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Risk PhrasesIndication of Particular RisksR1:Explosive when dry2:Risk of explosion by shock, friction, fire or other sources of ignition3:Extreme risk of explosion by shock, friction, fire or other sources of ignition4:Forms very sensitive explosive metallic compounds5:Heating may cause an explosion6:Explosive with or without contact with air7:May cause fire8:Contact with combustible material may cause fire9:Explosive when mixed with combustible material10:Flammable11:Highly Flammable12:Extremely Flammable14:Reacts violently with water15:Contact with water liberates extremely flammable gases16:Explosive when mixed with oxidizing substances17:Spontaneously flammable in air18:In use may form flammable/explosive vapor-air mixture19:May form explosive peroxides20:Harmful by inhalation21:Harmful in contact with skin22:Harmful if swallowed23:Toxic by inhalation24:Toxic in contact with skin25:Toxic if swallowed26:Very Toxic by inhalation27:Very Toxic in contact with skin28:Very Toxic if swallowed29:Contact with water liberates toxic gas30:Can become highly flammable in use31:Contact with acids liberates toxic gas32:Contact with acids liberates very toxic gas33:Danger of cumulative effects34:Causes burns35:Causes severe burns36:Irritating to the eyes37:Irritating to the respiratory system38:Irritating to the skin39:Danger of very serious irreversible effects40:Limited evidence of a carcinogenic effect41:Risk of serious damage to eyes42:May cause sensitization by inhalation43:May cause sensitization by skin contact44:Risk of explosion if heated under confinement45:May cause cancer46:May cause heritable genetic damage48:Danger of serious damage to health by prolonged exposure49:May cause cancer by inhalation50:Very Toxic to aquatic organisms51:Toxic to aquatic organisms52:Harmful to aquatic organisms53:May cause long-term adverse effects in the aquatic environment54:Toxic to flora55:Toxic to fauna56:Toxic to soil organisms57:Toxic to bees58:May cause long-term adverse effects in the environment59:Dangerous for the ozone layer60:May impair fertility61:May cause harm to the unborn child62:Possible risk of impaired fertility63:Possible risk of harm to the unborn child64:May cause harm to breast-fed babies65:Harmful: May cause lung damage if swallowed66:Repeated exposure may cause skin dryness or cracking67:Vapors may cause drowsiness and dizziness68:Possible risk of irreversible effectsRisk PhrasesCombination of Particular Risks14/15:Reacts violently with water, liberating extremely flammable gases15/29:Contact with water liberates toxic, extremely flammable gas20/21:Harmful by inhalation and in contact with skin20/21/22:Harmful by inhalation, in contact with skin and if swallowed20/22:Harmful by inhalation and if swallowed21/22:Harmful in contact with skin and if swallowed23/24:Toxic by inhalation and in contact with skin23/24/25:Toxic by inhalation, in contact with skin and if swallowed23/25:Toxic by inhalation and if swallowed24/25:Toxic in contact with skin and if swallowed26/27:Very Toxic by inhalation and in contact with skin26/27/28:Very Toxic by inhalation, in contact with skin and if swallowed26/28:Very Toxic by inhalation and if swallowed27/28:Very Toxic in contact with skin and if swallowed36/37:Irritating to eyes and respiratory system36/37/38:Irritating to eyes, respiratory system and skin36/38:Irritating to eyes and skin37/38:Irritating to respiratory system and skin39/23:Toxic: danger of very serious irreversible effects through inhalation39/23/24:Toxic: danger of very serious irreversible effects through inhalation in contact with skin39/23/24/25:Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed39/23/25:Toxic: danger of very serious irreversible effects through inhalation and if swallowed39/24:Toxic: danger of very serious irreversible effects in contact with skin39/24/25:Toxic: danger of very serious irreversible effects in contact with skin and if swallowed39/25:Toxic: danger of very serious irreversible effects if swallowed39/26:Very Toxic: danger of very serious irreversible effects through inhalation39/26/27:Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skin39/26/27/28:Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed39/26/28:Very Toxic: danger of very serious irreversible effects through inhalation and if swallowed39/27:Very Toxic: danger of very serious irreversible effects in contact with skin39/27/28:Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowed39/28:Very Toxic: danger of very serious irreversible effects if swallowed42/43:May cause sensitization by inhalation and skin contact48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation48/20/21:Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin48/20/21/22:Harmful: danger of serious damage to health by prolonged exposure through inhalation, and in contact with skin and if swallowed48/20/22:Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed48/21:Harmful: danger of serious damage to health by prolonged exposure in contact with skin48/21/22:Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed48/22:Harmful: danger of serious damage to health by prolonged exposure if swallowed48/23:Toxic: danger of serious damage to health by prolonged exposure through inhalation48/23/24:Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin48/23/24/25:Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed48/23/25:Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed48/24:Toxic: danger of serious