追化工人1设计5 1附录一物料平衡书

物料目 物料方 物料任 环丁烯砜工 环丁砜工 亚硫酸钠工 1870吨,工业级环丁通过对整个生产系统、生产车间，以及部分重要的生产单元进行物料计算出主、副产品的产量，原材料的消耗、“三废”排放量及组成，以及产品收率等物料目工艺设计中，物料是在工艺流程确定后进行的。目的是根据原料与产品生产过程中各阶段的消耗量以及组成，进而为热量、其他工艺计算及设备计算打基础。对于已有装置，物料可以弄清原料的来龙去脉，找出生产中的薄利用率及三废处理完善程度的一种。物料方物料是根据质量守恒定律利用某进出化工过程中某些已知物流的流量的过程。系统中物料一般表达式为：输入=3-1所示：表3-1各方法适用情式总式式式式式式式式共有五个工段，分别为尾气处理工段、二氧化硫解吸工段、环丁烯砜工段、环丁砜工段、亚硫酸钠工段。物料任物料的主要任务在于各主要工艺物流的物料，指导工艺设备的选型及设计4-1 MoleMassVolumeC1Vapor100100Liquid011011Solid000000Molar ------Mass ------Enthalpy ------Molar CAL/MOL-----Mass CAL/GM-----Molar Mass AverageMolecularComponentMass 5.13E-5.13E- 00 0000 02.63E-01.11E-1.57E-0 001.79E-0 0000 0000 04.86E-04.31E- 00CO3- 01.20E-3.18E-05.04E-2.11E-SO3- 01.56E-02.17E-SO4- 0000HPO4- 0000PO4-- 0000 06.70E-1.16E-07.75E-2.51E-ComponentMass1.43E-1.89E-2.07E-2.35E-1.25E-4.99E-1.25E-4.87E-5.37E-6.69E-5.37E-5.45E-2.86E-3.70E-2.86E-01.47E-01.21E-000002.03E-03.86E-1.24E-004.73E-06.22E-1.72E-002.29E-004.28E-0000003.80E-1.18E-01.81E-1.05E-00CO3-09.26E-7.73E-04.00E-5.13E-SO3-03.79E-05.27E-SO4-0000HPO4-0000PO4--08.92E-001.68E-005.19E-2.83E-06.15E-6.11E-含硫尾气吸收塔物料4-2T0101流股信 待处理烟 吸收贫 排空尾 吸收富Mole Mass Volume 1Vapor1010Liquid0101Solid0000Molar ----Mass ----Enthalpy ----Molar CAL/MOL---MassCAL/GM---MolarMassAverageComponentMass000009.93E-1.11E-1.57E-01.79E-00000000CO3-01.28E-05.04E-SO3-00SO4-00HPO4-00PO4--00007.75E-ComponentMass2.00E-1.89E-2.07E-2.35E-4.99E-4.87E-6.69E-6.37E-3.70E-01.55E-01.21E-0007.69E-3.86E-1.24E-05.83E-6.22E-1.72E-03.27E-04.28E-0003.67E-01.81E-00CO3-09.88E-04.00E-SO3-00SO4-00HPO4-00PO4--01.08E-01.68E-09.45E-06.15E-4-3盐盐MoleMassVolumeCVapor000010Liquid111101Solid000000------Mass ------Enthalpy ------Molar-K-----

吸收贫 含磷废

MassCAL/GM-------MolarMassAverageMolecularComponentMass3.58E-1.41E-01.09E-1.10E-04.21E-09.25E-9.75E-5.66E-0001.57E-4.11E-2.63E-2.77E-00006.00E-1.73E-000004.53E-01.69E-0CO3-5.04E-01.20E-1.05E-01.30E-SO3-04.81E-SO4-00HPO4-00PO4--007.75E-3.13E-6.70E-7.16E-09.74E-ComponentMass2.07E- 2.19E-1.43E-4.69E-4.99E- 2.35E-3.61E-2.06E-6.69E- 4.87E-1.40E-1.62E-3.70E- 5.45E-3.07E-7.98E- 1.21E- 5.96E-1.47E-1.88E-0 001.24E- 2.51E-2.03E-9.20E-001.72E- 1.02E-4.73E-9.54E-004.28E- 3.67E-2.29E-5.75E-00 001.81E- 3.80E-1.51E-03.16E- 4.24E-0CO3-4.00E- 9.26E-3.50E-02.42E-SO3- 08.99E-SO4- 00HPO4- 00PO4--1.68E- 1.75E-8.92E-1.24E-006.15E- 1.91E-5.19E-2.38E-01.82E-4.44-4 二氧化 中间产物环流股信 丁二烯原 补充氮 分子筛脱气MoleMassVolumeC53Vapor1010Liquid0101Solid00000Molar ----Mass ----Enthalpy ----Molar CAL/MOL-----Mass CAL/GM-----Molar Mass AverageMolecularComponentMass 000 0 000 000 000 0002.99E-0 0009.58E-0CO3- 0005.84E-0 0008.77E-0 000 0000ComponentMass000010000000000001.22E-00003.93E-0CO3-0002.39E-00003.60E-001000000表4-5环丁烯砜工段总物料（一MoleMassVolumeCVapor 001Liquid 100Solid 010Molar ---Mass ---Enthalpy --7.22E--Molar CAL/MOL- ---Mass CAL/GM- ---Molar Mass AverageMolecular ComponentMass 000 000 00 000 000 000 00 00ComponentMass 000 000 100000000000000104-6MoleMassVolumeC33Vapor10010Liquid0101Solid00000Molar -----Mass -----Enthalpy -----Molar CAL/MOL-------Mass CAL/GM-------Molar Mass AverageMolecularComponentMass8.43E-9.91E-1.55E-2.41E-9.16E-2.22E-2.92E-7.48E-9.21E-9.18E-4.31E-2.75E-2.29E-8.58E-7.83E-8.32E-8.21E-00000Mass3.63E-1.08E-1.04E-9.98E-6.12E-2.98E-3.23E-1.00E-1.19E- 2.91E- 1.99E-06 2.36E- 7.98E- 亚硫酸钠工0品MoleMassVolumeCVapor001001Liquid11010Solid00000Molar ------Mass ------Enthalpy ------Molar-K-----

