虎特-科威特原油分析.pdf

5 ATTACHMENT 1 32 0 API Hout CRUDE OIL KPR T Reference Number 2006 15760 Inspection Data Density at 15 C D 4052 kg l 0 8647 Specific Gravity 15 6 15 6 C 0 8652 Gravity API 32 0 Characterisation Factor UOP 375 11 9 Viscosity Kin at 37 8 C D 445 mm2 s 8 79 Vapour Pressure D 323 kPa 44 3 Pour Point D 97 C 18 Water D 4006 volume 0 025 Water Sediment D 4007 volume 0 025 Salt Content ASTM D 3230 lb 1000 bbl 10 4 Sulphur D 2622 mass 2 04 Hydrogen Sulphide UOP 163 mg kg 5 Mercaptan Sulphur UOP 163 mg kg 141 Basic Nitrogen mg kg UOP 269 mg kg 411 Nickel D 3327 mg kg 9 9 Vanadium D 3327 mg kg 36 Carbon Residue Conr D 4530 mass 5 60 Total Acidity D 664 mg KOH g 0 20 Ash ASTM D 482 mass 0 006 Distillation D 86 modified Over Point C 44 3 Condensed at 100 C volume 5 2 Condensed at 140 C volume 12 5 Condensed at 160 C volume 16 5 Condensed at 200 C volume 23 7 Condensed at 220 C volume 27 3 Condensed at 240 C volume 29 9 Condensed at 270 C volume 36 1 Recovery Loss volume 36 3 Residue 270 C volume 63 7 Light Ends Determination KPI 118 Volume on crude oil ethane 0 23 propane 0 52 i butane 0 31 n butane 1 49 i pentane 0 98 n pentane 1 79 Cyclopentane 2 3 dimethylbutane 0 11 2 methylpentane 0 93 3 methylpentane 0 65 n hexane 1 70 6 ATTACHMENT 2 32 0 API Hout Crude Oil TBP Cut Point C Volume mass Cut Cumulative Cut Cumulative 20 1 73 1 73 1 13 1 13 25 0 41 2 15 0 27 1 40 30 0 45 2 60 0 31 1 70 35 0 49 3 09 0 34 2 05 40 0 52 3 61 0 38 2 43 45 0 55 4 16 0 41 2 83 50 0 58 4 73 0 44 3 27 55 0 60 5 34 0 47 3 74 60 0 63 5 96 0 49 4 23 65 0 65 6 61 0 52 4 75 70 0 67 7 28 0 54 5 29 75 0 69 7 97 0 56 5 85 80 0 71 8 68 0 58 6 43 85 0 72 9 40 0 60 7 02 90 0 74 10 14 0 61 7 64 95 0 75 10 89 0 63 8 27 100 0 76 11 65 0 64 8 91 105 0 77 12 43 0 66 9 57 110 0 78 13 21 0 67 10 23 115 0 79 14 00 0 68 10 91 120 0 80 14 80 0 69 11 60 125 0 81 15 60 0 70 12 30 130 0 81 16 41 0 71 13 00 135 0 82 17 23 0 71 13 72 140 0 82 18 05 0 72 14 44 145 0 82 18 87 0 73 15 16 150 0 83 19 70 0 73 15 89 160 1 66 21 36 1 48 17 37 170 1 67 23 03 1 49 18 87 180 1 67 24 70 1 51 20 38 190 1 67 26 38 1 52 21 90 200 1 67 28 05 1 53 23 42 210 1 67 29 72 1 54 24 96 220 1 67 31 38 1 54 26 51 230 1 66 33 04 1 55 28 06 240 1 66 34 70 1 56 29 61 250 1 65 36 35 1 56 31 18 260 1 65 38 00 1 57 32 74 270 1 64 39 64 1 57 34 32 280 1 64 41 27 1 58 35 89 290 1 63 42 90 1 58 37 48 300 1 62 44 53 1 59 39 06 310 1 62 46 14 1 59 40 65 320 1 61 47 75 1 59 42 25 330 1 60 49 35 1 59 43 84 340 1 59 50 94 1 59 45 43 350 1 57 52 51 1 59 47 02 360 1 56 54 07 1 58 48 60 7 ATTACHMENT 3 32 0 API Hout Crude Oil Yield vs Temperature 0 0 10 0 20 0 30 0 40 0 50 0 60 0 050100150200250300350400 Temperature C Yield Mass Volume 8 ATTACHMENT 4 32 0 API Hout Crude Oil Properties vs TBP Mid Point Temperature TBP Cut Point Sulphur Density Refractive Index Aromatics C mass at 15 C kg l mass 20 0 5885 25 0 5998 30 0 6105 35 0 