8-1附录一物料衡算一览表

附录一：物料衡算一览表 2018年“东华科技-陕鼓杯”第十二届全国大学生化工设计竞赛茂名石化6.5万吨/年甲基丙烯酸甲酯项目物料衡算一览表团队名称：在烯望的田野上指导老师：陈中合 牟宗刚 李平 倪献智 杨成团队成员：占杰 陈玉强 姜振朝 宋广 聂美华2018年8月15日物料衡算一览表1.1 第一工段物料衡算1.1.1 醚化反应器（R0101）表1.1 醚化反应器R0101进出料流股表序号组分名称质量流量kg/hr进料流股出料流股温度/29.365压力/bar88气相分率001丙烷35.20135.2012正丁烷1236.41236.43异丁烷485.101485.1014顺-2-丁烯866.809866.8095反-2-丁烯408.107408.1076异丁烯4923.911267.81371-丁烯3044.823044.2118甲醇2949.772293.2619甲基叔丁基醚 0.0017307.10710水1.0941.04711二异丁烯trace4.91212叔丁醇 0.001 0.25313二甲醚 0.0010.03614甲基仲丁基醚 0.0010.95715氧气16氮气17甲基丙烯醛18甲基丙烯酸甲酯19一氧化碳20二氧化碳21丙酮22氢醌23丙烯24丙烯酸甲酯25甲基丙烯酸26氯仿合计13951.21613951.216序号组分名称质量分率进料流股出料流股1丙烷0.0030.0032正丁烷0.0890.0893异丁烷0.0350.0354顺-2-丁烯0.0620.0625反-2-丁烯0.0290.0296异丁烯0.3530.01971-丁烯0.2180.2188甲醇0.2110.0219甲基叔丁基醚6 PPB0.52410水78 PPM75 PPM11二异丁烯trace352 PPM12叔丁醇17 PPB18 PPM13二甲醚2 PPB3 PPM14甲基仲丁基醚1 PPB69 PPM15氧气16氮气17甲基丙烯醛18甲基丙烯酸甲酯19一氧化碳20二氧化碳21丙酮22氢醌23丙烯24丙烯酸甲酯25甲基丙烯酸26氯仿合计111.1.2 反应精馏塔（T0101）表1.2 反应精馏塔T0101进出料流股表序号组分名称质量流量kg/hr进料流股1进料流股2塔顶出料塔釜出料温度/653526.159.8压力/bar88107.7气相分率00001丙烷35.201 0.001 0.00135.2012正丁烷1236.403 0.0014.5691231.8343异丁烷485.101 0.0010.178484.9234顺-2-丁烯866.809 0.0017.565859.2445反-2-丁烯408.107 0.0019.322398.7846异丁烯267.8130.0080.2060.00271-丁烯3044.2110.0013.7983040.4138甲醇293.26179.9260.214220.1439甲基叔丁基醚7307.107trace7727.55trace10水1.0470.030.4760.611二异丁烯4.912trace4.912trace12叔丁醇0.253trace0.253trace13二甲醚0.036tracetrace0.03614甲基仲丁基醚0.957trace0.957trace15氧气16氮气17甲基丙烯醛18甲基丙烯酸甲酯19一氧化碳20二氧化碳21丙酮22氢醌23丙烯0024丙烯酸甲酯0025甲基丙烯酸0026氯仿00合计63110.50061928.3201182.175序号组分名称质量分率进料流股进料流股2塔顶出料塔釜出料1丙烷0.003356 PPB21 PPB0.0062正丁烷0.089879 PPB589 PPM0.1963异丁烷0.035174 PPB23 PPM0.0774顺-2-丁烯0.0623 PPM975 PPM0.1375反-2-丁烯0.0292 PPM0.0010.0646异丁烯0.019105 PPM27 PPM377 PPB71-丁烯0.2187 PPM489 PPM0.4858甲醇0.021128 PPM0.0359甲基叔丁基醚0.52427 PPB0.996trace10水75 PPM371 PPM61 PPM96 PPM11二异丁烯352 PPMtrace633 PPMtrace12叔丁醇18 