油性漆-MSDS.doc

物質安全資料表一、物品名稱與廠商資料物品名稱: 油性漆 其他名稱: (不因顏色改變而改變其主要成分) 建議用途及限制使用: 限工業用途使用製造商或供應商名稱地址及電話:太原實業股份有限公司04-25622009 (東莞聯興鞋材製品緊急聯絡電話/傳真電話：TEL:119 or 04-25622009 ( 86-769-2295635 ) FAX: 04-25620931 ( 86-769-2257172)二、危害辨識資料:物品危害分類:易燃液體第2級，吸入性危害物質第2級，腐蝕/刺激皮膚物質第3級，嚴重損傷/刺激眼睛物質第2級，急毒性物質(吞食)第5級，特定標的器官系統毒性物質-重複暴露第2級標示內容:警示語 : 危險危害警告訊息：易燃液體和蒸氣、吞食可能有害造成輕微皮膚刺激、造成眼睛刺激長期暴露可能會損害神經、肝臟如果吞食並進入呼吸道可能有害危害防範措施：置容器於通風良好的地方遠離引燃品禁止抽煙若覺得不適，則洽詢醫療(出示醫療人員此標籤) 避免長期暴露其他危害: -三、成分辨識資料 ( 混合物 )化學性質 ： 危害成分之中英文名稱 濃度或濃度範圍(成分百分比)EAC 乙酸乙酯48MEK 丁酮56 64PMA 乙酸丙二醇單甲基醚酯4 8PU樹脂6-20顏料0-15四、急救措施 :不同暴露途徑之急救方法 吸入：將患者移至空氣流通處，若狀況嚴重立即就醫。皮膚接觸:移開衣物,以肥皂、水清將接觸部位洗淨。眼睛接觸：以大量清水沖洗，立即送醫。食入：立即就醫。最重要症狀及危害效應 : 頭痛、暈眩、睏倦、刺激感對急救人員之防護：無對醫師之提示 : 依據症候治療五、滅火措施 :適用滅火劑：二氧化碳.化學乾粉.泡沫。滅火時可能遭遇之特殊危害：燃燒產生刺激煙霧。特殊滅火程序：噴水可冷卻容器，保護暴露於火場之物質消防人員之特殊防護設備：消防人員必須戴空氣呼吸器、防護衣及手套。六、洩漏處理方法 個人應注意事項：在污染區尚未完全清理乾淨前，限制人員進入該區。環境注意事項：避免外洩物進入下水道。清理方法：用泥沙或類似穩定不可燃的物質吸附，徹底清洗。 七、安全處置與儲存方法 處置：工作場所禁止抽煙，工作場所避免高溫，保持良好通風。儲存：容器置放於通風良好處,遠離熱與火源o八、暴露預防措施 工程控制 ：局部排器裝置或整體換氣裝置控制參數 ： 小時日時量平均容許濃度 / 短時間時量平均容許濃度 / 最高容許濃度 /生物指標乙酸乙酯 400ppm / 500ppm / - / -甲基乙基酮 200ppm / 250ppm / - / -乙酸丙二醇單甲基醚酯 - / - / - / - 個人防護設備： 呼吸防護：戴口罩手部防護：戴抗化學品手套。眼睛防護：戴護目鏡. 皮膚及身體防護：穿戴防護衣或實驗衣。衛生措施 : 工作場所嚴禁飲食，處理後徹底洗手。九、物理及化學性質外觀(物質狀態、顏色)：有色或透明液狀氣味：酮類氣味嗅覺閾值:2-85 ppm熔點: 無pH值 ：無資料沸點 / 沸點範圍 : 80160 分解溫度 : 無資料閃火點 ： -2 測試方法： 閉杯自燃溫度：400爆炸界限：( LEL ) 1.8% ( UEL ) 10% 蒸氣壓：77 毫米汞柱蒸氣密度： ( 空氣=1 ) 2.4克/立方公分密度：0.8-1.0克/立方公分溶解度：水中不溶辛醇/水分配係數(log Kow):0.32揮發速率: -十、安定性及反應性安定性：正常狀況下安定. 特殊狀況下可能之危害反應：長期高熱或燃燒下，可能產生分解物應避免之狀況：有火源存在時會導致容器爆破起火。應避免之物質：強氧化劑.危害分解物：著火時釋放出有毒蒸氣及氣體. 如一氧化碳&二氧化碳 。十一、毒性資料暴露途徑: 皮膚、吸入、食入、眼睛症狀:頭痛、暈眩、困倦、嘔吐、刺激感急毒性：皮膚：引起輕度刺激。吸入：200ppm會刺激鼻、喉。更高濃度會引起頭痛、噁心、困倦。食入：影響與吸入同眼睛：蒸氣會引起刺激慢毒性或長期毒性：對神經、肝、皮膚有影響。 十二、生態資料生態毒性:LC50(魚類) EC50(水生無脊椎動物) BCF(生物濃縮係數) MEK 1690-5640 mg/L/96H - 1EAC - - -PMA - - -持久性及降解性: 1. 丁酮及其代謝物在24小時內會由體內完全排出，乙酸乙酯相當容易被生物分解， 2. 丁酮MEK 乙酸乙酯EAC 乙酸丙二醇單甲基醚酯PMA 半衰期(空氣) 64-642小時 35-353小時 - 半衰期(水表面) 24-168小時 24-168小時 - 半衰期(地下水) 48-336小時 48-336小時 - 半衰期(土壤) 24-168小時 24-168小時 -生物積蓄性:丁酮MEK:-乙酸乙酯EAC:不具積蓄性 乙酸丙二醇單甲基醚酯PMA: -土壤中之流動性: 釋放至土壤中，部分會蒸發，部分會滲入地面。其他不良效應: -十三、廢棄處置方法廢棄處置方法：於政府認可之焚化爐焚化。十四、運送資料聯合國編號：1263運輸危害分類: 第三類易燃液體包裝類別: III海洋污染物(是/否): 是 特殊運送方法及注意事項：無十五、法規資料適用法規：勞工安全衛生設施規則，有機溶劑中毒預防規則，道路交通安全規則，危害物與有害物標示及通識規則，勞工作業環境空氣中有害物容許濃度標準，事業廢棄物貯存清除處理方法及設施標準十六、其他資料參考文獻CHEMINFO資料庫，HSDB資料庫製表單位名稱：太原實業股份有限公司 東莞聯興鞋材製品廠地址/電話：台中縣神岡鄉中山路1400號 TEL; 04-25622009 廣東東莞市附城區光明管理區 表 人職稱：經理姓名：吳慧玲日期2011/03/15Material Safety Data Sheet1、Identification of the substance / preparation and companyProduct Information: S/B PAINTProduct Number: (Different colors can not change the main composition)And the use of the proposed restrictions on the use of: limit the use of industrial