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动力锂离子电池现状、安全性及寿命1
评测内容清华大学核研院锂离子电池实验室介绍动力电池现状锂离子动力电池的安全性锂离子动力电池的使用寿命The
Great
WallInstitute
of
New
Energy
Technology,
INET,
Tsinghua
UniversityMingInstitute
of
Nuclear
and
New
Energy
TechnologyTsinghua
UniversityLess
than
50
minutes
drive45
kmThe
InstituteTsinghuaBeijing锂离子电池研究概况Institute
of
New
Energy
Technology,
INET,
Tsinghua
University20会车动ww力电材料合成,机理诊断,电极/电池工程化,数学模型ge池研t.从纳米尺度到微米尺度,再到毫米尺度性能电极结构电池结构结构材料合成材料修饰表面/安界全性面化学长寿命新工艺
电极制造新材料
电池制备模型高锂电极电极池模型腾负极正极w.top-讨会evencom20Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universityww力电ge池研动力锂离子电池的现状1腾会车动务w.top-讨会event.com目前市场上的混合动力车Institute
of
New
Energy
Technology,
INET,
Tsinghua
University20ww力电ge池研Toyota
HighlanderLexus
RX400hHonda
InsightLexus
GS45Toyota
CamryHonda
CivicToyota
PriusHonda
AccordSaturn
VueChevy
SilveradoFord
Escapemore
and
more1腾会车动务w.top-讨会event.com20混合动力车ELECTRIC
ACCESSORIESPETROLEUM
ONLY76hp
gasoline
engine,
67hp
electric
motor,
1.5kWh
batteryInstitute
of
New
Energy
Technology,
INET,
Tsinghua
University1会车腾动ww力电ADVANCED
ENGINEge池研
top-讨会event.com20ww力电Fuel
Flexgeib池i研lity插电式混合动力车ELECTRIC
ACCESSORIESADVANCED
ENGINEPETROLEUMAND/ORELECTRICITYBATTERY
RECHARGE76hp
gasoline
engine,
67hp
electric
motor,
9.0kWh
battery
(30mi)Institute
of
New
Energy
Technology,
INET,
Tsinghua
University1腾会车动务w.top-讨会event.com102025500105hicle2F0leet
In
Use
(%)15Time
of
Day
(hr)152530Institute
of
New
Energy
Technology,
INET,
Tsinghua
University30150250300PHEV408647
total
miles
driven共行驶8647英里58Cmupmgul&ative
Fuel20C0onsumed(gallons)140
Wh/miPHEVs:>40%
reduction
inoperating
costs>$500
annual
savings037
mpg10076
mpg
&50211
Wh/miAssumes
$2.41/gal
and
9¢/kWhCV$3.45---9.1HEV$2.48---6.5PHEV20$1.58$0.485.4PHEV40$1.21$0.725.1混合动力车的实际节油效果1会w.40040Conventional35350会车动ww力电ge池研p-讨会E-Transportation
is
the
most
significant
technological
revoluafter
the
cellular
and
the
internet.电动交通是移动电话和互联网后的最重要的技术革命。Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universi腾务电动车对动力电池的需求在持续20增长evenw.tot.comp-讨会Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universityevt.要市场会车动ww力电gwe.池研钛酸锂电池移动储能电站Electrovaya,
International
Battery,
Ultralife,
Valance,
Saft.
BYD磷酸铁锂电池固定储能电站to腾务Manage
fluctuations
in
electricity
demand.平抑电网波动。MW
reserve
power
plants.兆瓦级储能电站。Manufacturers
to
take
a
part:
A123,
Altairnano,
Enerdel,规模储能是动力电池的又一2重0encomww力电Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universityge池研High
power高功率(>10C)-84
manufacturers,>1500Ultra
High
power超高功率(>20C)-19
manufacturers,Market
grow
of
15%CAGR(复合年均增长率)peryear
driven
by
the
EV
growing
market,Cell
costsare
decreasing
by
8%
per
year
(Source:
IIT).动力电池的现状杰2011汽腾会车动务w.different
cell
modelso.pt-
e讨会ve>120
different
cell
models.t.nc
om中日韩在动力电池制造方面占支配腾
务车
力Institute
of
New
Energy
Technology,
INET,
Tsinghua
University地动位20ev会t.Far-East
manufacturers
dominate
the
market台湾1会ww
.电池geto研讨p-encom20Institute
of
New
Energy
Technology,
INET,
Tsinghua
University动力电池的包装方式Prismaticcell•较好的传热安全性好
使用寿命长1务腾会车动ww力电w.ge池研p-讨会enPouch
.
