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蚈蚂肄膅薄蚂膇莁蒀螁袆膄莆螀罿荿节蝿膁膂蚁螈袁蒇薇螇羃芀蒃螆肅蒆荿螆膈艿蚇螅袇肁薃袄羀芇葿袃肂肀莅袂螂芅莁袁羄肈蚀袀肆莃薆袀膈膆蒂衿袈莂莈袈羀膄蚆羇肃莀薂羆膅膃蒈羅袅莈蒄薂肇芁莀薁腿蒇虿薀衿艿薅蕿羁蒅蒁薈肄芈莇蚇膆肀蚅蚇袆芆薁蚆羈聿薇蚅膀莄蒃蚄袀膇荿蚃羂莃蚈蚂肄膅薄蚂膇莁蒀螁袆膄莆螀罿荿节蝿膁膂蚁螈袁蒇薇螇羃芀蒃螆肅蒆荿螆膈艿蚇螅袇肁薃袄羀芇葿袃肂肀莅袂螂芅莁袁羄肈蚀袀肆莃薆袀膈膆蒂衿袈莂莈袈羀膄蚆羇肃莀薂羆膅膃蒈羅袅莈蒄薂肇芁莀薁腿蒇虿薀衿艿薅蕿羁蒅蒁薈肄芈莇蚇膆肀蚅蚇袆芆薁蚆羈聿薇蚅膀莄蒃蚄袀膇荿蚃羂莃蚈蚂肄膅薄蚂膇莁蒀螁袆膄莆螀罿荿节蝿膁膂蚁螈袁蒇薇螇羃芀蒃螆肅蒆荿螆膈艿蚇螅袇肁薃袄羀芇葿袃肂肀莅袂螂芅莁袁羄肈蚀袀肆莃薆袀膈膆蒂衿袈莂莈袈羀膄蚆羇肃莀薂羆膅膃蒈羅袅莈蒄薂肇芁莀薁腿蒇虿薀衿艿薅蕿羁蒅蒁薈肄芈莇蚇膆肀蚅蚇袆芆薁蚆羈聿薇蚅膀莄蒃蚄袀膇荿蚃羂莃蚈蚂肄膅薄蚂膇莁蒀螁袆膄莆螀罿荿节蝿膁膂蚁螈袁蒇薇螇羃芀蒃螆肅蒆荿螆膈 1废聚乙烯塑料制氧化聚乙烯蜡的研究 王莹;易玉峰;丁福臣;汪树军;, 北京石油化工学院学报, 2006,(02), 6-10 研究了以聚乙烯类废塑料制高附加值产品氧化聚乙烯蜡的技术。应用不同的聚乙烯类废塑料,优化了热解氧化反应工艺条件,测定了所得产物的酸值、针入度、软化点,并用IR考察了含氧基团。实验结果表明:HDPE和LDPE都能制备高收率、色度较好的低相对分子质量聚乙烯蜡,产品软化点在80110,相对分子质量为5004 000。LDPE比HDPE更易降解。以废HDPE和废LDPE工业废料制得的低分子裂解蜡在120160下空气或氧气氧化可得到色度较好、软化点较高的氧化聚乙烯蜡产品。 2聚乙烯蜡的研究进展与工业生产方法探讨 陈作义,潘朝群,江涛, 辽宁化工, 2004,(08), 474-476 在处理废旧塑料时可以利用热裂解或者催化裂解获得聚乙烯蜡。聚乙烯蜡作为具有广泛应用前景的有机中间体 ,可以应用于各种领域。综合概括了聚乙烯蜡的研究进展 ,并介绍了自主设计的一套得到分子量为 12 0 0 15 0 0的聚乙烯蜡产品生产装置。 3功能化聚乙烯蜡的制备与表征 章永化,许德雄,钟伟东,覃丽生,龚克成, 塑料工业, 2003,(02), 13-15+18 用溶液接枝法制备了马来酸酐 (MAH)和马来酸酐 /苯乙烯 (St)双单体接枝的功能化聚乙烯蜡 (PEW ) ,考察了反应时间、温度、引发剂、单体用量对产物接枝率的影响。结果表明 ,接枝改性的最佳条件为温度 110 12 0 ,反应时间 2h ,原料质量比为m (PEW ) /m (MAH) /m (St) /m (BPO) =10 0 /4 /2 /0 3。用傅立叶红外光谱和差示扫描量热分析表征了接枝产物的结构 4聚乙烯蜡超细粉的生产工艺和应用 李红, 硫磷设计与粉体工程, 2002,(04), 13-15+1 对物料进行超细化处理 ,使其物理化学性能发生许多特殊的变化 ,这一高新技术正日益受到重视 ,有着广阔的应用前景。通过对聚乙烯蜡超细粉生产工艺的比较 ,确定冷冻喷雾粉化生产工艺是最好的。利用现有的氧化聚乙烯装置 ,建成 30 0t/a聚乙烯蜡超细粉生产装置。介绍了此产品的生产工艺过程 ,以及其作为添加剂使油墨和涂料的性能得到提高 ,用途更加广泛 5乳状分散聚乙烯蜡的研制 杨飘,陈霞,凌安定, 造纸化学品, 2002,(02), 26-28 对乳状分散聚乙烯蜡制备的乳化温度、搅拌速度、初期转相水量和助剂等进行了研究。实验结果表明 ,乳化温度为 1 0 5 5、搅拌速度为 60 0 30 0 0r/min、初期转相水质量分数为2 5 %时 ,能得到具有良好性能的乳状分散聚乙烯蜡产品 6改性聚乙烯蜡乳液的制备 张建雨,颜涌捷,杨孔盛,WanChen, 石油炼制与化工, 2000,(01), 63-64Bibliographic Information Preparation of polyethylene wax modified organopolysiloxane and toner compositions therewith. Hino, Kenichi; Toyama, Takatoshi. (Nippon Unicar Co., Ltd., Japan). Jpn. Kokai Tokkyo Koho (2002), 12 pp. CODEN: JKXXAF JP 2002069193 A2 20020308 Patent written in Japanese. Application: JP 2000-262786 20000831. Priority: . CAN 136:224203 AN 2002:169668 CAPLUS (Copyright (C) 2007 ACS on SciFinder (R) Patent Family InformationPatent No.KindDateApplication No.Date JP2002069193A20020308JP2000-26278620000831 Priority ApplicationJP2000-26278620000831 AbstractPolyethylene modified polysiloxanes are obtained by hydrosilation reaction between polyethylene wax and hydrosilyl-contg. organopolysiloxanes. Thus, 340.2 g dimethylsilyl-terminated dimethylsiloxane (Mw 5260, Mn 3310) and 659.8 g Sanwax 171P in 1000 mL toluene were agitated at 80, catalytic chloroplatinic acid was added, and reacted for 6 h to give a compd. A. Styrene 73, 2-ethylhexyl acrylate 27, divinylbenzene 0.5, MA 100S 5, Disparlon 1.5, and the compd. A 16 parts were agitated at 18000 rpm for 30 min in nitrogen, 15 