PPM83 PPB33 PPMtrace13二甲醚3 PPM9 PPBtrace6 PPM14甲基仲丁基醚69 PPM5 PPB123 PPMtrace15氧气00016氮气00017甲基丙烯醛00018甲基丙烯酸甲酯00019一氧化碳00020二氧化碳21丙酮22氢醌23丙烯24丙烯酸甲酯25甲基丙烯酸26氯仿合计1111.1.3 水萃取塔（T0102）表1.3 水萃取塔T0102进出料流股表序号组分名称质量流量kg/hr进料流股1进料流股2塔釜出料塔顶出料温度/2559.855.828.4压力/bar6.57.76.56.5气相分率00001丙烷35.2010.00135.22正丁烷1231.8340.0031231.8323异丁烷484.9230.001484.9224顺-2-丁烯859.2440.008859.2365反-2-丁烯398.7840.005398.7796异丁烯0.002trace0.00271-丁烯3040.4130.023040.3938甲醇220.143219.1760.9679甲基叔丁基醚tracetracetrace10水3783.2090.63747.94135.68611二异丁烯trace12叔丁醇tracetracetrace13二甲醚0.0360.0010.03614甲基仲丁基醚trace15氧气16氮气17甲基丙烯醛18甲基丙烯酸甲酯19一氧化碳20二氧化碳21丙酮22氢醌23丙烯0024丙烯酸甲酯0025甲基丙烯酸0026氯仿00合计3783.2096271.1813967.1556087.235序号组分名称质量分率进料流股进料流股2塔顶出料塔釜出料1丙烷0.006273 PPB0.0062正丁烷0.196634 PPB0.2023异丁烷0.077132 PPB0.084顺-2-丁烯0.1372 PPM0.1415反-2-丁烯0.0641 PPM0.0666异丁烯377 PPBtrace388 PPB71-丁烯0.4855 PPM0.4998甲醇0.0350.055159 PPM9甲基叔丁基醚tracetracetrace10水196 PPM0.9450.00611二异丁烯trace 12叔丁醇tracetracetrace13二甲醚6 PPM7 PPB6 PPM14甲基仲丁基醚trace15氧气0016氮气0017甲基丙烯醛0018甲基丙烯酸甲酯0019一氧化碳0020二氧化碳21丙酮22氢醌23丙烯24丙烯酸甲酯25甲基丙烯酸26氯仿合计1111在烯望的田野上 251.2 第二工段物料衡算1.2.1 裂解反应器（R0201）表1.4 裂解反应器R0201进出料流股表序号组分名称质量流量kg/hr进料流股出料流股温度/180180压力/bar55气相分率111丙烷 0.001 0.0012正丁烷4.5694.5693异丁烷0.1780.1784顺-2-丁烯7.5657.5655反-2-丁烯9.3229.3226异丁烯0.2064905.38871-丁烯3.7983.7988甲醇0.2142803.4529甲基叔丁基醚7727.5515.69410水0.4760.47611二异丁烯4.9128.34912叔丁醇0.2530.25313二甲醚tracetrace14甲基仲丁基醚0.9570.95715氧气16氮气17甲基丙烯醛18甲基丙烯酸甲酯19一氧化碳20二氧化碳21丙酮22氢醌23丙烯24丙烯酸甲酯25甲基丙烯酸26氯仿合计77607760序号组分名称质量分率进料流股出料流股1丙烷21 PPB21 PPB2正丁烷589 PPM589 PPM3异丁烷23 PPM23 PPM4顺-2-丁烯975 PPM975 PPM5反-2-丁烯0.0010.0016异丁烯27 PPM0.63271-丁烯489 PPM489 PPM8甲醇28 PPM0.3619甲基叔丁基醚0.9960.00210水61 PPM61 PPM11二异丁烯633 PPM0.00112叔丁醇33 PPM33 PPM13二甲醚tracetrace14甲基仲丁基醚123 PPM123 PPM15氧气16氮气17甲基丙烯醛18甲基丙烯酸甲酯19一氧化碳20二氧化碳21丙酮22氢醌23丙烯24丙烯酸甲酯25甲基丙烯酸26氯仿合计111.2.2 异丁烯水洗塔（T0201）表1.5 