南京土壤检测中心

中国合格评定国家认可委员会认可证书附件（注册号：CNASL2464）名称：中国科学院南京土壤研究所土壤与环境分析测试中心地址：江苏省南京市北京东路71号签发日期：2010年12月10日有效期至：2013年12月09日更新日期：2012年04月09日附件1认可的授权签字人及领域序号姓名授权签字领域备注1章钢娅土壤、空气、植物与食品、水、肥料的检测项目2曹亚澄土壤、空气、植物与食品、水、肥料的检测项目ThescopeoftheaccreditationinChineseremainsthedefinitiveversion.CHINANATIONALACCREDITATIONSERVICEFORCONFORMITYASSESSMENT

APPENDIXOFACCREDITATIONCERTIFICATE(RegistrationNo.CNASL2464)NAME:SoilandEnvironmentAnalysisCenterofNanjingInstituteofSoilScience,ChineseAcademyofSciencesADDRESS:No.71,BeijingEastRoad,Nanjing,Jiangsu,ChinaDateofIssue:2010-12-10DateofExpiry:2013-12-09DateofUpdate：2012-04-09APPENDIX1ACCREDITEDSIGNATORIESANDSCOPE卬NameAuthorizedScopeofSignatureNote1ZhangGangyaAllapprovedprojects2CaoYachengAllapprovedprojects中国合格评定国家认可委员会认可证书附件（注册号：CNASL2464）名称：中国科学院南京土壤研究所土壤与环境分析测试中心地址：江苏省南京市北京东路71号认可依据：ISO/IEC17025:2005以及CNAS特定认可要求签发日期：2010年12月10日有效期至：2013年12月09日更新日期：2012年04月09日附件2认可的检测能力范围序号检测对象项目/参数领域代码检测标准（方法）名称及编号（含年号）限制范围说明序号名称1土壤1pH0238LY/T1239-1999森林土壤pH值的测定2有机质0238LY/T1237-1999森林土壤有机质的测定及碳氮比的计算3水分0238LY/T1213-1999森林土壤含水量的测定4全氮0238NY/T53-1987土壤全氮测定法（半微量凯氏法）ThescopeoftheaccreditationinChineseremainsthedefinitiveversion.序号检测对象项目/参数领域代码检测标准（方法）名称及编号（含年号）限制范围说明序号名称1土壤5全磷0238LY/T1232-1999森林土壤全磷的测定6有效磷0238LY/T1233-1999森林土壤有效磷的测定7全钾0238LY/T1234-1999森林土壤全钾的测定8速效钾0238LY/T1236-1999森林土壤速效钾的测定9水溶性盐分0238LY/T1251-1999森林土壤水溶性盐分分析10有效铜0238LY/T1260-1999森林土壤有效铜的测定11有效锌0238LY/T1261-1999森林土壤有效锌的测定12有效铁0238LY/T1262-1999森林土壤有效铁的测定13六八八、滴滴涕0238GB/T14550-2003土壤中六八八和滴滴涕测定的气相色谱法14碳稳定性同位素比值0238有机化合物的碳同位素质谱分析《土壤农业化学分析方法》中国农业科技出版社，1999年，564-570页15氮稳定性同位素比值0238氮同位素质谱分析《土壤农业化学分析方法》中国农业科技出版社，1999年，558-564页。16总铬0238HJ491—2009土壤总铬的测定火焰原子吸收分光光度法不用6.2.2ThescopeoftheaccreditationinChineseremainsthedefinitiveversion.序号检测对象项目/参数领域代码检测标准（方法）名称及编号（含年号）限制范围说明序号名称1土壤17铅，镉0238GB/T17141-1997土壤质量铅、镉的测定石墨炉原子吸收分光光度法18铜，锌0238GB/T17138-1997土壤质量铜、锌的测定火焰原子吸收分光光度法19总汞0238GB/T22105.1-2008土壤质量总汞、总砷、总铅的测定原子荧光法第1部分：土壤中总汞的测定20总砷0238GB/T22105.2-2008土壤质量总汞、总砷、总铅的测定原子荧光法第2部分：土壤中总砷的测定21电导率0238DINISO11265-1997土壤质量.特定电导率的测定22水解性氮0238LY/T1229-1999森林土壤水解性氮的测定23铵态氮、硝态氮、亚硝态氮0238ISO14256-2-2005土壤质量-氯化钾萃取法测定潮湿土壤中的硝酸盐、亚硝酸盐和氨盐基的含量-第2部分：以分段流程分析进行的自动测定方法24氯离子0238NY/T1121.17-2006土壤检测第17部分：土壤氯离子含量的测定仅用前处理方法24氯离子0238HJ/T84-2001水质无机阴离子的测定离子色谱法仅用测定方法序号检测对象项目/参数领域代码检测标准（方法）名称及编号（含年号）限制范围说明序号名称1土壤25硫酸根离子0238NY/T1121.18-2006土壤检测第18部分:土壤硫酸根离子含量的测定HJ/T84-2001水质无机阴离子的测定离子色谱法26矿质全量0238偏硼酸锂熔融-ICP-AES法《土壤农业化学分析方法》中国农业科技出版社，1999年，45-47页。