G-Professional-FAIRY-手动洗碗液安全数据表说明书

P&GProfessionalFAIRYManualWashingUpLiquid

SafetyDataSheet

accordingtoRegulation(EC)No.453/2010

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

Productidentifier

1.1.

Dateofissue:28/01/2015 Revisiondate: : Version:1.0

Productform :Mixture

Tradename :P&GProfessionalFAIRYManualWashingUpLiquid

Productcode :PA00185795

Productgroup :Tradeproduct

1.2. Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst

Relevantidentifieduses

Mainusecategory :Professionaluse

Functionorusecategory :Washingandcleaningproducts(includingsolventbasedproducts)

Usesadvisedagainst

Noadditionalinformationavailable

1.3. Detailsofthesupplierofthesafetydatasheet

Procter&GambleUKBrooklands,Weybridge,Surrey,KT130XP,UKTel:01932896000Fax:01932896200

1.4. Emergencytelephonenumber

Professional:

customerservice@

Emergencynumber :(UK)EmergencyTel:08003288304(IRL)EmergencyTel:1800509497

SECTION2:Hazardsidentification

Classificationofthesubstanceormixture

2.1.

ClassificationaccordingtoRegulation(EC)No.1272/2008[CLP]

EyeIrrit.2 H319AquaticChronic3H412

FulltextofH-phrases:seesection16

ClassificationaccordingtoDirective67/548/EEC[DSD]or1999/45/EC[DPD]

Xi;R36

FulltextofR-phrases:seesection16

Adversephysicochemical,humanhealthandenvironmentaleffects

Noadditionalinformationavailable

2.2. Labelelements

LabellingaccordingtoRegulation(EC)No.1272/2008[CLP]

Hazardpictograms(CLP) :

Signalword(CLP) :Warning

Hazardstatements(CLP) :H319-Causesseriouseyeirritation

H412-Harmfultoaquaticlifewithlonglastingeffects

Precautionarystatements(CLP) :P102-Keepoutofreachofchildren

P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontactlenses,ifpresentandeasytodo.Continuerinsing

P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention

P501-Disposeofcontents/containertoanappropriatelocalwastesystem

2.3. Otherhazards

Otherhazardsnotcontributingtotheclassification

:NopresenceofPBTandvPvBingredients.

28/01/2015 EN(English) 1/9

P&GProfessionalFAIRYManualWashingUpLiquid

SafetyDataSheet

accordingtoRegulation(EC)No.453/2010

28/01/2015

EN(English)

8/9

SECTION3:Composition/informationoningredients

Substance

3.1.

Notapplicable

3.2. Mixture

Name

Productidentifier

%

ClassificationaccordingtoDirective67/548/EEC

ClassificationaccordingtoRegulation(EC)No.

1272/2008[CLP]

SodiumLaurylSulphate

(CASNo)1231880-35-5

(REACH-no)01-2119582870-31

10-20

Xn;R22Xi;R41Xi;R38

AcuteTox.4(Oral),H302SkinIrrit.2,H315

EyeDam.1,H318AquaticChronic3,H412

SodiumC12-14Pareth-3Sulfate

(CASNo)68891-38-3

(ECno)Polymer

5-10

Xi;R41Xi;R38

SkinIrrit.2,H315EyeDam.1,H318

AquaticChronic3,H412

LauramineOxide

(CASNo)308062-28-4

(ECno)931-292-6

(REACH-no)01-2119490061-47

5-10

Xn;R22Xi;R41Xi;R38N;R50

AcuteTox.4(Oral),H302SkinIrrit.2,H315

EyeDam.1,H318AquaticAcute1,H400AquaticChronic2,H411

SodiumC12-14AlkylSulfate

(CASNo)85586-07-8

(ECno)287-809-4

(REACH-no)01-2119489463-28

1-5

Xn;R22Xi;R41Xi;R38

AcuteTox.4(Oral),H302SkinIrrit.2,H315

EyeDam.1,H318AquaticChronic3,H412

FulltextofR-andH-phrases:seesection16

SECTION4:Firstaidmeasures

Descriptionoffirstaidmeasures

4.1.

First-aidmeasuresafterinhalation :IFINHALED:removevictimtofreshairandkeepatrestinapositioncomfortableforbreathing.

CallaPOISONCENTERordoctor/physicianifyoufeelunwell.

First-aidmeasuresafterskincontact :IFONSKIN:Washwithplentyofsoapandwater.Takeoffcontaminatedclothingandwash

beforereuse.Ifskinirritationoccurs:Getmedicaladvice/attention.Discontinueuseofproduct.