damage to health by prolonged exposure in contact with skin48/24/25:Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed48/25:Toxic: danger of serious damage to health by prolonged exposure if swallowed50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment68/20:Harmful: possible risk of irreversible effects through inhalation68/20/21:Harmful: possible risk of irreversible effects through inhalation and in contact with skin68/20/21/22:Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed68/20/22:Harmful: possible risk of irreversible effects through inhalation and if swallowed68/22:Harmful: possible risk of irreversible effects if swallowed68/21:Harmful: possible risk of irreversible effects in contact with skin68/21/22:Harmful: possible risk of irreversible effects in contact with skin and if swallowed68/22:Harmful: possible risk of irreversible effects if swallowedSafety PhrasesIndication of Safety PrecautionsS1:Keep locked up2:Keep out of the reach of children3:Keep in a cool place4:Keep away from living quarters5:Keep contents under . (appropriate liquid to be specified by the manufacturer)6:Keep under . (inert gas to be specified by the manufacturer)7:Keep container tightly closed8:Keep container dry9:Keep container in a well-ventilated place12:Do not keep the container sealed13:Keep away from food, drink and animal feeding stuffs14:Keep away from . (incompatible materials to be indicated by the manufacturer)15:Keep away from heat16:Keep away from sources of ignition - No smoking17:Keep away from combustible material18:Handle and open container with care20:When using, do not eat or drink21:When using, do not smoke22:Do not breathe dust23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)24:Avoid contact with skin25:Avoid contact with eyes26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice27:Take off immediately all contaminated clothing28:After contact with skin, wash immediately with plenty of . (to be specified by the manufacturer)29:Do not empty into drains30:Never add water to this product33:Take precautionary measures against static discharges35:This material and its container must be disposed of in a safe way36:Wear suitable protective clothing37:Wear suitable gloves38:In case of insufficient ventilation, wear suitable respiratory equipment39:Wear eye/face protection40:To clean the floor and all objects contaminated by this material use . (to be specified by the manufacturer)41:In case of fire and/or explosion do not breathe fumes42:During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified)43:In case of fire, use . (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)46:If swallowed, seek medical advice immediately and show this container or label47:Keep at temperature not exceeding . E C (to be specified by the manufacturer)48:Keep wetted with . (appropriate material to be specified by the manufacturer)49:Keep only in the original container50:Do not mix with . (to be specified by the manufacturer)51:Use only in well-ventilated areas52:Not recommended for interior use on large surface areas53:Avoid exposure - obtain special instruction before use56:Dispose of this material and its container to hazardous or special waste collection point57:Use appropriate container to avoid environmental contamination59:Refer to manufacturer/supplier for information on recovery/recycling60:This material and/or its container must be disposed of as hazardous waste61:Avoid release to the environment. Refer to special instructions safety data sheet62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label63:In case of accident by inhalation, remove casualty to fresh air and keep at rest64:If swallowed, rinse mouth with water (only if the person is conscious)Safety PhrasesCombination of Safety Precautions1/2:Keep locked up and out of the reach of children3/7:Keep container tightly closed in a cool place3/9/14:Keep in a cool well-ventilated place away from . (incompatible materials to be indicated by manufacturer)3/9/14/49:Keep only in the original container in a cool well-ventilated place away from . (incompatible materials to be indicated by manufacturer)3/9/49:Keep only in the original container in a cool well-ventilated place3/14:Keep in a cool place away from . (incompatible materials to be indicated by the manufacturer)7/8:Keep container tightly closed and dry7/9:Keep container tightly closed and in a well-ventilated place7/47:Keep container tightly closed and at a temperature not exceeding . C (to be specified by manufacturer)20/21:When using, do not eat, drink or smoke24/25:Avoid contact with skin and eyes27/28:After contact with skin, take off immediately all contaminated clothing and wash imediately with plenty of. (to be specified by the manufacturer)29/35:Do not empty into drains, dispose of this container and its material in a safe way29/56:Do not empty into drains, dispose of this material and its container to hazardous or special waste-collection point36/37:Wear suitable protective clothing and gloves36/37/39:Wear suitable protective clothing, gloves and eye/face protection36/39:Wear suitable protective clothing and eye/face protection37/39:Wear suitable gloves and eye/face protection47/49:Keep only in the original container at temperature not exceeding . C (to be specified by manufacturer)FLUKA BRAND F CODES F 1 Sensitive to air and humidity.F 2 Sensitive to air and CO2.F 3 Hygroscopic.F 4 Do not heat over C. 1 = 10 C 2 = 20 C 3 = 30 C 4 = 40

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