异丁烯水洗塔T0201进出料流股表序号组分名称质量流量kg/hr进料流股1进料流股2塔顶出料塔釜出料温度/180252587.2压力/bar521.81.8气相分率10101丙烷 0.001 0.001trace2正丁烷4.5694.568 0.0013异丁烷0.1780.178trace4顺-2-丁烯7.5657.5640.0015反-2-丁烯9.3229.3210.0016异丁烯4905.3884905.0690.31971-丁烯3.7983.798 0.0018甲醇2803.452trace2803.4529甲基叔丁基醚15.69415.694 0.00110水0.47616844.28724.56916820.19411二异丁烯8.3498.349trace12叔丁醇0.2530.252 0.00113二甲醚tracetracetrace14甲基仲丁基醚0.9570.957 0.00115氧气16氮气17甲基丙烯醛18甲基丙烯酸甲酯19一氧化碳20二氧化碳21丙酮22氢醌23丙烯0024丙烯酸甲酯0025甲基丙烯酸0026氯仿00合计776016844.2874980.31819623.968序号组分名称质量分率进料流股进料流股2塔顶出料塔釜出料1丙烷21 PPB32 PPBtrace2正丁烷589 PPM917 PPM8 PPB3异丁烷23 PPM36 PPMtrace4顺-2-丁烯975 PPM0.00240 PPB5反-2-丁烯0.0010.00271 PPB6异丁烯0.6320.98516 PPM71-丁烯489 PPM763 PPM13 PPB8甲醇0.3612 PPB0.1439甲基叔丁基醚0.0020.0034 PPB10水61 PPM10.0050.85711二异丁烯0.0010.002trace12叔丁醇33 PPM51 PPM13 PPB13二甲醚tracetracetrace14甲基仲丁基醚123 PPM192 PPMtrace15氧气16氮气17甲基丙烯醛18甲基丙烯酸甲酯19一氧化碳20二氧化碳21丙酮22氢醌23丙烯24丙烯酸甲酯25甲基丙烯酸26氯仿合计1111.2.3 甲醇回收塔（T0202）表1.6 甲醇回收塔T0202进出料流股表序号组分名称质量流量kg/hr进料流股塔顶出料塔釜出料温度/65.370.9107.2压力/bar1.81.31.3气相分率0001丙烷0.0010.001trace2正丁烷0.0030.003trace3异丁烷0.0010.001trace4顺-2-丁烯0.0090.009trace5反-2-丁烯0.0070.007trace6异丁烯0.3190.319trace71-丁烯0.020.02trace8甲醇3022.6283021.9480.689甲基叔丁基醚 0.001 0.001trace10水20568.1351.11620567.01911二异丁烯tracetracetrace12叔丁醇 0.001 0.001trace13二甲醚 0.001 0.001trace14甲基仲丁基醚 0.001 0.001trace15氧气16氮气17甲基丙烯醛18甲基丙烯酸甲酯19一氧化碳20二氧化碳21丙酮22氢醌23丙烯24丙烯酸甲酯25甲基丙烯酸26氯仿合计23591.1233023.42420567.699序号组分名称质量分率进料流股塔顶出料塔釜出料1丙烷46 PPB358 PPBtrace2正丁烷113 PPB883 PPBtrace3异丁烷22 PPB175 PPBtrace4顺-2-丁烯371 PPB3 PPMtrace5反-2-丁烯286 PPB2 PPMtrace6异丁烯14 PPM106 PPMtrace71-丁烯855 PPB7 PPMtrace8甲醇0.128133 PPM9甲基叔丁基醚4 PPB27 PPBtrace10水0.872369 PPM111二异丁烯tracetracetrace12叔丁醇11 PPB83 PPBtrace13二甲醚1 PPB9 PPBtrace14甲基仲丁基醚trace5 PPBtrace15氧气16氮气17甲基丙烯醛18甲基丙烯酸甲酯19一氧化碳20二氧化碳21丙酮22氢醌23丙烯24丙烯酸甲酯25甲基丙烯酸26氯仿合计1111.2.4 异丁烯精制塔（T0203）表1.7 