parts SA 302 (styrene/acrylic resin) was added, 5 parts V-65 (polymn. initiator) was added, phosphoric acid tricalcium and calcium chloride dispersant was added, heated at 65 for 8 h, and Aerosil R 972 was added to give a black toner. Bibliographic Information Preparation of polyethylene wax fine powders. Li, Qingshan; Xing, Fenglan; Yu, Tianshi. Institute of Material, Qiqihar University, Qiqihar, Peop. Rep. China. Zhongguo Fenti Jishu (2000), 6(5), 23-24. Publisher: Zhongguo Fenti Jishu Zazhishe, CODEN: ZHFJF9 ISSN: 1008-5548. Journal written in Chinese. CAN 134:353811 AN 2000:852020 CAPLUS (Copyright (C) 2007 ACS on SciFinder (R) AbstractLow mol. wt. polyethylene wax fine powders with av. particle size 30 mm (most 0.5-10 mm), useful for coating vehicles, ink dispersing agent, cosmetic fillers, etc., was prepd. by dispersing in emulsion, pneumatic spray-drying, freezing and ball-milling. Bibliographic Information Preparation of polyethylene wax using homogeneous titanium-based catalyst. Choi, Byung-Ryul. Daeduk Res. Inst., Honam Petrochem. Co., Taejeon, S. Korea. Kongop Hwahak (1997), 8(5), 844-852. Publisher: Korean Society of Industrial and Engineering Chemistry, CODEN: KOHWE9 ISSN: 1225-0112. Journal written in Korean. CAN 127:293694 AN 1997:676433 CAPLUS (Copyright (C) 2007 ACS on SciFinder (R) AbstractIn the polymn. of ethylene to produce cryst. polyethylene wax using a homogeneous Ti-based catalyst, the effects were investigated of various parameters such as cocatalyst, temp., pressure, comonomer and time on catalyst performance and product properties. The properties of the polyethylene wax were characterized in terms of mol. wt., mol. wt. distribution, crystallinity, d. and morphol. Among the polymn. features with a series of mixed cocatalysts, including; Et3Al, i-Bu3Al, Et2AlCl and Et3Al2Cl3, the combination of Et3Al and Et3Al2Cl3 was most effective. The activity of the catalyst and the properties of polyethylene wax were affected by the polymn. parameters, i.e. time, temp. and H partial pressure. Bibliographic Information Preparation of polyethylene wax by gas-phase polymerization. Chang, Main. (Exxon Chemical Patents, Inc., USA). U.S. (1990), 6 pp. CODEN: USXXAM US 4914253 A 19900403 Patent written in English. Application: US 88-267216 19881104. Priority: . CAN 113:98282 AN 1990:498282 CAPLUS (Copyright (C) 2007 ACS on SciFinder (R) Patent Family InformationPatent No.KindDateApplication No.Date US4914253A19900403US1988-26721619881104EP367597A119900509EP1989-31132819891101EP367597B119920708R: AT, BE, DE, ES, FR, GB, IT, LU, NL, SEWO9005151A119900517WO1989-US489819891101W: AU, BR, DK, FI, HU, JP, KR, NO, SUAU8946271A19900528AU1989-4627119891101BR8907147A19910213BR1989-714719891101JP03502209T19910523JP1990-50034419891101HU55419A219910528HU1989-685919891101AT78046T19920715AT1989-31132819891101ES2034648T319930401ES1989-31132819891101JP2753518B219980520JP1989-50034419891101CA2001941A119900504CA1989-200194119891102CA2001941C20001017NO9002892A19900628NO1990-289219900628DK9001599A19900822DK1990-159919900703KR137960B119980501KR1990-70141619900703 Priority ApplicationUS1988-267216A19881104WO1989-US4898A19891101EP1989-311328A19891101 AbstractPolyethylene wax having a narrow mol. wt. distribution is prepd. by gas-phase polymn. of C2H4 in the presence of a supported metallocene-aluminoxane catalyst and H. Adding 100 g undehydrated silica gel (Davidson 948) to 260 mL 15% Me3Al-heptane soln. and 300 mL heptane, reacting 1 h, adding 2.50 g bis(n-butylcyclopentadienyl)zirconium dichloride, and stirring for 30 min gave a catalyst with Al/Zr mol ratio 67.4:1. The catalyst was used to polymerize a 40:53:7 mol% C2H4/N/H mixt. at 60F and 300 psig producing, after 15 h, polyethylene with polydispersity 3.99. Bibliographic Information Preparation of polyethylene wax and catalysts for use therein. Lueker, Hartmut. (Hoechst A.-G., Fed. Rep. Ger.). Ger. Offen. (1989), 7 pp. CODEN: GWXXBX DE 3743322 A1 19890629 Patent written in German. Application: DE 87-3743322 19871221. Priority: . CAN 111:195591 AN 1989:595591 CAPLUS (Copyright (C) 2007 ACS on SciFinder (R) Patent Family InformationPatent No.KindDateApplication No.Date DE3743322A119890629DE1987-374332219871221EP321851A119890628EP1988-12095019881215R: BE, DE, ES, FR, GB, IT, NLUS5023388A19910611US1988-28632619881219AU8827322A19890622AU1988-2732219881220JP01203410A19890816JP1988-31965519881220ZA8809473A19890830ZA1988-947319881220 Priority ApplicationDE1987-3743322A19871221 AbstractPolyethylene (I) wax with mol. wt. 2000-10,000, polydispersity 2-10, viscosity no. 20-60 mL/g, m.p. 129-131 (120-126 for copolymers), d. 0.93-0.97, bulk d. 200-400 g/dm3, and high crystallinity is prepd. Thus, stirring 100 dm3 diesel oil contg. 1 mmol dicyclopentadienyl zirconium dichloride and 1.043 mol (sic) Me aluminoxane with 150 dm3 H and C2H4 at 85 and 7 bar for 4 h gave 11 kg I with polydispersity 3.8, viscosity no. 32 mL/g, m.p. 129-131, and bulk d. 330 g/dm3. Bibliographic Information Anti-glare polymer compositions. Webb, Johannes A. V. (S. Afr.). U.S. (1987), 3 pp. CODEN: USXXAM US 4703077 A 19871027 Patent written in English. Application: US 86-867560 19860528. Priority: . CAN 108:39114 AN 1988:39114 CAPLUS (Copyright (C) 2007 ACS on SciFinder (R) Patent Family InformationPatent No.KindDateApplication No.Date US4703077A19871027US1986-86756019860528 Priority ApplicationUS1986-86756019860528 AbstractTitle compns. useful in television screens, picture frame glass, etc., are prepd. from Me methacrylate polymers dissolved in