电化学原理-第三版-李荻-课后答案.pdf

y S K 2 3 03 8 10 2 Lmol 7 HAco HClo NaAco NaClo 390 7 121 eqcm HAco 9 02 121 eqcm 0 0 023 1 69 K 2 1 V 5 10 8IR iS KS l K il K 1000 c IR 1000il c V79 0 5 0126 1010105 33 9log 0 5115 ZZI25 C 1 uvsmvs Cl 73 49mol50 14mol76 31mol NaCl73 49mol50 14mol76 31mol NaCl Cl 73 49mol50 14mol76 31mol NaCl73 49mol50 14mol76 31mol NaCl73 49mol50 14mol76 31mol NaCl73 49mol50 14mol76 31mol NaCl Na aoo N 62 7 62 7 K 62 7 62 7 OH 2y 2yK K o Ag c c bb 21 2 2q C b 3 1 q 1 1 22 aa a b b 2 q 2 1 22 aa a b b 12 1 1 a q b 2 2 2 a q b 3 2 131212 22 2 22 aa qqqqq C bbbb 2 8 0 0 11 0 119 0 30V 1 0qc 10 1 212 ln2lnln r y RTRTRT RTc FCFF 1 1 y a qq C 10 22 ln2lnln r RTRTRT RTc FqFF 12 3 0 32 8 85 1040 298 8 31 0 05912log2log0 3log 10 0 1 c 3 0 2220 0591log 10 c 0 001cmol L 1 0 222V 1 2 0 222 0 3 3 0 1cmol L 1 0 1038V 1 1 3 1 0 8 2 r F qcRTSh RT 1 2 F Z RT 3 2 648 10qcShZ 0 001cmol L 3 37 764 2 648 101 q ShZ 12 37 764ln 37 76437 76412 3log75 54 325ZSh 1 2 0 222 ZRT V F 0 1cmol L 1 0 1038V 9 Cd0 37VNaCl0 25 0 27V ClNaClCl 10 lnlnTcTclnlnlnln FqFFFqFF 0 32 8 85 1040 298 8 310 32 8 85 1040 298 8 310 32 8 85 1040 298 8 310 32 8 85 1040 298 8 310 32 8 85 1040 298 8 310 32 8 85 1040 298 8 31 1a a qqqq 1 1 qq 0 32 8 85 1040 298 8 310 32 8 85 1040 298 8 310 32 8 85 1040 298 8 310 32 8 85 1040 298 8 310 32 8 85 1040 298 8 310 32 8 85 1040 298 8 310 32 8 85 1040 298 8 310 32 8 85 1040 298 8 31 0 2220 222V V 1 0 222 0 3 1 0 222 0 3 0 222 0 3 0 10380 1038V copyright downskyer 11 1 2 2CueCu25oTC 2 07 2 32 3 log0 337100 13 22 Cu RTRT aV FF 2 1 2 HeH25oTC0 130 ac 2 3 log0 0591log 2 0 1300 230 28 c H RT aV F 0 28V 2 2 22HeHlog6 5 H a 0 0591log1 230 846 c HH aV 3 2 2ZneZn 2 2ZnZne 2 0 2 30 0591 log0 763log 0 1 0 150 817 22 Zna Zn RT aV F 22 2 HeH c 0 0591log0 0591log 0 2 0 2651 061 1354 cHH H aV c 1 135 c V 0 8171 1350 318 ZncZn V V0 8171 1350 50 818 ac IRV 4BAB 0 00 20 40 60 81 0 0 0 0 1 0 2 0 3 0 4 0 5 5 1 j 2 j 1 11 exp w jnFvnfKc RT 2 22 exp w jnFvnFKc RT 3 2121 1 4 10 expexpexp0 193 8 31 293 jwww jRTRT 2 21 0 19318 6jj81 mA cm ZnZnZn 0 8171 1350 50 8180 8171 1350 50 8180 8171 1350 50 818 0 0591log0 0591log 0 2 0 2651 061 13540 0591log0 0591log 0 2 0 2651 061 13540 0591log0 0591log 0 2 0 2651 061 13540 0591log0 0591log 0 2 0 2651 061 13540 0591log0 0591log 0 2 0 2651 061 13540 0591log0 0591log 0 2 0 2651 061 13540 0591log0 0591log 0 2 0 2651 061 1354 ZnZnZnZn 0 8171 1350 50 8180 8171 1350 50 8180 8171 1350 50 8180 8171 1350 50 8180 8171 1350 50 8180 8171 1350 50 8180 8171 1350 50 818 B B copyright downskyer 12 6 32 2 96500 1 10193jnFvA m 2 2 96500 0 2548250jnFvA m 2 193jA m 2 193jjA m 2 48250 19348057jjA m jjj 7 1 v 1 W 2 v 2 W 1 1 exp W vKc RT 2 2 exp W vKc RT 12 21 exp1000 WW vv RT 3 1221 lnln108 31 29817106WWWRTvvJ mol 17106J mol 8 2 0 2 30 0591 log0 763log 0 33 10 77 22 cZn Zn RT mV F 0 0 aH 0 777 ac EVV 1 24VVE Zn V ac EIRV1 240 7770 1640 10 199 ca EIRV 1 Cu 2 1d j 2d j 3d j 0 d c jnFD 32 2 dd jj 1dd jj 321dd jj 3 053 2 2 4 96500 6 100 1 10 0 046 5 10 d c jnFDA cm 4 2 Cd 2 Cd t c j 0 5 c j 1 240 7770 1640 10 1991 240 7770 1640 10 199 0 763log 0 33 10 770 763log 0 33 10 770 763log 0 33 10 770 763log 0 33 10 770 763log 0 33 10 770 763log 0 33 10 770 763log 0 33 10 770 763log 0 33 10 770 763log 0 33 10 77 1 240 7770 1640 10 1991 240 7770 1640 10 1991 240 7770 1640 10 1991 240 7770 1640 10 1991 240 7770 1640 10 199 CuCu copyright downskyer 13 5 0 0 0 0 s d d s x cc jj c j cc dc dx 52 0 2 96500 0 5 108 100 077 x 2 jnFD dc dxA cm 2 3 log 1 2 d RTj Fj 22 0 056 log 11 94 2 30 0577 d Fj jRT 10 0115 d j j 0 12 0 01150 023 s d j ccmol j L 6 023 2 2 2 96500 1 100 5 10 0 088 1 1 10 d c jnFDA cm 2 30 05910 044 log 1log 10 0099 20 088 c d RTj Vm nFj V 7 2 31 61 20 0 62 d jnFDc262 8ns 2 31 6 1 2 523 0 62 2 965001 101 09 1062 80 1 100 0935 d jA 2 cm 053 2 3 2 96500 1 100 1 10 0 0386 5 10 d c jnFDA cm 0 0935 2 42 0 0386 d d j j 8 22 2202253 2 222 4965003 14 1 2 100 1 10 5 6 10 4 4 10 5 n FD c ts j 1 1 3 2 2 03 2 1 10 10 1 1018 66 10 5 6 10 s OO t ccmol 2 L 02 2 8 67 10 s OO jt ccmol L nFD 9 043 2 2 96500 1 5 100 1 10 0 2895 0 01 d c jnFDA cm 1 2 ln d RTjj nFj 1 2 2 30 05910 28950 08 log0 12log0 132 220 08 d RTjj V Fj 2 0 2jA cm 1 2 2 30 05910 28950 2 log0 132log0 142 220 2 d RTjj V Fj nsnsns262 8262 8262 8262 8nsns262 8262 8 1 61 61 6 jA0 62 2 965001 101 09 1062 80 1 100 09350 62 2 965001 101 09 1062 80 1 100 09350 62 2 965001 101 09 1062 80 1 100 09350 62 2 965001 101 09 1062 80 1 100 09350 62 2 965001 101 09 1062 80 1 100 0935 0 00990 0099VmVm0 00990 00990 00990 0099 V 1 21 21 2 jAjA0 62 2 965001 101 09 1062 80 1 100 09350 62 2 965001 101 09 1062 80 1 100 09350 62 2 965001 101 09 1062 80 1 100 0935 1 21 21 2 0 62 2 965001 101 09 1062 80 1 100 09350 62 2 965001 