usesInformation on Producer/Supplier Name、Addresses、Phone : TAI YUANG INDUSTRIES CO., LTD. (THREE KINGS PAINT) 1400,CHUNG SHEN RD, SHEN KANG TAICHUNG TAIWAN.TEL: 04-25622009Emergency Phone / Fax：TEL:119 or 04-25622009 FAX:04-256209312. Hazard identification dataHazard classification of goods: Flammable liquid level 2，Inhalation of hazardous substances at level 2，Corrosion / materials to stimulate the skin level 3,Serious injury / substance irritates the eyes at level 2,Acute toxicity of the material (to eat) at level 5The subject of a specific organ system toxicity of the material - repeated exposure level 2 Labeled content Warnings: dangerousHazard warning:Flammable liquid and vapor，May be harmful to eatMinor skin irritation，Cause eye irritationLong-term exposure may damage the nerve, liverIf swallowed into the respiratory tract and may be harmfulPreventive measures against:Purchase containers in a well-ventilated placeAway from ignition products - to prohibit smokingIf that does not apply, contact the medical(The medical staff to produce labels)Avoid prolonged to exposure Other hazards : -3、Composition / Information on Ingredients ( Mixing)Chemical Character： Hazardous Components NameConcentration / PercentageEAC C4H8O2 ethyl acetate 48MEK C4H8O methyl ethyl ketone 5664Propylene Glycol Monomethylether Acetate 48PU RESIN 6-20PIGMENT 0-15 4、First Aid Measures :Emergency and First Aid Procedures Inhalation：Remove the patient to flesh air or send to hospital.Skin Contact：Remove clothing. Wash with water and soap very quicklyEye Contact：Irrigate with plenty of water and send to hospitalIngestion：Send to hospitalMajor Disease and Harm Effect：headache, drowsiness, irritation.First-Aid Personal Protection: NonePrompt to Doctor：Upon the symptom.5、Fire Fighting Measure :Suitable Extinguishing Media: CO2.Dry chemical powder, foam.Special Exposure Hazards: Burning produces irritant fumes.Special Extinguishing Procedure: Use water to cool fire-exposed containers and protect the other material.Special Protection Equipment: Firemen have to wear breathing apparatus and protective clothing& gloves.6、Accidental Release MeasuresPersonal Protection: Keep away from the area before cleaning the pollution area.Environmental Protection: Do not let product enter drains.Methods for Cleaning Up: Cover spill with inert absorbent material (sand).Clean contaminated surface thoroughly.7、Handling and StorageHandling: No smoking in the working area. The working place avoid in a high temperature closed room.Storage: Keep container away from heat fire and good ventilation.8、Exposure Control / Personal ProtectionProject