云南中环 表D-5参比方法评估气态污染物CEMS(含氧量)准确度

表D-5-1参比方法评估气态污染物CEMS（含氧量）准确度,,,,,,,

测试人员waqiala,,,CEMS生产厂商中科天融（北京）科技有限公司,,,,

测试地点云南中环,,,CEMS型号、编号TR—Ⅲ,,,,

测试位置3#高炉,,,CEMS原理紫外差分光谱吸收,,,,

参比方法仪器生产厂青岛崂应型号、编号3012HA08175428X原理电化学法,,,,,,,

测试时间2017年11月30日污染物名称NOx计量单位mg/m³,,,,,,,

,,,,,,,,

样品编号,时间（时、分）,参比方法测量值A,,CEMS测量值B,,数据对差=B-A,

1,8:28,26.32,,29.08,,2.76,

2,8:38,35.96,,39.64,,3.68,

3,8:48,43.65,,46.32,,2.67,

4,8:58,43.23,,39.01,,-4.22,

5,9:08,35.36,,38.63,,3.27,

6,9:18,37.56,,33.36,,-4.20,

7,9:28,45.21,,42.29,,-2.92,

8,9:38,35.19,,38.56,,3.37,

9,9:48,35.89,,37.23,,1.34,

平均值,,37.60,,38.24,,0.64,

数据对差的平均值的绝对值,,0.64,,,,,

数据对差的标准偏差,,3.40,,,,,

置信系数,,2.61,,,,,

相对准确度,,8.65%,,,,,

标准气体,名称,保证值,参比方法测定结果,,,相对误差（%）,

,,,采样前,,采样后,采样前,采样后

,NO,689.57,688.23,,690.15,-1.34,0.58

表D-5-2参比方法评估气态污染物CEMS（含氧量）相对准确度,,,,,,,

测试人员waqiala,,,CEMS生产厂商中科天融（北京）科技有限公司,,,,

测试地点云南中环,,,CEMS型号、编号TR—Ⅲ,,,,

测试位置3#高炉,,,CEMS原理紫外差分光谱吸收,,,,

参比方法仪器生产厂青岛崂应型号、编号3012HA08175428X原理电化学法,,,,,,,

测试时间2017年12月1日污染物名称NOx计量单位mg/m³,,,,,,,

,,,,,,,,

样品编号,时间（时、分）,参比方法测量值A,,CEMS测量值B,,数据对差=B-A,

1,8:24,38.69,,40.61,,1.92,

2,8:34,37.23,,35.83,,-1.40,

3,8:44,35.23,,30.09,,-5.14,

4,8:54,31.59,,28.34,,-3.25,

5,9:04,34.02,,31.96,,-2.06,

6,9:14,32.69,,36.27,,3.58,

7,9:24,36.09,,33.72,,-2.37,

8,9:34,35.67,,32.88,,-2.79,

9,9:44,33.39,,31.18,,-2.21,

平均值,,34.96,,33.43,,-1.52,

数据对差的平均值的绝对值,,1.52,,,,,

数据对差的标准偏差,,2.67,,,,,

置信系数,,2.05,,,,,

相对准确度,,10.23%,,,,,

标准气体,名称,保证值,参比方法测定结果,,,相对误差（%）,

,,,采样前,,采样后,采样前,采样后

,NO,689.57,687.32,,688.21,-2.25,-1.36

表D-5-3参比方法评估气态污染物CEMS（含氧量）相对准确度,,,,,,,

测试人员waqiala,,,CEMS生产厂商中科天融（北京）科技有限公司,,,,

测试地点云南中环,,,CEMS型号、编号TR—Ⅲ,,,,

测试位置3#高炉,,,CEMS原理紫外差分光谱吸收,,,,

参比方法仪器生产厂青岛崂应型号、编号3012HA08175428X原理电化学法,,,,,,,

测试时间2017年12月2日污染物名称NOx计量单位mg/m³,,,,,,,

,,,,,,,,

样品编号,时间（时、分）,参比方法测量值A,,CEMS测量值B,,数据对差=B-A,

1,8:50,29.63,,27.61,,-2.02,

2,9:00,25.30,,28.11,,2.81,

3,9:10,9.63,,4.82,,-4.81,

4,9:20,25.69,,29.27,,3.58,

5,9:30,29.96,,33.18,,3.22,

6,9:40,30.32,,33.06,,2.74,

7,9:50,31.20,,28.58,,-2.62,