异丁烯精制塔T0203进出料流股表序号组分名称质量流量kg/hr进料流股塔顶出料塔釜出料温度/25-0.552.1压力/bar1.81.31.3气相分率1001丙烷 0.001 0.001trace2正丁烷4.5684.2130.3563异丁烷0.1780.178 0.0014顺-2-丁烯7.5646.3151.2495反-2-丁烯9.3214.2875.0346异丁烯4905.0694897.7257.34471-丁烯3.7983.7910.0068甲醇tracetracetrace9甲基叔丁基醚15.694trace15.69410水24.569trace24.56911二异丁烯8.349trace8.34912叔丁醇0.252trace0.25213二甲醚tracetracetrace14甲基仲丁基醚0.957trace0.95715氧气16氮气17甲基丙烯醛18甲基丙烯酸甲酯19一氧化碳20二氧化碳21丙酮22氢醌23丙烯24丙烯酸甲酯25甲基丙烯酸26氯仿合计4980.3184916.50963.809序号组分名称质量分率进料流股塔顶出料塔釜出料1丙烷32 PPB33 PPBtrace2正丁烷917 PPM857 PPM0.0063异丁烷36 PPM36 PPM202 PPB4顺-2-丁烯0.0020.0010.025反-2-丁烯0.002872 PPM0.0796异丁烯0.9850.9960.11571-丁烯763 PPM771 PPM101 PPM8甲醇2 PPB1 PPB47 PPB9甲基叔丁基醚0.003trace0.24610水0.005trace0.38511二异丁烯0.002trace0.13112叔丁醇51 PPMtrace0.00413二甲醚tracetracetrace14甲基仲丁基醚192 PPMtrace0.01515氧气16氮气17甲基丙烯醛18甲基丙烯酸甲酯19一氧化碳20二氧化碳21丙酮22氢醌23丙烯24丙烯酸甲酯25甲基丙烯酸26氯仿合计1111.3 第三工段物料衡算1.3.1 MAL合成反应器（R0301）表1.8 MAL合成反应器R0301进出料流股表序号组分名称质量流量kg/hr进料流股出料流股温度/360360压力/bar11气相分率111丙烷 0.001 0.0012正丁烷4.2134.2133异丁烷0.1780.1784顺-2-丁烯6.3156.3155反-2-丁烯4.2874.2876异丁烯4897.72538.62271-丁烯3.7913.7918甲醇tracetrace9甲基叔丁基醚tracetrace10水47206415.29911二异丁烯trace12叔丁醇trace13二甲醚tracetrace14甲基仲丁基醚tracetrace15氧气61503033.20816氮气190761907617甲基丙烯醛5782.7518甲基丙烯酸甲酯19一氧化碳184.86920二氧化碳220.04921丙酮92.92822氢醌23丙烯24丙烯酸甲酯25甲基丙烯酸26氯仿合计34862.5134862.51序号组分名称质量分率进料流股出料流股1丙烷5 PPB5 PPB2正丁烷121 PPM121 PPM3异丁烷5 PPM5 PPM4顺-2-丁烯181 PPM181 PPM5反-2-丁烯123 PPM123 PPM6异丁烯0.140.00171-丁烯109 PPM109 PPM8甲醇tracetrace9甲基叔丁基醚tracetrace10水0.1350.18411二异丁烯trace12叔丁醇trace13二甲醚tracetrace14甲基仲丁基醚tracetrace15氧气0.1760.08716氮气0.5470.54717甲基丙烯醛0.16618甲基丙烯酸甲酯19一氧化碳0.00520二氧化碳0.00621丙酮0.00322氢醌23丙烯24丙烯酸甲酯25甲基丙烯酸26氯仿合计111.3.2 MAL吸收塔（T0301）表1.9 MAL吸收塔T0301进出料流股表序号组分名称质量流量kg/hr进料流股1进料流股2塔顶出料塔釜出料温度/3135.71773.8压力/bar1111气相分率01101丙烷trace 0.001 0.001 