应用于燃油系统的高性能材料优秀课件

1 AdvancedFuelSystemMaterials应用于燃油系统的高性能材料 SolvayShanghai苏威 上海 有限公司JimDotySeptember14 2007 MOREPLASTICSWITHMOREPERFORMANCE 2 Today sTopics 内容概要 IntroductiontoFuelSystems燃油系统介绍FuelSystemTrends燃油系统的发展趋势SolvayValueProposition苏威的产品特点KeyProducts主要产品InjectionMoldedApplications注塑应用ExtrudedApplications挤出应用BlowMoldedApplications吹塑应用Summary总结 3 MarketSummary MarketdefinitionFUELSYSTEMS HPPapplicationsinautomotivefuelsystemsrequiringlowpermeationandanycombinationoftemperatureresistance fuelresistance andchemicalresistance connectors senderunits valves fillpipesandtanksFUEL VAPORLINE ExtrudedlineusedtocarryfuelandvaporwithintheautomotivefuelsystemTrendsLowpermeationIncreasedfuelresistanceHighertemperature 4 ApplicationSlide 5 FuelSystemTrends发展趋势 IncreaseduseofDirectInjectionEngines更多的使用直接喷射引擎Bothgasolineanddiesel包括汽油机和柴油机Newfuelinjectiontechnology新的燃油喷射技术Piezoelectricfuelinjectors压电燃油喷射器Increaseduseoflowpermeationmaterials更多使用低渗透材料ReplacementofPA11 12 andPOMinquickconnects line andfuelsenders代替PA11 12和POM 在快速接头 油管和送油器应用Increaseduseofcap lessfuelsystem NorthAmerica 更多的使用无接头燃油系统 北美 IncreaseduseofElectro staticdissipativecomponents NorthAmerica 更多的使用抗静电部件 北美 Furtherdevelopmentindieselemissioncontrol更加深入的研究在柴油喷射控制方面Ureainjection particulatefilters NOXscrubbersIncreaseduseinBio FuelsandHybridTechnology更多的使用生物燃料和混合动力技术Ethanol RME SMEBio diesel乙醇 RME SME生物柴油 6 Euro4 5 欧洲 Maximum2g car 24hr小于2克 车 24小时Testfuelcontains2 3 O2测试油氧含量2 3 LevII0 5g car 24hr0 5克 车 24小时Testfuelcontains3 3 测试油含量3 3 CertificationbasedonCARB测试燃油为CARBPhase2testfuelPZEV0 054g car 24hr0 054克 车 24小时Testfuelcontains3 3 O2测试含氧量3 3 CertificationbasedonCARB测试燃油为CARBPhase2testfuel Amodel PPAFlanges Senderunits法兰 送油单元Quickconnects快速接头Rollovervalves翻转阀Filterhousings过滤器外壳Levelindicators液面指示器Fuel airrails油轨Airvalves throttlebodies空气阀和节气阀FuelLine燃油管VaporLine蒸汽管InTankLine油箱内管Ixef PAMXD6FillerPipes加油管FuelTank油箱 Lowpermeationresinsforthemostaggressiveenvironments SolvayProductsforFuelSystemApplications苏威高性能材料在燃油系统中的应用 7 AmodelPPAis Modifiedwithadditionof Amodelcompoundshave enhancedperformancecharacteristicsvs conventionalmidrangeengineeringpolymers CH2 6 C O O C N n N H H Modified6 Tsemi aromaticpolyamidePA6 T HO OH C O C O HO OH C O C O CH2 4 or 8 IxefPAAis Semi aromaticpolyarylamideUniquestructureimpartsuniqueproperties CH2 4 O C H n N O C CH2 CH2 H N Ixefcompoundshave thehigheststrengthtoweightratioofanysemi crystallinematerialthelowestcostperunitofstiffnessofanysemi