8,10:00,30.25,,34.04,,3.79,

9,10:10,35.29,,37.42,,2.13,

平均值,,27.47,,28.45,,0.98,

数据对差的平均值的绝对值,,0.98,,,,,

数据对差的标准偏差,,3.22,,,,,

置信系数,,2.47,,,,,

相对准确度,,12.57%,,,,,

标准气体,名称,保证值,参比方法测定结果,,,相对误差（%）,

,,,采样前,,采样后,采样前,采样后

,NO,689.57,687.36,,691.2,-2.21,1.63

,,,,,,,,

表D-5-4参比方法评估气态污染物CEMS（含氧量）相对准确度,,,,,,,

测试人员waqiala,,,CEMS生产厂商中科天融（北京）科技有限公司,,,,

测试地点云南中环,,,CEMS型号、编号TR—Ⅲ,,,,

测试位置3#高炉,,,CEMS原理紫外差分光谱吸收,,,,

参比方法仪器生产厂青岛崂应型号、编号3012HA08175428X原理电化学法,,,,,,,

测试时间2017年11月30日污染物名称SO2计量单位mg/m³,,,,,,,

,,,,,,,,

样品编号,时间（时、分）,参比方法测量值A,,CEMS测量值B,,数据对差=B-A,

1,8:28,27.53,,23.98,,-3.55,

2,8:38,34.62,,31.68,,-2.94,

3,8:48,36.33,,33.51,,-2.82,

4,8:58,35.23,,31.26,,-3.97,

5,9:08,36.66,,30.21,,-6.45,

6,9:18,28.86,,24.72,,-4.14,

7,9:28,31.21,,27.52,,-3.69,

8,9:38,31.63,,27.55,,-4.08,

9,9:48,36.41,,33.64,,-2.77,

平均值,,33.16,,29.34,,-3.82,

数据对差的平均值的绝对值,,3.82,,,,,

数据对差的标准偏差,,1.12,,,,,

置信系数,,0.86,,,,,

相对准确度,,14.13%,,,,,

标准气体,名称,保证值,参比方法测定结果,,,相对误差（%）,

,,,采样前,,采样后,采样前,采样后

,SO2,225,223,,224,-2.00,-1.00

,,,,,,,,

表D-5-5参比方法评估气态污染物CEMS（含氧量）相对准确度,,,,,,,

测试人员waqiala,,,CEMS生产厂商中科天融（北京）科技有限公司,,,,

测试地点云南中环,,,CEMS型号、编号TR—Ⅲ,,,,

测试位置3#高炉,,,CEMS原理紫外差分光谱吸收,,,,

参比方法仪器生产厂青岛崂应型号、编号3012HA08175428X原理电化学法,,,,,,,

测试时间2017年12月1日污染物名称SO2计量单位mg/m³,,,,,,,

,,,,,,,,

样品编号,时间（时、分）,参比方法测量值A,,CEMS测量值B,,数据对差=B-A,

1,8:24,25.36,,22.62,,-2.74,

2,8:34,23.13,,20.29,,-2.84,

3,8:44,26.36,,22.35,,-4.01,

4,8:54,24.96,,20.53,,-4.43,

5,9:04,23.31,,20.16,,-3.15,

6,9:14,29.65,,26.58,,-3.07,

7,9:24,19.64,,15.11,,-4.53,

8,9:34,24.36,,20.92,,-3.44,

9,9:44,25.36,,20.48,,-4.88,

平均值,,24.68,,21.00,,-3.68,

数据对差的平均值的绝对值,,3.68,,,,,

数据对差的标准偏差,,0.80,,,,,

置信系数,,0.62,,,,,

相对准确度,,17.39%,,,,,

标准气体,名称,保证值,参比方法测定结果,,,相对误差（%）,

,,,采样前,,采样后,采样前,采样后

,SO2,225,222,,223,-3.00,-2.00

表D-5-6参比方法评估气态污染物CEMS（含氧量）相对准确度,,,,,,,

测试人员waqiala,,,CEMS生产厂商中科天融（北京）科技有限公司,,,,

测试地点云南中环,,,CEMS型号、编号TR—Ⅲ,,,,

测试位置3#高炉,,,CEMS原理紫外差分光谱吸收,,,,

参比方法仪器生产厂青岛崂应型号、编号3012HA08175428X原理电化学法,,,,,,,

测试时间2017年12月2日污染物名称SO2计量单位mg/m³,,,,,,,

,,,,,,,,