comCylinCellInstitute
of
New
Energy
Technology,
INET,
Tsinghua
UniversitySize[mm]Cap[Ah]CyclelifeTemprangeWeight[gr]energydensity[Wh/Kg]energy[Wh/L]p-会Volumeevenpowert.coA123-AHR18700M1ULTRAD=18L=700.7
1000to90%-10to10038601291085523169A123-AHR32157M1HDD=32L=15710Saft-VL12VD=47L=173121000to80%500to80%-30to603041082611085526148-30to6064067144843718000Volume
20会车动[W/Kg]ge池d研ensity功率最高的磷酸铁锂电We池ightWeight1[W讨/L]density
腾constant务powerdenwswiwt力y
电mSee
also
‐.to北京中润恒动电池有限公司Institute
of
New
Energy
Technology,
INET,
Tsinghua
UniversityBeijing
C8h5i0nxa560
xPowerel71200
500
to
?80%7000102211028213有限公司深圳市龙锂实业
145
x55255
xLionik100500
toto806%036-02010518610551868单体电池容量最高的高功率动力电池CellSizeCap[mm]Cycle[Ah]TemplifeWeightrangeWeight[gr]densitytenergydensity[Wh/Kg]density[Wh/L][W/Kg]Volumeenergydensity[W/L]杰2011汽腾务w.t.CellVCapCycle[Ah]
lifeto80%Weight[gr]Weightenergydensity[Wh/Kg]Volumeenergydensity[Wh/L]务Weight力tVolumepowerdensity
[W/L]en[W/Kg]Advancedbatteryfactory12010073.31.210004392239552514372mQ-LiteIndustrial3.71.35004012027530066885ICR18650HHCENSEnergyTechCo3.21.1200045782122844774218650PAmericanLithiumInc3.21.5200034.314029027985806No-P.NHenanBideliEnergy3.71.45003813630627266129ICR18650PSamsung3.61.55004512032620005443INR18650-15R20
ww功率最高的18650电池pow1erw.
op-density腾会车ge动研讨会evHigh
competitive
market
with
almost
50
different
cell
modelsInstitute
of
New
Energy
Technology,
INET,
Tsinghua
UniversityCellV
CapCycle[Ah]
lifeto80%Highoper.Temp.WeightenergydensityVolumeenergydensityVolumeent.cpoweromdensity[W/L]SaftVL32600-125AdvancedBatteryFactory3.2v/60ah1060Weightpower2d0ensity]动w力电ge池1研29p-讨会操作温度最高的动力电池[c]
[Wh/Kg]
[Wh/L]腾[W1/Kg会车务w4.24200125123259613.66030009080127666EV
needs
batteries
with
up
to
80 C
hightemperature
operating
range…mInstitute
of
New
Energy
Technology,
INET,
Tsinghua
Universityw.toevCellI.DGPLbattery,GE-32AH-02,32AHWh/Kg
ChargeRate93
9.38CCycleLife500StandardChargeQuickCharge
FastCharge务力w.<C/3C/3<,<2C
>2C
>10C84
16C
500会车动快速充电动力电池UltraFastChargewwto研讨ev会t.短问题的最经济的方法。road
charging
stations.Current
Market
Ultra
fast
charging
cellUltra‐fast
charge
StationInstitute
of
New
Energy
Technology,
INET,
Tsinghua
University20腾1GAIAUHE-341440电,池7.5AHp-ToshibaSCiB
65
1en1.9C
c6o000快速充电(up
to
5
min,>80%capacity)是解决电动车续驶里程m20Institute
of
New
Energy
Technology,
INET,
Tsinghua
University车ev会t.Toshiba
Super
Charge
Lithium
IonBattery
-
SCiBLithium
Manganese
oxide
Spinel
cathode
-
LMOLithium
Titanate
Oxide
anode
–
LTORecharge
to
90%
of
full
capacity
in
less
than
5
minutes.Excellent
safety
because
of
high
level
anode
stability.6000
cycles
of
full
D.O.D
to
90%
of
initial
capacity.Low
temperature
discharge
from
-30C.SCIB
is
currently
available
on
the
Schwinn
Tailwind
electric
bike.2.4Voc65
Wh/Kg131
wh/l650
W/Kg1316
W/l/ind/data/tag_files/SCiB_Brochure_5383.pdfVW
&
Toshiba1腾会务动力www.电池geto研讨p-encom杰11汽Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universityww力电ge池研2nd
Generation
Li-Ion
ChemistriesBetter
performanceUp
to
300
Wh/kg
with
fast
recharge.Wider
operating
temperature
range.Fast
Charging.Improved
safety.Reduced