fast-evapg. solvents, e.g. trichloroethane, and polyethylene wax dissolved in slow evapg. solvents, e.g. xylene. Bibliographic Information Preparation of polyethylene wax by ionizable radiation. Yamabe, Masamori; Shimizu, Harumichi; Shinozaki, Yoshiharu; Iizuka, Yoshisuke. Jpn. Tokkyo Koho (1970), 4 pp. CODEN: JAXXAD JP 45025109 19700820 Showa. Patent written in Japanese. Application: JP 19641117. CAN 74:13778 AN 1971:13778 CAPLUS (Copyright (C) 2007 ACS on SciFinder (R) Patent Family InformationPatent No.KindDateApplication No.Date JP45025109B19700820JP19641117 AbstractWaxy polyethylene is prepd. by irradiating ethylene at low pressure with ionizing radiation in the presence of a telomer, or its mixt. with a satd. hydrocarbon, of the general formula X(CH2CH2)nY (where X is H or Cl, Y is CCl3, CH2OH, C2H4OH, or CN, and n is 2-3). Thus, a telomer (n .apprx.3) was prepd. by irradiating 30 kg/cm2 ethylene in an autoclave contg. CCl4 under N with 6.7 106 R of 60Co g-rays. In a 100-cm3 autoclave, a mixt. of 4 ml telomer and 38 ml cyclohexane was purged for 20 min with 100 ml/min N, then 30 kg/cm2 ethylene was introduced, and irradiated with 2.5 106 R of g-rays to yield 2.92 g waxy polymer.Bibliographic Information Development of CPE HPN wire. Wang, Baidong; Zeng, Liping; Liu, Jizhao. Department of Mechanics, Hunan College of Technology, Hengyang, Peop. Rep. China. Xiangjiao Gongye (2005), 52(12), 741-743. Publisher: Xiangjiao Gongye Bianjibu, CODEN: XIGOED ISSN: 1000-890X. Journal written in Chinese. AN 2006:1271714 CAPLUS (Copyright (C) 2007 ACS on SciFinder (R) AbstractThe chlorinated polyethylene (CPE) HPN wire with heat resistant grade of 105 was prepd. from CPE CM352L/CPE702P 100, ultrafine CaCO3 powder 55, ultrafine talc powder 30, calcined argil 20, C black N550 10, MgO 12, plasticizer TOTM 10, chlorinated paraffin wax 5, epoxidized soybean oil 4, curing agent F-80 4, crosslinking assistant PL-400 8, and other 21 phr. Bibliographic Information Preparation of fresh-keeping nanoscale packaging material for green tea with reduced oxygen and moisture permeability and improved tensile strength. Hu, Qiuhui; Yang, Fangmei; Huang, Yuanyuan; Xu, Juan; Lu, Zhaoxin; Yin, Fusheng; Yu, Fang; Mao, Jiugeng. (Nanjing Agricultural University, Peop. Rep. China). Faming Zhuanli Shenqing Gongkai Shuomingshu (2005), 7pp. CODEN: CNXXEV CN 1709979 A 20051221 Patent written in Chinese. Application: CN 1004-992 20050712. Priority: . CAN 145:456011 AN 2006:1129266 CAPLUS (Copyright (C) 2007 ACS on SciFinder (R) Patent Family InformationPatent No.KindDateApplication No.Date CN1709979A20051221CN2005-1004099220050712 Priority ApplicationCN2005-1004099220050712 AbstractThe title fresh-keeping nanometer packaging material is prepd. by (by wt.) high-speed