应用于燃油系统的高性能材料PPT幻灯片课件

AdvancedFuelSystemMaterials应用于燃油系统的高性能材料,SolvayShanghai苏威（上海）有限公司JimDotySeptember14,2007,MOREPLASTICSWITHMOREPERFORMANCE,1,TodaysTopics/内容概要,IntroductiontoFuelSystems燃油系统介绍FuelSystemTrends燃油系统的发展趋势SolvayValueProposition苏威的产品特点KeyProducts主要产品InjectionMoldedApplications注塑应用ExtrudedApplications挤出应用BlowMoldedApplications吹塑应用Summary总结,2,MarketSummary,MarketdefinitionFUELSYSTEMS-HPPapplicationsinautomotivefuelsystemsrequiringlowpermeationandanycombinationoftemperatureresistance,fuelresistance,andchemicalresistanceconnectors,senderunits,valves,fillpipesandtanksFUEL/VAPORLINE-ExtrudedlineusedtocarryfuelandvaporwithintheautomotivefuelsystemTrendsLowpermeationIncreasedfuelresistanceHighertemperature,3,ApplicationSlide,4,FuelSystemTrends发展趋势,IncreaseduseofDirectInjectionEngines更多的使用直接喷射引擎Bothgasolineanddiesel包括汽油机和柴油机Newfuelinjectiontechnology新的燃油喷射技术Piezoelectricfuelinjectors压电燃油喷射器Increaseduseoflowpermeationmaterials更多使用低渗透材料ReplacementofPA11/12,andPOMinquickconnects,line,andfuelsenders代替PA11/12和POM，在快速接头，油管和送油器应用Increaseduseofcap-lessfuelsystem(NorthAmerica)更多的使用无接头燃油系统（北美）IncreaseduseofElectro-staticdissipativecomponents(NorthAmerica)更多的使用抗静电部件（北美）Furtherdevelopmentindieselemissioncontrol更加深入的研究在柴油喷射控制方面Ureainjection,particulatefilters,NOXscrubbersIncreaseduseinBio-FuelsandHybridTechnology更多的使用生物燃料和混合动力技术Ethanol,RME&SMEBio-diesel乙醇，RME&SME生物柴油,5,Euro4&5（欧洲）Maximum2g/car/24hr小于2克/车/24小时Testfuelcontains2.3%O2测试油氧含量2.3LevII0.5g/car/24hr0.5克/车/24小时Testfuelcontains3.3%测试油含量3.3CertificationbasedonCARB测试燃油为CARBPhase2testfuelPZEV0.054g/car/24hr0.054克/车/24小时Testfuelcontains3.3%O2测试含氧量3.3CertificationbasedonCARB测试燃油为CARBPhase2testfuel,AmodelPPAFlanges/Senderunits法兰、送油单元Quickconnects快速接头Rollovervalves翻转阀Filterhousings过滤器外壳Levelindicators液面指示器Fuel&airrails油轨Airvalves&throttlebodies空气阀和节气阀FuelLine燃油管VaporLine蒸汽管InTankLine油箱内管IxefPAMXD6FillerPipes加油管FuelTank油箱,Lowpermeationresinsforthemostaggressiveenvironments,SolvayProductsforFuelSystemApplications苏威高性能材料在燃油系统中的应用,6,AmodelPPAis.,Modifiedwithadditionof.Amodelcompoundshaveenhancedperformancecharacteristicsvs.conventionalmidrangeengineeringpolymers,(CH2)6,C,O,O,C,N,n,N,H,H,Modified6,Tsemi-aromaticpolyamidePA6,T,HO,OH,C,O,C,O,HO,OH,C,O,C,O,(CH2)4,or,7,IxefPAAis.,Semi-aromaticpolyarylamideUniquestructureimpartsuniqueproperties,(CH2)4,O,C,H,n,N,O,C,CH2,CH2,H,N,Ixefcompoundshavethehigheststrengthtoweightratioofanysemi-crystallinematerialthelowestcostperunitofstiffnessofanysemi-crystallinematerial,8,SolvayValueProposition,FuelSystemsRequirements燃油系统的需求,LowPermeation低渗透,StaticChargeDissipation抗静电,HighTemperatureResistance耐高温,AlcoholResistance耐醇性,Diesel&Bio-DieselResistance耐柴油和生物燃油,SolvayFuelSystemValueProposition苏威高性能材料在燃油系统中的价值,9,ValueProposition,FocusednewmaterialsdevelopmentAmodelEXT-1800ExtrusionGradeLowPermeationandhighchemicalresistance.Vaporline,In-tankline,Oilline,WaterGlycolline.AmodelLTmCo-extrusionwithPA11/12.LowPermeationFuelLine.LowcostsolutiontoETFE,PVDF.IxefBXT-1000BlowMoldingandExtrusionGradeLowPermeation,Alcoholresistancematerialfor5/6layerblowmoldingIxefBXT-2000ImpactModifiedBlowMoldingandExtrusionGradeLowPermeation,Alcoholresistancematerialfor2/3layerblowmoldingConductivePortfolioAmodelA-1625HS&A-6625HSforinjectionmoldingIxefBXT-3000forBlowmolding,10,HighTemperatureResistance,TensileStrengthHalfLifeforGlassReinforcedPolyamides,ISO2578ThermalAging耐高温,5.000Hrs,AmodelA-1133,35%GRPA66,23%GRPA12,185oC,150oC,120oC,ISO2578热老化,玻纤增强聚酰胺拉伸强度的半衰期,11,Bio-DieselResistance耐生物柴油,50%Diesel+50%RMEBio-diesel+5%Water(1),100%Diesel+5%Water(1),InitialValueAfter5,000HrsExposure110oC,(1)Solutionalsocontains100mgeachCu,Fe,Almetals(1)Solutionalsocontains100mgofCu,Fe,Almetals,100柴油+5水（1）,溶液中含有铜，铁，铝各100mg,50柴油+50RME生物柴油+5水（1）,（1）溶液钟还含有铜，铁，铝各100mg,原始值,100C5000小时浸泡后,12,Ethanol/MethanolResistance耐乙醇/甲醇,AmodelAT-1002Comparisontoacetal(POM)MechanicalStrengthSimilartoPOMafterlongtermexposureinmethanolfuelDimensionalStabilityLessdimensionalchange(swell)afterlongtermexposuretomethanolfuel,FuelImmersion60oCfor1000Hours,燃油浸泡1000小时60C,AmodelAT-1002与POM的对比,机械强度,长时间浸泡与甲醇溶液中后与POM类似,尺寸稳定性,长时间浸泡与甲醇溶液中后尺寸发生很小的变化,13,StaticChargeDissipation防静电,Applicationsrequiringstiffness,impactstrengthandstaticchargedissipationFuelflanges燃油发兰Connectors连接器Pumpcomponents油泵部件Fuelfilterhousings燃油过滤器壳体,AmodelA-1625HS,应用需要强度,抗冲击和防静电,14,LowPermeation低渗透,TestFuelCE10Testing60CThefilmsampleisincontactwithfuel(300-500hours)Filmthickness50-100micronsSimilartoSAEJ2659,PermeationTestSetUpforFilm薄膜渗透测试,试验用燃油CE10,试验温度60C,薄膜与燃油接触（300-500小时）,薄膜厚度50-100微米,类似SAEJ2659,15,LowPermeation低渗透,MaterialBarrierProperties-TestFuelCE1060oC(1),FuelCE10=45%Isooctane,45%Toluene,10%Ethanol,16,InjectionMoldedApplications注塑应用,17,APPLICATIONPROFILE,Application:Fuel&VaporLineQuickConnectors应用：燃油&蒸汽管快速接头Material（材料）:AmodelAT-1116HSApplicationRequirements应用要求Highcontinuoususetemperature(170C)连续使用温度170CLowpermeation(0.54g.mm/m2.d)低渗透0.54g.mm/m2.dLowswellinallfuels各种燃油中保持低膨胀ResistancetoZnCl2attack耐ZnCl2腐蚀Resistanttoallfuels耐任何燃油Costeffectivevs.GRPA12低成本vs.GRPA12,APPLICATIONPROFILE应用解析,18,Application:ESDFuelLineQuickConnectors应用：ESD燃油管快速接头Material（材料）:AmodelA-1625HSApplicationRequirements应用要求Highcontinuoususetemperature(170C)连续使用温度170CLowpermeation低渗透(0.54g.mm/m2.d)Resistancetofuelattack耐燃油腐蚀Flexfuels,alcoholfuels,bio-fuels乙醇燃料，生物燃料ResistancetoZnCl2attack耐ZnCl2腐蚀Electro-staticchargedissipation防静电Costeffectivevs.conductiveGRPA12低成本VS.