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qcvn 24: 2009/btnmt socialist republic of vietnamqcvn 24: 2009/btnmtnational technical regulation on industrial wastewaterh ni - 2009forewordqcvn 24: 2009/btnmt was complied by drafting committee of national technical regulations on water quality, submitted by vietnam environment administration and department of legislation and promulgated in line with circular no. 25/2009/tt-btnmt dated november 16, 2009 issued by ministry of natural resource and environment national technical regulation on industrial wastewater1. general provisions1.1. scope of regulation this regulation provides for maximum allowable values of pollution parameters in industrial wastewater discharged into receiving facilities1.2. subjects of application 1.2.1. this regulation applies to individuals and organizations carrying out activities related to the discharge of industrial wastewater in to receiving facilities 1.2.2. wastewater of some industries and field of particular activities shall be regulated separately 1.3. interpretation of termsin this regulation, the terms below are construed as follows1.3.1. industrial wastewater means solution discharged from industrial manufacturing, processing, trading and servicing premises into wastewater-receiving facilities 1.3.2. kq means discharge coefficient/volumetric capacity of the receiving facilities corresponding to flow discharge of river, stream, spring, canal, channel, streamlet, rillet and volumetric capacity of reservoir, lake, pond and swamp 1.3.3. kf discharge coefficient of wastewater-discharging sources of industrial manufacturing, processing, trading and servicing premises into wastewater-receiving facilities1.3.4. wastewater-receiving facilities means surface water bodies or coastal water areas used with particular and specific purpose where industrial wastewater is discharged into1. technical regulation2.1. the allowable maximum value of pollution parameters in industrial wastewater is calculated as follows:cmax = c x kq x kf where:- cmax is allowable maximum value of the pollution parameter in industrial wastewater discharged into receiving facilities, measured in milligram per liter (mg/l);- c is value of pollution parameter in industrial wastewater stipulated at section 2.3- kq is discharge coefficient/volumetric capacity of the receiving facilities stipulated at section 2.4- kf is discharge coefficient of wastewater source stipulated at section 2.52.2. cmax = c (without coefficient of kq and kf) is applied to parameters: temperature, ph, odour, colour, coliform, gross activity and gross activity 2.3. the c value of pollution parameters in industrial wastewater is stipulated at the table no. 1 below:table 1: the c value of pollution parameters in industrial wastewatero. noparameterunitc valueab1temperature0c40402ph-6-95,5-93odour气味-khng kh chukhng kh chu4colour (co-pt at ph = 7)色度-20705bod5 (200c)mg/l30506codmg/l501007suspended solids悬浮物mg/l501008arsenic砷mg/l0,050,19mercury 汞mg/l0,0050,0110lead铅mg/l0,10,511cadimium镉mg/l0,0050,0112chromium (vi) 六价铬mg/l0,050,113chromium (iii) 三价铬mg/l0,2114cooper mg/l2215zinc锌mg/l3316nickel镍mg/l0,20,517manganese锰mg/l0,5118iron铁mg/l1519tin锡mg/l0,2120cyanide氰化物mg/l0,070,121phenol酚mg/l0,10,522mineral oil and fatmg/l5523animal-vegetable oil and fatmg/l102024chlroine residual mg/l1225pcbsmg/l0,0030,0126pesticide: organic phosphrous mg/l0,3127pesticide: organic chlorinemg/l0,10,128sunfidemg/l0,20,529fluoride mg/l51030chloride氯化物mg/l50060031ammonia (as n)mg/l51032total nitrogen mg/l153033total phosphorous mg/l4634coliformmpn/100ml3000500035gross activitybq/l0,10,136gross activity bq/l1,01,0where:- colume a stipulates value c of pollution parameter in industrial wastewater discharged into receiving facilities using for sources of domestic water supply- colume b stipulats value c of pollution parameter in industrial wastewater discharged into receiving facilities not using for sources of domestic water supply- parameter of chlorine shall not be applied to receiving facilities which are brackish and salt water2.4. discharge coefficient/volumetric capacity of receiving facilities kq is stipluated as follows2.4.1. coefficient kq corresponding to flow discharge of receiving facilities whichs are river, stream, spring, canal, channel, streamlet, rillet is stipulated at the table no. 2 below:table 2: coefficient kq of receiving facilities whichs are river, stream, spring, canal, channel, streamlet, rilletflow discharge of watewater-receiving facilities (q)calculated unit: cubic meter/second (m3/s)coefficient kqq 500,950 q 2001200 1000 1,2q is calculated in average value of flow discharge of river, stream, spring, canal, channel, streamlet, rillet during 03 driest months of 03 successive years (data issued by meteorological-hydrological agency). if there is no data on flow discharge of river, stream, spring, canal, channel, streamlet, rillet the value kq=0,9 shall be applied or department of natural