mixing nanopowder 25-35%, polyethylene (PE) plastic 50-60%, silane coupling agent 10-15%, and wax 4-10% for 0.5-1.5 h, kneading, extruding, cooling, granulating; and mixing prepd. granules 1-2 kg with PE plastic granules 30-40 kg for 0.5-1 h, and blowing to obtain thin film. Bibliographic Information Antibacterial synthetic resin compositions containing nano silver/silica composite particles and having no black spots. Park, Tae Soo. (S. Korea). Repub. Korean Kongkae Taeho Kongbo (2005), No pp. given. CODEN: KRXXA7 KR 2005012316 A 20050202 Patent written in Korean. Application: KR 2003-51233 20030725. Priority: . CAN 145:357601 AN 2006:853265 CAPLUS (Copyright (C) 2007 ACS on SciFinder (R) Patent Family InformationPatent No.KindDateApplication No.Date KR2005012316A20050202KR2003-5123320030725 Priority ApplicationKR2003-5123320030725 AbstractThe title compns. contain 100 parts transparent and semi-transparent synthetic resins, 0.5-10 parts title composite particles, an aq. soln. contg. 1,000-100,000 ppm effective Ag, 1-20 parts 1 or 2 lubricants selected from liq. paraffins, polyethylene glycol, glycerin, high-mol.-wt. fatty acids, high-mol.-wt. fatty acid esters, sorbitol and derivs. thereof, solid-phase polyethylene waxes having m.p. 100, acryl waxes, stearic acid, and oleic acid, and 1-10 parts 1 or 2 dispersants selected from Si and titanate coupling agents. Bibliographic Information Fragrant multi-vein microporous thermoplastic resin artificial wood. Lu, Liqin; Yan, Xiuqin. (Guilin Shukang Building Material Co., Ltd., Peop. Rep. China). Faming Zhuanli Shenqing Gongkai Shuomingshu (2005), 5 pp. CODEN: CNXXEV CN 1690112 A 20051102 Patent written in Chinese. Application: CN 1002-2458 20040428. Priority: . CAN 145:189742 AN 2006:662598 CAPLUS (Copyright (C) 2007 ACS on SciFinder (R) Patent Family InformationPatent No.KindDateApplication No.Date CN1690112A20051102CN2004-1002245820040428 Priority ApplicationCN2004-1002245820040428 AbstractThe title artificial wood material is prepd. from (by wt. parts) polyvinyl chloride 100, pptd. calcium carbonate 10-50, calcium stearate 0.3-0.6, ZnO 3-4, MgO 2-3, polyethylene wax or paraffin wax 0.2-0.4, stearic acid 0.2-0.4, azobisformamide 0.2-0.6, ZB530 foaming regulator 3-8, dioctyl phthalate 2-4, chlorinated polyethylene 3-6, zinc di-Bu dithiocarbamate 0.2-0.4, fumaric diester 0.2-0.6, titanium dioxide 0.5-2, ester or alc. fragrance 0.2-0.4, and cationic surfactant 0.01-0.04 by mixing, granulating, injection molding and surface treating. The wood vein is formed by transferring pattern from a water-resistant printing film to surface of the artificial wood material. Bibliographic Information Water, oil and soil repellent plastic tablecloth. Chen, Jianqiang; Huang, Xiaoshi; Liu, Jun; Chen, Ying. (Shanghai