First-aidmeasuresaftereyecontact :IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontactlenses,ifpresent

andeasytodo.Continuerinsing.ImmediatelycallaPOISONCENTERordoctor/physician.

First-aidmeasuresafteringestion :IFSWALLOWED:rinsemouth.DoNOTinducevomiting.ImmediatelycallaPOISONCENTER

ordoctor/physician.

4.2. Mostimportantsymptomsandeffects,bothacuteanddelayed

Symptoms/injuriesafterinhalation :Coughing.sneezing.Symptoms/injuriesafterskincontact :Redness.Swelling.dryness.Itching.

Symptoms/injuriesaftereyecontact :Severepain.Redness.Swelling.Blurredvision.

Symptoms/injuriesafteringestion :Oralmucosalorgastro-intestinalirritation.Nausea.Vomiting.Excessivesecretion.Diarrhea.

4.3. Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded

Refertosection4.1.

SECTION5:Firefightingmeasures

Extinguishingmedia

5.1.

Suitableextinguishingmedia :Drychemicalpowder,alcohol-resistantfoam,carbondioxide(CO2).

5.2. Specialhazardsarisingfromthesubstanceormixture

Firehazard :Nofirehazard.Noncombustible.

Explosionhazard :Productisnotexplosive.

Reactivity :Nodangerousreactionsknown.

5.3. Adviceforfirefighters

Firefightinginstructions :Nospecificfirefightinginstructionsrequired.

Protectionduringfirefighting :Incaseofinadequateventilationwearrespiratoryprotection.

SECTION6:Accidentalreleasemeasures

Personalprecautions,protectiveequipmentandemergencyprocedures

6.1.

Fornon-emergencypersonnel

Protectiveequipment :Wearsuitableglovesandeye/faceprotection.

Foremergencyresponders

Protectiveequipment :Wearsuitableglovesandeye/faceprotection.

6.2. Environmentalprecautions

Consumerproductsendingupdownthedrainafteruse.Preventsoilandwaterpollution.Preventspreadinginsewers.

6.3. Methodsandmaterialforcontainmentandcleaningup

Forcontainment :Scoopabsorbedsubstanceintoclosingcontainers.

Methodsforcleaningup :Smallquantitiesofliquidspill:takeupinnon-combustibleabsorbentmaterialandshovelinto

containerfordisposal.Largespills:containreleasedsubstance,pumpintosuitablecontainers.Thismaterialanditscontainermustbedisposedofinasafeway,andasperlocallegislation.

6.4. Referencetoothersections

RefertoSections8and13.

SECTION7:Handlingandstorage

Precautionsforsafehandling

7.1.

Precautionsforsafehandling :Avoidcontactwitheyes.Usepersonalprotectiveequipmentasrequired.Donoteat,drinkor

smokewhenusingthisproduct.Donothandleuntilallsafetyprecautionshavebeenreadandunderstood.

7.2. Conditionsforsafestorage,includinganyincompatibilities

Storageconditions :Storeinoriginalcontainer.Refertosection10.

Incompatibleproducts :Refertosection10.

Incompatiblematerials :Notapplicable.

Prohibitionsonmixedstorage :Notapplicable.

Storagearea :Storeinacoolarea.Storeinadryarea.

7.3. Specificenduse(s)

Refertosection1.2.

SECTION8:Exposurecontrols/personalprotection

Controlparameters

8.1.

Nationallimitvalues

Noadditionalinformationavailable

Monitoringprocedures:DNELS,PNECS,OEL

LauramineOxide(308062-28-4)

DNEL/DMEL(Workers)

Long-term-systemiceffects,dermal

11mg/kgbodyweight/day

Long-term-systemiceffects,inhalation

6.2mg/m³

DNEL/DMEL(Generalpopulation)

Long-term-systemiceffects,oral

0.44mg/kgbodyweight/day

Long-term-systemiceffects,inhalation

1.53mg/m³

Long-term-systemiceffects,dermal

5.5mg/kgbodyweight/day

PNEC(Water)

PNECaqua(freshwater)

0.0335mg/l

PNECaqua(marinewater)

0.00335mg/l

PNECaqua(intermittent,freshwater)

0.0335mg/l

PNEC(Sediment)

PNECsediment(freshwater)

5.24mg/kgdwt

PNECsediment(marinewater)

0.524mg/kgdwt

PNEC(Soil)

PNECsoil

1.02mg/kgdwt

PNEC(STP)

PNECsewagetreatmentplant

24mg/l

SodiumC12-14AlkylSulfate(85586-07-8)

DNEL/DMEL(Workers)

