7-1附录一物料衡算一览表

富丽达30万吨/年含硫废气资源化利用项目.2017年“东华科技-陕鼓杯”第十一届全国大学生化工设计竞赛 物料衡算一览表张丹阳 刘思琦 程金星 丛皓 王亦寒福州大学至诚学院 zcThe One团队2017年“东华科技-陕鼓杯”第十一届全国大学生化工设计竞赛富丽达30万吨/年含硫废气资源化利用项目物料衡算一览表团队名称：zc_The One指导老师：罗祖云、吕燕根、韩淑萃、邱挺团队成员：张丹阳、程金星、丛皓、刘思琦、王亦寒完成时间：2017年7月 福州大学至诚学院The one团队 目录第一章 概述1第二章 物料衡算原理2第三章 物料衡算任务3第四章 物料衡算表44.1低温甲醇洗工段44.1.1混合器(M0201M0202)44.1.2换热器(E0201E0204)64.1.3塔设备(T0201T0205）94.1.4 闪蒸罐(V0201）134.1.5 压缩机(C0201）144.2生产四氢噻吩工段144.2.1反应器(R0301)144.2.2冷凝器(E0301)154.2.3塔设备(T0301T0302)162 福州大学至诚学院The one团队 第一章 概述本项目以总厂在浙江省杭州市萧山临江工业园区富丽达集团控股有限公司的含硫废气为原料，经脱有机硫、无机硫后，通过低温甲醇洗分离硫化氢和其他气体氧气，氮气，二氧化碳等。得到的纯净的硫化氢和1，4-丁二醇反应，生成四氢噻吩。分离的氧气氮气混合气经变压吸附分开，副产氧气和氮气。设计过程中利用Aspen Plus对全流程进行模拟，并在此基础上完成物料衡算、能量衡算，Aspen plus全模拟流程如图1-1所示。图1-1 Aspen plus全模拟流程25 福州大学至诚学院The one团队 第二章 物料衡算原理系统累计的质量输入系统的质量输出系统的质量反应生成的质量反应消耗的质量假设系统无泄漏，有：dFdt=FIN-FOUT+GR-CR当系统无化学反应发生时，有：dFdt=FIN-FOUT 在稳定状态下，有：dFdt=FIN-FOUT=0，FIN=FOUT注：FIN进入系统的物料流率；FOUT流出系统的物料流率；GR反应产生物料速率；CR反应消耗物料速率。第三章 物料衡算任务通过对系统整体以及部分主要单元的详细物料衡算，得到主、副产品的产量，原料的消耗量，“三废”的排放量以及最后产品的质量指标等关键经济技术指标，对所选工艺路线、设计流程进行定量评述，为后阶段的设计提供依据。第四章 物料衡算表4.1低温甲醇洗工段4.1.1混合器(M0201M0202)表4-1 混合器(M0201)物料衡算InOutStream No.1-91-101-20Temperature C-39.942793-39.978091-39.943012Pressure bar60.31.01325Vapor Frac111Mole Flow kmol/hr1338.294748.294514891346.58925Mass Flow kg/hr38583.9722240.76430138824.7365Volume Flow cum/hr4324.83702536.01040825768.3939Enthalpy Gcal/hr-0.6473137-0.0077784-0.6550922Mass Flow kg/hrH2S0.852581970.100686210.95326819O28735.7226763.54467788799.26734N229823.8136174.76748229998.5811CO210.78377330.7498342611.5336075CH4O12.79956551.6016214614.4011869H2O7.22E-391.07E-507.22E-39Mole Flow kmol/hrH2S0.025015690.002954240.02796994O2273.0015711.98584565274.987417N21064.623666.238692281070.86235CO20.245031180.017037890.26206907CH4O0.399460130.049984810.44944495H2O4.01E-405.93E-524.01E-40表4-2 混合器(M0202)物料衡算InOutStream No.1-121-191-13Temperature C165.926467184.98765864.5415129Pressure bar20301.01325Vapor Frac000.40910021Mole Flow kmol/hr1400.20571149.9238321550.12954Mass Flow kg/hr44858.29794803.8834449662.1813Volume Flow cum/hr76.10695818.7259116317611.7338Enthalpy Gcal/hr-73.669667-7.7589463-81.428613Mass Flow kg/hrH2S0.007673590.000256950.00793055O29.54E-111.54E-159.54E-11N21.52E-101.73E-151.52E-10CO24.25E-089.74E-114.26E-08CH4O44848.89164803.8831949652.7748H2O9.398582537.56E-089.3985826Mole Flow kmol/hrH2S0.000225157.54E-060.00023269O22.98E-124.81E-172.98E-12N25.41E-126.17E-175.41E-12CO29.65E-102.21E-129.67E-10CH4O1399.68378149.9238251549.60761H2O0.521700614.20E-090.52170061表4-3 混合器(M0203)物料衡算InOutStream No.1-11-61-21Temperature C65-178.394763.2046815Pressure bar1.013250.3039750.303975Vapor Frac101Mole Flow kmol/hr1416.788641.362973111418.15161Mass Flow kg/hr4014242.953918740184.9539Volume Flow cum/hr39311.99680.04300718130469.66Enthalpy Gcal/hr-3.5355217-0.0782241-3.6137458Mass Flow kg/hrH2S1051.05095014106.05095O288000.655266778800.65527N2300001.556495730001.5565CO2120.030600612.0306006CH4O2038.934733958.9347339H2O12050.72587161205.72587Mole Flow