6208 40 0 028 0 6306 1 3590 45 0 026 0 6400 1 3634 50 0 026 0 6489 1 3676 55 0 025 0 6574 1 3716 60 0 026 0 6656 1 3755 65 0 026 0 6733 1 3793 70 0 027 0 6808 1 3829 75 0 029 0 6878 1 3864 80 0 030 0 6946 1 3898 85 0 032 0 7010 1 3930 90 0 034 0 7071 1 3962 95 0 037 0 7130 1 3992 100 0 039 0 7186 1 4021 105 0 042 0 7239 1 4049 110 0 045 0 7290 1 4076 115 0 048 0 7339 1 4102 120 0 051 0 7386 1 4127 125 0 054 0 7430 1 4152 130 0 058 0 7473 1 4175 135 0 061 0 7514 1 4197 140 0 064 0 7553 1 4219 145 0 068 0 7591 1 4240 150 0 072 0 7628 1 4261 160 0 080 0 7697 1 4299 170 0 088 0 7761 1 4336 180 0 098 0 7822 1 4370 190 0 11 0 7880 1 4403 23 3 200 0 12 0 7936 1 4434 22 2 210 0 14 0 7990 1 4463 21 6 220 0 15 0 8043 1 4492 21 5 230 0 22 0 8095 1 4520 21 9 240 0 34 0 8147 1 4548 22 7 250 0 48 0 8199 1 4575 23 8 260 0 62 0 8252 1 4603 25 1 270 0 77 0 8305 1 4630 26 3 280 0 91 0 8359 1 4659 27 5 290 1 04 0 8414 1 4688 28 5 300 1 16 0 8471 1 4718 29 3 310 1 28 0 8528 1 4749 30 0 320 1 40 0 8587 1 4781 30 7 330 1 55 0 8648 1 4816 31 7 340 1 72 0 8709 1 4852 33 5 350 1 95 0 8771 1 4890 36 7 360 2 25 0 8834 1 4930 42 1 9 ATTACHMENT 5 32 0 API Hout Crude Oil Sulphur Content vs Mid Boiling Point 0 0 0 5 1 0 1 5 2 0 2 5 050100150200250300350400 Mid Boiling Point C Sulphur mass 10 ATTACHMENT 6 32 0 API Hout Crude Oil Density as Function of Mid Boiling Point 0 6000 0 6500 0 7000 0 7500 0 8000 0 8500 0 9000 0100200300400 Mid Boiling Point C Density at 15 C kg l 11 ATTACHMENT 7 32 0 API Hout Crude Oil Total Aromatics vs Mid Boiling Point 16 0 21 0 26 0 31 0 36 0 41 0 180200220240260280300320340360 TBP Mid Boiling Point C Aromatics mass 12 ATTACHMENT 8 GAS FRACTION OF 32 0 API HOUT CRUDE OIL TBP Boiling Range Gas Position in Crude volume 0 0 1 3 Position in Crude mass 0 0 0 9 Volume on Crude 1 3 Mass on Crude 0 9 Density at 15 C calculated kg l 0 5577 Specific Gravity 15 6 15 6 C 0 5577 Gravity API 122 2 Chromatographic Analysis UOP 551 volume ethane 0 8 propane 27 1 i butane 13 9 n butane 48 6 i pentane 5 4 n pentane 4 1 13 ATTACHMENT 9 LIGHT NAPHTHAS OF 32 0 API HOUT CRUDE OIL TBP Boiling Range C OP 60 60 77 Position in Crude volume 1 3 6 0 6 0 8 5 Position in Crude mass 0 9 4 3 4 3 6 3 Volume on Crude 4 7 2 5 Mass on Crude 3 4 2 0 Density at 15 C D 4052 kg l 0 6260 0 6776 Specific Gravity 15 6 15 6 C 0 6261 0 6777 Gravity API 94 5 77 3 Sulphur D 2622 mass 0 027 0 032 Mercaptan Sulphur UOP 212 mg kg 1 29 Refractive index at 20 C DIN 51423 TI 2 1 3573 1 3809 Chromatographic Analysis D 5443 volume ethane propane 0 16 0 20 i butane 1 72 0 17 n butane 14 8 0 54 i pentane 22 7 1 42 n pentane 40 7 6 70 2 2 dimethylbutane 0 23 0 22 cyclopentane 1 69 1 26 2 3 dimethylbutane 1 08 2 02 2 methylpentane 7 7 16 0 3 methylpentane 4 3 13 3 n hexane 4 4 40 1 methylcyclopentane 0 36 7 02 1 1 dimethylpentane 2 2 dimethylpentane 2 4 dimethylpentane 0 59 benzene 0 16 2 08 cis 1 3 