27全钙、镁、钠0238NY/T296-1995土壤全钙、镁、钠的测定28镍0238GB/T17139-1997土壤质量镍的测定火焰原子吸收分光光度法29全硒0238NY/T1104-2006土壤中全硒的测定原子荧光光度法30有机磷农药0238GB/T14552-2003水和土壤质量有机磷农药的测定气相色谱法31石油烃0238GB/T17378.5-2007海洋监测规范第5部分:沉积物分析2空气32空气中N2O氮、氧同位素比值0238GB/T6041-2002质谱分析方法通则；大气浓度下N2O、CH4和CO2中氮、碳和氧稳定同位素比值的质谱测定，土壤学报，2008，第45卷，第2期，249-258页。ThescopeoftheaccreditationinChineseremainsthedefinitiveversion.序号检测对象项目/参数领域代码检测标准（方法）名称及编号（含年号）限制范围说明序号名称2空气33空气中CH4碳同位素比值0238GB/T6041-2002质谱分析方法通则；大气浓度下N2O、CH4和CO2中氮、碳和氧稳定同位素比值的质谱测定，土壤学报，2008，第45卷，第2期，249-258页。34气体中N2氮同位素比值023835空气中CO2碳、氧同位素比值023836气体中CH4含量0238GB/T8984-2008气体中一氧化碳、二氧化碳和碳氢化合物的测定第1部分：气体中一氧化碳、二氧化碳和甲烷的测定气相色谱法37气体中CO2含量0238GB/T18204.24-2000气体中一氧化碳、二氧化碳和碳氢化合物的测定3植物与食品38六八八、滴滴涕0227GB/T5009.19-2008食品中有机氯农药多组分残留量的测定39植物粗灰分的测定0244GB/T5009.4-2010食品中灰分的测定40全氮0227LY/T1269-1999森林植物与森林枯枝落叶层全氮的测定ThescopeoftheaccreditationinChineseremainsthedefinitiveversion.序号检测对象项目/参数领域代码检测标准（方法）名称及编号（含年号）限制范围说明序号名称3植物与食品41全磷0227LY/T1271-1999森林植物与森林枯枝落叶层全氮、磷、钾、钠、钙、镁的测定42全钾0227LY/T1271-1999森林植物与森林枯枝落叶层全氮、磷、钾、钠、钙、镁的测定43镉0227GB/T5009.15-2003食品中镉的测定只做第一法44总汞0227GB/T5009.17-2003食品中总汞及有机汞的测定只做第一法45铅0227GB/T5009.12-2010食品中铅的测定只做第一法46硒0227GB5009.93—2010食品安全国家标准食品中硒的测定只做第一法47碳稳定性同位素比值0244有机化合物的碳同位素质谱分析《土壤农业化学分析方法》中国农业科技出版社，1999年，564-570页48氮稳定性同位素比值0244氮同位素质谱分析《土壤农业化学分析方法》中国农业科技出版社，1999年，558-564页。4水49pH0238GB/T6920-1986水质pH值的测定玻璃电极法50铜，锌，铅，镉0238GB/T7475-1987水质铜，锌，铅，镉的测定原子吸收分光光度法序号检测对象项目/参数领域代码检测标准（方法）名称及编号（含年号）限制范围说明序号名称4水51铵0238ISO11732-2005水质氨氮的测定.流动分析（CFA和FIA）和光谱测定法52硝酸盐氮0238ISO13395-1996水质用流动分析（CFA和FIA）和光谱检测法测定水中亚硝酸盐氮和硝酸盐氮及二者的总量53电导率0238DZ/T0064.6-1993地下水质检测方法电导率的测定54全盐量0238HJ/T51-1999水质全盐量的测定重量法55全钾0238EPA200.7水、固体、生物固体痕量元素的测定电感耦合等离子体原子发射光谱法56碳酸根、重碳酸根0238DZ/T0064.49-1993地下水质检测方法滴定法测定碳酸根、重碳酸根和氢氧根57氯离子和硫酸根0238HJ/T84-2001水质无机阴离子的测定离子色谱法58磷酸盐0238ISO10304-1-2007水质一用离子色谱法测定溶解的阴离子一第1部分：漠化物、氯化物、氟化物、硝酸盐、亚硝酸盐、磷酸盐和硫酸盐的测定ThescopeoftheaccreditationinChineseremainsthedefinitiveversion.序号检测对象项目/参数领域代码检测标准（方法）名称及编号（含年号）限制范围说明序号名称4水59铝0238EPA200.7水、固体、生物固体痕量元素的测定电感耦合等离子体原子发射光谱法60钙、镁0238EPA200.7水、固体、生物固体痕量元素的测定电感耦合等离子体原子发射光谱法61铁、锰0238EPA200.7水、固体、生物固体痕量元素的测定电感耦合等离子体原子发射光谱法62汞0238SL327.2-2005水质汞的测定原子荧光光度法63钠0238EPA200.7水、固体、生物固体痕量元素的测定电感耦合等离子体原子发射光谱法64镍0238EPA200.7水、固体、生物固体痕量元素的测定电感耦合等离子体原子发射光谱法65砷0238SL327.1-2005水质砷的测定原子荧光光度法66硒0238SL327.3-2005水质硒的测定原子荧光光度法ThescopeoftheaccreditationinChineseremainsthedefinitiveversion.