

W2+W3+W4 50

—% 6%~10% 4%~8%

W2—t

W3— t

W4—t

WNW2 WSW2

W 51W W

14 32 4

14 N 2

WNW2 WSW2

W 51WW

14 32 4

32 S 2

WN—%

WS—%

d

51

d=W1+W2+W3+W4 51

d—

t

W1—

t

W2—

t

W3—

W4—

t

t

7.1.2.4

52

d=d1+d2+d3 d4

d—m3

d1—m3

d2—m3

d3— m3

d4— m3

d5— m3

d6—m3

d7—m3

d5 d6 d7 52

7.1.3

53

D—t

Dy—t

Dc— t

D=Dy

Dc Dg Ds 53

Dg—t

Ds— t

6

6

D=D

y

D=D

y

D=D D D

y g s

D=D D

y c

D=D D D

y g s

7.1.4

100

54

D D0 1 54

D— t

D0— t

— %

7.2

7.2.1

7.2.2

5.2.2

7.2.3

54

7.3

7.3.1

7.3.2

353HJ/T354HJ/T355HJ/T356HJ/T373HJ630HJ853HJ880

55

HJ/T

n

D i qi

106 55

i=1

D— t

n—d

i—i mg/L

qi—i m3/d

7.3.3

HJ/T91HJ/T92HJ/T373HJ

630HJ853HJ880

56

n

i

D i1 Q

n i

106 56

D—t

n—

i— i mg/L

Qi—m3

7.4

7.4.1

57

d—t

d=cS 57

c—t/t

S—t

7.4.2

D0 cS

58

106 58

D0—t

c—g/t

S—t

7.4.3

54

8

8.1

C

8.2

9

9.1

9.1.1

59

D =D D D D D 59

D — t

D — t

D — t

D —t

D — t

D —t 60

D D

D = 60

1

D —t

—%

9.1.2

61

D =D D 61

D — t

D —t

D —t

9.1.3

HJ2045

9.2

5.2.2

9.3

9.4

62

d=c S 62

d— t

c— t/t

S—t

10

10.1

10.2

10.3

PAGE

29

PAGE

28

B

B.1

kg/104m3

18.71

kg/t

20×10-6×N

kg/t

0.204

kg/t

0.695

kg/t

0.695

kg/t

0.021

(a)

kg/t

0.0122

N B.2

B.2

150/

m3/t

65

m3/t

81

B.3

/

—

—

—

—

—

—

—

—

C

C

/dB(A)

/

<85

<85

—

90

90

80~90

90

85

90

<90

—

90

90

90

85~90

90

85

<85

—

90

90

90

85~90

90

85

<85

—

90

90

90

85~90

90

99

95

95

85~95

90

90

<85

—

90

/dB(A)

/

90

85~90

90

85~90

90

<85

—

90

90

95

85~90

90

85

<85

95

85~90

90

<85

85~90

90

85

85-92

—

90

90

93

92~96

85~90

90

85

<85

98

85~90

90

98

85~90

90

85-92

98

85~90

90