【《锂离子电池正极材料研究文献综述》3500字】

致谢-[44]。与大多数聚阴离子型正极材料一样，LiFePO4的电子电导率较低，如何加快脱嵌锂过程中的电荷传递速率成为解决问题的关键所在。金属离子掺杂、表面碳包覆以及颗粒纳米化成为当前改善LiFePO4电导率的主要手段。与其他正极材料相比较，LiFePO4具有更长的循环寿命和良好的安全性能，目前已被广泛应用于规模储能和电动汽车等领域。参考文献B,Qian,D,etal.Recentprogressincathodematerialsresearchforadvancedlithiumionbatteries[J].MaterialsScience&EngineeringR-Reports,2012,73:51-65.NaguraT.Lithiumionrechargeablebatttery[J].ProgressinBatteries&SolarCells,1990,9:209.OzawaK.Lithium-ionrechargeablebatterieswithLiCoO2andcarbonelectrodes:theLiCoO2/Csystem[J].SolidStateIonics,1994,69(3-4):212-221.ScrosatiB,HassounJ,SunYK.Lithium-ionbatteries.AlookintotheFuture[J].EnergyEnviron.Sci,2011,4,3287-3295.ArmandM,TarasconJM.Buildingbetterbatteries[J].Nature,2008,451,652-657.KimTH,ParkJS,ChangSK,etal.Thecurrentmoveoflithiumionbatteriestowardsthenextphase[J].AdvancedEnergyMaterials,2012,2(7):860-872.TarasconJM,ArmandM.Issuesandchallengesfacingrechargeablelithiumbatteries[J].Nature.WangJ,SunX.OlivineLiFePO4:theremainingchallengesforfutureenergystorage[J].EnergyEnviron.Sci,2015,8,1110-1138.WuB,RenY,MuD,etal.EffectoflithiumcarbonateprecipitatesontheelectrochemicalcyclingstabilityofLiCoO2cathodesatahighvoltage[J].RSCAdvances,2014,4:10196-10203.KoenigGM,BelharouakI,DengH,etal.Composition-tailoredsynthesisofgradienttransitionmetalprecursorparticlesforlithium-ionbatterycathodematerials[J].ChemistryofMaterials,2011,23:1954-1963.KimCJ,AhnIS,ChoKK,etal.CharacteristicsofLiNiO2thinfilmssynthesizedbyLidiffusiononthesurfaceoxidizedepitaxiallayerofNi-alloy[J].JournalofAlloysandCompounds,2008,449:335-338.HuG,JiangJ,PengZ,etal.SynthesesofLiMn2O4nanoparticleswithnano-sizeprecursoranditselectrochemistryperformance[J].JournalofNanoscienceandNanotechnolegy,2013,13:2262-2265.LiuT,ZhaoL,WangD,etal.Carbon-coatedsingle-crystallineLiFePO4nanocompositesforhigh-powerLi-ionbatteries:theimpactofminimizationoftheprecursorparticlesize[J].RSCAdvances,2014,4:10067-10075.PadhiAAK,NanjundaswamyKS,GoodenoughJBD.Phospho-Olivinesaspositive-electrodematerialsforrechargeablelithiumbatteries[J].JournalofTheElectrochemicalSociety,1997,144(4):1188-1194.LiuZ,YuA,LeeJY.SynthesisandcharacterizationofLiNi1-x-yCoxMnyO2asthecathodematerialsofsecondarylithiumbatteries[J].JournalofPowerSources,1999,s81-82:416-419.YoshioM,NoguchiH,ItohJI,etal.PreparationandpropertiesofLiCoyMnxNi1-x-yO2asacathodeforlithiumionbatteries[J].Journalofpowersources,2000,90(2):176-181.OhzukuT,MakimuraY.LayeredlithiuminsertionmaterialofLiCo1/3Ni1/3Mn1/3O2forlithium-ionbatteries[J].ChemistryLetters,2001,1(7):642-643.BruceP,ScrosatiB,TarasconJM.Nanomaterialsforrechargeablelithiumbatteries[J].AngewandteChemieInternationalEdition,2008,47(16):2930-2946.黄可龙，王兆翔，刘素琴.锂离子电池原理与关键技术[M].北京：化学工业出版社，2008.谢凯.新一代锂二次电池技术[M].北京：国防工业出版社，2013.马璨，吕迎春，李泓.锂离子电池基础科学问题(Ⅶ)——正极材料[J].储能科学与技术，2014,3(1):53~65.PaulsenJM,MuellerneuhausJR,DahnJR.LayeredLiCoO2withadifferentoxygenstacking(O2structure)asacathodematerialforrechargeablelithiumbatteries[J].JournaloftheElectrochemicalSociety,2000,147(2):508-516.ZouM,YoshioM,GopukumarS,etal.Synthesisofhigh-voltage(4.5V)cyclingdopedLiCoO2foruseinlithiumrechargeableCells[J].ChemInform,2004,35(9).BrousselyM,PertonF,BiensanP,etal.LixNiO2,apromisingcathodeforrechargeablelithiumbatteries[J].JournalofPo