Long-term-systemiceffects,dermal

4060mg/kgbodyweight/day

Long-term-systemiceffects,inhalation

285mg/m³

DNEL/DMEL(Generalpopulation)

Long-term-systemiceffects,oral

24mg/kgbodyweight/day

Long-term-systemiceffects,inhalation

85mg/m³

Long-term-systemiceffects,dermal

2440mg/kgbodyweight/day

PNEC(Water)

PNECaqua(freshwater)

0.102mg/l

PNECaqua(marinewater)

0.01mg/l

SodiumC12-14AlkylSulfate(85586-07-8)

PNECaqua(intermittent,freshwater)

0.036mg/l

PNEC(Sediment)

PNECsediment(freshwater)

3.58mg/kgdwt

PNECsediment(marinewater)

0.358mg/kgdwt

PNEC(Soil)

PNECsoil

0.654mg/kgdwt

PNEC(STP)

PNECsewagetreatmentplant

1084mg/l

SodiumLaurylSulphate(1231880-35-5)

DNEL/DMEL(Workers)

Long-term-systemiceffects,dermal

4060mg/kgbodyweight/day

Long-term-systemiceffects,inhalation

285mg/m³

DNEL/DMEL(Generalpopulation)

Acute-localeffects,inhalation

>=mg/m³

Long-term-systemiceffects,oral

24mg/kgbodyweight/day

Long-term-systemiceffects,inhalation

85mg/m³

Long-term-systemiceffects,dermal

2440mg/kgbodyweight/day

PNEC(Water)

PNECaqua(freshwater)

0.0782mg/l

PNECaqua(marinewater)

0.00782mg/l

PNECaqua(intermittent,freshwater)

0.036mg/l

PNEC(Sediment)

PNECsediment(freshwater)

4.52mg/kgdwt

PNECsediment(marinewater)

0.452mg/kgdwt

PNEC(Soil)

PNECsoil

0.86mg/kgdwt

PNEC(STP)

PNECsewagetreatmentplant

1084mg/l

8.2. Exposurecontrols

Appropriateengineeringcontrols : Notapplicable.

Personalprotectiveequipment

Protectivepersonalequipmentonlyrequiredincaseofprofessionaluseorforlargepacks(notforhouseholdpacks).Forconsumerusepleasefollowrecommendationasindicatedonthelabeloftheproduct.

Handprotection : Notapplicable.

Eyeprotection : Weareye/faceprotection.

Skinandbodyprotection : Notapplicable.

Respiratoryprotection : Notapplicable.

Environmentalexposurecontrols

Notavailable

SECTION9:Physicalandchemicalproperties

9.1. Informationonbasicphysicalandchemicalproperties

Property

Value

Unit

Testmethod/Notes

Appearance

Liquid.

Physicalstate

Liquid

Colour

Coloured.

Odour

pleasant(perfume).

Odourthreshold

Nodataavailable

pH

9

Meltingpoint

Nodataavailable

Freezingpoint

Nodataavailable

Boilingpoint

Nodataavailable

Property

Value

Unit

Testmethod/Notes

Flashpoint

95-100

°C

Relativeevaporationrate(butylacetate=1)

Nodataavailable

Flammability(solid,gas)

Nodataavailable

Explosivelimits

Nodataavailable

Vapourpressure

Nodataavailable

Relativedensity

Nodataavailable

Solubility

Solubleinwater.

LogPow

Nodataavailable

Auto-ignitiontemperature

Nodataavailable

Decompositiontemperature

Nodataavailable

Viscosity

1000

cP

Explosiveproperties

Noadditionalinformationavailable

Oxidisingproperties

Noadditionalinformationavailable

9.2. Otherinformation

Noadditionalinformationavailable

SECTION10:Stabilityandreactivity

10.1. Reactivity

Nodangerousreactionsknown.

10.2. Chemicalstability

Stableundernormalconditions.

10.3. Possibilityofhazardousreactions

Refertosection10.1onReactivity.

10.4. Conditionstoavoid

Notrequiredfornormalconditionsofuse.

10.5. Incompatiblematerials

Notapplicable.

10.6. Hazardousdecompositionproducts

Noneundernormaluse.