0.0012正丁烷trace4.2132.6071.6063异丁烷trace0.1780.1270.0514顺-2-丁烯trace6.3153.8682.4485反-2-丁烯trace4.2872.5061.7816异丁烯trace38.62226.35112.27171-丁烯trace3.7912.5961.1958甲醇0.68trace0.0420.6389甲基叔丁基醚tracetracetracetrace10水69999.3196415.299279.88976134.72911二异丁烯tracetracetrace12叔丁醇trace13二甲醚tracetracetracetrace14甲基仲丁基醚tracetracetracetrace15氧气3033.2083033.0550.15316氮气1907619075.4480.55217甲基丙烯醛5782.75trace5782.7518甲基丙烯酸甲酯19一氧化碳184.869184.8610.00720二氧化碳220.049219.8660.18321丙酮92.92870.51622.41222氢醌23丙烯24丙烯酸甲酯25甲基丙烯酸26氯仿合计3885.5741228.576804.7484309.402序号组分名称质量分率进料流股1进料流股2塔顶出料塔釜出料1丙烷trace5 PPB6 PPBtrace2正丁烷trace121 PPM114 PPM20 PPM3异丁烷trace5 PPM6 PPM619 PPB4顺-2-丁烯trace181 PPM169 PPM30 PPM5反-2-丁烯trace123 PPM109 PPM22 PPM6异丁烯trace0.0010.001150 PPM71-丁烯trace109 PPM113 PPM15 PPM8甲醇10 PPMtrace2 PPM8 PPM9甲基叔丁基醚tracetracetracetrace10水10.1840.0120.92911二异丁烯tracetracetrace12叔丁醇trace13二甲醚tracetracetracetrace14甲基仲丁基醚tracetracetracetrace15氧气0.0870.1322 PPM16氮气0.5470.8337 PPM17甲基丙烯醛0.166trace0.07118甲基丙烯酸甲酯19一氧化碳0.0050.00889 PPB20二氧化碳0.0060.012 PPM21丙酮0.0030.003273 PPM22氢醌23丙烯24丙烯酸甲酯25甲基丙烯酸26氯仿合计11111.3.3热泵-共沸耦合塔（T0302）表1.10热泵-共沸耦合塔T0302进出料流股表序号组分名称质量流量kg/hr进料流股1进料流股2进料流股3进料流股4塔顶出料塔釜出料温度/2564.799.673.868.699.6压力/bar111111气相分率0010101丙烷 0.001trace 0.001 0.001trace2正丁烷11.65trace1.60613.257trace3异丁烷0.368trace0.0510.419trace4顺-2-丁烯17.751trace2.44820.199trace5反-2-丁烯12.913trace1.78114.694trace6异丁烯89.015trace12.271101.285trace71-丁烯8.671trace1.1959.867trace8甲醇199914499.0010.4170.63816497.7231.3339甲基叔丁基醚tracetracetracetracetrace10水190.42821610.07676134.729103.19497733.0411二异丁烯tracetracetracetracetrace12叔丁醇13二甲醚tracetracetracetracetrace14甲基仲丁基醚tracetracetracetracetrace15氧气1.108trace0.1531.26trace16氮气4.007trace0.5524.56trace17甲基丙烯醛41947.266 0.0015782.7547730.016 0.00118甲基丙烯酸甲酯19一氧化碳0.053trace0.0070.06trace20二氧化碳1.328trace0.1831.511trace21丙酮162.575 0.00122.412184.986 