高一化学必修第三章第四节基本营养物质第课时脂肪蛋白质.ppt

第四节 基本营养物质 第2课时 Evaluation only.Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile .Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd.Copyright 2004-2011 Aspose Pty Ltd. 思考： CC ； CC ；OH ； COOH ； 一定条件下，下列物质能与以上哪 些官能团反应(填序号)，并注明反应类型： (1)H2: ； (2)Br2: ； (3)Na: ； (4)NaOH: ； (5)C2H5OH: ； (6)KMnO4: 。 (加成反应) (加成反应) (取代反应) (中和反应) (酯化或取代反应) (氧化反应) Evaluation only.Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile .Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd.Copyright 2004-2011 Aspose Pty Ltd. 糖类得水解 一、糖类、油脂和蛋白质的性质一、糖类、油脂和蛋白质的性质 1. 1.糖类和蛋白质的特征反应糖类和蛋白质的特征反应 2. 2.糖类、油脂和蛋白质的糖类、油脂和蛋白质的水解反应水解反应 实验实验现现象结论结论 取少量蔗糖溶液，加入少量新 制的氢氢氧化铜铜，加热热煮沸, 观观 察现现象。 取少量蔗糖溶液，加入35滴 稀硫酸。加热热后向该试该试 管中加 氢氢氧化钠钠溶液调节调节 溶液pH到 碱性，再加入少量新制的氢氢氧 化铜铜，加热热煮沸，观观察现现象。 Evaluation only.Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile .Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd.Copyright 2004-2011 Aspose Pty Ltd. Evaluation only.Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile .Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd.Copyright 2004-2011 Aspose Pty Ltd. 糖类得水解 一、糖类、油脂和蛋白质的性质一、糖类、油脂和蛋白质的性质 1. 1.糖类和蛋白质的特征反应糖类和蛋白质的特征反应 2. 2.糖类、油脂和蛋白质的糖类、油脂和蛋白质的水解反应水解反应 蔗糖不显还蔗糖不显还 原性；在催原性；在催 化剂和加热化剂和加热 的条件下，的条件下， 蔗糖能水解蔗糖能水解 ，生成有还，生成有还 原性的葡萄原性的葡萄 糖糖 实验实验现现象结论结论 取少量蔗糖溶液，加入少量新 制的氢氢氧化铜铜，加热热煮沸, 观观 察现现象。 取少量蔗糖溶液，加入35滴 稀硫酸。加热热后向该试该试 管中加 氢氢氧化钠钠溶液调节调节 溶液pH到 碱性，再加入少量新制的氢氢氧 化铜铜，加热热煮沸，观观察现现象。 出现 砖红色 沉淀 没有 砖红色 沉淀 Evaluation only.Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile .Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd.Copyright 2004-2011 Aspose Pty Ltd. 双糖、多糖在稀酸的催化下，最终水解生成葡 萄糖或果糖。 催化剂 C12H22O11 +H2O 蔗糖 催化剂 C12H22O11 +H2O 麦芽糖 2C6H12O6 葡萄糖 (C6H10O5)n +nH2O 催化剂 淀粉或纤维素 nC6H12O6 葡萄糖 糖类的水解 2.糖类、油脂和蛋白质的水解反应 C6H12O6C6H12O6 葡萄糖 果糖 +Evaluation only.Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile .Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd.Copyright 2004-2011 Aspose Pty Ltd. 思考：P78 第5题。 Evaluation only.Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile .Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd.Copyright 2004-2011 Aspose Pty Ltd. 油脂的水解 碱性条件下水解为甘油（丙三醇）、高级脂肪钠 。油脂在碱性条件下的水解反应称为皂化反应。 酸性条件下水解为甘油（丙三醇）、高级脂肪酸。 丙三醇的结构简式： CH2OH CHOH CH2OH 高级脂肪酸： 在一元羧酸里，酸分子的 烃基含有较多碳原子的叫高 级脂肪酸。 （如硬脂酸C17H35COOH、油 酸C17H33COOH ） 肥皂的主要成分是_。 高级脂肪钠 Evaluation only.Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile .Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd.Copyright 2004-2011 Aspose Pty Ltd. 二、糖类、油脂、蛋白质在生产、生活中的应用二、糖类、油脂、蛋白质在生产、生活中的应用 1.1.糖类的存在及主要应用糖类的存在及主要应用: : 糖类类 存在 主要应应用 葡萄糖 蔗糖 淀粉 纤维纤维 素 水果、蔬菜、水果、蔬菜、 血液血液 工业原料、食品加工业原料、食品加 工、医疗输液工、医疗输液 甘蔗、甜菜甘蔗、甜菜工业原料、食品加工工业原料、食品加工 植物的种子植物的种子 和块茎和块茎 做食品、生产葡萄糖做食品、生产葡萄糖 和酒精和酒精 植物的茎、植物的茎、 叶和皮叶和皮 用来造纸用来造纸 蛋白质的水解蛋白质的水解 蛋白质在蛋白质在酶等催化剂酶等催化剂作用下也可以水解，生成作用下也可以水解，生成氨基酸氨基酸。 Evaluation only.Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile .Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd.Copyright 2004-2011 Aspose Pty Ltd. 存在： 应用: 2 2、油脂的存在及应用、油脂的存在及应用: : 植物的种子（油：含有碳碳双键）植物的种子（油：含有碳碳双键） 动物的组织和器官（脂肪：碳碳单键）动物的组织和器官（脂肪：碳碳单键） 热能最高的营养物质，也是一种重要的工业原料热能最高的营养物质，也是一种重要的工业原料 ，可以用来制造肥皂和油漆等。，可以用来制造肥皂和油漆等。 Evaluation only.Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile .Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd.Copyright 2004-2011 Aspose Pty Ltd. 1.油和脂两者在外观上有何去别？从微观上分析，又 有何区别？ 2.石油和花生油都是油，它们属于同一类物质吗？ 室温下，呈液态的油脂称为油，呈固态的油脂 称为脂（外观上）； 微观上，油是不饱和高级脂 肪酸甘油酯（含碳碳双键）；脂是饱和高级脂肪酸 甘油酯（不含碳碳双键）。 石油和花生油不是同一类物质，石油是由各种烃 所组成；而花生油主要成分是高级脂肪酸甘油酯。 思考： Evaluation only.Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile .Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd.Copyright 2004-2011 Aspose Pty Ltd. 存在： 应用: 2 2、油脂的存在及应用、油脂的存在及应用: : 植物的种子（油：含有碳碳双键）植物的种子（油：含有碳碳双键） 动物的组织和器官（脂肪：碳碳单键）动物的组织和器官（脂肪：碳碳单键） 热能最高的营养物质，也是一种重要的工业原料热能最高的营养物质，也是一种重要的工业原料 ，可以用来制造肥皂和油漆等。，可以用来制造肥皂和油漆等。 3 3、蛋白质的存在及应用、蛋白质的存在及应用 存在：存在：一切细胞中，是组成细胞的基础物质。一切细胞中，是组成细胞的基础物质。 Evaluation only.Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile .Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd.Copyright 2004-2011 Aspose Pty Ltd. 蛋白质 动物的毛、 蚕丝是很好 的纺织原料 动物的皮 革是衣服 的原料 驴皮熬制的 胶是一种药 材阿胶 牛奶中的蛋 白质与甲醛 制酪素塑料 各种生物酶 均是蛋白质 人类的主要食品 蛋白质的主要应用： Evaluation only.Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile .Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd.Copyright 2004-2011 Aspose Pty Ltd. 1.将淀粉水解，并用新制的Cu(OH)2浊液检 验其水解产物的实验中，要进行的主要操作 是：加热；滴入稀硫酸；加入新制的 Cu(OH)2悬浊液；加入足量的氢氧化钠 溶液以上各步操作的先后顺序排列正确的 是 ( ) A B C D B Evaluation only.Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile .Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd.Copyright 2004-2011 Aspose Pty Ltd. 2.现有四种试剂：A.新制Cu(OH)2悬浊液； B.浓硝酸；C.AgNO3溶液；D.碘水。为了 鉴别下列四瓶无色溶液，请你选择合适 的试剂，将其填入相应的括号中。 (1) 葡萄糖溶液 （ ） (2)食盐溶液 （ ） (3) 淀粉溶液 （ ） (4)鸡蛋清溶液 （ ） A C D B Evaluation only.Evaluation only. 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