SECTION11:Toxicologicalinformation

11.1. Informationontoxicologicaleffects

Acutetoxicity :Notclassified

P&GProfessionalFAIRYManualWashingUpLiquid

LD50oralcalculated

>2000mg/kg

LauramineOxide(308062-28-4)

LD50oralrat

1064mg/kgOECD401

LD50dermalrat

>2000mg/kgOECD402

ATECLP(oral)

1064mg/kgbodyweight

SodiumC12-14AlkylSulfate(85586-07-8)

LD50oralrat

2000mg/kgEC440/2008B.1bis

LD50dermalrabbit

>500mg/kg

ATECLP(oral)

2000mg/kgbodyweight

SodiumC12-14Pareth-3Sulfate(68891-38-3)

LD50oralrat

4100mg/kg

LD50dermalrat

2001mg/kg

ATECLP(oral)

4100mg/kgbodyweight

ATECLP(dermal)

2001mg/kgbodyweight

SodiumLaurylSulphate(1231880-35-5)

LD50oralrat

1063mg/kg//OECD401

LD50dermalrabbit

>500mg/kgbodyweight//OECD402

ATECLP(oral)

1063mg/kgbodyweight

Skincorrosion/irritation :NotclassifiedpH:9

Seriouseyedamage/irritation :Causesseriouseyeirritation.pH:9

Respiratoryorskinsensitisation :Notclassified

Germcellmutagenicity :Notclassified

Carcinogenicity :Notclassified

Reproductivetoxicity :NotclassifiedSpecifictargetorgantoxicity(singleexposure) :Notclassified

Specifictargetorgantoxicity(repeatedexposure)

:Notclassified

Aspirationhazard :Notclassified

PotentialAdversehumanhealtheffectsandsymptoms

:AcuteToxicity:baseduponavailabledataofthesubstances,classificationcriteriaarenotmet.Carcinogenicity:baseduponavailabledataofthesubstances,classificationcriteriaarenotmet.Corrosivity:baseduponavailabledataofthesubstances,classificationcriteriaarenotmet.

Irritation:severlyirritanttoeyes.Mutagenicity:baseduponavailabledataofthesubstances,classificationcriteriaarenotmet.RepeatedDoseToxicity:baseduponavailabledataofthesubstances,classificationcriteriaarenotmet.Sensitization:baseduponavailabledataofthesubstances,classificationcriteriaarenotmet.ToxicityforReproduction:baseduponavailabledataofthesubstances,classificationcriteriaarenotmet.

Otherinformation :Likelyroutesofexposure:skinandeye.InformationonEffects:refertosection4.

SECTION12:Ecologicalinformation

Toxicity

Ecology-general :Noknownadverseeffectsonthefunctioningofwatertreatmentplantsundernormaluseconditionsasrecommended.Harmfultoaquaticorganisms,maycauselong-termadverseeffectsintheaquaticenvironment.

LauramineOxide(308062-28-4)

LC50fishes1

2.67mg/lPimephalespromelas

EC50Daphnia1

3.1mg/lOECD202;Daphniamagna

ErC50(algae)

0.266mg/l//OECD201;Pseudokirchneriellasubcapitata

NOEC(chronic)

24mg/lEC10;Pseudomonasputida

NOECchronicfish

0.42mg/l//USEPAOPPTS850.1500;Pimephalespromelas

NOECchroniccrustacea

0.7mg/l//OECD211;Daphniamagna

NOECchronicalgae

0.078mg/l//OECD201;Pseudokirchneriellasubcapitata

SodiumC12-14AlkylSulfate(85586-07-8)

LC50fishes1

3.6mg/lOECD203;Oncorhynchusmykiss

LC50otheraquaticorganisms1

3000mg/lDIN38412;Pseudomonasputida

EC50Daphnia1

4.7mg/lEC440/2008C.2;Daphniamagna

ErC50(algae)

>20mg/lEC440/2008C.3;Desmodesmussubspicatus

NOECchronicfish

0.11mg/l//OECD210;Pimephalespromelas

NOECchroniccrustacea

0.14mg/lOECD211;Daphniamagna

SodiumLaurylSulphate(1231880-35-5)

LC50fishes1

3.6mg/lOECD203;Oncorhynchusmykiss

EC50Daphnia1

4.7mg/lDaphniamagna

ErC50(algae)

>20mg/lEC440/2008C.3;Scenedesmussubspicatus

NOEC(chronic)

1083.85mg/lDIN38412;Pseudomonasputida

NOECchronicfish

0.11mg/l//OECD210;Pimephalespromelas

NOECchroniccrustacea

0.14mg/lOECD202;Daphniamagna

NOECchronicalgae

0.6mg/lEC440/2008C.3;Scenedesmussubspicatus

Persistenceanddegradability

LauramineOxide(308062-28-4)

Persistenceanddegradability

Biodegradable.

Biodegradation

90%OECD301B

SodiumC12-14AlkylSulfate(85586-07-8)

Persistenceanddegradability

Biodegradable.

