氯化橡胶涂料在集装箱行业的应用

1、 集装箱涂料相关标准集装箱涂料相关标准3 集装箱行业介绍集装箱行业介绍1氯化橡胶类涂料的缺陷及改进要求氯化橡胶类涂料的缺陷及改进要求4 集装箱涂装配套集装箱涂装配套2雏形雏形创立创立成长成长 成熟成熟1801 Dr. James AndersonWord War IIWeapons Transportation19561966Aril 26th,1956“Macedonia”(Pan-Atlantic Steamship Co.)Oct. 1957“Gateway City”19661980sConstruction of Container Terminal“Door to Door”Int

2、ernationalSystematic1980sContainerization, more than 80%Joint Venture Global Alliance1970s Starting in USA, and soon transferred to Europe中国韩国/台湾日本日本欧美欧美1970s1980s, Japan took over the baton1980s1990s, Korea was the main force in the container manufacturing1990s, More than 95% of container were prod

3、ucted in ChinaApril, 1955 Short-term trial operation1973 Maritime container trasportSept. 1973 1st international container1970s起步起步1980s成长成长1990s发展发展世界世界集装箱集装箱运输和运输和制造业制造业焦点焦点2011年全世界年全世界10个最大的集装箱港口中，有个最大的集装箱港口中，有6个在中国个在中国上海上海(1), 香港香港(3),深圳深圳(4),宁波宁波(6),青岛青岛(7),广州广州(8)中远中远COSCO, 中海中海China Shipping,

4、 东方海外东方海外OOCL(Hong Kong), 长荣长荣Evergreen(Taiwan)a，万海，万海Wan Hai(Taiwan) 等公司位居世界航运公司前等公司位居世界航运公司前20强。强。近年来集装箱产量在目前的管理水平下，每TEU集装箱约使用油漆65Kg。集装箱涂料市场份额集装箱结构 涂料品种涂料品种干膜厚度（干膜厚度（m）内表面内表面外表面外表面1环氧富锌车间底漆环氧富锌车间底漆10102环氧富锌底漆环氧富锌底漆20203环氧内面漆环氧内面漆454环氧中间漆环氧中间漆405丙烯酸面漆（氯化橡胶面漆）丙烯酸面漆（氯化橡胶面漆）40合计合计75110涂料 1960 1980 199

5、0 2004面漆醇酸氯化橡胶氯化橡胶 丙烯酸中间漆环氧底漆醇酸等氯化橡胶氯化橡胶环氧环氧富锌With the improvment of container owners requirment, the coating system tend to a uniform, which is “epoxy zinc rich primer+epoxy mid-coat+acrylic top-coat”.品种氯化橡胶丙烯酸防腐性好稍差施工性差好柔韧性好差成本稍高较低l 柔韧性差l 防腐性略差盐雾600hr 氯化橡胶面漆 丙烯酸面漆 环保问题 柔韧性-增韧剂的选择 施工性能遇水泛白 施工性能修补时的

6、色差施工性能 修补时的色差 光泽差异造成造成视觉色差 咬底 当用醇酸树脂作为增塑剂时，堆场修补（下线8小时至24小时）会出现咬底，影响施工进度。施工性能遇水泛白 采用环保的方法生产氯化橡胶树脂 降低成本 选用合适的增塑剂TestTest methodEvolution & RequirementResultScoreAbrasion resistanceASTM D 10441000cycles, 250g, CS 10 wheel0-1011-25251086Corrosion resistanceRust from scribe markASTM B117ASTM 165401.0mm2.

7、0mm3.0mm4.0mm5.0mm6.0mm10876544BlisterASTM B117ASTM 1654None1-23-78-1011-2526-401077643TestTest methodEvolution & RequirementResultScoreAccelerated weatheringColor changeASTM E 42(600hr)ASTM D 2244E2E3106Loss in glossASTM E 42(600hr)ASTM D 5230-10%11-24%25%1086FlexibilityASTM D 1713180 deg. 12.5mmOr

8、iginalNo crackingSlight crackingCracking1051After accelerated weathering(600hr)No crackingSlight crackingCracking1051TestTest methodEvolution & RequirementResultScoreAdhesionDIN 53151划格附着力OriginalNo removal5% removal15% removal35% removal50% removal108642After accelerated weathering(600hr)No removal

9、5% removal15% removal35% removal50% removal108642Salt water resistance5%NaCl,168hr,25No effectSlight dullingBlistering and/or other defects1062TestTest methodEvolution & RequirementResultScoreImpact resistanceASTM 2794Cm-Kg at FailureOriginal7563-7450-625010864After accelerated weathering(600hr)7563

10、-7450-625010864HardnessASTM D 3363(Pencil scratch)Oxidized and catalyzed coatings6H5H4H3H10642Evaporation coatings4H3H2HH10864IICL全称为国际集装箱出租商协会全称为国际集装箱出租商协会 成立于1971年，本部设立于华盛顿，随着第一代集装箱和集装箱船的快速发展，集装箱的安全和质量成为集装箱货运体系中至关重要的一个环节。在美国，IICL同美国国务院和海岸巡逻队一同制定国际集装箱安全公约（CSC）的各项条款和美国集装箱安全法案 Size:76Size:76* *152152

11、* *1.6mm1.6mmSbustrate:G3101(SS41)Sbustrate:G3101(SS41)Blasted:Sa2 Blasted:Sa2 RoughRough：25-40 Rmax 8025-40 Rmax 808h UV at 60 （UVA340） 4h condensation at 50 Repeat sub cycle for 72hrs4h wet at 302h dry at 40 Repeat sub cycle for 96hrs4h wet at 302h dry at 40 Repeat sub cycle for 96hrs8h dry/dark a

12、t 60 4h condensation (100%RH)at 60 Repeat sub cycle for 72hrsNo.10No.8No.6No.4No.2None20Few151050Medium1050Medium Dense50Dense0Rust GradeUnit ValueGrade 1010Grade 99Grade 86Grade 73Grade 60Average Scribe CreepUnit Value0-1mm102-3mm94-6mm77-9mm510-11mm311mm0ASTM ClassificationUnit Value5B154B123B72B3

13、1B or 0B2Kg M at FailureUnit Value0.23100.17-0.2280.12-0.1660.06-0.1140.03-0.0520. 02 or Less0Kg M at FailureUnit Value0.58100.52-0.5790.46-0.5180.40-0.4570.35-0.3960.29-0.3450.28 or Less0Weight LossUnit Value0-100mg15101-150mg12151-200mg9200mg0Color Change（E）Unit Value33425150Gloss ChangeUnit Value

14、0-20%221-30%130%0GroupScribed or notMaxMinTest WeightScore FactorCorrosive Group7555Blister TestUnscribed15%0.75Rusting Test25%2.50Undercutting TestScribe30%3.00Mechanical Group2515Adhesion TestUnscribed15%1.00Impact Test10%1.00Cosmetic Group5NoneColor TestUnscribed3%1.00Gloss Test2%1.00Total For All Test10070100%GroupScribed or notMaxMinTest WeightScore Fac