天津盛霖化工有限公司(德福油漆) MSDS.doc

33X-0602 MSDS- 4 -天津盛霖化工有限公司(德福油漆) MSDSTianjin Grow Green Coatings CO.,LTD 1 PRODUCT/COMPANY IDENTIFICATION Product name: 33X-0602MANUFACTURE/DISTRIBUTORTianjin Grow Green Coatings CO.,LTD.The Eastern Part of Jinwei Road ,XiaoDian Village In Beichen District, Tianjin , ChinaPostcode : 300402Telephone: 0086mergency Response Call:2. COMPOSITION/INFORMATION ON INGREDIENTScomponentsCAS % Alkyd resin -5060Butyl acetate123-86-41020Methyl isobutyl ketone (MIBK)108-10-1 510Ethylene glycol ethyl ether acetate111-15-9 5103. HAZARDS IDENTIFICATIONEmergency Overview:Caution! Class 3.3 Flammable liquid. May cause eye and skin irritation. Potential Health EffectsEye Contact: May cause irritation, include: tearing, redness.Inhalation: May cause slight irritation to the respiratory tract. Over exposure may Inhalation may cause: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness.Skin Contact: May cause slight irritation. Prolonged or repeated contact can result in defatting and drying of the skin. Can be absorbed through the skin and result in systemic effect same as ingestion.Ingestion: Large oral doses may be harmful, include: gastrointestinal irritation, nausea, vomiting, diarrhea, headache, dizziness, fatigue, incoordination and confusion.Chronic Exposure: No information found.Aggravation of Pre-existing Conditions: No information found.4. FIRST AID MEASURESInhalation: Remove to fresh air. Get medical attention for any breathing difficulty.Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.Skin Contact: Remove contaminated clothing and shoes. Immediately wipe off with paper towel or cloth, and flush skin with plenty of water and soap. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation persists.5. FIRE FIGHTING MEASURESFlash point: 22（butyl acetate）；23（MIBK）；52（Ethylene glycol ethyl ether acetate）Flammable limits in air % by volume: 1.77.6(ref to butyl acetate)Fire Extinguishing Media: dry chemical, foam or carbon dioxide.Special Information: Water spray may be used to keep fire exposed containers cool. The fire fighters must wear full protective clothing and approved self-contained breathing apparatus.Hazardous combustion products: Toxic fumes as carbon monoxide，carbon dioxide and ZnO etc.6. ACCIDENTAL RELEASE MEASURESVentilate area of leak or spill. Remove all sources of ignition. Avoid Wear appropriate personal protective equipment as specified in Section 8. Contain and recover liquid when possible. Use non-sparking tools and equipment. Collect liquid in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and dispose it according to the requirements of local EPA. 7. HANDLING AND STORAGEKeep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Containers of this material may be hazardous when empty since they retain organic solvent vapor.8. EXPOSURE CONTROLS/PERSONAL PROTECTIONOccupational Exposure Limits: Alkyd resinChina：none established；ACGIH：none establishedButyl acetate (123-86-4)China：TWA 200 mg/m3, STEL 300 mg/m3Methyl isobutyl ketone (108-10-1)China：none established；ACGIH：TWA 50 mg/m3，STEL 75 mg/m3Ethylene glycol ethyl ether acetate (111-15-9)China：TWA 30 mg/m3, STEL 60 mg/m3Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Personal Respirators: Use organic vapor respirators where the exposure concentration is in excess of the OEL. Eye Protection: Use chemical safety goggles.Skin Protection: Wear protective gloves and clean body-covering clothing.Others: Showering thoroughly after work and put on the clear cloth. Avoid prolonged and repeat exposure.9. PHYSICAL AND CHEMICAL PROPERTIESAppearance: liquid.Specific Gravity: 1.Boiling Point: No data.Flash point: 22（butyl acetate）；23（MIBK）；52（Ethylene glycol ethyl ether acetate）Solubility: solve in organic solvents.10. STABILITY AND REACTIVITYStability: Stable under ordinary conditions of use and storage.Conditions to Avoid: High temperature, all sources of ignition.Incompatibilities: Strong oxidizers. Hazardous Polymerization: Will not occur.Hazardous Decomposition Products: Burning may produce carbon dioxide, carbon monoxide and ZnO etc toxic fume.11. TOXICOLOGICAL INFORMATIONAcute ToxicityAlkyd resinorl-rat LD50: 5000 mg/kg.Butyl acetate (123-86-4)orl-rat LD50: 10768 mg/kgihl-rat LC50: 390 ppm/4Horl-mus LD50: 6 mg/kgihl-mus LC50: 6mg/m3/2Hskn-rbt LD50: 17600 mg/kgMethyl isobutyl ketone (108-10-1)orl-rat LD50: 2080 mg/kgihl-rat LC50: 100 mg/m3orl-mus LD50: 1900 mg/kgihl-mus LC50: 23300 mg/m3skn-rbt LD :3 gm/kgEthylene glycol ethyl ether acetate (111-15-9)orl-rat LD50: 2700 mg/kgihl-rat LC50: 12100 mg/m3/8Hskn-rbt LD50: 10500 uL/kg12. ECOLOGICAL INFORMATIONEnvironmental Fate: No information found.Environmental Toxicity: No information found.13. DISPOSAL CONSIDERATIONSDispose of container and unused contents in accordance with state and local EPA requirements.14. TRANSPORT INFORMATIONChina(GB12268-90)Ch No: 33646；Package class: IIILabel：3.3 flammable liquidIMOIMO Proper Shipping Name: PAINT IMO UN Number: 1263IMO UN Class: 3.3IATAIATA UN ID Number: 1263IATA Proper Shipping Name: PAINT IATA UN Class: 3IATA Label: FLAMMABLE LIQUID15REGULATORY INFORMATIONChina RegulationInventory of exiting chemical substance (SEPA): The hazardous components in this product are all listed. List of dangerous Goods (GB 12268-90): Product (33646)Identification of major ha