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Journal of Thermal Science and Technology Vol.3, No.1, 2008 Numerical Study of Heat Transfer Mechanism in Turbulent Supercritical CO2Channel Flow Xinliang LI, Katsumi HASHIMOTO, Yasuhiro TOMINAGA, Mamoru TANAHASHIand Toshio MIYAUCHI Department of Mechanical and Aerospace Engineering, Tokyo Institute of Technology 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8550, Japan E-mail: mtanahasmes.titech.ac.jp LNM, Institute of Mechanics, Chinese Academy of Sciences No. 15, Beisihuanxi-Road, Beijing, 100080, China Central Research Institute of Electric Power Industry 2-6-1, Nagasaka,Yokosuka-shi, Kanagawa 240-0196, Japan Abstract Direct numerical simulation (DNS) of supercritical CO2 turbulent channel fl ow has been performed to investigate the heat transfer mechanism of supercritical fl uid. In the present DNS, full compressible Navier-Stokes equations and Peng-Robison state equation are solved. Due to eff ects of the mean density variation in the wall normal direction, mean velocity in the cooling region becomes high compared with that in the heating region. The mean width between high- and low-speed streaks near the wall decreases in the cooling region, which means that turbulence in the cooling region is enhanced and lots of fi ne scale eddies are created due to the local high Reynolds number eff ects. From the turbulent kinetic energy budget, it is found that compress- ibility eff ects related with pressure fl uctuation and dilatation of velocity fl uctuation can be ignored even for supercritical condition. However, the eff ect of density fl uctuation on turbulent kinetic energy cannot be ignored. In the cooling region, low kinematic viscosity and high thermal conductivity in the low speed streaks modify fi ne scale structure and turbulent transport of temperature, which results in high Nusselt number in the cooling condition of the supercritical CO2. Keywords: Turbulent Heat Transfer, Supercritical Flow, Direct Numerical Simulation, Turbulent Channel Flow 1. INTRODUCTION The supercritical fl uid has both gas-like and liquid-like properties, and it is frequently used in many industrial applications such as chemical process and food production. Since the supercritical fl uid shows very strong heat transport capability near its pseudo-critical point, it is considered to be a good working fl uid in heat transfer. For example, in supercritical water-cooled reactor, the supercritical water is used as the medium of heat transfer instead of liquid water. The supercritical water-cooled reactor has higher heat transfer effi ciency, less complexity and more compact than the normal light water reactor(1). Similar to supercritical water, supercritical CO2is also one kind of promising heat transfer medium. Since the critical temperature of CO2(about 304K or 31C) is near normal temperature, it is a good refrigerant in hot water heating. Moreover, a CO2heat pump for domestic hot tap water supplier with high heat transfer effi ciency has been developed and commercialized in Japan. As addressed in Hashimoto et al.(2), to develop higher performance and further compact heat pump, high- pressure side heat exchanger of the CO2heat pump should have better performance and be smaller than conventional one. Therefore, it is very important to understand the heat transfer Received 12 Nov., 2007 (No. 07-0702) DOI: 10.1299/jtst.3.112 112 Journal of Thermal Science and Technology Vol.3, No.1, 2008 mechanism of supercritical fl ow. In many cases, the supercritical fl ows are in turbulent or transitional state and the fl uid fl ow is rather complicated. However, the research works on turbulent (or transitional) supercritical fl ow are very rare until now, and the research on tur- bulent supercritical fl ow is very useful to improve the industrial applications of supercritical fl uid. Direct numerical simulation (DNS) plays an important role in study of turbulent fl ow as a strong research tool. However, the DNS study of supercritical turbulent fl ow is very few because of its complexity. Hashimoto et al.(2)have conducted DNS of supercritical CO2tur- bulent channel fl ow, and investigated the near-wall heat transfer mechanism. In their DNS, eff ects of drastic change of Prandtl number and viscosity near the pseudo-critical point are considered under the incompressible assumption where the eff ects of density variation are ne- glected. DNS of turbulent CO2 fl uid at supercritical pressure in heated vertical tubes has been performed by Bae et al.