序号检测对象项目/参数领域代码检测标准（方法）名称及编号（含年号）限制范围说明序号名称4水67六八八、滴滴涕0238GB/T7492-1987水质六八八、滴滴涕的测定气相色谱法68有机磷农药0238GB/T14552-2003水、土中有机磷农药测定的气相色谱法69六价铬0238GB/T7467-1987水质六价铬的测定二苯碳酰二肼分光光度法5肥料70总氮0232GB/T17767.1-2008有机-无机复混肥料的测定方法第一部分:总氮含量71总磷0232GB/T17767.2-2010有机一无机复混肥料中总磷含量的测定72总钾0232GB/T17767.3-2010有机-无机复混肥料中总钾含量的测定73汞、砷、镉、铅、铬0232NY1110-2006水溶肥料汞、砷、镉、铅、铬的限量及其含量测定ThescopeoftheaccreditationinChineseremainsthedefinitiveversion.CHINANATIONALACCREDITATIONSERVICEFORCONFORMITYASSESSMENTAPPENDIXOFACCREDITATIONCERTIFICATE(RegistrationNo.CNASL2464)NAME:SoilandEnvironmentAnalysisCenterofNanjingInstituteofSoilScience,ChineseAcademyofSciencesADDRESS:No.71,BeijingEastRoad,Nanjing,Jiangsu,ChinaAccreditationCriteria:ISO/IEC17025:2005andrelevantrequirementsofCNASDateofIssue:2010-12-10DateofExpiry:2013-12-09DateofUpdate：2012-04-09APPENDIX2ACCREDITEDTESTING^TestObjectItem/ParameterCodeofFieldTitle,CodeofStandardorMethodLimitationNote^Item/Parameter1Soil1pH0238LY/T1239-1999DeterminationofpHvalueinforestsoil2OrganicMatter0238LY/T1237-1999Determinationoforganicmatterinforestsoilandcalculationcarbon-nitrogenratio3WaterContent0238LY/T1213-1999Determinationofforestsoilwatercontent

^TestObjectItem/ParameterCodeofFieldTitle,CodeofStandardorMethodLimitationNote^Item/Parameter1Soil4TotalNitrogen0238NY/T53-1987Methodforthedeterminationofsoiltotalnitrogen(Semi-microKjeldahlmethod)5TotalPhosphorus0238LY/T1232-1999Determinationoftotalphosphorusinforestsoil6AvailablePhosphorus0238LY/T1233-1999Determinationofavailablephosphorusinforestsoil7TotalPotassium0238LY/T1234-1999Determinationoftotalpotassiuminforestsoil8AvailablePotassium0238LY/T1236-1999Determinationofavailablepotassiuminforestsoil9Watersolublesaltsofsoil0238LY/T1251-1999Analysismethodsofwatersolublesaltsofforestsoil10AvailableCopper0238LY/T1260-1999Determinationofavailablecopperinforestsoil11AvailableZinc0238LY/T1261-1999Determinationofavailablezincinforestsoil^TestObjectItem/ParameterCodeofFieldTitle,CodeofStandardorMethodLimitationNote^Item/Parameter1Soil12AvailableIron0238LY/T1262-1999Determinationofavailableironinforestsoil13BHC,DDT0238GB/T14550-2003MethodofgaschromatographicfordeterminationofBHCandDDTinsoil14Cisotope-ratioanalysis0238Cisotope-radiomassspectrumanalysisinorganiccompounds<Methodsofagriculturalchemistryanalysisofsoil>ChinaAgriculturalScience&TechnologyPress,1999.p.564-57015Nisotope-ratioanalysis0238Nisotoperadiomassspectrumanalysis<Methodsofagriculturalchemistryanalysisofsoil>ChinaAgriculturalScience&TechnologyPress,1999.p.558-564ThescopeoftheaccreditationinChineseremainsthedefinitiveversion.