05-附录1-设计文档附录2010版

国投天津北疆21000MW机组烟气脱硫制IS项目 附录“东华科技陕鼓杯”第十一届全国大学生化工设计大赛国投天津北疆2300万Nm/h烟气脱硫制IS项目附录设计单位常州大学石油化工学院设计团队E.R.S成员姓名朱晓磊 袁乔 姚恩 仝志方 姜芸佳指导教师马江权 王俊 戚律 魏科年 高晓新2017年7月20日37附录一 物料衡算一览表1.1 第一工段物料衡算1.1.1 膜吸收反应器（R0101A）表1.1膜吸收反应器进出料流股表序号组分名称质量流量kg/hr进料流股1进料流股2出料流股1出料流股2温度/25253025压力/bar1211.6气相分率10011N22542683.93002542683.932O2235291.5800235291.583CO21069155.95001069155.954SO215728.7901.50314.525NO22823.75002823.756NO368.3500368.357HCL447.5800447.588HF245.5900245.599H2O0199992.95195660.08010H3O+000.01011Na+018241.1018241.10012HSO3-05.7339009.10013SO3-031758.8012502.26014OH-01.1900合计3866745.52249999.78265414.053851331.25序号组分名称质量分率进料流股1进料流股2出料流股1出料流股2温度/25253025压力/bar1211.6气相分率10011N20.6576000.66022O20.0609000.06113CO20.2765000.27764O2S0.004100.00000.00015NO20.0007000.00076NO0.0001000.00017HCL0.0001000.00018HF0.0001000.00019H2O00.80000.7372010H3O+000.0000011Na+00.07300.0687012HSO3-00.00000.1470013SO3-00.12700.0471014OH-00.000000合计11111.1.2 膜吸收反应器（R0101B）表1.2膜吸收反应器进出料流股表序号组分名称质量流量kg/hr进料流股1进料流股2出料流股1出料流股2温度/25253025压力/bar121.01.6气相分率10011N22542683.93002542683.932O2235291.5800235291.583CO21069155.95001069155.954SO215728.7901.5314.525NO22823.75002823.756NO368.3500368.357HCL447.5800447.588HF245.5900245.599H2O0199992.95195660.08010H3O+000.01011Na+018241.1018241.10012HSO3-05.7339009.10013SO3-031758.8012502.26014OH-01.1900合计3866745.52 249999.78 265414.05 3851331.25 序号组分名称质量分率进料流股1进料流股2出料流股1出料流股2温度/25253025压力/bar121.01.6气相分率10011N20.6576000.66022O20.0609000.06113CO20.2765000.27764SO20.004100.00000.00015NO20.0007000.00076NO0.0001000.00017HCL0.0001000.00018HF0.0001000.00019H2O00.80000.7372010H3O+000.0000011Na+00.07300.0687012HSO3-00.00000.1470013SO3-00.12700.0471014OH-00.000000合计11111.1.3 吸收富液进料罐（V0101）表1.3吸收富液进料罐进出料流股表序号组分名称质量流量kg/hr进料流股1进料流股2出料流股温度/303030压力/bar111气相分率1111SO21.51.53.012H2O195660.08195660.08391320.153H3O+0.010.010.014Na+18241.1018241.1036482.215HSO3-39009.1039009.1078018.206SO3-12502.2612502.2625004.52合计265414.05265414.05530828.10序号组分名称质量分率进料流股1进料流股2出料流股温度/303040压力/bar111.01325气相分率1101SO20.00000.000002H2O0.73720.73720.73723H3O+0.00000.00000.00004Na+0.06870.06870.06875HSO3-0.14700.14700.14706SO3-0.04710.04710.0471合计1111.1.4 解吸塔（T0101）表1.4解吸塔进出料流股表序号组分名称质量流量kg/hr进料流股1出料流股1出料流股2温度/4037.62108.17压力/bar1.0132511.1气相分率0101SO23.0130828.5002H2O391320.15490.36399466.353H3O+0.0101.774Na+36482.21036482.215HSO3-78018.200142.876SO3-25004.52063387.917OH-029.92合计530828.1031318.86 