kmol/hrH2S3.080815960.030836033.111652O2275.0103130.02047785275.030791N21070.9130.055562381070.96857CO20.272666540.000695310.27336186CH4O0.624177651.215109531.83928717H2O66.88766420.0402919966.92795624.1.2换热器(E0201E0204)表4-4 换热器(E0201)物料衡算InOutStream No.1-211-2Temperature C63.204681515Pressure bar0.3039751.01325Vapor Frac10.96871037Mole Flow kmol/hr1418.151611418.15161Mass Flow kg/hr40184.953940184.9539Volume Flow cum/hr130469.6632483.038Enthalpy Gcal/hr-3.6137458-4.56217Mass Flow kg/hrH2S106.05095106.05095O28800.655278800.65527N230001.556530001.5565CO212.030600612.0306006CH4O58.934733958.9347339H2O1205.725871205.72587Mole Flow kmol/hrH2S3.1116523.111652O2275.030791275.030791N21070.968571070.96857CO20.273361860.27336186CH4O1.839287171.83928717H2O66.927956266.9279562表4-5 换热器(E0202)物料衡算InOutStream No.1-21-3Temperature C15-40Pressure bar1.013251.01325Vapor Frac0.968710370.95158992Mole Flow kmol/hr1418.151611418.15161Mass Flow kg/hr40184.953940184.9539Volume Flow cum/hr32483.03825818.973Enthalpy Gcal/hr-4.56217-5.3933655Mass Flow kg/hrH2S106.05095106.05095O28800.655278800.65527N230001.556530001.5565CO212.030600612.0306006CH4O58.934733958.9347339H2O1205.725871205.72587Mole Flow kmol/hrH2S3.1116523.111652O2275.030791275.030791N21070.968571070.96857CO20.273361860.27336186CH4O1.839287171.83928717H2O66.927956266.9279562表4-6 换热器(E0203)物料衡算InOutStream No.1-161-17Temperature C29.618646225Pressure bar620Vapor Frac00Mole Flow kmol/hr1411.641411.64Mass Flow kg/hr45205.815945205.8159Volume Flow cum/hr57.547849557.1441812Enthalpy Gcal/hr-79.666853-79.827481Mass Flow kg/hrH2S104.147419104.147419O264.277334764.2773347N2176.186412176.186412CO21.216226761.21622676CH4O44850.589944850.5899H2O9.39858269.3985826Mole Flow kmol/hrH2S3.055800293.05580029O22.008742042.00874204N26.2893446.289344CO20.027635360.02763536CH4O1399.736781399.73678H2O0.521700610.52170061表4-7 换热器(E0204)物料衡算InOutStream No.1-211-23Temperature C63.204681525Pressure bar0.30397530Vapor Frac10Mole Flow kmol/hr1418.15161153.139783Mass Flow kg/hr40184.95394913.0777Volume Flow cum/hr130469.666.20258053Enthalpy Gcal/hr-3.6137458-8.5742308Mass Flow kg/hrH2S106.05095104.039059O28800.655270.73265692N230001.55651.41893092CO212.03060060.46639246CH4O58.93473394806.42066H2O1205.725877.56E-08Mole Flow kmol/hrH2S3.1116523.0526209O2275.0307910.02289638N21070.968570.05065171CO20.273361860.01059746CH4O1.83928717150.003017H2O66.92795624.20E-094.1.3塔设备(T0201T0205）表4-8 塔设备(T0201)物料衡算InOutStream No.1-51-61-7Temperature C-40-178.394768.225641Pressure bar0.5066250.3039750.303975Vapor Frac000Mole Flow kmol/hr68.21687241.3629731166.8538993Mass Flow kg/hr1254.1898542.95391871211.23593Volume Flow cum/hr1.202297210.043007181.27824006Enthalpy Gcal/hr-4.7011825-0.0782241-4.5066868Mass Flow kg/hrH2S1.050949311.050950142.38E-30O20.655266270.655266777.41E-60N21.556494511.55649574.21E-61CO20.030600570.03060064.91E-42CH4O54.5692538.934733915.6345214H2O1196.327290.72587161195.60141Mole Flow kmol/hrH2S0.030836010.030836036.98E-32O20.020477830.020477852.32E-61N20.055562340.055562381.50E-62CO20.000695310.000695311.12E-43CH4O1.70304531.215109530.48793594H2O66.40625560.0402919966.3659634表4-9 