电子自旋共振核磁共振谱(ESRNMR)元素周期表.pdf

Robin K Harris NMR nomenclature Nuclear spin properties and conventions for chemical shifts IUPAC Recommendations 2001 Pure Appl Chem 2001 Vol 73 No 11 pp 1795 1818 http www nyu edu cgi bin cgiwrap aj39 NMRmap cgi Isot ope Symb ol NameSpin Natural Abund Recepti vity rel to 13C Magneti c Moment Gamma x 10 7rad Tx Quadr up Momen t Q fm 2 Frequenc y Reference materials 191 IrIridium3 237 3 0 000010 19460 481281 66 872 197 AuGold3 2100 0 00003 0 191270 4730654 76 916 235 UUranium7 20 72 0 43 0 52 493 67 366 193 IrIridium3 262 7 0 000020 21130 522775 17 484 187 OsOsmium1 21 96 0 00143 0 111980 61929 9 129 OsO4 179 HfHafnium9 213 62 0 00007 0 7085 0 6821 379 310 068 41 KPotassium3 26 7302 0 000010 27740 686077 1110 245 KCl 167 ErErbium7 222 93 0 6394 0 77157 356 511 52 155 GdGadolinium3 214 8 0 3321 0 8213212712 28 103 RhRhodium1 21000 186 0 1531 0 8468 12 746 Rh acac 3p 57 FeIron1 22 119 0 00425 0 156960 86806 12 951 Fe CO 5 145 NdNeodymium7 28 3 0 744 0 898 3313 44 161 DyDysprosium5 218 91 0 5683 0 9201 250 713 76 149 SmSamarium7 213 82 0 7616 0 91927 413 76 73 GeGermanium9 27 73 0 00011 0 9723 0 93603 19 613 953 CH3 4Ge 83 KrKrypton9 211 49 0 00022 1 0731 1 033125 915 39 Kr 177 HfHafnium7 218 6 0 000260 89971 086 336 516 028 157 GdGadolinium3 215 65 0 4354 1 076913516 12 107 AgSilver1 251 8390 205 0 1969 1 08892 16 191 AgNO3 183 WTungsten1 214 310 0631 0 204011 12824 16 666 Na2WO4 147 SmSamarium7 214 99 0 9239 1 115 25 916 68 87 SrStrontium9 27 0 00019 1 209 1 1639433 517 335 SrCl2 105 PdPalladium5 222 33 0 00025 0 76 1 236618 304 K2PdCl6 99 RuRuthenium5 212 76 0 00014 0 7588 1 2297 918 421 K4 Ru CN 6 109 AgSilver1 248 1610 29 0 2264 1 25186 18 614 AgNO3 39 KPotassium3 2 93 2581 0 00048 0 505431 250065 8518 665 KCl 163 DyDysprosium5 224 9 0 79581 289 264 819 28 173 YbYtterbium5 216 13 0 8045 1 302528019 284 89 YYttrium1 21000 7 0 238 1 31628 19 601 Y NO3 3 101 RuRuthenium5 217 06 0 00027 0 8505 1 37745 720 645 K4 Ru CN 6 143 NdNeodymium7 212 2 1 208 1 457 6321 8 47 TiTitanium5 27 44 0 00016 0 9329 1 510530 222 55 TiCl4 49 TiTitanium7 25 410 0002 1 252 1 5109524 722 556 TiCl4 53 CrChromium3 29 501 0 00009 0 6126 1 5152 1522 61 K2CrO4 40 KPotassium1 40 01170 1 4513 1 55429 7 323 208 KCl 25 MgMagnesium5 210 0 00027 1 0122 1 63887 19 9424 487 MgCl2 67 ZnZinc5 24 1 0 00012 1 035561 676691525 027 Zn NO3 2 95 MoMolybdenium5 215 92 0 00052 1 082 1 751 2 226 068 Na2MoO4 201 HgMercury3 213 180 0002 0 7233 1 7887738 626 446 CH3 2HgD 97 MoMolybdenium5 29 55 0 00033 1 105 1 78825 526 615 Na2MoO4 43 CaCalcium7 20 135 0 00001 1 4941 1 80307 4 0826 92 CaCl2 14 NNitrogen1 199 6320 0010 5711 93378 2 04428 905 CH3NO2 33 SSulfur3 20 76 0 00002 0 831172 05568 6 7830 704 NH4 2SO4 189 OsOsmium3 216 150 0004 0 851972 1071385 631 062 OsO4 21 NeNeon3 20 27 0 00001 0 8544 2 11308 10 1631 577 Ne 176 LuLutetium1 72 59 3 3882 168449732 524 37 ClChlorine3 224 22 0 000660 88322 18437 6 4432 623 NaCl 131 XeXenon3 221 180 0006 0 893192 20908 11 432 976 XeOF4 169 TmThulium1 2100 0 4011 2 218 33 16 61 NiNickel3 21 1399 0 00004 0 9683 2 394816 235 744 Ni CO 4 91 ZrZirconium5 211 22 0 00107 