序号组分名称质量分率进料流股1进料流股2出料流股温度/4037.62108.17压力/bar1.0132511.1气相分率0101SO200.984302H2O0.73720.01570.79973H3O+0.0000004Na+0.068700.07305HSO3-0.147000.00036SO3-0.047100.12697OH-000.0001合计1111.1.5 三级气液分离降温器(V0103)表1.5三级气液分离降温器进出料流股表序号组分名称质量流量kg/hr进料流股出料流股1出料流股2温度/37.622020压力/bar155气相分率1101SO230828.5030483.31339.212H2O490.3637.71449.303H3O+001.774Na+0005HSO3-007.566SO3-0007OH-000合计31318.86 30521.02 797.84 序号组分名称质量分率进料流股出料流股1出料流股2温度/37.622020压力/bar155气相分率1101SO20.98430.99880.42522H2O0.01570.00120.56313H3O+000.00224Na+0005HSO3-000.00956SO3-0007OH-00合计1111.1.6 三级气液分离降温器(V0104)表1.6三级气液分离降温器进出料流股表序号组分名称质量流量kg/hr进料流股出料流股1出料流股2温度/201010压力/bar555气相分率1101SO230483.3130446.3936.792H2O37.7117.8919.753H3O+000.044HSO3-000.16合计30521.0230464.2856.74序号组分名称质量分率进料流股出料流股1出料流股2温度/201010压力/bar555气相分率1101SO20.99880.99940.64842H2O0.00120.00060.34803H3O+000.00074HSO3-000.0029合计1111.1.7 三级气液分离降温器(V0105)表1.7三级气液分离降温器进出料流股表序号组分名称质量流量kg/hr进料流股出料流股1出料流股2温度/10015.19压力/bar555气相分率1101SO230446.3930289.67533.482H2O17.895.06482.303H3O+001.594HSO3-006.76合计30521.0230294.731024.13序号组分名称质量分率进料流股出料流股1出料流股2温度/10015.19压力/bar555气相分率1101SO20.99940.999802H2O0.00060.00020.47093H3O+000.00154HSO3-000.0066合计1111.2 第二工段物料衡算1.2.1 反应搅拌进料罐（V0201）表1.8 反应搅拌进料罐进出料流股表序号组分名称质量流量kg/hr进料流股1进料流股2出料流股1出料流股2温度/2010015.19压力/bar5555气相分率00001SO2339.2136.79156.71533.482H2O449.3019.7512.83482.33H3O+1.770.0401.594HSO3-7.560.1606.76合计797.8456.74169.551024.13序号组分名称质量流量kg/hr进料流股1进料流股2出料流股1温度/2010015.19压力/bar5555气相分率00001SO20.42520.64840.92430.52092H2O0.56310.34800.07570.47093H3O+0.00220.000700.00154HSO3-0.00950.002900.0066合计11111.2.2 反应搅拌罐（R0202）表1.9 反应搅拌罐进出料流股表序号组分名称质量流量kg/hr进料流股1进料流股2出料流股温度/15.1920137.9压力/bar555气相分率0001SO2533.48002HO2482.31801.532437.393H3O+1.59004Na+00385.895HSO3-6.76385.894.356SO3-00669.10合计1024.132472.913497.04序号组分名称质量分率进料流股1进料流股2出料流股2温度/15.1920137.9压力/bar555气相分率0001SO20.520900.69702HO20.47090.728503H3O+0.001500.11034Na+0.00660.15600.00125HSO3-0.520900.19136SO3-0.470900合计1111.2.3 蒸发器（E0202）表1.10 蒸发器进出料流股表序号组分名称质量流量kg/hr进料流股出料流股1出料流股2温度/137.9250150压力/bar54.94.9气相分率0101SO200.0302H2O2437.391808.5903H3O+0004Na+385.890385.895HSO3-4.3508.606SO3-669.100664.87合计1024.131808.621688.42序号组分名称质量分率进料流股出料流股1出料流股2温度/15.19250150压力/bar54.94.9气相分率0101SO20.69700.000002H2O01.0000037193H3O+0.1103004Na+0.001200.22865HSO3-0.191300.00516SO3-000.3938合计1111.2.4 