样品编号,时间（时、分）,参比方法测量值A,,CEMS测量值B,,数据对差=B-A,

1,8:50,24.00,,19.01,,-4.99,

2,9:00,23.00,,19.37,,-3.63,

3,9:10,28.36,,24.39,,-3.97,

4,9:20,25.23,,21.06,,-4.17,

5,9:30,25.01,,21.03,,-3.98,

6,9:40,24.25,,21.03,,-3.22,

7,9:50,23.32,,21.04,,-2.28,

8,10:00,19.63,,17.74,,-1.89,

9,10:10,24.36,,19.24,,-5.12,

平均值,,24.13,,20.43,,-3.69,

数据对差的平均值的绝对值,,3.69,,,,,

数据对差的标准偏差,,1.09,,,,,

置信系数,,0.84,,,,,

相对准确度,,18.80%,,,,,

标准气体,名称,保证值,参比方法测定结果,,,相对误差（%）,

,,,采样前,,采样后,采样前,采样后

,SO2,225,221,,226,-4.00,-1.00

表D-5-7参比方法评估气态污染物CEMS（含氧量）相对准确度,,,,,,,

,,,,,,,,

测试人员waqiala,,,CEMS生产厂商中科天融（北京）科技有限公司,,,,

测试地点云南中环,,,CEMS型号、编号TR—Ⅲ,,,,

测试位置3#高炉,,,CEMS原理紫外差分光谱吸收,,,,

参比方法仪器生产厂青岛崂应型号、编号3012HA08175428X原理电化学法,,,,,,,

测试时间2017年11月30日污染物名称O2计量单位%,,,,,,,

,,,,,,,,

样品编号,时间（时、分）,参比方法测量值A,,CEMS测量值B,,数据对差=B-A,

1,8:28,3.45,,3.56,,0.11,

2,8:38,0.10,,0.08,,-0.02,

3,8:48,0.35,,0.40,,0.05,

4,8:58,0.73,,0.68,,-0.05,

5,9:08,0.70,,0.62,,-0.08,

6,9:18,0.31,,0.27,,-0.04,

7,9:28,0.71,,0.61,,-0.10,

8,9:38,0.79,,0.82,,0.03,

9,9:48,2.12,,2.10,,-0.02,

平均值,,1.03,,1.02,,-0.01,

数据对差的平均值的绝对值,,0.01,,,,,

数据对差的标准偏差,,0.07,,,,,

置信系数,,0.05,,,,,

相对准确度,,6.24%,,,,,

标准气体,名称,保证值,参比方法测定结果,,,相对误差（%）,

,,,采样前,,采样后,采样前,采样后

,O2,21,20.69,,21.12,-0.31,0.12

表D-5-8参比方法评估气态污染物CEMS（含氧量）相对准确度,,,,,,,

,,,,,,,,

测试人员waqiala,,,CEMS生产厂商中科天融（北京）科技有限公司,,,,

测试地点云南中环,,,CEMS型号、编号TR—Ⅲ,,,,

测试位置3#高炉,,,CEMS原理紫外差分光谱吸收,,,,

参比方法仪器生产厂青岛崂应型号、编号3012HA08175428X原理电化学法,,,,,,,

测试时间2017年12月1日污染物名称O2计量单位%,,,,,,,

,,,,,,,,

样品编号,时间（时、分）,参比方法测量值A,,CEMS测量值B,,数据对差=B-A,

1,8:24,0.70,,0.61,,-0.09,

2,8:34,1.06,,1.01,,-0.05,

3,8:44,0.42,,0.39,,-0.03,

4,8:54,0.81,,0.71,,-0.10,

5,9:04,0.56,,0.53,,-0.03,

6,9:14,0.30,,0.24,,-0.06,

7,9:24,0.70,,0.68,,-0.02,

8,9:34,0.90,,0.86,,-0.04,

9,9:44,0.25,,0.22,,-0.03,

平均值,,0.63,,0.58,,-0.05,

数据对差的平均值的绝对值,,0.05,,,,,

数据对差的标准偏差,,0.03,,,,,

置信系数,,0.02,,,,,

相对准确度,,11.33%,,,,,

标准气体,名称,保证值,参比方法测定结果,,,相对误差（%）,

,,,采样前,,采样后,采样前,采样后

,O2,21,21.23,,20.57,0.23,-0.43

表D-5-9参比方法评估气态污染物CEMS（含氧量）相对准确度,,,,,,,

,,,,,,,,

测试人员waqiala,,,CEMS生