^TestObjectItem/ParameterCodeofFieldTitle,CodeofStandardorMethodLimitationNote^Item/Parameter1Soil16TotalChromium0238HJ491—2009Soilquality—Determinationoftotalchromium—FlameatomicabsorptionspectrometryExceptfor6.2.217Lead,Cadmium0238GB/T17141-1997Soilquality-Determinationoflead,cadmium-Graphitefurnaceatomicabsorptionspectrophotometry18Copper,Zinc0238GB/T17138-1997Soilquality-Determinationofcopper,zinc-Flameatomicabsorptionspectrophotometry19Mercury0238GB/T22105.1-2008Soilquality-Analysisoftotalmercury,arsenicandleadcontents-Atomicfluorescencespectrometry-Part1:AnalysisoftotalmercurycontentsinsoilsThescopeoftheaccreditationinChineseremainsthedefinitiveversion.^TestObjectItem/ParameterCodeofFieldTitle,CodeofStandardorMethodLimitationNote^Item/Parameter1Soil20TotalArsenic0238GB/T22105.2-2008Soilquality-analysisoftotalmercury,arsenicandleadcontents-Atomicfluorescencespectrometry-Part2：Analysisoftotalarseniccontentsinsoils21Conductivity0238DINISO11265-1997Soilquality-Determinationofthespecificelectricalconductivity22HydrolyzableNitrogen0238LY/T1229-1999Determinationofhydrolyzablenitrogeninforestsoil23Ammonia,Nitrate,NitriteNitrogen0238ISO14256-2-2005Soilquality-Determinationofnitrate,nitrite,andammoniuminfield-moistsoilsbyextractionwithpotassiumchloridesolution-Part2:Automatedmethodwithsegmentedflowanalysis

^TestObjectItem/ParameterCodeofFieldTitle,CodeofStandardorMethodLimitationNote^Item/Parameter1Soil24Chloride0238NY/T1121.172006SoilTestingPart17:MethodfordeterminationofsoilchlorideioncontentAccreditedonlyfortreatmentmethodHJ/T84-2001Waterquality-Determinationofinorganicanions-IonchromatographymethodAccreditedonlyfordeterminationmethod25Sulfate0238NY/T1121.18-2006SoilTestingPart18:MethodfordeterminationofsoilsulfatecontentHJ/T84-2001Waterquality-Determinationofinorganicanions-Ionchromatographymethod26MineralTotalElements0238Lithiummetaboratefusion-ICP-AESmethod<Methodsofagriculturalchemistryanalysisofsoil>ChinaAgriculturalScience&TechnologyPress,1999.p,45-57