resource and environment managing areas where wastewater-discharging sources are located shall appoint a unit with appropriate function to define average discharge during 03 driest of year for the basis of selecting coefficient kq2.4.2. coefficient kq corresponding to volumetric capacity of wastewater receiving facilities which are reservoir, lake, pond and swamp is stipulated at the table no. 3 below:table 3: coefficient kq of reservoir, lake, pond, swamp volumetric capacity of wastewater receiving facilities (v)calculated unit: cubic meter (m3)coefficient kqv 10 x 1060,610 x 106 100 x 106 1,0q is calculated in average value of volumetric capacity of eservoir, lake, pond and swamp during 03 driest months of 03 successive years (data issued by meteorological-hydrological agency). if there is no data on volumetric capacity the value kq=0,6 shall be applied or department of natural resource and environment managing areas where wastewater-discharging sources are located shall appoint a unit with appropriate function to define average value of volumetric capacity during 03 driest of year for the basis of defining coefficient kq2.4.3. regaring the receiving facilities which are coastal areas not using for the purpose of aquatic organism protection, water sport or recreation, kq = 1,3 shall be applied. regaring the receiving facilities which are coastal areas using for the purpose of aquatic organism protection, water sport or recreation, kq = 1,3 shall be applied2.5. discharge coefficient kf of wastewater discharging sources is stipulated at the table no. 4 belowbng 4: discharge coefficient kf of wastewater discharging sourcesdischarge of wastewater discharging sources i (f)calculated unit: cubic meter/day (m3/24h)coefficient kff 501,250 f 5001,1500 5.0000,92.6. in the case that wastewater stored in dumping pond within area of wastewater-creating premises and used for the purpose of irrigation, the water in the pond must comply with the national standard tcvn 6773:2000 on water quality water quality guidelines for irrigation3. method of determination3.1. method for definition of pollution parameters in industrial wastewater shall be carried out in accordance with national standards below:- tcvn 4557:1988 water quality method for determination of temperature;- tcvn 6492:1999 (iso 10523:1994) water quality - determination of ph;- tcvn 6185:2008 water quality examination and determination of colour;- tcvn 6001-1: 2008 water quality. determination of biochemical oxygen demand after n days (bodn). part 1: dilution and seeding method with allylthiourea addition- tcvn 6491:1999 (iso 6060:1989) water quality. determination of the chemical oxigen demand (cod);- tcvn 6625:2000 (iso 11923:1997) water quality - determination of suspended solids by filtration through glass-fibre filters;- tcvn 6626:2000 water quality - determination of arsenic - atomic absorption spectrometric method (hydride technique;- tcvn 7877:2008 (iso 5666 -1999) water quality. determination of mecury; - tcvn 6193:1996 water quality. determination of cobalt nickel, copper, zinc, cadmium, and lead. flame atomic absorption spectrometric methods;- tcvn 6002:1995 (iso 6333-1986) water quality - determination of manganese - formaldoxime spectrometric method;- tcvn 6222:2008 water quality. determination of chromium. atomic absorption spectrometric methods;- tcvn 6177:1996 (iso 6332-1988) water quality - determination of iron . spectrometric method using. 1,10-phenantrolin;- tcvn 6181:1996 (iso 6703-1-1984) water quality - determination of total cyanide;- tcvn 6216:1996 (iso 6439-1990) water quality. determination of phenol index. 4-aminoantipyrine spectrometric methods after distillation;- tcvn 5070:1995 water quality - weight method for determination of oil and oil product;- method for determination of total vegetable oil and fat carried oyut according to us epa method 1664 extraction and gravimetry (oil and grease and total petroleum hydrocarbons);- tcvn 6225-3:1996 water quality. determination of free chlorine and total chlorine. part 3: iodometric titration method for the determination of total chlorine;- tcvn 4567:1988 water quality method for determination of suldide and sulfate content;- tcvn 6494:1999 water quality - determination of dissolved fluoride, chloride, nitrite, orthophosphate, bromide, nitrate and sulfate ions, using liquid chromatography of ions - method for water with low contamination- tcvn 5988:1995 (iso 5664-1984) water quality - determination of aminonium - distillation and titration method;- tcvn 6638:2000 water quality - determination of nitrogen - catalytic digestion after reduction with devardas alloy;- tcvn 6187-1:2009 (iso 9308-1: 2000/cor 1: 2007) water quality. detection and enumeration of escherichia coli and coliform bacteria. part 1: membrane filtration method;- tcvn 6053:1995 water quality - measurement of gross alpha activity in non-saline water - thick source metho
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