结晶器（CR0201）表1.11 结晶器进出料流股表序号组分名称质量流量kg/hr进料流股出料流股温度/2505压力/bar4.91气相分率001SO2002H2O627.84629.133H3O+004Na+385.89104.895HSO3-8.602.816SO3-664.87181.267Na2SO30770.33合计1688.421688.42序号组分名称质量分率进料流股出料流股温度/2505压力/bar4.91气相分率001SO2002HO20.37190.37263H3O+004Na+0.22860.06215HSO3-0.00510.00176SO3-0.39380.10747Na2SO300.4562合计111.2.5 晶体过滤机(FI0201)表1.12 晶体过滤机进出料流股表序号组分名称质量流量kg/hr进料流股出料流股1出料流股2温度/555压力/bar111气相分率0001SO20002H2O629.138.42.163H3O+0004Na+104.8901.765HSO3-2.8100.056SO3-181.2603.047Na2SO3770.330770.33合计1688.428.4777.34序号组分名称质量分率进料流股出料流股1出料流股2温度/555压力/bar111气相分率0001SO20002H2O0.013410.00283H3O+0004Na+0.002200.00235HSO3-0.00100.00016SO3-0.003900.00397Na2SO30.980400.9910合计1111.2.6 晶体干燥器(D0201)表1.13 晶体干燥器进出料流股表序号组分名称质量流量kg/hr进料流股出料流股1出料流股2温度/555压力/bar111气相分率0001SO20002H2O10.568.402.163H3O+0004Na+1.7601.765HSO3-0.0500.056SO3-3.0403.047Na2SO3770.330770.33合计785.748.4777.34序号组分名称质量分率进料流股出料流股1出料流股2温度/5250150压力/bar14.94.9气相分率0101SO20002H2O0.372610.00283H3O+0004Na+0.062100.00235HSO3-0.001700.00016SO3-0.107400.00397Na2SO30.456200.9910合计1111.3 第三工段物料衡算1.3.1 还原反应器进料罐（V0301）表1.14还原反应器进料罐流股表序号组分名称质量流量kg/hr进料流股出料流股温度/068.90压力/bar55气相分率111CO2002SO230289.6730289.673H2O5.065.064CO026497.845S00合计30294.7356792.57序号组分名称质量分率进料流股出料流股温度/068.90压力/bar55气相分率111CO2002SO20.99980.53333H2O0.00020.00014CO00.46665S00合计111.3.2 第一还原反应器（R0301A）表1.15第一还原反应器进出料流股表序号组分名称质量流量kg/hr进料流股出料流股温度/68.90390.00压力/bar1010气相分率111CO2029572.812SO230289.678765.193H2O5.065.064CO26497.847675.985S010773.53合计56792.5756792.57序号组分名称质量分率进料流股出料流股温度/68.90390.00压力/bar1010气相分率111CO200.52072SO20.53330.15433H2O0.00010.00014CO0.46660.13525S00.1897合计111.3.3 第二还原反应器（R0301B）表1.16第二还原反应器进出料流股表序号组分名称质量流量kg/hr进料流股出料流股温度/390.00407.00压力/bar109.8气相分率111CO229572.8140456.092SO28765.19843.833H2O5.065.064CO7675.98749.225S10773.5314738.37合计56792.5756792.57序号组分名称质量分率进料流股出料流股温度/390.00407.00压力/bar109.8气相分率111CO20.52070.71232SO20.15430.01493H2O0.00010.00014CO0.13520.01325S0.18970.2595合计111.3.4 还原反应器气液分离器（R0301B）表1.17 还原反应器气液分离器进出料流股表序号组分名称质量流量kg/hr进料流股出料流股1出料流股2温度/176.95105105压力/bar9.89.89.8气相分率1101CO240456.0940058.75397.342SO2843.83815.6528.183H2O5.061.093.974CO749.22747.691.535S14738.37014738.37合计56792.5741623.1815169.38序号组分名称质量分率进料流股出料流股1出料流股2温度/176.95105105压力/bar9.89.89.8气相分率1101CO20.71230.96240.02622SO20.01490.01960.00193H2O0.000100.00034CO0.01320.01800.00015S0.25950.00000.9716合计1111.4 