dimethylcyclopentane 0 16 trans 1 2 dimethylcyclopentane 0 31 2 3 dimethylpentane 0 57 3 3 dimethylpentane 0 06 cyclohexane 3 17 2 methylhexane 1 52 3 methylhexane 1 35 toluene 0 03 n heptane 0 83 Hydrocarbon Type Analysis D 5443 volume iso Paraffins 37 7 37 3 n Paraffins 60 0 48 4 Naphthenes 2 1 12 2 Aromatics 0 2 2 1 Research Octane No D 2699 61 0 14 ATTACHMENT 10 MEDIUM NAPHTHAS OF 32 0 API HOUT CRUDE OIL TBP Boiling Range C 77 154 154 177 154 191 Position in Crude volume 8 5 20 4 20 4 24 5 20 4 26 7 Position in Crude mass 6 3 16 5 16 5 20 2 16 5 22 2 Volume on Crude 11 9 4 1 6 3 Mass on Crude 10 3 3 7 5 7 Density at 15 C D 4052 kg l 0 7320 0 7749 0 7763 Specific Gravity 15 6 15 6 C 0 7322 0 7752 0 7766 Gravity API 61 8 51 0 50 7 Characterisation Factor UOP 375 12 2 12 0 11 9 Sulphur D 2622 mass 0 043 0 107 0 084 Mercaptan Sulphur UOP 212 mg kg 103 125 37 Refractive index at 20 C DIN 51423 TI 2 1 4114 1 4337 1 4360 Distillation D 86 Over Point C 96 5 160 0 159 9 End Point C 149 5 181 4 186 9 5 Recovery C 102 5 163 6 165 0 10 Recovery C 105 2 164 7 165 0 20 Recovery C 107 9 165 4 165 5 30 Recovery C 110 6 166 6 166 7 40 Recovery C 113 6 167 5 167 8 50 Recovery C 117 2 168 9 169 0 60 Recovery C 121 0 169 6 170 2 70 Recovery C 125 7 170 8 171 9 80 Recovery C 130 8 172 2 174 1 90 Recovery C 137 4 174 5 177 8 95 Recovery C 142 0 177 5 181 3 Recovery volume 97 8 99 0 98 4 Residue Loss volume 2 2 1 0 1 6 Hydrocarbon Type Analysis D 5443 volume iso Paraffins 32 7 34 4 34 2 n Paraffins 36 9 30 2 30 0 Naphthenes 19 7 9 6 12 9 Aromatics 10 7 22 1 22 9 Olefins 0 1 0 1 0 1 15 ATTACHMENT 11 KEROSINES OF 32 0 API HOUT CRUDE OIL TBP Boiling Range C 154 191 154 271 177 271 191 271 Position in Crude volume 20 4 26 7 20 4 39 8 24 5 39 8 26 7 39 8 Position in Crude mass 16 5 22 2 16 5 34 5 20 2 34 5 22 2 34 5 Volume on Crude 6 3 19 4 15 3 13 1 Mass on Crude 5 7 18 0 14 3 12 3 Density at 15 C D 4052 kg l 0 7763 0 8002 0 8067 0 8062 Specific Gravity 15 6 15 6 C 0 7766 0 8006 0 8071 0 8066 Gravity API 50 7 45 2 43 8 43 9 Characterisation Factor UOP 375 11 9 11 9 11 9 12 0 Sulphur D 2622 mass 0 084 0 256 0 30 0 34 Mercaptan Sulphur UOP 212 mg kg 37 48 32 24 Refractive index at 20 C DIN 51423 TI 2 1 4360 1 4465 1 4499 1 4514 Freezing Point D 2386 C 60 38 37 32 Pour Point D 97 C 51 51 45 39 Aniline Point D 611 C 55 4 64 2 66 2 67 8 Smoke Point IP 57 mm 25 0 24 0 23 0 22 5 Cetane Index D 976 39 2 47 9 49 6 51 9 Cetane Index D 4737 43 5 49 7 51 4 54 3 Viscosity Kin at 37 8 C mm2 s 0 925 1 416 1 623 1 747 Hydrocarbon Type Analysis by Aromatic Hydrocarbon Distr IP 391 Total Aromatics mass 23 1 23 2 23 3 23 3 1 Ring Aromatics mass 22 9 20 2 19 5 19 0 2 Ring Aromatics mass 0 2 3 0 3 7 4 3 3 Ring Aromatics mass 0 1 0 1 0 1 0 1 Distillation D 86 Over Point C 159 9 172 9 195 1 206 8 End Point C 186 9 256 3 257 1 257 7 5 Recovery C 165 0 184 3 203 5 214 1 10 Recovery C 165 