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动力锂离子电池现状、安全性及寿命1

评测内容清华大学核研院锂离子电池实验室介绍动力电池现状锂离子动力电池的安全性锂离子动力电池的使用寿命The

Great

WallInstitute

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UniversityMingInstitute

of

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and

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UniversityLess

than

50

minutes

drive45

kmThe

InstituteTsinghuaBeijing锂离子电池研究概况Institute

of

New

Energy

Technology,

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Tsinghua

University20会车动ww力电材料合成,机理诊断,电极/电池工程化,数学模型ge池研t.从纳米尺度到微米尺度,再到毫米尺度性能电极结构电池结构结构材料合成材料修饰表面/安界全性面化学长寿命新工艺

电极制造新材料

电池制备模型高锂电极电极池模型腾负极正极w.top-讨会evencom20Institute

of

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Universityww力电ge池研动力锂离子电池的现状1腾会车动务w.top-讨会event.com目前市场上的混合动力车Institute

of

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Energy

Technology,

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University20ww力电ge池研Toyota

HighlanderLexus

RX400hHonda

InsightLexus

GS45Toyota

CamryHonda

CivicToyota

PriusHonda

AccordSaturn

VueChevy

SilveradoFord

Escapemore

and

more1腾会车动务w.top-讨会event.com20混合动力车ELECTRIC

ACCESSORIESPETROLEUM

ONLY76hp

gasoline

engine,

67hp

electric

motor,

1.5kWh

batteryInstitute

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University1会车腾动ww力电ADVANCED

ENGINEge池研

top-讨会event.com20ww力电Fuel

Flexgeib池i研lity插电式混合动力车ELECTRIC

ACCESSORIESADVANCED

ENGINEPETROLEUMAND/ORELECTRICITYBATTERY

RECHARGE76hp

gasoline

engine,

67hp

electric

motor,

9.0kWh

battery

(30mi)Institute

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University1腾会车动务w.top-讨会event.com102025500105hicle2F0leet

In

Use

(%)15Time

of

Day

(hr)152530Institute

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University30150250300PHEV408647

total

miles

driven共行驶8647英里58Cmupmgul&ative

Fuel20C0onsumed(gallons)140

Wh/miPHEVs:>40%

reduction

inoperating

costs>$500

annual

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mpg

&50211

Wh/miAssumes

$2.41/gal

and

9¢/kWhCV$3.45---9.1HEV$2.48---6.5PHEV20$1.58$0.485.4PHEV40$1.21$0.725.1混合动力车的实际节油效果1会w.40040Conventional35350会车动ww力电ge池研p-讨会E-Transportation

is

the

most

significant

technological

revoluafter

the

cellular

and

the

internet.电动交通是移动电话和互联网后的最重要的技术革命。Institute

of

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Tsinghua

Universi腾务电动车对动力电池的需求在持续20增长evenw.tot.comp-讨会Institute

of

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INET,

Tsinghua

Universityevt.要市场会车动ww力电gwe.池研钛酸锂电池移动储能电站Electrovaya,

International

Battery,

Ultralife,

Valance,

Saft.

BYD磷酸铁锂电池固定储能电站to腾务Manage

fluctuations

in

electricity

demand.平抑电网波动。MW

reserve

power

plants.兆瓦级储能电站。Manufacturers

to

take

a

part:

A123,

Altairnano,

Enerdel,规模储能是动力电池的又一2重0encomww力电Institute

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Universityge池研High

power高功率(>10C)-84

manufacturers,>1500Ultra

High

power超高功率(>20C)-19

manufacturers,Market

grow

of

15%CAGR(复合年均增长率)peryear

driven

by

the

EV

growing

market,Cell

costsare

decreasing

by

8%

per

year

(Source:

IIT).动力电池的现状杰2011汽腾会车动务w.different

cell

modelso.pt-

e讨会ve>120

different

cell

models.t.nc

om中日韩在动力电池制造方面占支配腾

务车

力Institute

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dominate

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market台湾1会ww

.电池geto研讨p-encom20Institute

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University动力电池的包装方式Prismaticcell•较好的传热安全性好

使用寿命长1务腾会车动ww力电w.ge池研p-讨会enPouch

.