cost.1st
Generation
Li-Ion
ChemistriesWill
dominate
the
rechargeable
market
for
the
near
and
mid future.锂空气电池?下一代锂离子电池动力电池20腾会车动务w.top-讨会event.com杰11汽ww力电ge池研动力电池的安全性问题将影响其市场命运p-讨会coIf
it
is
not
safe
it
will
not
survive…Institute
of
New
Energy
Technology,
INET,
Tsinghua
University动力电池的安全性问题20腾会车动务w.toevent.m20Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universityww力电ge池研锂离子电池的安全性1腾会车动务w.top-讨会event.com20Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universityww力电ge池研1腾会车动务w.top-讨会event.com20Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universityww力电ge池研安全性问题引起的损失1腾会车动务w.top-讨会event.com20Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universityww力电ge池研Safety
cases1腾会车动务w.top-讨会event.com20Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universityww力电ge池研Safety
cases1腾会车动务w.top-讨会event.com20Institute
of
New
Energy
Technology,
INET,
Tsinghuaww力电ge池研•安全性的概念滥用安全性
abuse
thermal
runawayMechanical
机械的crush,nail
penetration挤压、针刺Electrical
电的short
circuit,overcharge短路、过充Thermal
热的thermal
ramp,simulated
fire热箱、火烧•现场安全性
field
failure
thermal
runaway–Manufacturing
defects
由制造瑕疵引起Loose
connection,separator
damage,foreign
debris连接问题、隔 膜损坏、粉尘Can
develop
into
an
internal
short
circuit随机发生,引起内短路Can
lead
to
overheating
and
thermal
runaway引起过热与热失控1腾会车动务w.top-讨会event.com20Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universityww力电ge池研滥用安全性1腾会车动务w.top-讨会event.com20Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universityww力电ge池研现场(随机)安全性1腾会车动务w.top-讨会event.com两种安全性概念的差异Institute
of
New
Energy
Technology,
INET,
Tsinghua
University20ww力电ge池研现场安全性滥用安全性Predictable可预测的
Common
to
all
cells对每一个电池Can/should
be
evaluatedat
the
cell
level可以通过测试进行评估
Time
constants
relativelylong发生过程较长Can
be
augmented
byprotection
devices可以通过保护措施进行改善Not
predictable不可预测的
One-in-a-million
(or
less)随机小概率发生
Difficult
to
evaluate
at
thecell
level,or
through
QC无法通过测试进行评估,也不能通过质量管理来完全消除can
occur
quickly发生很突然PTC,
CID,
shutdownseparators,electroniccontrols
not
are
effective目前所有的安全性措施,均不
能完全消除锂离子电池安全
隐患1腾会车动务w.top-讨会event.com20会车动ww力电ge池研top-讨会发生安全事故的锂离子电池,之前均通过UL安全认证。even对于笔记本电脑电池,发生概率在几百万分之一。发生原因基本上是不可预测的内短路所造成。而这种内 路似乎是不能完全消除。引起安全事故的电池在制造时,均是合格品。目前滥用安全性标准的测试结果,与发或者不发生安全性 事故,之间没有任何联系。Institute
of
New
Energy
Technology,
INET,
Tsinghua
Univer锂离子电池安全性1腾务w.t.com20会车动Major
effort
has
been
payed
to
improve
the
waywws力w电ege池研在人们如此重视锂离子电池安全性的今天,严重的安全性问 题还时有发生。The
battery
community
does
not
have
adequate
teststo
evaluate
safety
as
it
relates
to
the
safety
incidthat
have
taken
place
or
could
take
place.人们还没有找到合适的方法来预测和评测这类安全隐患问题我们在做工作,希望“十二五”结束时,这个问题得到一定程 度的解决。Institute
of
New
Energy
Technology,
INET,
Tsinghua
University1锂离子电池的安全性腾serious
safety
incidents
can
always
occur.t.务w.address
safety
in
lithium-ion
batteries,howevetorp-讨会evencom热失控的机腾会1Institute
of
New
Energy
Technology,
INET,
Tsinghua
University车杰理务动力ev会t.249.9378292.573.716400.90300200100700600500Energy
Released
(J)400Anode/Binder
Anode/Solvent
SEIDecompnCathodeBreakdownSeparatorOxidnSolvent
Oxdn
JouleHeating@Cathode
@Cathode锂离子电池安全性9008000.8
Ah钴酸锂手机电池201汽ww