0 185 4 204 5 214 5 20 Recovery C 165 5 189 0 207 6 216 8 30 Recovery C 166 7 195 0 211 1 219 3 40 Recovery C 167 8 201 5 215 3 222 8 50 Recovery C 169 0 208 7 220 3 226 3 60 Recovery C 170 2 216 8 225 4 230 4 70 Recovery C 171 9 225 9 231 6 235 2 80 Recovery C 174 1 235 1 238 4 241 1 90 Recovery C 177 8 244 6 246 3 248 0 95 Recovery C 181 3 250 5 251 3 252 9 Recovery volume 98 4 98 5 99 1 98 3 Residue volume 1 3 1 4 0 9 1 4 Loss volume 0 3 0 1 0 0 0 3 Note Equations for Cetane Index are not recommended for these boiling ranges 16 ATTACHMENT 12 ATMOSPHERIC GASOILS OF 32 0 API HOUT CRUDE OIL TBP Boiling Range C 191 271 191 360 271 360 Position in Crude volume 26 7 39 8 26 7 54 0 39 8 54 0 Position in Crude mass 22 2 34 5 22 2 48 6 34 5 48 6 Volume on Crude 13 1 27 3 14 2 Mass on Crude 12 3 26 3 14 1 Density at 15 C D 4052 kg l 0 8062 0 8349 0 8577 Specific Gravity 15 6 15 6 C 0 8066 0 8353 0 8582 Gravity API 43 9 43 9 33 4 Characterisation Factor UOP 375 12 0 11 9 11 8 Sulphur D 2622 mass 0 34 0 93 1 43 Refractive index at 20 C DIN 51423 TI 2 1 4514 1 4654 1 4779 Cloud Point D 5773 C 36 12 1 Pour Point D 97 C 39 15 3 Aniline Point D 611 C 67 8 72 2 76 2 Cetane Index D 976 51 9 52 6 51 5 Cetane Index D 4737 54 3 54 4 58 3 Viscosity Kin at 37 8 C mm2 s 1 747 2 887 5 081 Hydrocarbon Type Analysis by Aromatic Hydrocarbon Distr IP 391 Total Aromatics mass 23 3 27 1 31 0 1 Ring Aromatics mass 19 0 17 2 16 0 2 Ring Aromatics mass 4 3 9 5 14 1 3 Ring Aromatics mass 0 1 0 4 0 9 Distillation D 86 Over Point C 206 8 212 9 286 3 End Point C 257 7 336 0 340 2 5 Recovery C 214 1 224 9 292 3 10 Recovery C 214 5 229 6 293 6 20 Recovery C 216 8 236 9 296 5 30 Recovery C 219 3 245 5 299 0 40 Recovery C 222 8 257 3 301 8 50 Recovery C 226 3 268 6 305 1 60 Recovery C 230 4 281 1 309 1 70 Recovery C 235 2 293 8 314 8 80 Recovery C 241 1 306 9 320 8 90 Recovery C 248 0 320 8 329 0 95 Recovery C 252 9 329 2 334 7 Recovery volume 98 3 98 6 98 2 Residue volume 1 4 1 4 1 7 Loss volume 0 3 0 0 0 1 17 ATTACHMENT 13 VACUUM GASOILS OF 32 0 API HOUT CRUDE OIL TBP Boiling Range C 360 475 475 538 360 538 Position in Crude volume 54 0 70 6 70 6 77 9 54 0 77 9 Position in Crude mass 48 6 65 9 65 9 73 8 48 6 73 8 Volume on Crude 16 6 7 3 23 8 Mass on Crude 17 3 7 9 25 2 Density at 15 C D 4052 kg l 0 9045 0 9384 0 9163 Specific Gravity 15 6 15 6 C 0 9050 0 9389 0 9168 Gravity API 24 9 19 2 22 8 Characterisation Factor UOP 375 11 9 11 9 11 9 Sulphur D 2622 mass 2 13 2 66 2 23 Aniline Point D 611 C 86 4 91 8 86 8 Pour Point D 97 C 30 48 36 Viscosity Kin at 37 8 C mm2 s 33 8 245 58 4 Viscosity Kin at 50 C mm2 s 20 6 117 33 3 Viscosity Kin at 60 C mm2 s 14 5 70 1 22 4 Viscosity Kin at 100 C mm2 s 5 16 15 7 7 01 Carbon Residue Conr D 4530 mass 0 03 1 06 0 20 Nitrogen KPI 40 mass 0 23 0 28 0 23 Distillation D 1160 Over Point C 356 421 361 End Point C 504 564 548 5 Recovery C 382 467