comCylinCellInstitute

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UniversitySize[mm]Cap[Ah]CyclelifeTemprangeWeight[gr]energydensity[Wh/Kg]energy[Wh/L]p-会Volumeevenpowert.coA123-AHR18700M1ULTRAD=18L=700.7

1000to90%-10to10038601291085523169A123-AHR32157M1HDD=32L=15710Saft-VL12VD=47L=173121000to80%500to80%-30to603041082611085526148-30to6064067144843718000Volume

20会车动[W/Kg]ge池d研ensity功率最高的磷酸铁锂电We池ightWeight1[W讨/L]density

腾constant务powerdenwswiwt力y

电mSee

also

‐.to北京中润恒动电池有限公司Institute

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?80%7000102211028213有限公司深圳市龙锂实业

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toto806%036-02010518610551868单体电池容量最高的高功率动力电池CellSizeCap[mm]Cycle[Ah]TemplifeWeightrangeWeight[gr]densitytenergydensity[Wh/Kg]density[Wh/L][W/Kg]Volumeenergydensity[W/L]杰2011汽腾务w.t.CellVCapCycle[Ah]

lifeto80%Weight[gr]Weightenergydensity[Wh/Kg]Volumeenergydensity[Wh/L]务Weight力tVolumepowerdensity

[W/L]en[W/Kg]Advancedbatteryfactory12010073.31.210004392239552514372mQ-LiteIndustrial3.71.35004012027530066885ICR18650HHCENSEnergyTechCo3.21.1200045782122844774218650PAmericanLithiumInc3.21.5200034.314029027985806No-P.NHenanBideliEnergy3.71.45003813630627266129ICR18650PSamsung3.61.55004512032620005443INR18650-15R20

ww功率最高的18650电池pow1erw.

op-density腾会车ge动研讨会evHigh

competitive

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with

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50

different

cell

modelsInstitute

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UniversityCellV

CapCycle[Ah]

lifeto80%Highoper.Temp.WeightenergydensityVolumeenergydensityVolumeent.cpoweromdensity[W/L]SaftVL32600-125AdvancedBatteryFactory3.2v/60ah1060Weightpower2d0ensity]动w力电ge池1研29p-讨会操作温度最高的动力电池[c]

[Wh/Kg]

[Wh/L]腾[W1/Kg会车务w4.24200125123259613.66030009080127666EV

needs

batteries

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up

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Universityw.toevCellI.DGPLbattery,GE-32AH-02,32AHWh/Kg

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>2C

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16C

500会车动快速充电动力电池UltraFastChargewwto研讨ev会t.短问题的最经济的方法。road

charging

stations.Current

Market

Ultra

fast

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University车ev会t.Toshiba

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-

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-

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to

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of

full

capacity

in

less

than

5

minutes.Excellent

safety

because

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high

level

anode

stability.6000

cycles

of

full

D.O.D

to

90%

of

initial

capacity.Low

temperature

discharge

from

-30C.SCIB

is

currently

available

on

the

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Tailwind

electric

bike.2.4Voc65

Wh/Kg131

wh/l650

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W/l/ind/data/tag_files/SCiB_Brochure_5383.pdfVW

&

Toshiba1腾会务动力www.电池geto研讨p-encom杰11汽Institute

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Technology,

INET,

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Universityww力电ge池研2nd

Generation

Li-Ion

ChemistriesBetter

performanceUp

to

300

Wh/kg

with

fast

recharge.Wider

operating

temperature

range.Fast

Charging.Improved

safety.Reduced

cost.1st

Generation

Li-Ion

ChemistriesWill

dominate

the

rechargeable

market

for

the

near

and

mid future.锂空气电池?下一代锂离子电池动力电池20腾会车动务w.top-讨会event.com杰11汽ww力电ge池研动力电池的安全性问题将影响其市场命运p-讨会coIf

it

is

not

safe

it

will

not

survive…Institute

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Energy

Technology,

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Tsinghua

University动力电池的安全性问题20腾会车动务w.toevent.m20Institute

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Universityww力电ge池研锂离子电池的安全性1腾会车动务w.top-讨会event.com20Institute

of

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Energy

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INET,

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Universityww力电ge池研1腾会车动务w.top-讨会event.com20Institute

