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Potassium hydroxide Section 1 Product Identification Synonyms Caustic Caustic soda Potassium hydrate Chemical Name Potassium hydroxide Molecular Weight 56 11 Chemical Formula KOH Section 2 Composition Information on Ingredients Ingredient Potassium Hydroxide CAS No 1310 58 3 Percent 90 Hazardous Yes Section 3 Physical and Chemical Properties Appearance white solid Odor Odorless Solubility Complete Specific Gravity 2 04 Volatiles by volume 20c 36 5 Boiling Point 1320C Melting Point 360 4C Vapor Density Air 1 Not Available Vapor Pressure mm Hg Negligible Evaporation Rate Not Available Section 4 First Aid Measures Inhalation Remove to fresh air If not breathing give artificial respiration If breathing is difficult give oxygen Call a physician Ingestion DO NOT INDUCE VOMITING Give large quantities of water or milk if available Never give anything by mouth to an unconscious person Get medical attention immediately Skin Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes Call a physician immediately Wash clothing before reuse Eye Immediately flush eyes with plenty of water for at least 15 minutes lifting lower and upper eyelids occasionally Get medical attention immediately Note to Physician Perform endoscopies in all cases of suspected Potassium hydroxide ingestion In cases of severe esophageal corrosion the use of therapeutic doses of steroids should be considered General supportive measures with continual monitoring of gas exchange acid base balance electrolytes and fluid intake are also required Chronic Not Available Section 5 Fire Fighting Measures Flash Point Method Used Not Applicable Flammable Limits by Volume in Air LEL Not Established UEL Not Established Fire LAB COAT Storage Color Code White Stripe Store Separately Protective Equipment GOGGLES LAB COAT VENT HOOD PROPER GLOVES Potential Health Effects Inhalation Severe irritant Effects from inhalation of dust or mist vary from mild irritation to serious damage of the upper respiratory tract depending on severity of exposure Symptoms may include sneezing sore throat or runny nose Severe pneumonitis may occur Ingestion Corrosive Swallowing may cause severe burns of mouth throat and stomach Severe scarring of tissue and death may result Symptoms may include bleeding vomiting diarrhea fall in blood pressure Damage may appear days after exposure Skin Contact Corrosive Contact with skin can cause irritation or severe burns and scarring with greater exposures Eye Contact Corrosive Causes irritation of eyes and with greater exposures it can cause burns that may result in permanent impairment of vision even blindness Chronic Exposure Prolonged contact with dilute solutions or dust has a destructive effect upon tissue Section 10 Stability and Reactivity Stability Stable under ordinary conditions of use and storage Very hygroscopic Can slowly pick up moisture from air and react with carbon dioxide from air to form Potassium carbonate Hazardous Decomposition Products Potassium oxide Decomposition by reaction with certain metals releases flammable and explosive hydrogen gas Hazardous Polymerization Will not occur Incompatibilities Potassium hydroxide in contact with acids and organic halogen compounds especially trichloroethylene may causes violent reactions Contact with nitro methane and other similar nitro compounds causes formation of shock sensitive salts Contact with metals such as aluminum magnesium tin and zinc cause formation of flammable hydrogen gas Potassium hydroxide even in fairly dilute solution reacts readily with various sugars to produce carbon monoxide Precautions should be taken including monitoring the tank atmosphere for carbon monoxide to ensure safety of personnel before vessel entry Conditions to Avoid Moisture dusting and incompatibles Section 11 Toxicological Information Irritation data skin rabbit 500 mg 24H severe eye rabbit 50 ug 24H severe investigated as a mutagen Cancer Lists NTP Carcinogen IngredientPotassium Hydroxide KnownNo AnticipatedNo IARC CategoryNone Section 12 Ecological Information Environmental Fate No information found Environmental Toxicity Not Available Section 13 Disposal Considerations Waste Disposal Insure Conformity with all Applicable Disposal Regulations
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