crystallinematerial 9 SolvayValueProposition FuelSystemsRequirements燃油系统的需求 LowPermeation低渗透 StaticChargeDissipation抗静电 HighTemperatureResistance耐高温 AlcoholResistance耐醇性 Diesel Bio DieselResistance耐柴油和生物燃油 SolvayFuelSystemValueProposition苏威高性能材料在燃油系统中的价值 10 ValueProposition FocusednewmaterialsdevelopmentAmodel EXT 1800 ExtrusionGradeLowPermeationandhighchemicalresistance Vaporline In tankline Oilline WaterGlycolline Amodel LTm Co extrusionwithPA11 12 LowPermeationFuelLine LowcostsolutiontoETFE PVDF Ixef BXT 1000 BlowMoldingandExtrusionGradeLowPermeation Alcoholresistancematerialfor5 6layerblowmoldingIxef BXT 2000 ImpactModifiedBlowMoldingandExtrusionGradeLowPermeation Alcoholresistancematerialfor2 3layerblowmoldingConductivePortfolioAmodelA 1625HS A 6625HSforinjectionmoldingIxefBXT 3000forBlowmolding 11 HighTemperatureResistance TensileStrengthHalfLifeforGlassReinforcedPolyamides ISO2578ThermalAging耐高温 5 000Hrs AmodelA 1133 35 GRPA66 23 GRPA12 185oC 150oC 120oC ISO2578热老化 玻纤增强聚酰胺拉伸强度的半衰期 12 Bio DieselResistance耐生物柴油 50 Diesel 50 RMEBio diesel 5 Water 1 100 Diesel 5 Water 1 InitialValueAfter5 000HrsExposure 110oC 1 Solutionalsocontains100mgeachCu Fe Almetals 1 Solutionalsocontains100mgofCu Fe Almetals 100 柴油 5 水 1 溶液中含有铜 铁 铝各100mg 50 柴油 50 RME生物柴油 5 水 1 1 溶液钟还含有铜 铁 铝各100mg 原始值 100 C5000小时浸泡后 13 Ethanol MethanolResistance耐乙醇 甲醇 Amodel AT 1002Comparisontoacetal POM MechanicalStrengthSimilartoPOMafterlongtermexposureinmethanolfuelDimensionalStabilityLessdimensionalchange swell afterlongtermexposuretomethanolfuel FuelImmersion 60oCfor1000Hours 燃油浸泡1000小时 60 C Amodel AT 1002与POM的对比 机械强度 长时间浸泡与甲醇溶液中后与POM类似 尺寸稳定性 长时间浸泡与甲醇溶液中后尺寸发生很小的变化 14 StaticChargeDissipation防静电 Applicationsrequiringstiffness impactstrengthandstaticchargedissipationFuelflanges燃油发兰Connectors连接器Pumpcomponents油泵部件Fuelfilterhousings燃油过滤器壳体 AmodelA 1625HS 应用需要强度 抗冲击和防静电 15 LowPermeation低渗透 TestFuelCE10Testing 60 CThefilmsampleisincontactwithfuel 300 500hours Filmthickness 50 100micronsSimilartoSAEJ2659 PermeationTestSetUpforFilm薄膜渗透测试 试验用燃油CE10 试验温度60 C 薄膜与燃油接触 300 500小时 薄膜厚度50 100微米 类似SAEJ2659 16 LowPermeation低渗透 MaterialBarrierProperties TestFuelCE10 60oC 1 FuelCE10 45 Isooctane 45 Toluene 10 Ethanol 17 InjectionMoldedApplications注塑应用 18 APPLICATIONPROFILE Application Fuel VaporLineQuickConnectors应用 燃油 蒸汽管快速接头Material 材料 AmodelAT 1116HSApplicationRequirements应用要求Highcontinuoususetemperature 170 C 连续使用温度170 CLowpermeation 0 54g mm m2 d 低渗透0 54g mm m2 