101 09 1062 80 1 100 09350 62 2 965001 101 09 1062 80 1 100 0935 3 3 2 96500 1 100 1 102 96500 1 100 1 10 5 105 10 2 96500 1 100 1 102 96500 1 100 1 102 96500 1 100 1 102 96500 1 100 1 102 96500 1 100 1 10 2202222022 22 4 4 n FD cn FD c 220222202222022 tsts 22 n FD cn FD cn FD c 22022 4 4 tststs copyright downskyer 14 10 0 0 0 0 s d d s x cc jj c j cc dc dx 52 0 96500 6 107 100 405 x dc jFDA cm dx 2 3 0 2 2 0 1 0 110 1 29 10 7 10 s x cc cm dc dx 2 3 log 1 d RTj Fj 0 059 log 11 2 30 0591 d Fj jRT 01 11 100 1 s d j ccmol L j 1 2 2ZneZn 0 0 2 0 7 copyright downskyer 15 0 expexp aa a FF jjjj RTRT 0 22 expexp aa a FF jj RTRT 3NaCN 2 4 Zn CN 1 j W 4Tafel 2 2NieNi 0 c jj 09 2 32 30 05810 0581 logloglog 2 10log0 040 424 11 c RTRT jj FF V 5 2 2ZnZne 0 05 a V1 1 n 042 0 9 96500 0 051 1 96500 0 05 expexp1 13 10 8 31 2988 31 298 a jjA cm 2 4 0 05 442 5 1 13 10 p Rcm j TAFEL 0 50 a jj1 6 2 2CueCu 2 0 2 log 2 3 Cu F a RT 2 0 20 31 0 3372 log0 94 2 30 0577 Cu F a RT 2 0 116 Cu amol L 0 0 3448V 2 0 06 Cu amol L 0 2 32 3 loglog cc RTRT jj FF 09 10 310 23 logloglog 1 3 100 473 2 30 0577 c F jj RT 2 2 97 c jA cm 7 0 2 3 log c RTj jF 9 0 0 0581log1 log10 2 3 log0 94 0 556 c RTj Fj 09 0 94 2 0 556 logloglog108 99 2 30 0581 cc F jj RT 82 9 8 10 c jA cm 0 9 96500 0 051 1 96500 0 050 9 96500 0 051 1 96500 0 050 9 96500 0 051 1 96500 0 050 9 96500 0 051 1 96500 0 05 jAjA 0 9 96500 0 051 1 96500 0 050 9 96500 0 051 1 96500 0 05 jAjAjAjAjAjAjAjAjAjAjA 8 31 2988 31 2988 31 2988 31 2988 31 2988 31 298 jAjA 8 31 2988 31 2988 31 2988 31 2988 31 2988 31 2988 31 2988 31 2988 31 2988 31 298 jAjA1 13 101 13 10jAjAjAjAjAjAjAjAjAjAjAjAjAjAjAjAjAjAjAjAjAjAjAjAjAjAjAjAjAjAjA 50 50 50 50 50 1 1 logloga copyright downskyer 16 c jj d j d j 8TAFEL 0 c jj c 9 0 2 3 log0 0591 log1 log 1 100 532 c RTj V jF 0 V0 832 j EV V1 7650 8320 5320 40 001 ac EIRV a 02 8 31 298 1 12 83 2 96500 0 001 a a RTj jA nF cm 0 j 0 j 0 j 92 22 44H OOeOH log0j0 36 c V0 36aVTAFELtg 0 093 log btg j 0 0 36 log3 87 0 093 a j b 04 1 35 10 2 jA cm 10log0j1 185 c V1 185aVTAFELtg 0 289 log btg j 2 30 0591 0 20 0 289 RT bF 0 1 185 log4 10 0 289 a j b 05 7 94 10 2 jA cm 1 2 3 log0 0581log 0 5 2 0 1540 4790 432 H H RT aV F 0 154 1 051 101 151 201 251 301 35 0 00 0 05 0 10 0 15 0 20 0 25 0 30 0 0000 0050 0100 0150 0200 0250 030 0 60 0 65 0 70 0 75 0 80 0 85 90 950 0 0 10 0 150 15 OOeOH 0 360 36V V