【《Pickering乳液分离机理及应用概述》2800字】

Pickering乳液分离机理及应用概述目录TOC\o"1-3"\h\u13836Pickering乳液分离机理及应用概述 1162411.1乳液分离机理 2257181.2Pickering乳液在物质分离方面的应用 3乳液是一种多相体系，由分散相、连续相和乳化剂三部分所组成，在乳化剂的作用下，分散相以微小液滴的形式存在于与之不相溶的连续相中，因其液滴粒径小，表面积大所以具有较大的界面面积和界面能。乳液的用途颇为广泛，既可以作为载体应用于化妆品ADDINEN.CITE<EndNote><Cite><Author>Boonme</Author><Year>2007</Year><RecNum>126</RecNum><DisplayText><styleface="superscript">[63,64]</style></DisplayText><record><rec-number>126</rec-number><foreign-keys><keyapp="EN"db-id="x2eewften55xsheaxe95zpajwd0strsfzspz"timestamp="1647623801">126</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Boonme,Prapaporn</author></authors></contributors><titles><title>Applicationsofmicroemulsionsincosmetics</title><secondary-title>Journalofcosmeticdermatology</secondary-title></titles><periodical><full-title>Journalofcosmeticdermatology</full-title></periodical><pages>223-228</pages><volume>6</volume><number>4</number><dates><year>2007</year></dates><isbn>1473-2130</isbn><urls></urls></record></Cite><Cite><Author>Klier</Author><Year>2000</Year><RecNum>127</RecNum><record><rec-number>127</rec-number><foreign-keys><keyapp="EN"db-id="x2eewften55xsheaxe95zpajwd0strsfzspz"timestamp="1647623888">127</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Klier,John</author><author>Tucker,ChristopherJ</author><author>Kalantar,ThomasH</author><author>Green,DP</author></authors></contributors><titles><title>Propertiesandapplicationsofmicroemulsions</title><secondary-title>AdvancedMaterials</secondary-title></titles><periodical><full-title>AdvancedMaterials</full-title></periodical><pages>1751-1757</pages><volume>12</volume><number>23</number><dates><year>2000</year></dates><isbn>0935-9648</isbn><urls></urls></record></Cite></EndNote>[63,64]、食品ADDINEN.CITE<EndNote><Cite><Author>Tang</Author><Year>2015</Year><RecNum>128</RecNum><DisplayText><styleface="superscript">[65]</style></DisplayText><record><rec-number>128</rec-number><foreign-keys><keyapp="EN"db-id="x2eewften55xsheaxe95zpajwd0strsfzspz"timestamp="1647623986">128</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Tang,Juntao</author><author>Quinlan,PatrickJames</author><author>Tam,KamChiu</author></authors></contributors><titles><title>Stimuli-responsivePickeringemulsions:recentadvancesandpotentialapplications</title><secondary-title>SoftMatter</secondary-title></titles><periodical><full-title>SoftMatter</full-title></periodical><pages>3512-3529</pages><volume>11</volume><number>18</number><dates><year>2015</year></dates><urls></urls></record></Cite></EndNote>[65]、个人护理用品ADDINEN.CITE<EndNote><Cite><Author>Simovic</Author><Year>2011</Year><RecNum>129</RecNum><DisplayText><styleface="superscript">[66]</style></DisplayText><record><rec-number>129</rec-number><foreign-keys><keyapp="EN"db-id="x2eewften55xsheaxe95zpajwd0strsfzspz"timestamp="1647624042">129</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Simovic,Spomenka</author><author>Ghouchi-Eskandar,N</author><author>Prestidge,CA</author></authors></contributors><titles><title>Pickeringemulsionsfordermaldelivery</title><secondary-title>JournalofDrugDeliveryScienceandTechnology</secondary-title></titles><periodical><full-title>JournalofDrugDeliveryScienceandTechnology</full-title></periodical><pages>123-133</pages><volume>21</volume><number>1</number><dates><year>2011</year></dates><isbn>1773-2247</isbn><urls></urls></record></Cite></EndNote>[66]、生物医药ADDINEN.CITE<EndNote><Cite><Author>Fernandes</Author><Year>2016</Year><RecNum>130</RecNum><DisplayText><styleface="superscript">[67,68]</style></DisplayText><record><rec-number>130</rec-number><foreign-keys><keyapp="EN"db-id="x2eewften55xsheaxe95zpajwd0strsfzspz"timestamp="1647624088">130</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Fernandes,DonaldA</author><author>Fernandes,DennisD</author><author>Li,Yuchong</author><author>Wang,Yan</author><author>Zhang,Zhenfu</author><author>Rousseau,Derick</author><author>Gradinaru,ClaudiuC</author><author>Kolios,MichaelC</author></authors></contributors><titles><title>Synthesisofstablemultifunctionalperfluorocarbonnanoemulsionsforcancertherapyandimaging</title><secondary-title>Langmuir</secondary-title></titles><periodical><full-title>Langmuir</full-title></periodical><pages>10870-10880</pages><volume>32</volume><number>42</number><dates><year>2016</year></dates><isbn>0743-7463</isbn><urls></urls></record></Cite><Cite><Author>Cheng</Author><Year>2008</Year><RecNum>131</RecNum><record><rec-number>131</rec-number><foreign-keys><keyapp="EN"db-id="x2eewften55xsheaxe95zpajwd0strsfzspz"timestamp="1647624128">131</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Cheng,Mao-Bo</author><author>Wang,Jian-Cheng</author><author>Li,Yu-Hua</author><author>Liu,Xiao-Yan</author><author>Zhang,Xuan</author><author>Chen,Da-Wei</author><author>Zhou,Shu-Feng</author><author>Zhang,Qiang</author></authors></contributors><titles><title>Characterizationofwater-in-oilmicroemulsionfororaldeliveryofearthwormfibrinolyticenzyme</title><secondary-title>JournalofControlledRelease</secondary-title></titles><periodical><full-title>JournalofControlledRelease</full-title></periodical><pages>41-48</pages><volume>129</volume><number>1</number><dates><year>2008</year></dates><isbn>0168-3659</isbn><urls></urls></record></Cite></EndNote>[67,68]、石油开采ADDINEN.CITE<EndNote><Cite><Author>Klier</Author><Year>2000</Year><RecNum>127</RecNum><DisplayText><styleface="superscript">[64]</style></DisplayText><record><rec-number>127</rec-number><foreign-keys><keyapp="EN"db-id="x2eewften55xsheaxe95zpajwd0strsfzspz"timestamp="1647623888">127</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Klier,John</author><author>Tucker,ChristopherJ</author><author>Kalantar,ThomasH</author><author>Green,DP</author></authors></contributors><titles><title>Propertiesandapplicationsofmicroemulsions</title><secondary-title>AdvancedMaterials</secondary-title></titles><periodical><full-title>AdvancedMaterials</full-title></periodical><pages>1751-1757</pages><volume>12</volume><number>23</number><dates><year>2000</year></dates><isbn>0935-9648</isbn><urls></urls></record></Cite></EndNote>[64]、产物分离提纯ADDINEN.CITE<EndNote><Cite><Author>Klier</Author><Year>2000</Year><RecNum>127</RecNum><DisplayText><styleface="superscript">[64]</style></DisplayText><record><rec-number>127</rec-number><foreign-keys><keyapp="EN"db-id="x2eewften55xsheaxe95zpajwd0strsfzspz"timestamp="1647623888">127</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Klier,John</author><author>Tucker,ChristopherJ</author><author>Kalantar,ThomasH</author><author>Green,DP</author></authors></contributors><titles><title>Propertiesandapplicationsofmicroemulsions</title><secondary-title>AdvancedMaterials</secondary-title></titles><periodical><full-title>AdvancedMaterials</full-title></periodical><pages>1751-1757</pages><volume>12</volume><number>23</number><dates><year>2000</year></dates><isbn>0935-9648</isbn><urls></urls></record></Cite></EndNote>[64]等领域中，也可作为模板应用于微胶囊、Janus粒子等材料的制备ADDINEN.CITE<EndNote><Cite><Author>Wolf</Author><Year>2016</Year><RecNum>132</RecNum><DisplayText><styleface="superscript">[69]</style></DisplayText><record><rec-number>132</rec-number><foreign-keys><keyapp="EN"db-id="x2eewften55xsheaxe95zpajwd0strsfzspz"timestamp="1647624180">132</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Wolf,Silke</author><author>Feldmann,Claus</author></authors></contributors><titles><title>Microemulsions:optionstoexpandthesynthesisofinorganicnanoparticles</title><secondary-title>AngewandteChemieInternationalEdition</secondary-title></titles><periodical><full-title>AngewandteChemieInternationalEdition</full-title></periodical><pages>15728-15752</pages><volume>55</volume><number>51</number><dates><year>2016</year></dates><isbn>1433-7851</isbn><urls></urls></record></Cite></EndNote>[69]。如图1.7所示，根据分散相以及连续相的类型不同可分为：水包油型乳液（O/W）、油包水型乳液（W/O）以及油包水包油（O/W/O）型和水包油包水（W/O/W）型多重乳液。根据乳化剂类型，乳液可分为传统表面活性剂或水溶性聚合物所稳定的普通乳液，以及由固体颗粒稳定的Pickering乳液ADDINEN.CITE<EndNote><Cite><Author>赵振国</Author><Year>2008</Year><RecNum>134</RecNum><DisplayText><styleface="superscript">[70]</style></DisplayText><record><rec-number>134</rec-number><foreign-keys><keyapp="EN"db-id="x2eewften55xsheaxe95zpajwd0strsfzspz"timestamp="1647624223">134</key></foreign-keys><ref-typename="Book">6</ref-type><contributors><authors><author>赵振国</author></authors></contributors><titles><title>应用胶体与界面化学</title></titles><dates><year>2008</year></dates><publisher>应用胶体与界面化学</publisher><urls></urls></record></Cite></EndNote>[70]。图1.7（a）水包油型乳液（O/W）；（b）油包水型乳液（W/O）；（c）水包油包水型乳液（W/O/W）；（d）油包水包油型乳液（O/W/O）Figure1.7(a)Oil-in-wateremulsion(O/W);(b)Water-in-oilemulsion(W/O);(c)Water-in-oilemulsion(W/O/W);(d)Oil-in-oilemulsion(O/W/O)普通乳液是由表面活性剂或水溶性聚合物所稳定的，因其具有巨大的界面面积而被广泛应用。1903年，牛津大学的Ramsden教授实验发现将固体颗粒用作乳化剂时，所得乳液稳定性强且不易聚结ADDINEN.CITE<EndNote><Cite><Author>Ramsden</Author><Year>1904</Year><RecNum>141</RecNum><DisplayText><styleface="superscript">[71]</style></DisplayText><record><rec-number>141</rec-number><foreign-keys><keyapp="EN"db-id="x2eewften55xsheaxe95zpajwd0strsfzspz"timestamp="1648185259">141</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Ramsden,W</author></authors></contributors><titles><title>Separationofsolidsinthesurface-layersofsolutionsand‘suspensions’(observationsonsurface-membranes,bubbles,emulsions,andmechanicalcoagulation).