^TestObjectItem/ParameterCodeofFieldTitle,CodeofStandardorMethodLimitationNote^Item/Parameter1Soil27Totalcalcium,magnesium,sodium0238NY/T296-1995Determinationoftotalcalcium,magnesium,sodiuminsoil28Nickel0238GB/T17139-1997Soilquality-Determinationofnickel-Flameatomicabsorptionspectrophotometry29TotalSelenium0238NY/T1104-2006DeterminationofseleniuminsoilsAtomicfluorescencespectrometrymethod30Organo-phosphoruspesticides0238GB/T14552-2003Methodofgaschromatographicfordeterminationoforganophosphoruspesticidesinwaterandsoil31Petroleum-hydrocarbon0238GB17378.5-2007Thespecificationformarinemonitoring-Part5:Sedimentanalysis

^TestObjectItem/ParameterCodeofFieldTitle,CodeofStandardorMethodLimitationNote^Item/Parameter2Air32N、OIsotopiccompositiontoN2Oinair0238GB/T6041-2002Generalrulesformassspectrometricanalysis;Determinationofnitrogen,carbonandoxygenstableisotoperatioinN2O,CH4andCO2atnaturalabundancelevelsbyMassSpectrometry,Actapedologicasinca,Vol.45,No.2,Mar.,2008,pp249-25833CIsotopiccompositiontoCH4inair023834NIsotopiccompositiontoN2inair023835C、OIsotopiccompositiontoCO2inair023836CH4content0238GB/T8984-2008Determinationofcarbonmonoxide,carbondioxideandhydrocarboninthegases-Gaschromatographicmethod^TestObjectItem/ParameterCodeofFieldTitle,CodeofStandardorMethodLimitationNote^Item/Parameter2Air37CO2content0238GB/T18204.24-2000Methodsfordeterminationofcarbondioxideinairofpublicplace3PlantandFoods38BHC,DDT0227GB/T5009.19-2008Determinationoforganochlorinepesticidemultiresiduesinfoods39Ash0244GB/T5009.4-2010Determinationofashinfoods40Totalnitrogen,phosphorus,potassium0227LY/T1269-1999Determinationoftotalnitrogeninforestplantandforestfloor41Totalphosphorus0227LY/T1271-1999Determinationoftotalnitrogen,phosphorus,potassium,sodium,calcium,magnesiuminforestplantandforestfloorThescopeoftheaccreditationinChineseremainsthedefinitiveversion.^TestObjectItem/ParameterCodeofFieldTitle,CodeofStandardorMethodLimitationNote^Item/Parameter3PlantandFoods42Totalpotassium0227LY/T1271-1999Determinationoftotalnitrogen,phosphorus,potassium,sodium,calcium,magnesiuminforestplantandforestfloor43Cadmium0227GB/T5009.15-2003DeterminationofcadmiuminfoodsAccreditedonlyforthefirstmethod44Totalmercury0227GB/T5009.17-2003Determinationoftotalmercuryandorganic-mercuryinfoodsAccreditedonlyforthefirstmethod45Lead0227GB/T5009.12-2010DeterminationofleadinfoodsAccreditedonlyforthefirstmethod46Selenium0227GB5009.93—2010NationalfoodsafetystandardDeterminationofseleniuminfoodsAccreditedonlyforthefirstmethod