第四工段物料衡算1.4.1 连续搅拌釜式反应器（R0401）表1.18 釜式反应器进出料流股表序号组分名称质量流量kg/hr进料流股1进料流股2出料流股温度/220260260压力/bar9.79921.01331.0133气相分率1001CO2397.350397.352SO228.18028.173H2O3.9703.964CO1.5301.535S14738.4007089.426FeCl2014.7214.727(NH4)2S2O8058.8758.878IS007648.94合计15169.4273.5915242.97序号组分名称质量分率进料流股1进料流股2出料流股温度/220260260压力/bar9.79921.01331.0133气相分率1001CO20.026200.02612SO20.001900.00183H2O0.000300.00034CO0.000100.00015S0.971600.46516FeCl200.20.00107(NH4)2S2O800.80.00398IS000.5018合计1111.4.2 急冷塔（T0401）表1.19 急冷塔进出料流股表序号组分名称质量流量kg/hr进料流股1进料流股2出料流股温度/2602525压力/bar1.01331.01331.0133气相分率0001CO2397.350397.352SO228.17028.173H2O3.961500015153.964CO1.5301.535S7089.4207089.426FeCl214.72014.727(NH4)2S2O858.87058.878IS7648.9407648.94合计14014.91500030392.97序号组分名称质量分率进料流股1进料流股2出料流股温度/2602525压力/bar1.01331.01331.0325气相分率0001CO20.026100.01312SO20.001800.00093H2O0.000310.49864CO0.000100.00015S0.465100.23336FeCl20.001000.00057(NH4)2S2O80.003900.00198IS0.501800.2517合计1111.4.3 过滤机（FI-0401）表1.20 过滤机进出料流股表序号组分名称质量流量kg/hr进料流股1进料流股2出料流股温度/2602525压力/bar1.01331.01331.0133气相分率0001CO2397.35396.950.402SO228.1728.140.033H2O15153.9615138.8115.154CO1.531.5305S7089.420.717088.716FeCl214.7214.700.017(NH4)2S2O858.8758.810.068IS7648.940.767648.18合计30392.9715640.4314752.54序号组分名称质量分率进料流股出料流股1出料流股2温度/2602525压力/bar1.01331.01331.033气相分率0001CO20.01310.02540.00002SO20.00090.00180.00003H2O0.49860.96790.00104CO0.00010.00010.00005S0.23330.00000.48056FeCl20.00050.00090.00007(NH4)2S2O80.00190.00380.00008IS0.25170.00000.5184合计1111.4.4 干燥机（D-0401）表1.21 干燥机进出料流股表序号组分名称质量流量kg/hr进料流股出料流股1出料流股2温度/2525200压力/bar1.01331.01331.0133气相分率0011CO20.400.000.402SO20.030.000.033H2O15.150.0215.144CO00.000.005S7088.717088.710.006FeCl20.010.000.017(NH4)2S2O80.060.000.068IS7648.187648.180.00合计1291014736.9015.64序号组分名称质量分率进料流股出料流股1出料流股2温度/2525200压力/bar1.01331.01331.0133气相分率0011CO20.00000.00000.02542SO20.00000.00000.00183H2O0.00100.00000.96804CO0.00000.00000.00015S0.48050.48100.00006FeCl20.00000.00000.00097(NH4)2S2O80.00000.00000.00388IS0.51840.51900.0000合计1111.4.5 萃取釜(M-0401)表1.22 