—Preliminaryaccount</title><secondary-title>ProceedingsoftheroyalSocietyofLondon</secondary-title></titles><periodical><full-title>ProceedingsoftheroyalSocietyofLondon</full-title></periodical><pages>156-164</pages><volume>72</volume><number>477-486</number><dates><year>1904</year></dates><isbn>0370-1662</isbn><urls></urls></record></Cite></EndNote>[71]。1907年，Pickering针对这种由固体颗粒稳定的乳液进行了深入研究，并给出了该乳液的构建方法，因此该乳液被后人称为Pickering乳液ADDINEN.CITE<EndNote><Cite><Author>Pickering</Author><Year>1907</Year><RecNum>140</RecNum><DisplayText><styleface="superscript">[72]</style></DisplayText><record><rec-number>140</rec-number><foreign-keys><keyapp="EN"db-id="x2eewften55xsheaxe95zpajwd0strsfzspz"timestamp="1648185168">140</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Pickering,SpencerUmfreville</author></authors></contributors><titles><title>Cxcvi.—emulsions</title><secondary-title>JournaloftheChemicalSociety,Transactions</secondary-title></titles><periodical><full-title>JournaloftheChemicalSociety,Transactions</full-title></periodical><pages>2001-2021</pages><volume>91</volume><dates><year>1907</year></dates><urls></urls></record></Cite></EndNote>[72]。目前，Pickering乳液已被广泛应用研究，其较大的油水相界面以及强稳定性可以实现油水两相中物质的转移，从而达到物质分离和回收的目的，因此Pickering乳液在该方面逐渐得到应用。1.1乳液分离机理在乳液中，介于连续相和分散相间的中间相可称为乳化液膜，而乳状液膜是乳液分离物质的基础，乳液分离物质可分为无载体的液膜分离和有流动载体的液膜分离。1.1.1无流动载体的液膜传质机理当液膜中不含流动载体时，其分离机理可分为：（a）选择性渗透；（b）微滴内化学反应；（c）液膜内发生反应；（d）萃取和吸附。（a）选择性渗透当发生选择性渗透时，物质的分离首先取决于物质是否溶于乳化液膜，而液膜的选择性则由物质在液膜中的溶解度决定，两物质溶解度相差越大，选择性越高。若物质能够溶于并穿过液膜，其传质速度就取决于膜内外物质浓度，当膜两侧被迁移的溶质浓度相等时，就会停止传质。如图1.7中（a）所示，欲分离A和B，物质A可溶于液膜进入内相，物质B不溶，从而分离。（b）微滴内化学反应为加强乳液的选择性以及分离效果，也可以让待分离的物质在乳状液膜内部发生化学反应来促进传输过程，其机理主要可概括为待分离物质进入内相与液膜内物质发生了不可逆反应，所生成的物质同样无法逆扩散穿过液膜，使得液膜内待分离物质的浓度保持在较低的水平，膜内外浓度梯度保持在最大水平上，因此可提高传输效率，实现高效传输。如图1.7中（b）所示，欲分离物质C，C渗透过膜相与内相中D反应生成不能透过液膜的产物E，C因此由料液富集于微滴内。（c）液膜内发生反应同微滴内化学反应促进分离的机理相似，待分离物质可与膜相中部分溶质或微粒发生反应，从而进入内相，又在内相中发生反应而实现分离。如图1.7中（c）所示，外相中F为欲分离物。膜相中有可与其反应的X1，F进入膜相，与X1反应生成产物Y1，Y1进入乳液内相与X2反应生成Y2。Y1不能回渗料液，Y2不能溶于膜相，膜内外保持高浓度差，F实现高效分离。（d）萃取和吸附如图1.7中（d）所示，料液中待分离物质G（f）若能溶于膜相或某些物质可吸附在膜表面，得以分离。图1.7无载体液膜分离机理示意图Fig.1.7Schematicdiagramofseparationmechanismofcarrier-freeliquidmembrane1.1.2含流动载体的乳化液膜分离机理使用含流动载体的液膜，其选择性分离主要取决于所添加的流动载体，所以提高液膜的选择性的关键在于找到合适的流动载体。如果能够物色一种载体单一地同混合物的一种溶质或离子发生反应，那么就可以直接提取某一元素或化合物，这类载体可以是萃取剂、络合剂、液体离子交换剂等。流动载体除了能提高选择性之外，还能增大溶质通量，它实质上是流动载体在膜内外2个界面之间来回穿梭地传递被迁移的物质。通过流动载体和被迁移物质之间选择性可逆反应，极大地提高了渗透溶质在液膜中的有效溶解度，增大了膜内浓度梯度，提高了输送效果ADDINEN.CITE<EndNote><Cite><Author>孙志娟</Author><Year>2006</Year><RecNum>145</RecNum><DisplayText><styleface="superscript">[73]</style></DisplayText><record><rec-number>145</rec-number><foreign-keys><keyapp="EN"db-id="x2eewften55xsheaxe95zpajwd0strsfzspz"timestamp="1648260078">145</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>孙志娟</author><author>张心亚</author><author>黄洪</author><author>陈焕钦</author></authors></contributors><auth-address>华南理工大学化工学院化工所,华南理工大学化工学院化工所,华南理工大学化工学院化工所,华南理工大学化工学院化工所广东广州510641,广东广州510641,广东广州510641,广东广州510641</auth-address><titles><title>乳状液膜分离技术的发展与应用</title><secondary-title>现代化工</secondary-title></titles><periodical><full-title>现代化工</full-title></periodical><pages>63-66</pages><number>09</number><keywords><keyword>乳状液膜</keyword><keyword>分离</keyword><keyword>废水处理</keyword></keywords><dates><year>2006</year></dates><isbn>0253-4320</isbn><call-num>11-2172/TQ</call-num><urls></urls><electronic-resource-num>10.16606/ki.issn0253-4320.2006.09.025</electronic-resource-num><remote-database-provider>Cnki</remote-database-provider></record></Cite></EndNote>[73]。这种利用载体的传输形式使乳液液膜具有高效的分离选择性，它是应用最多、最广泛的方法，有关载体的合成与选择也是研究最活跃的课题ADDINEN.CITE<EndNote><Cite><Author>崔正刚</Author><Year>2013</Year><RecNum>133</RecNum><DisplayText><styleface="superscript">[74]</style></DisplayText><record><rec-number>133</rec-number><foreign-keys><keyapp="EN"db-id="x2eewften55xsheaxe95zpajwd0strsfzspz"timestamp="1647624223">133</key></foreign-keys><ref-typename="Book">6</ref-type><contributors><authors><author>崔正刚</author></authors></contributors><titles><title>表面活性剂、胶体与界面化学基础</title></titles><dates><year>2013</year></dates><publisher>表面活性剂、胶体与界面化学基础</publisher><urls></urls></record></Cite></EndNote>[74]。1.2Pickering乳液在物质分离方面的应用传统的液液萃取过程常常存在传质界面小，传质效率低，两相分离困难等问题，而Pickering乳液具有较强稳定性的同时，还具备比较大的相界面，从而推动特定分子在两相的迁移与扩散，加速传质过程。此外Pickering乳液是固体颗粒包裹的乳液，经过简单的离心就可与萃余液相分离，因此目前Pickering乳液被大量应用于物质分离与提纯等方面。刘登卫等ADDINEN.CITE<EndNote><Cite><Author>刘登卫</Author><Year>2012</Year><RecNum>70</RecNum><DisplayText><styleface="superscript">[75]</style></DisplayText><record><rec-number>70</rec-number><foreign-keys><keyapp="EN"db-id="x2eewften55xsheaxe95zpajwd0strsfzspz"timestamp="1645186990">70</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>刘登卫</author><author>贺拥军</author><author>郭晓滨</author><author>张超</author><author>李紫萱</author><author>高绮</author></authors></contributors><auth-address>西安科技大学化学与化工系;西北大学化学与材料科学学院;</auth-address><titles><title>基于Pickering乳液介质萃取苯胺的研究</title><secondary-title>高校化学工程学报</secondary-title></titles><periodical><full-title>高校化学工程学报</full-title></periodical><pages>418-423</pages><volume>26</volume><number>03</number><keywords><keyword>苯胺</keyword><keyword>Pickering乳液</keyword><keyword>萃取</keyword><keyword>固定床</keyword></keywords><dates><year>2012</year></dates><isbn>1003-9015</isbn><call-num>33-1141/TQ</call-num><urls></urls><remote-database-provider>Cnki</remote-database-provider></record></Cite></EndNote>[75]将Pickering乳液作为固定床的“填料”，使得萃取过程以类似于固定床连续吸附或者吸收的方式进行，用来进行苯胺的静态萃取研究，实验结果表明在静态条件下，乳液单级萃取苯胺的效率为70%，三级萃取效率超过98%，为乳液去除芳香胺的工业化提供了新的思路。