0.00122氢醌23丙烯24丙烯酸甲酯25甲基丙烯酸26氯仿合计200056846.13521610.49381960.77664683.03197734.373序号组分名称质量分率进料流股1进料流股2进料流股3进料流股4塔顶出料塔釜出料1丙烷2 PPBtracetrace2 PPBtrace2正丁烷205 PPMtrace20 PPM205 PPMtrace3异丁烷6 PPMtrace619 PPB6 PPMtrace4顺-2-丁烯312 PPMtrace30 PPM312 PPMtrace5反-2-丁烯227 PPMtrace22 PPM227 PPMtrace6异丁烯0.002trace150 PPM0.002trace71-丁烯153 PPMtrace15 PPM153 PPMtrace8甲醇10.25519 PPM8 PPM0.25514 PPM9甲基叔丁基醚tracetracetracetracetrace10水500 PPM0.00210.9290.002111二异丁烯tracetracetracetracetrace12叔丁醇13二甲醚tracetracetracetracetrace14甲基仲丁基醚tracetracetracetracetrace15氧气19 PPMtrace2 PPM19 PPMtrace16氮气70 PPMtrace7 PPM70 PPMtrace17甲基丙烯醛0.738trace0.0710.738trace18甲基丙烯酸甲酯19一氧化碳929 PPBtrace89 PPB929 PPBtrace20二氧化碳23 PPMtrace2 PPM23 PPMtrace21丙酮0.003trace273 PPM0.003trace22氢醌23丙烯24丙烯酸甲酯25甲基丙烯酸26氯仿合计1111111.4 第四工段物料衡算1.4.1 MMA合成反应器（R0401）表1.11 MMA合成反应器R0401进出料流股表序号组分名称质量流量kg/hr进料流股出料流股温度/44.760压力/bar33气相分率0.2620.2911丙烷 0.001 0.0012正丁烷1.6061.6063异丁烷0.0510.0514顺-2-丁烯2.4472.4475反-2-丁烯1.781.786异丁烯12.27212.27271-丁烯1.1951.1958甲醇49550.45646909.5699甲基叔丁基醚tracetrace10水13.2611505.42811二异丁烯tracetrace12叔丁醇13二甲醚tracetrace14甲基仲丁基醚trace15氧气3411.3532073.01716氮气10583.02210583.02217甲基丙烯醛6225.678448.57418甲基丙烯酸甲酯121.6668332.32519一氧化碳0.0070.00720二氧化碳0.18318.17221丙酮57.58557.58522氢醌0.4530.45323丙烯24丙烯酸甲酯42.68277.87125甲基丙烯酸trace0.32326氯仿合计70025.69870025.698序号组分名称质量分率进料流股出料流股1丙烷tracetrace2正丁烷23 PPM23 PPM3异丁烷725 PPB725 PPB4顺-2-丁烯35 PPM35 PPM5反-2-丁烯25 PPM25 PPM6异丁烯175 PPM175 PPM71-丁烯17 PPM17 PPM8甲醇0.7080.679甲基叔丁基醚tracetrace10水189 PPM0.02111二异丁烯tracetrace12叔丁醇13二甲醚tracetrace14甲基仲丁基醚trace15氧气0.0490.0316氮气0.1510.15117甲基丙烯醛0.0890.00618甲基丙烯酸甲酯0.0020.11919一氧化碳104 PPB104 PPB20二氧化碳3 PPM260 PPM21丙酮822 PPM822 PPM22氢醌6 PPM6 PPM23丙烯24丙烯酸甲酯610 PPM0.00125甲基丙烯酸trace5 PPM26氯仿合计111.4.2 排不凝气塔（T0401）表1.12 排不凝气塔T0401进出料流股表序号组分名称质量流量kg/hr进料流股塔顶出料塔釜出料温度/604.596压力/bar333气相分率0.291101丙烷 0.001 0