^TestObjectItem/ParameterCodeofFieldTitle,CodeofStandardorMethodLimitationNote^Item/Parameter3PlantandFoods47Cisotope-ratioanalysis0244Cisotope-radiomassspectrumanalysisinorganiccompounds<Methodsofagriculturalchemistryanalysisofsoil>ChinaAgriculturalScience&TechnologyPress,1999.p.564-57048Nisotope-ratioanalysis0244Nisotoperadiomassspectrumanalysis<Methodsofagriculturalchemistryanalysisofsoil>ChinaAgriculturalScience&TechnologyPress,1999p.558-56449pH0238GB/T6920-1986Waterquality-DeterminationofpHvalue-Glasselectrodemethod50Copper,Zinc,Lead,Cadmium0238GB/T7475-1987Waterquality-Determinationofcopper,zinc,lead,cadmium-Atomicabsorptionspectrometry

^TestObjectItem/ParameterCodeofFieldTitle,CodeofStandardorMethodLimitationNote^Item/Parameter3PlantandFoods51Ammonium0238ISO11732-2005Waterquality-Determinationofammoniumnitrogen-Methodbyflowanalysis(CFAandFIA)andspectrometricdetection4Water52Nitrate0238ISO13395-1996Waterquality-Determinationofnitritenitrogenandnitratenitrogenandthesumofbothbyflowanalysis(CFAandFIA)andspectrometricdetection53Conductivity0238DZ/T0064.6-1993Analysismethodofgroundwaterquality-Determinationofelectricalconductivity54Totalsalt0238HJ/T51-1999Waterquality-Determinationoftotalsalt-Gravimetricmethod

^TestObjectItem/ParameterCodeofFieldTitle,CodeofStandardorMethodLimitationNote^Item/Parameter4Water55Totalpotassium0238EPA200.7Traceelementsinwater,solids,andbiosolidsbyinductivelycoupledplasma-atomicemissionspectrometry56Carbonate,Bicarbonate0238DZ/T0064.49-1993Analysismethodofgroundwaterquality-Determinationofcarbonate,bicarbonateandhydroxyl-Titrimetricmethod57Chloride,Sulfate0238HJ/T84-2001Waterquality-Determinationofinorganicanions-Ionchromatographymethod58Phosphate0238ISO10304-1-2007Waterquality-Determinationofdissolvedanionsbyliquidchromatographyofions-Part1:Determinationofbromide,chloride,fluoride,nitrate,nitritephosphateandsulfate

^TestObjectItem/ParameterCodeofFieldTitle,CodeofStandardorMethodLimitationNote^Item/Parameter4Water59Aluminium0238EPA200.7Traceelementsinwater,solids,andbiosolidsbyinductivelycoupledplasma-atomicemissionspectrometry60Calcium,magnesium0238EPA200.7Traceelementsinwater,solids,andbiosolidsbyinductivelycoupledplasma-atomicemissionspectrometry61Iron,manganese0238EPA200.7Traceelementsinwater,solids,andbiosolidsbyinductivelycoupledplasma-atomicemissionspectrometry62Mercury0238SL327.2-2005Waterquality-determinationofmercury-atomicfluorescencespectrometri