(3)with low Mach number approximation. In their work, temperature range includes the pseudo-critical region and buoyancy eff ects on turbulent statistics were in- vestigated. It should be noted that low Mach number approximation can not represent acoustic interactions and compressibility eff ect exactly. In this research, DNS of supercritical CO2 turbulent channel fl ow is performed to inves- tigate the turbulent heat transfer mechanism of supercritical fl ow. Full compressible Navier- Stokes equations are solved with temperature dependence of physical properties of CO2. DNS of full compressible Navier-Stokes equation takes an advantage that all compressibility eff ects can be considered. However, DNS is suff ered by the severe time step restriction as addressed in Bae et al.(3). Since the background of this study is development of the supercritical CO2 domestic heat pump with high effi ciency, the temperature range in this DNS is chosen within normal temperature, and forced convective heat transfer is focused by neglecting buoyancy eff ects. 2. NUMERICAL METHOD Full compressible Navier-Stokes equations and energy conservation equation are solved to take into account temperature dependence of thermal and transport properties of the su- percritical fl uid. Followings are continuity, Navier-Stokes and energy conservation equations analyzed in this study. t + ( ui) xi = 0,(1) ui t + uj ui xj = p xi + ij xj + fi,(2) ? h t + uj h xj ? = xj ? k T xj ? + ui xj ji+ p t + uj p xj + fiui,(3) where ij is the shear stress tensor defi ned as ij= ? ui xj + uj xi 2 3 uk xk ij ? ,(4) and h = e + p/ is the enthalpy. fi= f i1 is a uniform body force to drive the channel fl ow. Since, the pressure fl uctuation is very low because of low Mach number, the enthalpy can be assumed only the function of temperature, i.e. h = h(P0, T), where P0is 8MPa in this study. The term p/ t in Eq. 3 can be ignored by the same reason. Considering cp= ( h/ T)p, the energy equation (Eq. 3) can be rewrited as following: cp ? T t + uj T xj ? = xj ? k T xj ? + ui xj ji+ uj p xj + fiui.(5) 113 Journal of Thermal Science and Technology Vol.3, No.1, 2008 Table 1NUMERICAL PARAMETERS IDRemMamTwT0Lx Ly LzNx Ny Nz Case 128000.2311.15K 321.15K316.15K48 2 2 2304 193 160 Case 228000.2309.15K 319.15K314.15K48 2 2 2880 256 192 Fig. 1Thermal conductivity and viscosity for CO2at P = 8MPa. Theaboveconservationequationsshouldbesolvedwiththestateequationwhichgivespressure- density-temperature relationship. The following Peng-Robinson equation(4)is used to esti- mate pressure from density and temperature. p = RT Vm b a V2 m+ 2bV2m b2 ,(6) where Vmrepresents the molar volume and Vm= (0.044 kg/mol)/for CO2. R = 8. 314472 J/(mol K) is the universal gas constant. Other parameters are given as follows: = 1 + (0. 37464 + 1. 54226 0. 26992 2)(1 T0. 5 r )2, Tr= T/ Tc, a = 0. 45724R2T2 c/ pc, b = 0. 07780RTc/ pc, where Tc= 304. 1282K is the critical temperature and pc= 7. 3773MPa is the critical pres- sure. The acentric factor in the Peng-Robinson equation is tuned according to experimental data(5) , and set to be = 0. 3 in this DNS. Since the pressure fl uctuation is very small relative to mean pressure (8MPa), the transport and thermal properties such as viscosity ( ), specifi c heat (cp) and thermal conductivity (k) are assumed to be only the function of temperature, i.e. = (P0, T), cp= cp(P0, T), and k = k(P0, T), where P0= 8MPa in this study. Parti- tion parabolic interpolation equations are introduced to calculate these properties. In Fig. 1, thermal conductivity and viscosity predicted by the interpolation are compared with those by Span et al.(5). The interpolated values agree well with the results of Span et al.(5)including near the pseudo-critical point. To approximate the convective terms in momentum and energy equations, 7th-order up- wind fi nite diff erence scheme is used. For other terms, 8th-order central fi nite diff erence scheme is used. Time advancement is implemented by a 3rd-order TVD type Runge-Kutta scheme(6). 