1 5425 2 49743 17 637 185 Zr C5H5 2Cl2 85 RbRubidium5 272 17 0 00767 1 601312 5927127 638 62 RbCl 35 ClChlorine3 275 78 0 00358 1 061032 6242 8 1739 192 NaCl 135 BaBarium3 26 592 0 00033 1 081782 67551639 738 BaCl2 50 VVanadium1 60 25 0 00014 3 613762 670652139 881 VOCl3 15 NNitrogen1 20 3680 0225 0 4905 2 71262 40 547 MeNO2 10 BBoron1 319 9 0 00395 2 079212 87468 8 45942 975 BF3 Et2O 153 EuEuropium5 252 19 1 81392 9369 241 243 92 137 BaBarium3 211 232 0 00079 1 210132 9929524 544 452 BaCl2 175 LuLutetium7 297 41 2 53163 055234945 616 181 TaTantalum7 299 9880 03742 68793 243831747 958 KTaCl6 123 SbAntimony7 242 790 01992 89123 4892 4951 837 KSbCl6 133 CsCesium7 21000 0484 2 927743 53325 0 3452 465 CsNO3 138 LaLanthanum1 50 09 0 00008 4 068093 557244552 777 LaCl3 17 OOxygen5 20 038 0 00001 2 2408 3 62808 2 5654 226 D2O 9 BeBeryllium3 21000 0139 1 5201 3 75967 5 28856 207 BeSO4 139 LaLanthanum7 299 910 0605 3 155683 808332056 503 LaCl3 6 LiLithium1 17 59 0 00064 1 162563 93717 0 0858 864 LiCl 2 HDeuterium1 10 011501 21264 10663 0 28661 402 CD3 4Si 209 BiBismuth9 21000 1444 54444 375 51 664 277 Bi NO3 2 75 AsArsenic3 21000 0254 1 858354 5961631 468 49 NaAsF6 171 YbYtterbium1 214 28 0 855064 7288 69 997 199 HgMercury1 216 875 89 0 876224 84579 71 643 Me2Hgr 77 SeSelenium1 27 633 15 0 926785 12539 76 286 Me2Se 29 SiSilicon1 24 68322 16 0 9618 5 319 79 469 Me4Si 127 IIodine5 21000 0954 3 328715 38957 7180 03 KI 207 PbLead1 222 111 8 1 009065 58046 83 682 Me4Pb 111 CdCadmium1 212 87 27 1 0304 5 69831 84 862 Me2Cd 165 HoHolmium7 2100 4 7325 7135885 36 195 PtPlatinum1 233 83220 71 05575 8385 85 987 Na2PtCl6 113 InIndium9 24 290 01516 11245 884579 987 463 In NO3 3 115 InIndium9 295 710 3386 12565 89728187 651 In NO3 3 113 CdCadmium1 212 227 94 1 0779 5 96092 88 773 Me2Cd 99 TcTechnetium9 20 6 2816 046 12 990 033 NH4TcO4 185 ReRhenium5 237 40 05193 7716 105721890 098 KReO4 187 ReRhenium5 262 60 08953 80966 168220791 006 KReO4 59 CoCobalt7 21000 2785 2476 3324294 908 K3 Co CN 6 121 SbAntimony5 257 210 09333 97966 4435 3695 722 KSbCl6 69 GaGallium3 260 1080 04192 60346 4388617 196 005 Ga NO3 3 159 TbTerbium3 2100 2 66 431 143 296 16 45 ScScandium7 21000 302 5 393356 5088 2297 167 Sc NO3 3 93 NbNiobium9 21000 4886 82176 5674 3297 905 K NbCl6 55 MnManganese5 21000 179 4 104246 645253399 157 KMnO4 151 EuEuropium5 247 81 4 10786 65190 399 44 79 BrBromine3 250 690 0403 2 719356 7256231 3100 216 NaBr 13 CCarbon1 21 071 1 216616 72828 100 58 Me4Si 27 AlAluminum5 21000 207 4 308696 97627 14 66104 227 Al NO3 3 123 TeTellurium1 20 890 961 1 2764 7 0591 104 679 Me2Te 51 VVanadium7 299 750 383 5 838087 04551 5 2105 212 VOCl3 23 NaSodium3 21000 0927 2 862987 0808510 4105 808 NaCl 63 CuCopper3 269 170 065 2 875497 11179 22106 062 Cu CH3CN 4 ClO4 81 BrBromine3 249 310 0491 2 931287 2497826 2108 026 NaBr 129 XeXenon1 226 4433 6 1 3475 7 4521 111 241 XeOF4 65 CuCopper3 230 830 0354 3 074657 60435 20 4113 615 Cu CH3CN 4 ClO4 71 GaGallium3 239 8920 0571 3 307878 1811710 7121 987 Ga NO3 3 141 PrPraseodymium 5 2100 5 05878 1907 5 89122 48 125 TeTellurium1 27 0713 4 1 5389 8 51084 126 199 Me2Te 11 BBoron3 280 10 13