.电池geto研讨826.2p-encom20Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universityww力电ge池研负极材料的安全性改进1腾会车动务w.top-讨会event.com20Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universityww力电ge池研正极材料1腾会车动务w.top-讨会event.com20Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universityww力电ge池研Heat
release1腾会车动务w.top-讨会event.comSafety
of
cathode
Materials杰
会1Institute
of
New
Energy
Technology,
INET,
Tsinghua
University动20ww力电ge池研腾1汽车务w.top-讨会event.comww力电Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universityge池研隔膜201腾会车动务影响电池安全性的重要指标Shutdown
performance隔膜关闭的温度范围Strength
and
physical
integrity抗压机械强度Shrinkage
allowance 热收缩率w.top-讨会event.com20Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universityww力电ge池研Solvent,non-flamableSalts,high
decomposition
temperatureAdditives,Flame-RetardantGel
electrolyte电解质1腾会车动务w.top-讨会event.com20Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universityww力电ge池研凝胶电解质凝胶电解质的放热量与放热速率P(VdF-HFP)凝胶电解质在. m
o
c燃烧过程中的放热总量非接近于纯液态电解液体系并且随着P(VdF-HFP)在凝胶电解质中浓度的增加,相应的热释放速率逐渐降。采用P(VdF-HFP)凝胶电解质比液态电解液更为安PMMA凝胶电解质体系中,情况却是相反:其燃烧反应放热总量和热释放速率都PMMA的加入而显著增大。黄倩,厦门大学博士论文1腾会车动务w.top-讨会event20Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universityww力电ge池研锂离子电池的安全性是一个复杂的系统问题动力电池安全性是一个系统问题。从单纯的电池材料改性(正极、负极、电解质、隔膜…)是不能完全解决安全性问题,但可以大幅度地提高。1腾会车动务w.top-讨会event.comww力电Institute
of
New
Energy
Technology,
INET,
Tsinghua
Universityge池研正极材料包覆201腾会车动务w.top-讨会event.comww力电ge池研钴酸锂包覆磷酸铝201腾会车动务5-10nm
AlPO4过充电前过充电后自制安全性手机电池过充电试验未燃烧、未爆炸。过充电市售品牌电池电芯Institute
of
New剧烈燃TechnolEongeyr,gyIN烧ET,Tsinghua
Universityw.top-讨会event.com高性能高安全性动力电池20ww力电采用正极材料表面与界面控制技术、电解质添ge池研加剂等技术,制备出高安全性动力电池。20V过充150℃热箱5小时以上标称容量12Ah,三元氧化物正极材料。电池比能量大于
160wh/kg,比功率大于1200W/kg,Institute
of
New
Energy
Technology,
INET,
Tsinghua
University安全很好的倍率性能1腾会车动务w.top-讨会event.com目前市售三元动力电池的过充电Institute
of
New
Energy
Technology,
INET,
Tsinghua
University20ww力电ge池研充电到5.2V时,发生剧烈燃烧1腾会车动务w.top-讨会event.com目前市售三元动力电池Institute
of
New
Energy
Technology,
INET,
Tsinghua
University20ww力电ge池研充电到4.15V,加热到120℃,发生剧烈燃烧1腾会车动务w.top-讨会event.com会车动ww力电ge池研动力电池的使用寿命与成本如何评测动力电池的使用寿命现场检测电池的寿命状态(SOH)Institute
of
New
Energy
Technology,
INET,
Tsinghua
University务锂离子动力电池的使用寿20
命top-讨会evenw.t.com20力Also
need
to
consider
combination
of
high
and
low
frequency
cycling
and
calendarw
wlife
电池ev会t.电池循环寿命70%50%4000Data
presented
by
Christian
Rosenkranz
(Johnson
Controls)
at
EVS
20,
2006Institute
of
New
Energy
Technology,
INET,
Tsinghua
University1腾会车动PHEV
battery
likely
to
deep-cycle
each
day
driven:15
yrs
equates
to
4000-5000
de务ep
cyclesgeto研讨p-encomww力电-e
会ntomInstitute
of
New
Energy
Technology,
INET,
Tsinghua
University$4,005$2,865$2,919$3,002$1,998$1,992$2,004$2,020$2,079$2,407$2,454$2,433$5,117$8,433$663$-$2,000$4,000$6,000$10,000$8,000$14,000$12,000$18,000$16,000CVHEVPHEV20PHEV40transmissionengine25%电池占电动车成本比例2)
all
component
costs
assume
projected
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电池的成本占整个电动车成本的25~60%。是一个非常重要的零部件。车的使用寿命:10-15年动力电池目前的使用寿命是3-7年,LG化学声称可 以有10-15年的寿命保证。因此大幅度地延长动力锂离子电池的使用寿
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