3. DIRECT NUMERICAL SIMULATION The channel is assumed to be full with supercritical CO2at 8MPa. The periodic condi- tionsareadoptedinstreamwiseandspanwisedirectionsbyapplyingperiodicwall-temperature in the streamwise direction. Two cases are computed in this research. The diff erence between the two cases is the wall temperature. The distribution of wall temperatures Tware shown in Fig. 2. Twis set to be the maximum value in 4 x 20and the minimum value in 28 x 44 . The maximum wall temperature is 321.15K for case1 and 319.15K for case2, 114 Journal of Thermal Science and Technology Vol.3, No.1, 2008 Fig. 2Distribution of wall temperature. Fig. 3Distribution of friction Reynolds number in streamwise directions for case1. and the minimum wall temperature is 311.15K for case1 and 309.15K for case2. DNS is conducted for the temperature range higher than the pseudo-critical temperature for the both cases. Uniform body force is applied to drive the fl ow. The magnitude of the body force is set to be that for Re= 180 (Rem = 2800) in incompressible channel fl ow. The numerical param- eters are shown in Table 1. Here, Rem is Reynolds number defi ned by the mean bulk velocity um, the mean density m, the channel half width and the viscosity at mean temperature T0. Mam is the Mach number defi ned by umand the sound speed at T0. T0denotes mean tem- perature of the maximum and minimum wall temperature. In the streamwise direction, length of the computational domain is chosen enough to investigate eff ects of variable density and physical properties on the turbulence structure and heat transfer. DNS was conducted until statistically steady state. 4. TURBULENCE STATISTICS In the present DNS, friction Reynolds number(Re) is not constant in the streamwise direction. Figure 3 shows streamwise variation of Refor case1. Since the added body force corresponds to Re= 180 for the incompressible case, Re in Fig. 3 fl uctuates near 180. From thecharacteristicsofCO2nearthepseudo-criticalpointasshowninFig. 1, kinematic viscosity ( = / ) is low in the cooling region (28 x 44 ). Therefore, Rein the cooling region is higher than that in the heating region. Figure 4 shows mean streamwise velocity profi le and Van Direst mean velocity profi le at x = 15. 9(in the heating region) and x = 41. 4(in the cooling region) for case1. The Van Direst mean velocity is defi ned as U+ VD= ? u+ 0 ? / wdu+. (7) The meanvelocityinthecoolingregionismuchhigherthanthatintheheatingregion, whereas the Van Direst velocities in two regions agree with each other. These facts suggest that the 115 Journal of Thermal Science and Technology Vol.3, No.1, 2008 Fig. 4 Profi les of mean velocity and Van Dirst mean velocity for case1. Fig. 5 Profi les of r. m. s. of velocity fl uctuations for case1. Fig. 6Autocorrelation function of u?in spanwise direction at y+5 for case1. mean velocities are aff ected by the density variation, but not by acoustic eff ects or intrinsic compressibility eff ects. Figure 5 shows the r. m. s. of velocity fl uctuations normalized by local u at x = 15. 9and x = 41. 4for case1. The r. m. s. of velocity fl uctuations in the cooling region is higher than that in the heating region. Therefore, turbulent motion is enhanced in the cooling region and is depressed in the heating region. As turbulent intensities are normalized by local u , the diff erence between heating and cooling region can not be explained only from physical properties of supercritical CO2. To interpret this phenomena, turbulent structures should be discussed. As one of the important near-wall structures, high- and low-speed streaks are well- known. Themeanwidthofthestreakscanbeestimatedfromautocorrelationofthestreamwise velocity fl uctuation. Figure 6 shows two-points autocorrelation function of streamwise veloc- ity fl uctuation at y+5 for case1. From the location of the minimum value, the mean space between the high- and low-speed streak is estimated to l+= 53. 5(l = 0. 31 ) in the heating region and l+= 49. 2(l = 0. 27 ) in the cooling region. This decreasing shows that there are more streaks in the cooling region. It has been shown that near-wall streamwise eddies, which 116 Journal of Thermal Science and Technology Vol.3, No.1, 2008 Fig. 7Distribution of u? ? T? ?correlations for case1. is one of coherent fi ne scale eddies(7), tend to exist near boundary of high- and low-speed streaks. Therefore, the increase of streaks suggests that lots of the coherent fi ne scale eddies appear. Since the near-wall coherent fi ne scale eddy has an important role in turbulent heat transfer, the increasing of the coherent fi ne scale eddy enhances the heat transfer ability of the supercritical fl ow. Figure 7 shows