dLowswellinallfuels各种燃油中保持低膨胀ResistancetoZnCl2attack耐ZnCl2腐蚀Resistanttoallfuels耐任何燃油Costeffectivevs GRPA12低成本vs GRPA12 APPLICATIONPROFILE应用解析 19 Application ESDFuelLineQuickConnectors应用 ESD燃油管快速接头Material 材料 AmodelA 1625HSApplicationRequirements应用要求Highcontinuoususetemperature 170 C 连续使用温度170 CLowpermeation低渗透 0 54g mm m2 d Resistancetofuelattack耐燃油腐蚀Flexfuels alcoholfuels bio fuels乙醇燃料 生物燃料ResistancetoZnCl2attack耐ZnCl2腐蚀Electro staticchargedissipation防静电Costeffectivevs conductiveGRPA12低成本VS 防静电的GRPA12 APPLICATIONPROFILE应用解析 APPLICATIONPROFILE应用解析 Application FuelPumpEndCap应用 燃油泵节流阀端盖Material材料 AmodelAT 1002HSApplicationRequirements应用要求Resistancetoallfuels耐各种燃油腐蚀Goodelongation impactresistanceforpressfitoftubesandconnectors在压装油管和连接器时有良好的断裂生长率和耐冲击性能ImprovedthermalperformancevsPOM 120oCvs80oC 提高热性能Superiorcreepresistancevs POM较好的抗蠕变性vs POMSuperiorfatigueresistancevs POM较好的抗疲劳性vs POM 20 APPLICATIONPROFILE应用解析 Application应用 FuelRail油轨Material材料 AmodelAS 1145HSApplicationRequirements应用要求Dimensionalstability尺寸稳定Highstrength stiffness高强度和硬度Thermalshockresistance 40oCto121oCwith0 2barpressure在0 2bar压力下抗热冲击 40oC到121oCResistancetoallfuels 121oC 耐各种燃油的腐蚀 121oC Resistancetounderhoodchemicalenvironment抵抗引擎下的化学环境Lowpermeation低渗透 21 22 APPLICATIONPROFILE Application DieselFuelSendingUnit应用 柴油机送油单元Material材料 AMODEL AT 1002HSApplicationRequirements 应用要求Chemicalresistancetodieselfuel biodiesel 125 C在125 C下耐柴油和生物燃油IncreasedtemperatureperformanceoverPOM PBTorPA66比POM PBT或PA66提高了耐热性能Highimpactandstiffnessoverthetemperaturerange 40oCto125oC 在 40oCto125oC 的温度范围外保持较高的耐冲击性和强度Elongationforsnapfits pressfits andlivinghinges在装配中保持良好的伸长率Resistancetoacids耐酸性Creepandfatigueresistance抗蠕变和疲劳性 APPLICATIONPROFILE应用解析 23 APPLICATIONPROFILE APPLICATIONPROFILE应用解析 Head Bowl Application DieselFuelFilter应用 柴油过滤器Material材料 AMODEL AS 1145HSApplicationRequirements 应用要求Chemicalresistancetodieselfuel biodiesel 125 C在125 C时耐柴油和生物燃油Metallikeperformance具有金属性能Strength强度Stiffness硬度Creep蠕变MayneedtobeESDforfutureNorthAmericanApplications抗静电 北美 24 APPLICATIONPROFILE Application应用 FuelFlange燃油法兰Material材料 AMODEL AT 1125HSApplicationRequirements 应用要求Chemicalresistancetohotdiesel bio dieselupto140 C在140 C以下耐柴油和生物燃油HighercontinuoususetemperaturethanPOM PBTorPA66连续使用温度高于POM PBT或PA66Highimpactresistance抗高冲击性Resistancetoacids耐酸性Creepandfatigueresistance抗蠕变和疲劳性 APPLICATIONPROFILE应用解析 25 APPLICATIONPROFILE Application应用 RollOverValve翻转阀Material材料 AMODEL AT 1002HSApplicationRequirements 