萃取釜进出料流股表序号组分名称质量流量kg/hr进料流股1进料流股2出料流股温度/255.080压力/bar1.01331.11460.5066气相分率0001CO20.0000.002SO20.0000.003H2O0.0200.024CO0.0000.005S7088.7107092.986FeCl20.0000.007(NH4)2S2O80.0000.008IS7648.183.567648.949CS20.0083999.5083999.80合计14736.9084003.0698741.74序号组分名称质量分率进料流股1进料流股2出料流股温度/255.080压力/bar1.01331.11460.5066气相分率0001CO20.0000002SO20.0000003H2O0.000000.00004CO0.0000005S0.481000.07186FeCl20.0000007(NH4)2S2O80.0000008IS0.519000.07759CS20.000010.8507合计1111.4.6 过滤机(FI-0402)1.23 过滤机进出料流股表序号组分名称质量流量kg/hr进料流股出料流股1出料流股2温度/02525压力/bar5.0664.0534.053气相分率0001CO20.00002SO20.00003H2O0.0200.024CO0.00005S7092.9870.937022.056FeCl20.000.0007(NH4)2S2O80.000.0008IS7648.947648.9409CS283999.80840.0083159.80合计98741.748559.8790181.87序号组分名称质量分率进料流股出料流股出料流股2温度/02525压力/bar5.0664.0534.053气相分率0001CO20002SO20003H2O0.00000.00000.00004CO0005S0.07180.00830.07796FeCl20007(NH4)2S2O80008IS0.07750.893609CS20.85070.09810.9221合计1111.4.7 干燥机(M-0402)1.24 干燥机进出料流股表序号组分名称质量流量kg/hr进料流股出料流股1出料流股2温度/25200200压力/bar4.0531.01331.0133气相分率0001CO20002SO20003H2O000.004CO0005S70.9370.220.716FeCl20.00007(NH4)2S2O80.00008IS7648.947572.4576.499CS2840.008.40831.60合计8559.877651.07908.80序号组分名称质量分率进料流股出料流股1出料流股2温度/25200200压力/bar4.0531.01331.0133气相分率0001CO20002SO20003H2O0.000000.00004CO0005S0.00830.00920.00086FeCl20007(NH4)2S2O80008IS0.89360.98970.08429CS20.09810.00110.9151合计1111.4.8 萃取剂闪蒸罐（V-0402）1.25 萃取剂闪蒸罐进出料流股表序号组分名称质量流量kg/hr进料流股出料流股1出料流股2温度/256464压力/bar4.0531.0331.033气相分率0101CO20002SO20003H2O0.020.0204CO0005S7022.053.567018.496FeCl20007(NH4)2S2O80008IS0009CS283159.8082546.00616.78合计90181.8782546.887635.27序号组分名称质量分率进料流股出料流股1出料流股2温度/256464压力/bar4.0531.0331.033气相分率0101CO20002SO20003H2O0.00000.000004CO0005S0.07790.00000.91926FeCl20007(NH4)2S2O80008IS0009CS20.92211.00000.0808合计1111.5 第五工段物料衡算1.5.1 二效催化反应器（R0501）表1.26 二效催化反应器进出料流股表序号组分名称质量流量kg/hr进料流股1进料流股2出料流股温度/104.1525120压力/bar314气相分率1011N25085367.8605085704.8672O2470583.160470541.81083CO22178370.6502179543.1114SO21444.6901444.761245NO25647.5005647.496916NO736.69014.733841447HCL895.160895.15893848HF491.180491.18320689H2O1.09294857.001.08924563110CO747.6901.477267067合计7744285.68294857.007744285.69序号组分名称质量分率进料流股1进料流股2出料流股温度/104.1525120压力/bar314气相分率1011N20.656700.65672O20.060800.06083CO20.281300.28144SO20.000200.00025NO20.000700.00076NO0.000100.00007HCL0.000100.00018HF0.000100.00019H2O0.00001010CO0.000100合计1111.5.2 尾气吸收塔（T0501）表1.27 尾气吸收塔进出料流股表序号组分名称质量流量kg/hr进料流股1进料流股2出料流股1出料流股2