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INET,

Tsinghua

Universityww力电ge池研安全性问题引起的损失1腾会车动务w.top-讨会event.com20Institute

of

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Energy

Technology,

INET,

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Universityww力电ge池研Safety

cases1腾会车动务w.top-讨会event.com20Institute

of

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Energy

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Tsinghua

Universityww力电ge池研Safety

cases1腾会车动务w.top-讨会event.com20Institute

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Technology,

INET,

Tsinghuaww力电ge池研•安全性的概念滥用安全性

abuse

thermal

runawayMechanical

机械的crush,nail

penetration挤压、针刺Electrical

电的short

circuit,overcharge短路、过充Thermal

热的thermal

ramp,simulated

fire热箱、火烧•现场安全性

field

failure

thermal

runaway–Manufacturing

defects

由制造瑕疵引起Loose

connection,separator

damage,foreign

debris连接问题、隔 膜损坏、粉尘Can

develop

into

an

internal

short

circuit随机发生,引起内短路Can

lead

to

overheating

and

thermal

runaway引起过热与热失控1腾会车动务w.top-讨会event.com20Institute

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Universityww力电ge池研滥用安全性1腾会车动务w.top-讨会event.com20Institute

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Energy

Technology,

INET,

Tsinghua

Universityww力电ge池研现场(随机)安全性1腾会车动务w.top-讨会event.com两种安全性概念的差异Institute

of

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Energy

Technology,

INET,

Tsinghua

University20ww力电ge池研现场安全性滥用安全性Predictable可预测的

Common

to

all

cells对每一个电池Can/should

be

evaluatedat

the

cell

level可以通过测试进行评估

Time

constants

relativelylong发生过程较长Can

be

augmented

byprotection

devices可以通过保护措施进行改善Not

predictable不可预测的

One-in-a-million

(or

less)随机小概率发生

Difficult

to

evaluate

at

thecell

level,or

through

QC无法通过测试进行评估,也不能通过质量管理来完全消除can

occur

quickly发生很突然PTC,

CID,

shutdownseparators,electroniccontrols

not

are

effective目前所有的安全性措施,均不

能完全消除锂离子电池安全

隐患1腾会车动务w.top-讨会event.com20会车动ww力电ge池研top-讨会发生安全事故的锂离子电池,之前均通过UL安全认证。even对于笔记本电脑电池,发生概率在几百万分之一。发生原因基本上是不可预测的内短路所造成。而这种内 路似乎是不能完全消除。引起安全事故的电池在制造时,均是合格品。目前滥用安全性标准的测试结果,与发或者不发生安全性 事故,之间没有任何联系。Institute

of

New

Energy

Technology,

INET,

Tsinghua

Univer锂离子电池安全性1腾务w.t.com20会车动Major

effort

has

been

payed

to

improve

the

waywws力w电ege池研在人们如此重视锂离子电池安全性的今天,严重的安全性问 题还时有发生。The

battery

community

does

not

have

adequate

teststo

evaluate

safety

as

it

relates

to

the

safety

incidthat

have

taken

place

or

could

take

place.人们还没有找到合适的方法来预测和评测这类安全隐患问题我们在做工作,希望“十二五”结束时,这个问题得到一定程 度的解决。Institute

of

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Energy

Technology,

INET,

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University1锂离子电池的安全性腾serious

safety

incidents

can

always

occur.t.务w.address

safety

in

lithium-ion

batteries,howevetorp-讨会evencom热失控的机腾会1Institute

of

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Energy

Technology,

INET,

Tsinghua

University车杰理务动力ev会t.249.9378292.573.716400.90300200100700600500Energy

Released

(J)400Anode/Binder

Anode/Solvent

SEIDecompnCathodeBreakdownSeparatorOxidnSolvent

Oxdn

JouleHeating@Cathode

@Cathode锂离子电池安全性9008000.8

Ah钴酸锂手机电池201汽ww

.电池geto研讨826.2p-encom20Institute

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Universityww力电ge池研负极材料的安全性改进1腾会车动务w.top-讨会event.com20Institute

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Technology,

INET,

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Universityww力电ge池研正极材料1腾会车动务w.top-讨会event.com20Institute

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Technology,

INET,

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Universityww力电ge池研Heat

release1腾会车动务w.top-讨会event.comSafety

of

cathode

Materials杰

会1Institute

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Energy

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University动20ww力电ge池研腾1汽车务w.top-讨会event.comww力电Institute