塔设备(T0202)物料衡算InOutStream No.1-81-141-91-16Temperature C196.910764-40-39.94279329.6186462Pressure bar6666Vapor Frac1010Mole Flow kmol/hr1349.9347414001338.294741411.64Mass Flow kg/hr38930.764144859.02438583.972245205.8159Volume Flow cum/hr8793.1156251.78578554324.8370257.5478495Enthalpy Gcal/hr1.55292141-81.867079-0.6473137-79.666853Mass Flow kg/hrH2S105.00000100.85258197104.147419O2880008735.7226764.2773347N230000029823.8136176.186412CO212010.78377331.21622676CH4O4.3654838544859.02412.799565544850.5899H2O9.398582607.22E-399.3985826Mole Flow kmol/hrH2S3.0808159900.025015693.05580029O2275.0103130273.0015712.00874204N21070.91301064.623666.289344CO20.2726665400.245031180.02763536CH4O0.1362418714000.399460131399.73678H2O0.5217006104.01E-400.52170061表4-10 塔设备(T0203)物料衡算InOutStream No.1-171-111-12Temperature C2520.8022235165.926467Pressure bar202020Vapor Frac010Mole Flow kmol/hr1411.6411.43429811400.20571Mass Flow kg/hr45205.8159347.51800544858.2979Volume Flow cum/hr57.144181213.972802676.1069581Enthalpy Gcal/hr-79.827481-0.0205479-73.669667Mass Flow kg/hrH2S104.147419104.1397450.00767359O264.277334764.27733479.54E-11N2176.186412176.1864121.52E-10CO21.216226761.216226724.25E-08CH4O44850.58991.6982858444848.8916H2O9.39858267.56E-089.39858253Mole Flow kmol/hrH2S3.055800293.055575140.00022515O22.008742042.008742042.98E-12N26.2893446.2893445.41E-12CO20.027635360.027635369.65E-10CH4O1399.736780.05300161399.68378H2O0.521700614.20E-090.52170061表4-11 塔设备(T0204)物料衡算InOutStream No.1-111-151-101-22Temperature C20.8022235-40-39.978091-34.522965Pressure bar201.013250.30.3Vapor Frac1010Mole Flow kmol/hr11.43429811508.29451489153.139783Mass Flow kg/hr347.5180054806.324240.7643014913.0777Volume Flow cum/hr13.97280265.54847702536.0104085.71335207Enthalpy Gcal/hr-0.0205479-8.7714727-0.0077784-8.7842437Mass Flow kg/hrH2S104.13974500.10068621104.039059O264.2773347063.54467780.73265692N2176.1864120174.7674821.41893092CO21.2162267200.749834260.46639246CH4O1.698285844806.3241.601621464806.42066H2O7.56E-0801.07E-507.56E-08Mole Flow kmol/hrH2S3.0555751400.002954243.0526209O22.0087420401.985845650.02289638N26.28934406.238692280.05065171CO20.0276353600.017037890.01059746CH4O0.05300161500.04998481150.003017H2O4.20E-0905.93E-524.20E-09表4-12塔设备(T005)物料衡算InOutStream No.1-231-181-19Temperature C2574.3394657184.987658Pressure bar303030Vapor Frac010Mole Flow kmol/hr153.1397833.21595076149.923832Mass Flow kg/hr4913.0777109.194264803.88344Volume Flow cum/hr6.202580533.09711298.72591163Enthalpy Gcal/hr-8.5742308-0.0185242-7.7589463Mass Flow kg/hrH2S104.039059104.0388020.00025695O20.732656920.732656921.54E-15N21.418930921.418930921.73E-15CO20.466392460.466392469.74E-11CH4O4806.420662.537477344803.88319H2O7.56E-081.09E-147.56E-08Mole Flow kmol/hrH2S3.05262093.052613367.54E-06O20.022896380.022896384.81E-17N20.050651710.050651716.17E-17CO20.010597460.010597462.21E-12CH4O150.0030170.07919183149.923825H2O4.20E-096.06E-164.20E-094.1.4 闪蒸罐(V0201）表4-13 闪蒸罐(V0201)物料衡算InOutStream No.1-31-41-5Temperature C-40-40-40Pressure bar1.013250.5066250.506625Vapor