应用要求Chemicalresistancetoallfuels耐各种燃料Resistancetoacids耐酸性MeetPZEVPermeation符合PZEV标准Highimpactresistance抗高冲击Over moldcapability可以2次成型 APPLICATIONPROFILE应用解析 26 ExtrudedApplications挤出应用 27 Application应用 Fuel VaporLine燃油 蒸汽管Material材料 AmodelEXT 1800ApplicationRequirements应用要求Thermalresistanceto90oCwithpeektemperaturesof115oC耐温到90oC 短期温度可达115oC 40oCcoldtemperatureimpactresistance 40oC的低温下抗冲击Resistancetoallfuels 耐化学性Lowpermeation低渗透Spinweldedconnectionstoimprovejointintegrity旋转焊接Acidresistance耐酸Fatigueresistance耐疲劳Costeffectiveness低成本 APPLICATIONPROFILE应用解析 28 Application ConvolutedTubingforIn TankandVaporLineApplications应用 波纹管Material材料 AmodelEXT 1800ApplicationRequirements应用要求Thermalresistanceto90oCwithpeektemperaturesof115oC耐温到90oC 短期温度可达115oC 40oCcoldtemperatureimpactresistance 40oC的低温下抗冲击Resistancetoallfuels 耐化学性Lowpermeation低渗透Costeffectiveness低成本ImprovedFlexibility提高弹性Acidresistance耐酸性Fatigueresistance耐疲劳性 APPLICATIONPROFILE应用解析 29 IntroducingNewAmodel LowTmPPA低熔点Amodel PPA ImprovedProcessingvs AmodelEXT 1800改善加工vs AmodelEXT 1800SimilartypechemistryasEXT 1800与EXT 1800类似的化学性能Muchwiderextrusionwindow更加宽的加工窗口ExtrudesinthesamerangeasETFE 290 310oC 与ETFE 290 310oC 相同的挤出温度DesignedforCo extrusionwithPA11 12可以与PA11 12共挤Performance性能Highelongation 100 高延展性大于100 Highimpact NoBreak 40oC 高冲击 不断 40oC Excellentthermalaging 125oC 卓越的耐热老化 125oC Lowpermeation 1 0g mm m2 day 低渗透 1 0g mm m2 day 30 Co extrusionofAmodelLowTmPPAwithPA11andPA12低熔点PPA与PA11和PA12共挤Twolayersystem2层管Notielayerisrequired无需粘接层Benefits优点Lowercostthan3to6layersystems低成本VS3或6层管Nopatentissues无专利限制Reductionofstiffnessofmono layer更加柔软VS单层管LowcostETFEReplacement低成本VSETFE管 AmodelLowTmPPA低熔点PPA PA11or12 LowTmPPA 31 BlowMoldedApplications吹塑应用 32 IntroductionofIxef PAMXD6BarrierTechnology Polymerwithmeltpoint 235oC熔点 235oCGoodmeltviscosityandmeltelasticity好的熔融粘度和熔体弹性Exceptionalmeltstability superiortoEVOH 较好的熔体稳定性 优于EVOH Wideprocessingwindow likePA6 较宽的加工范围 类似PA6 Lowpermeation similartoEVOH 低渗透 类似EVOH Pinchoffdirectlyonbarrierlayer直接在阻挡层修剪Canbeusedindirectfuelcontact可直接与燃油接触ExcellentadhesiontoPEwithtielayer与PE和粘接层的优异的粘接性Highimpactformulationavailable可提供抗冲击牌号Laboratoryvalidationofthemulti layerblowmoldingprocessiscomplete实验室证明可以多层吹塑成型 33 PermeationonMulti layerPolyethyleneConstruction Construction结构1LiterClosedBottle1公升容量的密封瓶5Layers5层WallSection刨面结构Soak浸泡Sealed密封40oC3 360hoursFuelCE10Testing测试Mini SHED40oC24hoursisothermal24小时恒温HydrocarbonemissionanalysisbyFIDFID检测碳氢挥发物Propanereferencestandard参考标准丙烷 2mm PEPE BARRIER 0 06mm