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Energy

Technology,

INET,

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Universityge池研隔膜201腾会车动务影响电池安全性的重要指标Shutdown

performance隔膜关闭的温度范围Strength

and

physical

integrity抗压机械强度Shrinkage

allowance 热收缩率w.top-讨会event.com20Institute

of

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Energy

Technology,

INET,

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Universityww力电ge池研Solvent,non-flamableSalts,high

decomposition

temperatureAdditives,Flame-RetardantGel

electrolyte电解质1腾会车动务w.top-讨会event.com20Institute

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Universityww力电ge池研凝胶电解质凝胶电解质的放热量与放热速率P(VdF-HFP)凝胶电解质在. m

o

c燃烧过程中的放热总量非接近于纯液态电解液体系并且随着P(VdF-HFP)在凝胶电解质中浓度的增加,相应的热释放速率逐渐降。采用P(VdF-HFP)凝胶电解质比液态电解液更为安PMMA凝胶电解质体系中,情况却是相反:其燃烧反应放热总量和热释放速率都PMMA的加入而显著增大。黄倩,厦门大学博士论文1腾会车动务w.top-讨会event20Institute

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Universityww力电ge池研锂离子电池的安全性是一个复杂的系统问题动力电池安全性是一个系统问题。从单纯的电池材料改性(正极、负极、电解质、隔膜…)是不能完全解决安全性问题,但可以大幅度地提高。1腾会车动务w.top-讨会event.comww力电Institute

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Universityge池研正极材料包覆201腾会车动务w.top-讨会event.comww力电ge池研钴酸锂包覆磷酸铝201腾会车动务5-10nm

AlPO4过充电前过充电后自制安全性手机电池过充电试验未燃烧、未爆炸。过充电市售品牌电池电芯Institute

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Universityw.top-讨会event.com高性能高安全性动力电池20ww力电采用正极材料表面与界面控制技术、电解质添ge池研加剂等技术,制备出高安全性动力电池。20V过充150℃热箱5小时以上标称容量12Ah,三元氧化物正极材料。电池比能量大于

160wh/kg,比功率大于1200W/kg,Institute

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University安全很好的倍率性能1腾会车动务w.top-讨会event.com目前市售三元动力电池的过充电Institute

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Technology,

INET,

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University20ww力电ge池研充电到5.2V时,发生剧烈燃烧1腾会车动务w.top-讨会event.com目前市售三元动力电池Institute

of

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Technology,

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University20ww力电ge池研充电到4.15V,加热到120℃,发生剧烈燃烧1腾会车动务w.top-讨会event.com会车动ww力电ge池研动力电池的使用寿命与成本如何评测动力电池的使用寿命现场检测电池的寿命状态(SOH)Institute

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University务锂离子动力电池的使用寿20

命top-讨会evenw.t.com20力Also

need

to

consider

combination

of

high

and

low

frequency

cycling

and

calendarw

wlife

电池ev会t.电池循环寿命70%50%4000Data

presented

by

Christian

Rosenkranz

(Johnson

Controls)

at

EVS

20,

2006Institute

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Technology,

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University1腾会车动PHEV

battery

likely

to

deep-cycle

each

day

driven:15

yrs

equates

to

4000-5000

de务ep

cyclesgeto研讨p-encomww力电-e

会ntomInstitute

of

New

Energy

Technology,

INET,

Tsinghua

University$4,005$2,865$2,919$3,002$1,998$1,992$2,004$2,020$2,079$2,407$2,454$2,433$5,117$8,433$663$-$2,000$4,000$6,000$10,000$8,000$14,000$12,000$18,000$16,000CVHEVPHEV20PHEV40transmissionengine25%电池占电动车成本比例2)

all

component

costs

assume

projected

statuscharger/plug40%batterymotor/inverterProjected

Retail

Powertrain

Costs-Midsize

Sedans

腾会车动1)including

manufacturer

and

deale务r

markupsw52%

.

p研o

t

e

g

池20

160%$663.c动力电池的使用寿命20ww力电ge池研

电池的成本占整个电动车成本的25~60%。是一个非常重要的零部件。车的使用寿命:10-15年动力电池目前的使用寿命是3-7年,LG化学声称可 以有10-15年的寿命保证。因此大幅度地延长动力锂离子电池的使用寿

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