生物柴油精馏尾气分析报告.doc

instrument:agilent 6890-5973n gc-mscolumn:db-wax 60m*0.25mm*0.25uminformation from data file: file: d:2013test20130517snapshot13120505.d operator: zys date acquired: 3 jan 2000 16:34 method file: 131204gj sample name: misc info: vial number: 1search libraries: c:databasenist98.l minimum quality: 0 c:databasenist98.l minimum quality: 0 unknown spectrum: apexintegration events: chemstation integrator - autoint1.e pk# rt area% library/id ref# cas# qual_ 1 4.89 32.16 c:databasenist98.l carbon dioxide 10466 000124-38-9 4 carbon dioxide 110470 000124-38-9 4 ethylene oxide 108063 000075-21-8 3 2 5.01 38.72 c:databasenist98.l pentane 109386 000109-66-0 90 pentane 4653 000109-66-0 86 pentane 109385 000109-66-0 86 3 5.14 2.25 c:databasenist98.l methane, chloro- 111051 000074-87-3 91 methane, chloro- 111052 000074-87-3 90 methane, chloro- 12334 000074-87-3 90 4 5.19 2.72 c:databasenist98.l hexane 112279 000110-54-3 90 hexane 112278 000110-54-3 87 hexane 112277 000110-54-3 78 5 5.33 0.43 c:databasenist98.l 1-hexene 108657 000592-41-6 59 1-hexene 108674 000592-41-6 53 1-hexene 111823 000592-41-6 50 6 5.38 0.53 c:databasenist98.l hexane, 2-methyl- 109353 000591-76-4 52 2-pyrrolidinone 116669 000616-45-5 47 pentane, 2-methyl- 109402 000107-83-5 43 7 5.46 2.37 c:databasenist98.l methanethiol 111010 000074-93-1 87 methanethiol 12281 000074-93-1 83 methanethiol 111011 000074-93-1 59 8 5.55 1.37 c:databasenist98.l heptane 109668 000142-82-5 91 heptane 109303 000142-82-5 72 heptane 4133 000142-82-5 72 9 5.82 0.63 c:databasenist98.l 1-buten-3-yne, 2-methyl- 113614 000078-80-8 83 1,3-cyclopentadiene 113626 000542-92-7 52 1,3-cyclopentadiene 20825 000542-92-7 49 10 5.89 0.83 c:databasenist98.l dimethyl sulfide 111017 000075-18-3 94 dimethyl sulfide 111016 000075-18-3 94 dimethyl sulfide 20468 000075-18-3 91 11 6.22 1.09 c:databasenist98.l furan 108396 000110-00-9 90 furan 108394 000110-00-9 90 furan 21740 000110-00-9 90 12 7.49 1.46 c:databasenist98.l propanoic acid, methyl ester 108079 000554-12-1 83 propanoic acid, methyl ester 108078 000554-12-1 83 propanoic acid, methyl ester 485 000554-12-1 72 13 7.67 0.46 c:databasenist98.l 1,3-cyclopentadiene, methyl- 30694 026519-91-5 86 1,3-cyclohexadiene 115902 000592-57-4 80 1,3-cyclopentadiene, 1-methyl- 30697 000096-39-9 80 14 7.72 0.37 c:databasenist98.l propanoic acid, 2-methyl-, meth. 6292 000547-63-7 64 thiophene, tetrahydro-2-methyl- 35544 001795-09-1 35 butanoic acid, methyl ester 109993 000623-42-7 17 15 8.01 2.78 c:databasenist98.l benzene 115810 000071-43-2 91 benzene 115809 000071-43-2 91 benzene 115807 000071-43-2 90 16 8.13 0.53 c:databasenist98.l furan, 2-ethyl- 31551 003208-16-0 90 furan, 2-ethyl- 116087 003208-16-0 83 2,4-hexadienal, (e,e)- 116029 000142-83-6 78 17 8.66 5.42 c:databasenist98.l butanoic acid, methyl ester 109994 000623-42-7 91 butanoic acid, methyl ester 109995 000623-42-7 91 butanoic acid, methyl ester 28207 000623-42-7 90 18 9.06 0.52 c:databasenist98.l butanoic acid, 2-methyl-, methy. 17385 053955-81-0 72 butanoic acid, 2-methyl-, methy. 117026 000868-57-5 72 butanoic acid, 2-methyl-, methy. 17382 000868-57-5 64 19 9.21 0.65 c:databasenist98.l butanoic acid, 3-methyl-, methy. 28211 000556-24-1 80 butanoic acid, 3-methyl-, methy. 115361 000556-24-1 78 butanoic acid, 3-methyl-, methy. 115345 000556-24-1 9 20 9.67 0.22 c:databasenist98.l bicyclo3.2.0hepta-2,6-diene 37273 002422-86-8 4 1,3,5-cycloheptatriene 117284 000544-25-2 4 1,3,5-cycloheptatriene 37276 000544-25-2 4 21 10.50 4.49 c:databasenist98.l pentanoic acid, methyl ester 115365 000624-24-8 91 pentanoic acid, methyl ester 115353 000624-24-8 91 pentanoic acid, methyl ester 28342 000624-24-8 64 mon jan 03 16:47:33 2000主 要 组 分含量%（v:v）carbon dioxide (二氧化碳)32.16pentane (戊烷)1.7-9.838.72methane, chloro- (甲烷氯-)2.25hexane (己烷)1.2-8.32.72methanethiol （甲硫醇）3.9-21.82.37heptane （庚烷）1.1-7.51.37furan （呋喃）2.3-14.31.09propanoic acid, methyl ester （丙酸甲酯）2.5-131.46benzene （苯）1.2-8.02.78butanoic acid, methyl ester （丁酸甲酯）1.6-8.85.42pentanoic acid, methyl ester （戊酸甲酯）4.49甲烷5-15.4乙烷3-16丙烷2.1-9.5丁烷1.5-8.5戊烷1.7-9.8庚烷1.1-7.5甲酸甲酯4.5-32乙酸甲酯3.1-16丙酸甲酯2.5-13丁酸甲酯1、呋喃，是最简单的含氧五元杂环化合物1。无色液体。有特殊的气味。有麻醉和弱刺激作用，极度易燃。吸入后可引起头痛、头晕、恶心、呼吸衰竭。呋喃环具芳环性质，可发生卤化、硝化、磺化等亲电取代反应，主要用于有机合成或用作溶剂。2、己烷是常用的非极性具汽油味的有机溶剂，被广泛应用于色谱法中。正己烷作为良好的有机溶剂，被广泛使用在化工有机合成，机械设备表面清洗去污等环节。但其具有一定的毒性，会通过呼吸道、皮肤等途径进入人体，长期接触可导致人体出现头痛、头晕、乏力、四肢麻木等慢性中毒症状，严重的可导致晕倒、神志丧失、甚至死亡。3、无色气体，有不愉快的气味。不溶于水，溶于乙醇、乙醚等有机溶剂。4、氯代甲烷是