Mass CAL/GM-------Molar Mass AverageMolecularComponentMass 3.24E-1.11E-3.64E-3.10E-7.40E- 1.10E-01.09E-8.81E-00 02.56E-1.86E- 2.45E-6.41E- 1.02E-06.90E-0 0000 1.69E-4.75E-01.29E-0 1.02E-00CO3- 1.30E-01.68E-4.62E-0SO3-4.81E-01.62E-09.74E-01.58E-2.89E-0Mass4.47E-2.88E-3.87E-9.96E-2.02E-2.06E-02.84E-9.37E-001.62E-01.39E-8.22E-5.06E-7.98E-3.37E-4.31E-2.06E-6.06E-1.40E-06.20E-2.21E-000003.16E-6.55E-09.41E-4.13E-01.41E-01.39E-0CO3-2.42E-01.79E-1.48E-0SO3-8.99E-1.73E-01.73E-01.82E-01.68E-9.26E-000000MoleMassVolumeCVapor001001Liquid11010Solid00000Molar ------Mass ------Enthalpy ------MolarK------MassCAL/GM-------MolarMassAverageMolecular 22.86236 MoleMassVolumeC53Vapor10010010Liquid01101001Solid00000100Molar ------Mass ------Enthalpy ---2.62E--7.22E---Molar CAL/MOL-------Mass CAL/GM-------Molar Mass AverageMolecularComponentMass 3.58E-000003.24E- 000000 0000000 0000002.45E- 0000 09.75E-000001.02E- 0 04.11E-000000 0000000 06.00E-000000 0000000 00000004.75E- 0000001.02E-CO3- 0000000SO3- 000000SO4- 0000000HPO4- 0000000PO4-- 0000000 03.13E-00000 0000000 0000000ComponentMass ComponentMass2.19E-000004.47E-0010000000000003.37E-0010005.96E-000001.40E-00000002.51E-00000001.02E-00000003.67E-000000000000000000006.55E-04.24E-000001.41E-CO3-0000000SO3-0000001.73E-SO4-0000000HPO4-0000000PO4--01.75E-00000001.91E-00000001000000000001000000100表4-9全流程物料表（出口）（一 MoleMassVolumeC3Vapor01001Liquid1010Solid000000Molar ------Mass ------Enthalpy------MolarCAL/MOL-------MassCAL/GM-------MolarMassAverageMolecularComponentMass 1.41E-08.43E-9.91E- 1.09E-1.55E-2.41E-9.16E-2.22E- 4.21E-00000 9.25E-00000 5.66E-2.99E-00000 4.53E-9.58E-00000 000000CO3- 1.05E-5.84E-00000SO3- 000000SO4- 000000HPO4- 000000PO4-- 000000 7.16E-8.77E-00000 07.48E-9.21E- 09.18E-4.31E- 02.75E-2.29E-8.58E- 08.32E-8.21E- 00000ComponentMass 4.69E-03.63E-1.08E- 3.61E-1.04E-9.98E-6.12E- 1.40E-00000 3.07E-00000 1.88E-1.22E-00000 000000 9.20E-000000 9.54E-000000 5.75E-000000 000000 1.51E-3.93E-00000 000000CO3-3.50E-2.39E-00000SO3-000000SO4-000000HPO4-0PO4--1.24E-0000002.38E-3.60E-00000003.23E-1.00E-001.19E-002.91E-1.99E-2.36E-003.59E-8.94E-000000表4-10全流程物料表（出口）（二 Mole