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1、東東莞莞市市超超華華化化工工有有限限公公司司Material Safety Data Sheet物物質質安安全全資資料料表表MSDS No. 編號:1Product Detail 物物品品與與廠廠商商資資 Name 產品名稱:Non-phthalates Polyvinyl Chloride Compound 環保聚氯乙烯塑膠粒Company Identification 廠廠商商資資 Name 供應商名稱:東莞市超華化工有限公司Tel 電話ax 傳真ddress 地址:常平鎮大京九塑膠市場塑通7路701-703號2Informati
2、on of Ingredients 成成分分辨辨資資 Chemical Name 化學成份:% by ratio 成份比例CAS No 化學文摘社登記號碼:Polyvinyl Chloride 聚氯乙烯45-559002-86-2Plasticizer 增塑劑25-356422-86-2Stabilizer 安定劑1-257583-35-4Calcium Carbonate 碳酸鈣0-1072608-12-93Hazards Identification Emergency Overview 危危害害辨辨資資 At normal situation 在正常情況下:In its manufact
3、ured and transported state the product is considered as non-hazardous 在生產及運輸中, 此產品被視為非危害物質Inhalation 吸入:Exposures to high concentration of vapors may possibly cause lung disorder 如身處或吸入高濃度的產品燒焦或氣化氣體會引致肺部功能不正常運作Eye 眼部接觸:Particulate matter or fumes may cause irritation 產品在氣態, 粉態下接觸可能會引起敏感Skin Contact
4、皮膚接觸:Particulate matter or fumes may cause irritation 產品在氣態, 粉態下接觸可能會引起敏感Skin Absorption 皮膚吸入:Not expected to entry into body 產品不會直接由皮膚進入人體Ingestion 食入:Large quantity of particulate matter may cause intestinal distress. 大量進食可能會引致腸胃不息4First aid measures 急急救救措措施施Inhalation 吸入:Remove exposed person to
5、fresh air in open area 即將患者移到新鮮空氣處If breathing is difficult, oxygen may be administered 如呼吸困難, 需使用氧氣Eye 眼部接觸:Flush with tape water for at least 20 minutes 用大水清洗至少20分鐘Seek medical attention if irritation develops 如敏感持續需要就醫Skin Contact 皮膚接觸:Wash thoroughly with mild soap and running water 以動的水或浴沖洗之,再以
6、水和肥皂或溫和的清潔劑清洗Ingestion 食入:Drink plenty of water immediately 刻給予患者大的水喝Try to vomit after drinking water 喝水後,協助患者以手指伸入喉嚨內催吐5Fire Fighting measures 滅滅火火措措施施Extinguish fire by 適用滅火劑:Carbon Dioxide 二氧化碳、Sand powder 沙堆、Water 水 Help 協助:Products in or near fires should be sprayed with a water. 向燃燒物及其旁邊物品射水B
7、e claim to call fire station. 冷靜致電消防部門Arrange people to exit 幫助他人有序離開現場Caution 注意:Burning of product may emit toxic gases like carbon monoxide, people should keep away from them 產品撚燒時可能會產生有毒氣體如一氧化碳, 現場人員應盡量遠離燃燒物6Accidental Release Measures 洩洩處處方方法法 Reuse released product if not contaminated. If prod
8、uct not reusable, place in approved containers for disposal. Any wastes should be cleaned up with respect tohazardous and solid waste regulation and dispose in a properly permitted facility in accordance with local regulation 如可重用, 請盡量重用. 一旦不能使用, 廢物應放置於化學品專用回收桶中, 並跟據當地法規及程序把洩漏的廢物恰當處理7Handling and St
9、orage 安安全全處處置置與與儲儲存存方方法法Keep working and storage area with fresh air 保持車間及倉庫空氣通.Keep electricity and high temperature source away from product 把熱源及電源遠離產品. Keep strong oxidizing agent and strong solvent away from product 把強氧化物和溶劑遠離產品.8Exposure Control - Personal Protection 預預防防措措施施Engineering Control
10、s 工程控制:Local exhaust ventilation systems should be installed. Clear of toxic gas should be done before work started可使用一般通風,工作前必須排除殘有害氣體及粉塵Respiratory 呼吸防護:Respiratory protection is not normally required 一般情況呼吸防護不是必需If working area need to have respiratory protection, a mask which able to filter powd
11、er, steam, chemical mist or with self-air-supply system is more preferable 現場工作之人員如需配戴保護面具, 具有機蒸氣罐、粉塵和霧滴過器之化學罐式呼吸防護具,或供氣式呼吸防護具,或自攜式呼吸防護具會比較理想Eye Protection 眼睛防護:When the material may eye contact, wear the safety glasses with side shield are recommended. When there are fumes orvapors may apply, wear
12、chemical safety goggles are recommended 如工作人員對產品可能有眼部接髑時, 應配帶護眼鏡(有則保護), 如可能會有氣體及霧狀物在現場, 化學品護眼鏡會比較適合Protective Gloves 保護手套:Polymeric gloves are recommended to prevent irritation 塑膠手套可防止因接髑產品而產生的敏感9Physical and Chemical Properties 物物及及化化學學性性質質Appearance & Physical State 外觀及物質態:Solid state in diffe
13、rent color 不同顏色的固體粒狀Melting Point 溶點:135Odor: 氣味Slight 輕微Density 比重:1.31-1.32Hardness 硬度:Shore A 20 100Solubility in H2O 溶水能:Insoluble 不溶於水Decomposition temp 分解温度:190Brittleness temp 脆化温度:60Dissolve in 溶解於:Cyclohexanone 环已酮10Stability and Reactivity 安安定定性性及及反反應應性性Stability 安定性:Product is stable unde