control: local row overall ventilation device or devicesControl Factor： TWA / STEL / CEILING / Biotic IndexEAC 400ppm / 500ppm / - / -MEK 200ppm / 250ppm / - / -PMA - / - / - /- Personal Protection Equipment： Respiratory Protection: Wear a mask.Hand Protection：Glove resistant to chemical.Eye Protection：Wear goggles.Skin & Body Protection: Protective clothing or lab coats must be wormHygiene Procedures: Do not eat on work, wash hands after work.9、Physical and Chemical Properties / CharacteristicsAppearance(Form & Color): color or transparent liquidOdor: with ketone odorOlfactory Threshold:2-85 ppmMelting point: nonepH value：No dataBoiling Point / Boiling Range: 80160Decomposition Temperature：No dataFlash Point： -2 Test Method： Close CupSpontaneous Temperature：400Exposure Limits：LEL: 1.8% UEL : 10 % Vapor Pressure： 77 mmHg Vapor Density： 2.4 g/cm (Air=1.0)Specific Gravity：0.8-1.0 g/cmSolubility in Water：InsolubleOctanol / Water distribution coefficient (log Kow): 0.3-2Vaporize rate: -10、Stability and ReactivityStability：Stable at normal condition.Special Conditions of Hazardous Reaction: At high temperature, dry matter may cause decomposition.Conditions to Avoid: Fire source may cause container burn and explosive.Incompatibility: Strong oxidizing agents to avoid.Hazardous Decomposition Products: CO, CO2 may from when heated to decomposition.11、Toxicological InformationExposure means: skin, inhalation, ingestion, eyeSymptoms: headache, dizziness, drowsiness, vomiting, to stimulate a sense ofAcute toxicitySkin: cause mild stimulationInhalation: 200ppm will stimulate the nose and throat. Give rise to a higher concentration of headache, nausea and drowsiness.Ingestion: effects of inhaled with the sameEyes: steam will stimulateChronic toxicity or long-term toxicity: nerves, liver, skin influential.12、Ecological InformationBiological toxicityLC50(Fish) EC50(Aquatic invertebrates) BCF MEK 1690-5640 mg/L/96H - 1EAC - - -PMA - - -Degradation and persistent:1Butanone and its metabolites within 24 hours will be fully discharged from the body, ethyl acetate quite easily biodegradable2. MEK EAC PMAHalf-life (air) 64-642 hr. 35-353 hr. -Half-life (water surface) 24-168 hr. 24-168 hr. -Half-life (water) 48-336 hr. 48-336 hr. -Half-life (soil) 24-168 hr. 24-168 hr. -Biological savings:MEK:- ， EAC: Non-savings ， PMA: -The soil of mobility: to release the soil, some will evaporate, some will infiltrate the groundOther adverse effects: -13、Disposal InformationDisposal Information: Incinerate only in officially approved incinerator.14、Transport InformationNumber of the United Nations:1263Transport hazard