correlation coeffi cients between streamwise velocity fl uctuation and tem- perature fl uctuation for case1. The correlations are evaluated from fl uctuations based on a density-weighted average (Favre average defi ned in the next section). There are strong nega- tive correlations in the heating regions and strong positive correlations in the cooling regions, especially, in the near wall regions. This result means that high-speed streaks have low lo- cal temperatures in the heating region, and high-speed streaks have high local temperatures in the cooling region. This correlation of turbulent supercritical fl ow is diff erent from that of ordinary compressible turbulence. In the ordinary compressible wall turbulence under the adi- abatic wall condition, the u? ?T? ?correlation is always negative according to strong Reynolds analogy (SRA) theory(8). In the cases of unilateral cooling and heating, low speed streaks tends to be near the wall temperature. 5. TURBULENT KINETIC ENERGY BUDGET The transport equation for turbulent kinetic energy in compressible fl ows is written as follow: ( K) t +C = P + T + t+ d+ D + M ,(8) where K and C denote the turbulent kinetic energy and convection terms defi ned by K = 1 2 u? ? i u? ? i , C = ( uj K) xj . As for other terms in Eq. 8, P, T, t, d,D,M and are the production term, the tur- bulent diff usion term, the pressure diff usion term, the pressure-dilatation term, the viscous diff usion term, the term associated with density fl uctuations and the viscous dissipation term, respectively. Each term is defi ned as follow: P = u? ? i u? ? j ui xj , T = 1 2 xj ( u? ? i u? ? i u? ? j), t= xj (p?u? ? j), 117 Journal of Thermal Science and Technology Vol.3, No.1, 2008 Fig. 8Distribution of turbulent kinetic energy production term (P), viscous dissipation term ( ), viscous diff usion term (D) and turbulent transport term (T). Fig. 9Distribution of pressure dilatation term (d), dilatation dissipation term (? d) and the term associated with density fl uctuation (M). d= p? u? ? i xi , M = u? ? i ? ij xj p xi ? , D = xi u? ? i ? ij, = ? ij u? ? i xj . In the above expressions,represents the Favre average of (= / ), and ?= , ? ?= are the fl uctuations based on Reynolds average and Favre average, respectively. Turbulent kinetic energy budget at x = 15. 9 (heating region) and 41. 4 (cooling region) are evaluated in this study. The production term, viscous dissipation term, viscous diff usion term and turbulent diff usion term are dominant in the energy equation, and other terms are small relative to these four terms. In Fig. 8, the dominant four terms are compared in the cooling and heating regions for the two cases. This balance of the energy budget is similar to those of incompressible turbulence(7),(9),(10). It should be noted that the convection terms are not exactly zero for the present case because of the periodic cooling and heating in the streamwise direction. However, the results of DNS show that the convection terms are very small compared with the major terms. The production term and viscous dissipation terms show large magnitude in the cooling region. In the buff er layer (y+10 30), the increase of the production term balances with that of the viscous dissipation term, which implies that turbulence structure in the buff er layer is signifi cantly diff erent in the cooling and heating region. Near the wall, the viscous diff usion term in the cooling region is larger than that in 118 Journal of Thermal Science and Technology Vol.3, No.1, 2008 Fig. 10Distribution of Nusselt number for case1. (x?= x 4 in the heating region, x?= x 28 in the cooling region) Fig. 11 Distribution of turbulent heat fl ux for case1. the heating region due to viscosity variation. Note that oscillations in Fig. 8 is caused by short average time due to the huge DNS, and will disappear if the average was taken in longer time. In variable density turbulent fl ows, the pressure-dilatation term, dilatation dissipation term, which is included in the viscous dissipation term ( ), and the term associated with den- sity fl uctuation have possibilities to change the energy budget. The dilatation dissipation term is defi ned as follow: d= 4 3 ? u? ? i xi ?2 .(9) In Fig. 9, these three terms are shown in the cooling and heating region for the two cases. Both of pressure dilatation and dilatation dissipatio

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