14、r normal handling and storage condition 正常況及常温下安定 Conditions to avoid 應避免之況:Avoid contact with strong solvents and oxidizing agents 與強氧化劑臥及溶劑接觸會造成解Hazardous decomposition products 危害分解物:May produce dense smoke, carbon monoxide, hydrochloric acid vapor, PAHs and low molecular weight organic compounda
15、fter burn 產品燃燒後可能會放出濃煙, 一氧化碳, 鹽酸氣, 多環芳烴或低份子有機物等11Toxicological Information 毒毒性性資資 PVC materials has a very low toxicity. Fumes or vapors generated from decomposing resin may have irritation to eyes PVC為低毒產品, 但膠分解反應釋出之濃煙、蒸汽,會激眼睛12Ecological Information 生生態態資資Difficult to decompose in nature, should a
16、void pellets released to nature 產品難以在大自然分解, 應盡量減少流入大自然中May have health impact on animals after intake of product 動物進食產品後可能會導致不適13Disposal Considerations 廢廢棄棄處處置置方方法法Disposal by recycling is the preferred method of disposal. Alternatively, the product may be disposed in an approved landfill. All wast
17、es should be landfilled under solidwaste and hazardous regulations. It is the users responsibility to dispose of all wastes in accordance with local area regulations at properly permitted or authorizedfacilities. Inappropriate burning of product may emit toxic gases like Carbon Monoxide/ PAHs 如未污損,盡
18、可能回收再使用, 依照法規規章,應予以焚化或以垃圾掩埋,防止污染及危害人體健康。 當之燃燒會產生有毒氣體如一氧化碳及多環芳烴化合物14Transportation Information 運運送送資資 Not Currently regulated 暫未有關於此產品的運輸限制15Regulatory Information 法法規規資資Product complied with standards of EU Directive, ASTM, CPSC, etc including below listed standard:產品符合歐盟指令, 美國材料及測試協會, 美國消費品安全協會等以下標
19、準:EU Directive 2002:95 EC (RoHS)ASTM 963-08EN71-Part 3:1994EU Directive 2009:425/EC (Organotin)16Other InformationDocument created by 文件製作:東莞市超華化工有限公司Issue Date 發報日期:1 九月 2015END 完完FE MSDS 15-08 v1.0東東莞莞市市超超華華化化工工有有限限公公司司Material Safety Data Sheet物物質質安安全全資資料料表表常平鎮大京九塑膠市場塑通7路701-703號In its manufactur
20、ed and transported state the product is considered as non-hazardous 在生產及運輸中, 此產品被視為非危害物質Exposures to high concentration of vapors may possibly cause lung disorder 如身處或吸入高濃度的產品燒焦或氣化氣體會引致肺部功能不正常運作Particulate matter or fumes may cause irritation 產品在氣態, 粉態下接觸可能會引起敏感Particulate matter or fumes may cause
21、irritation 產品在氣態, 粉態下接觸可能會引起敏感Large quantity of particulate matter may cause intestinal distress. 大量進食可能會引致腸胃不息Wash thoroughly with mild soap and running water 以動的水或浴沖洗之,再以水和肥皂或溫和的清潔劑清洗Products in or near fires should be sprayed with a water. 向燃燒物及其旁邊物品射水Burning of product may emit toxic gases like
22、carbon monoxide, people should keep away from them 產品撚燒時可能會產生有毒氣體如一氧化碳, 現場人員應盡量遠離燃燒物Reuse released product if not contaminated. If product not reusable, place in approved containers for disposal. Any wastes should be cleaned up with respect tohazardous and solid waste regulation and dispose in a pro
23、perly permitted facility in accordance with local regulation 如可重用, 請盡量重用. 一旦不能使用, 廢物應放置於化學品專用回收桶中, 並跟據當地法規及程序把洩漏的廢物恰當處理Keep working and storage area with fresh air 保持車間及倉庫空氣通.Keep electricity and high temperature source away from product 把熱源及電源遠離產品. Keep strong oxidizing agent and strong solvent awa
24、y from product 把強氧化物和溶劑遠離產品.Local exhaust ventilation systems should be installed. Clear of toxic gas should be done before work startedIf working area need to have respiratory protection, a mask which able to filter powder, steam, chemical mist or with self-air-supply system is more preferable 現場工作
25、之人員如需配戴保護面具, 具有機蒸氣罐、粉塵和霧滴過器之化學罐式呼吸防護具,或供氣式呼吸防護具,或自攜式呼吸防護具會比較理想When the material may eye contact, wear the safety glasses with side shield are recommended. When there are fumes orvapors may apply, wear chemical safety goggles are recommended 如工作人員對產品可能有眼部接髑時, 應配帶護眼鏡(有則保護), 如可能會有氣體及霧狀物在現場, 化學品護眼鏡會比較適合Polymeric gloves are recommended to prevent irritation 塑膠手套可防止因接髑產品而產生的敏感Product is stable under normal handling and storage condition 正常況及常温下安定 Avoid contact with strong solvents and oxidizing agents 與強氧化劑臥及溶劑接觸會造成解May produce dense smoke, carbon monoxide, hydro
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