Frac0.9515899210Mole Flow kmol/hr1418.151611349.9347468.2168724Mass Flow kg/hr40184.953938930.76411254.18985Volume Flow cum/hr25818.97351652.20131.20229721Enthalpy Gcal/hr-5.3933655-0.6884739-4.7011825Mass Flow kg/hrH2S106.05095105.0000011.05094931O28800.6552788000.65526627N230001.5565300001.55649451CO212.0306006120.03060057CH4O58.93473394.3654838554.56925H2O1205.725879.39858261196.32729Mole Flow kmol/hrH2S3.1116523.080815990.03083601O2275.030791275.0103130.02047783N21070.968571070.9130.05556234CO20.273361860.272666540.00069531CH4O1.839287170.136241871.7030453H2O66.92795620.5217006166.40625564.1.5 压缩机(C0201）表4-14 压缩机(C0201）物料衡算InOutStream No.1-41-8Temperature C-40196.910764Pressure bar0.5066256Vapor Frac11Mole Flow kmol/hr1349.934741349.93474Mass Flow kg/hr38930.764138930.7641Volume Flow cum/hr51652.20138793.11562Enthalpy Gcal/hr-0.68847391.55292141Mass Flow kg/hrH2S105.000001105.000001O288008800N23000030000CO21212CH4O4.365483854.36548385H2O9.39858269.3985826Mole Flow kmol/hrH2S3.080815993.08081599O2275.010313275.010313N21070.9131070.913CO20.272666540.27266654CH4O0.136241870.13624187H2O0.521700610.521700614.2生产四氢噻吩工段4.2.1反应器(R0301)表4-15 反应器(R0301)物料衡算InOutStream No.2-12-52-82-2Temperature C74.3189.00634274.3250Pressure bar303301.01325Vapor Frac0.99986394001Mole Flow kmol/hr3.215950760.16076033.051933939.48057891Mass Flow kg/hr109.1942614.2983465275.047398.539606Volume Flow cum/hr3.096360350.017214990.28332565406.978749Enthalpy Gcal/hr-0.0185276-0.008367-0.3601732-0.3564013Mass Flow kg/hr1,4-B-0105.90017154275.0475.90017155H2S104.0388023.10E-1400.02315604C4H8S08.39713950277.496897H2O00.001035220109.963924O20.732656922.75E-1800.73265692N21.418930923.40E-1801.41893092CH4O2.537477342.00E-0702.53747754CO20.466392461.64E-1500.46639246Mole Flow kmol/hr1,4-B-0100.065468573.051933930.06546857H2S3.052613359.10E-1600.00067942C4H8S00.0952342503.14716818H2O05.75E-0506.10392532O20.022896388.60E-2000.02289638N20.050651711.21E-1900.05065171CH4O0.079191836.25E-0900.07919183CO20.010597463.72E-1700.010597464.2.2冷凝器(E0301)表4-15 冷凝器(E0301)物料衡算InOutStream No. 2-22-3Temperature C25025Pressure bar1.013253.5Vapor Frac10.00412339Mole Flow kmol/hr9.480578919.48057891Mass Flow kg/hr398.539606398.539606Volume Flow cum/hr406.9787490.66164128Enthalpy Gcal/hr-0.3564013-0.4849732Mass Flow kg/hr1,4-B-015.900171555.90017155H2S0.023156040.02315604C4H8S277.496897277.496897H2O109.963924109.963924O20.732656920.73265692N21.418930921.41893092CH4O2.537477542.53747754CO20.466392460.46639246Mole Flow kmol/hr1,4-B-010.065468570.06546857H2S0.000679420.00067942C4H8S3.147168183.14716818H2O6.103925326.10392532O20.022896380.02289638N20.050651710.05065171CH4O0.079191830.07919183CO20.010597460.010597464.2.3塔设备(T0301T0302)表4-16 塔设备(T0301)物料衡算InOutStream No. 2-32-42-5Temperature C25-51.216112189.006342Pressure bar3.533Vapor Frac0.0041233900Mole Flow kmol/hr9.480578919.319822520.1607603Mass Flow kg/hr398.539606384.24160414.2983465Volume Flow cum/hr0.661641280.345974960.01721499Enthalpy Gcal/hr-0.4849732-0.4899769-0.008367Mass Flow kg/hr1,4-B-015.900171559.76E-235.90017154H2S