Biodegradation

75.7%OECD301B

SodiumLaurylSulphate(1231880-35-5)

Biodegradation

95.3%OECD301E

Bioaccumulativepotential

LauramineOxide(308062-28-4)

LogPow

<2.7

Bioaccumulativepotential

NotexpectedtobioaccumulateduetothelowlogKow(logKow<4).

SodiumC12-14AlkylSulfate(85586-07-8)

LogPow

<-2.42OECD107;20°C

Bioaccumulativepotential

NotexpectedtobioaccumulateduetothelowlogKow(logKow<4).

SodiumLaurylSulphate(1231880-35-5)

LogPow

1.9

Bioaccumulativepotential

NotexpectedtobioaccumulateduetothelowlogKow(logKow<4).

Mobilityinsoil

LauramineOxide(308062-28-4)

Mobilityinsoil

307OECD106;23.6°C

SodiumC12-14AlkylSulfate(85586-07-8)

Mobilityinsoil

316

SodiumLaurylSulphate(1231880-35-5)

Mobilityinsoil

608-64225°C

ResultsofPBTandvPvBassessment

P&GProfessionalFAIRYManualWashingUpLiquid

ResultsofPBTassessment

NopresenceofPBTandvPvBingredients

Component

Alcohol(64-17-5)

Thissubstance/mixturedoesnotmeetthePBTcriteriaofREACHregulation,annexXIIIThissubstance/mixturedoesnotmeetthevPvBcriteriaofREACHregulation,annexXIII

SodiumHydroxide(1310-73-2)

PBT:notrelevant–noregistrationrequiredvPvB:notrelevant–noregistrationrequired

LauramineOxide(308062-28-4)

Thissubstance/mixturedoesnotmeetthePBTcriteriaofREACHregulation,annexXIIIThissubstance/mixturedoesnotmeetthevPvBcriteriaofREACHregulation,annexXIII

SodiumC12-14AlkylSulfate(85586-07-8)

Thissubstance/mixturedoesnotmeetthePBTcriteriaofREACHregulation,annexXIIIThissubstance/mixturedoesnotmeetthevPvBcriteriaofREACHregulation,annexXIII

2-Propylheptanolethoxylated(160875-66-1)

Thissubstance/mixturedoesnotmeetthePBTcriteriaofREACHregulation,annexXIIIThissubstance/mixturedoesnotmeetthevPvBcriteriaofREACHregulation,annexXIII

SodiumLaurylSulphate(1231880-35-5)

Thissubstance/mixturedoesnotmeetthePBTcriteriaofREACHregulation,annexXIIIThissubstance/mixturedoesnotmeetthevPvBcriteriaofREACHregulation,annexXIII

Otheradverseeffects

Otherinformation :Noothereffectsknown.

SECTION13:Disposalconsiderations

Wastetreatmentmethods

Regionallegislation(waste) :Disposalmustbedoneaccordingtoofficialregulations.

Disposalrecommendations :Thewastecodes/wastedesignationsbelowareinaccordancewithEWC.Waste

mustbedeliveredtoanapprovedwastedisposalcompany.Thewasteistobekeptseparatefromothertypesofwasteuntilitsdisposal.Donotthrowwasteproductintothesewer.Wherepossiblerecyclingispreferredtodisposalorincineration.

.Forhandlingwaste,seemeasuresdescribedinsection7.Empty,uncleanedpackagingneedthesamedisposalconsiderationsasfilledpackaging.

EURALWastecodeproduct :200129*-detergentscontainingdangeroussubstances

150110*-packagingcontainingresiduesoforcontaminatedbydangeroussubstances

SECTION14:Transportinformation

UNnumber

Notapplicable

UNpropershippingname

Notapplicable

14.3. Transporthazardclass(es)

14.4. Packinggroup

Notapplicable

Notapplicable

14.5. Environmentalhazards

14.6. Specialprecautionsforuser

Notapplicable

Notapplicable

14.7. TransportinbulkaccordingtoAnnexIIofMARPOL73/78andtheIBCCode

Notapplicable

SECTION15:Regulatoryinformation

Ingredientlabel :15-30%Anionicsurfactants;5-15%Non-ionicsurfactants;Methylisothiazolinone,Phenoxyethanol,Perfumes.

15.1. Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture

EU-Regulations

NoREACHAnnexXVIIrestrictions

ContainsnosubstanceontheREACHcandidatelist

CESIOrecommendations :Thesurfactant(s)containedinthispreparationcomplies(comply)withthebiodegradabilitycriteria

aslaiddowninRegulation(EC)No.648/2004ondetergents.DatatosupportthisassertionareheldatthedisposalofthecompetentauthoritiesoftheMemberStatesandwillbemadeavailabletothem,attheirdirectrequestorattherequestofa