Jiao Tong University, Peop. Rep. China). Faming Zhuanli Shenqing Gongkai Shuomingshu (2005), 4 pp. CODEN: CNXXEV CN 1687514 A 20051026 Patent written in Chinese. Application: CN 1002-4923 20050407. Priority: . CAN 145:104718 AN 2006:615064 CAPLUS (Copyright (C) 2007 ACS on SciFinder (R) Patent Family InformationPatent No.KindDateApplication No.Date CN1687514A20051026CN2005-1002492320050407 Priority ApplicationCN2005-1002492320050407 AbstractThe title tablecloth is prepd. from poly(tetrafluoroethylene) nanopowder 1%-5%, titanium dioxide nanopowder 2%-5%, mixt. of Mg(OH)2 and AL2O3 1%-2%, stearic acid 1%-2%, polyethylene wax 1%-3% and polyolefin (polypropylene or dacron) in balance. Bibliographic Information Method for preparation of agricultural plastic film masterbatch with insect-repellent property. Zhang, Huaji; Zhang, Wen; Xiao, Liren. (Fujian Normal University, Peop. Rep. China). Faming Zhuanli Shenqing Gongkai Shuomingshu (2005), 7 pp. CODEN: CNXXEV CN 1687214 A 20051026 Patent written in Chinese. Application: CN 1006-5489 20050406. Priority: . CAN 145:104706 AN 2006:586601 CAPLUS (Copyright (C) 2007 ACS on SciFinder (R) Patent Family InformationPatent No.KindDateApplication No.Date CN1687214A20051026CN2005-1006548920050406 Priority ApplicationCN2005-1006548920050406 AbstractThe title masterbatch is prepd. from ethylene-vinyl acetate copolymer 44-50, flufenoxuron 4-5, acetamiprid 2-3, amitraz 2-3, polyethylene wax 1.4-1.8, calcium silicate 36-42, a silane coupling agent 0.6-0.8, and UV absorbent (UV 531) 0.8-1.2% by coating insect repellents with polyethylene wax; mixing the coated insect repellents with calcium silicate treated with silane coupling agent; adding EVA and UV 531; plasticizing; extruding and pelletizing. The masterbatch can be added into linear low-d. polyethylene in a ratio of 3-4:100 to prep. agricultural film with insect repellent property. Bibliographic Information Composite calcium carbonate filler with good dispersability and compatibility for plastic and rubber products and its preparation. Zhou, Xuemei; Chen, Yuanlan. (Peop. Rep. China). Faming Zhuanli Shenqing Gongkai Shuomingshu (2005), 4 pp. CODEN: CNXXEV CN 1680495 A 20051012 Patent written in Chinese. Application: CN 1000-8131 20040304. Priority: . CAN 145:28737 AN 2006:519897 CAPLUS (Copyright (C) 2007 ACS on SciFinder (R) Patent Family InformationPatent No.KindDateApplication No.Date CN1680495A20051012CN2004-1000813120040304 Priority ApplicationCN2004-1000813120040304 AbstractTitle composite calcium carbonate filler is prepd. from calcium carbonate 70-90, oxidized polyethylene wax 2-6, stearic acid 2-4, resin 5-15, and polyvinyl chloride composite stabilizer 8-12 parts b
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