该课题组ADDINEN.CITE<EndNote><Cite><Author>刘登卫</Author><Year>2011</Year><RecNum>71</RecNum><DisplayText><styleface="superscript">[76]</style></DisplayText><record><rec-number>71</rec-number><foreign-keys><keyapp="EN"db-id="x2eewften55xsheaxe95zpajwd0strsfzspz"timestamp="1645186990">71</key></foreign-keys><ref-typename="Thesis">32</ref-type><contributors><authors><author>刘登卫</author></authors><tertiary-authors><author>贺拥军,</author></tertiary-authors></contributors><titles><title>Pickering乳液的制备及应用研究</title></titles><keywords><keyword>固体粒子</keyword><keyword>Pickering乳液</keyword><keyword>稳定性</keyword><keyword>甲基紫</keyword><keyword>苯胺</keyword><keyword>分离</keyword></keywords><dates><year>2011</year></dates><publisher>西安科技大学</publisher><work-type>硕士</work-type><urls></urls><remote-database-provider>Cnki</remote-database-provider></record></Cite></EndNote>[76]还以SiO2/ZnO和MgO为乳化剂，以三氯甲烷为油相，制备了水包油型Pickering乳液，研究了该乳液对甲基紫的分离效果，发现甲基紫的三级分离效率超过98%。涂项琛课题组ADDINEN.CITE<EndNote><Cite><Author>涂项琛</Author><Year>2018</Year><RecNum>136</RecNum><DisplayText><styleface="superscript">[77]</style></DisplayText><record><rec-number>136</rec-number><foreign-keys><keyapp="EN"db-id="x2eewften55xsheaxe95zpajwd0strsfzspz"timestamp="1647624593">136</key></foreign-keys><ref-typename="Thesis">32</ref-type><contributors><authors><author>涂项琛</author></authors><tertiary-authors><author>祝方,</author></tertiary-authors></contributors><titles><title>诺氟沙星-Pickering乳液分子印迹聚合物的制备及其吸附和固相萃取性能的研究</title></titles><keywords><keyword>Pickering乳液聚合</keyword><keyword>分子印迹聚合物</keyword><keyword>诺氟沙星</keyword><keyword>吸附</keyword><keyword>固相萃取</keyword></keywords><dates><year>2018</year></dates><publisher>太原理工大学</publisher><work-type>硕士</work-type><urls></urls><remote-database-provider>Cnki</remote-database-provider></record></Cite></EndNote>[77]利用一定量的诺氟沙星（NOR）与蒸馏水混合，并加入适量的自制纳米SiO2混合均匀作为水相，将功能单体甲基丙烯酸（MAA），交联剂乙二醇二甲基丙烯酸酯（EGDMA）、引发剂偶氮二异丁腈（AIBN）以及溶剂甲苯混合作为油相。随之，将油水两相混合制成Pickering乳液，并在热引发的条件下引发自由基聚合反应，得到分子印迹聚合物（MIP），对诺氟沙星(NOR)进行连续萃取，最终萃取率可高达97.92%。LinADDINEN.CITE<EndNote><Cite><Author>Lin</Author><Year>2016</Year><RecNum>135</RecNum><DisplayText><styleface="superscript">[78]</style></DisplayText><record><rec-number>135</rec-number><foreign-keys><keyapp="EN"db-id="x2eewften55xsheaxe95zpajwd0strsfzspz"timestamp="1647624529">135</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Lin,Zhaoyun</author><author>Zhang,Zhe</author><author>Li,Youming</author><author>Deng,Yulin</author></authors></contributors><titles><title>Magneticnano-Fe3O4stabilizedPickeringemulsionliquidmembraneforselectiveextractionandseparation</title><secondary-title>ChemicalEngineeringJournal</secondary-title></titles><periodical><full-title>ChemicalEngineeringJournal</full-title></periodical><pages>305-311</pages><volume>288</volume><dates><year>2016</year></dates><isbn>1385-8947</isbn><urls></urls></record></Cite></EndNote>[78]则制备了油酸包覆Fe3O4纳米粒子稳定的Pickering乳液，并将其用于废水中酚类化合物的提取。与普通Pickering乳液相比，该乳液在磁场作用下萃取后易于破乳，大大提高了油相的重复利用率，降低了乳液操作的能耗。结果表明，在最佳条件下，可提取了80%的4-甲基苯酚、95%的2-氨基苯酚和3-氨基苯酚，88%的苯酚。贺拥军课题组ADDINEN.CITE<EndNote><Cite><Author>Yuan</Author><Year>2021</Year><RecNum>143</RecNum><DisplayText><styleface="superscript">[79]</style></DisplayText><record><rec-number>143</rec-number><foreign-keys><keyapp="EN"db-id="x2eewften55xsheaxe95zpajwd0strsfzspz"timestamp="1648185464">143</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Yuan,Songbai</author><autho