防静电的GRPA12,APPLICATIONPROFILE应用解析,19,APPLICATIONPROFILE应用解析,Application:FuelPumpEndCap应用：燃油泵节流阀端盖Material材料:AmodelAT-1002HSApplicationRequirements应用要求Resistancetoallfuels耐各种燃油腐蚀Goodelongation/impactresistanceforpressfitoftubesandconnectors在压装油管和连接器时有良好的断裂生长率和耐冲击性能ImprovedthermalperformancevsPOM(120oCvs80oC)提高热性能Superiorcreepresistancevs.POM较好的抗蠕变性vs.POMSuperiorfatigueresistancevs.POM较好的抗疲劳性vs.POM,20,APPLICATIONPROFILE应用解析,Application应用:FuelRail油轨Material材料:AmodelAS-1145HSApplicationRequirements应用要求Dimensionalstability尺寸稳定Highstrength&stiffness高强度和硬度Thermalshockresistance-40oCto121oCwith0-2barpressure在0-2bar压力下抗热冲击-40oC到121oCResistancetoallfuels(121oC)耐各种燃油的腐蚀(121oC)Resistancetounderhoodchemicalenvironment抵抗引擎下的化学环境Lowpermeation低渗透,21,APPLICATIONPROFILE,Application:DieselFuelSendingUnit应用：柴油机送油单元Material材料:AMODELAT-1002HSApplicationRequirements:应用要求Chemicalresistancetodieselfuel/biodiesel125C在125C下耐柴油和生物燃油IncreasedtemperatureperformanceoverPOM,PBTorPA66比POM,PBT或PA66提高了耐热性能Highimpactandstiffnessoverthetemperaturerange(-40oCto125oC)在(-40oCto125oC)的温度范围外保持较高的耐冲击性和强度Elongationforsnapfits,pressfits,andlivinghinges在装配中保持良好的伸长率Resistancetoacids耐酸性Creepandfatigueresistance抗蠕变和疲劳性,APPLICATIONPROFILE应用解析,22,APPLICATIONPROFILE,APPLICATIONPROFILE应用解析,Head,Bowl,Application:DieselFuelFilter应用：柴油过滤器Material材料:AMODELAS-1145HSApplicationRequirements:应用要求Chemicalresistancetodieselfuel/biodiesel125C在125C时耐柴油和生物燃油Metallikeperformance具有金属性能Strength强度Stiffness硬度Creep蠕变MayneedtobeESDforfutureNorthAmericanApplications抗静电（北美）,23,APPLICATIONPROFILE,Application应用:FuelFlange燃油法兰Material材料:AMODELAT-1125HSApplicationRequirements:应用要求Chemicalresistancetohotdiesel/bio-dieselupto140C在140C以下耐柴油和生物燃油HighercontinuoususetemperaturethanPOM,PBTorPA66连续使用温度高于POM,PBT或PA66Highimpactresistance抗高冲击性Resistancetoacids耐酸性Creepandfatigueresistance抗蠕变和疲劳性,APPLICATIONPROFILE应用解析,24,APPLICATIONPROFILE,Application应用:RollOverValve翻转阀Material材料:AMODELAT-1002HSApplicationRequirements:应用要求Chemicalresistancetoallfuels耐各种燃料Resistancetoacids耐酸性MeetPZEVPermeation符合PZEV标准Highimpactresistance抗高冲击Over-moldcapability可以2次成型,APPLICATIONPROFILE应用解析,25,ExtrudedApplications挤出应用,26,Application应用:Fuel&VaporLine燃油&蒸汽管Material材料:AmodelEXT-1800ApplicationRequirements应用要求Thermalresistanceto90oCwithpeektemperaturesof115oC耐温到90oC，短期温度可达115oC-40oCcoldtemperatureimpactresistance-40oC的低温下抗冲击Resistancetoallfuels.耐化学性Lowpermeation低渗透Spinweldedconnectionstoimprovejointintegrity旋转焊接Acidresistance耐酸Fatigueresistance耐疲劳Costeffectiveness低成本,APPLICATIONPROFILE应用解析,27,Application:ConvolutedTubingforIn-TankandVaporLineApplications应用：波纹管Material材料:AmodelEXT-1800ApplicationRequirements应用要求Thermalresistanceto90oCwithpeektemperaturesof115oC耐温到90oC，短期温度可达115oC-40oCcoldtemperatureimpactresistance-40oC的低温下抗冲击Resistancetoallfuels.耐化学性Lowpermeation低渗透Costeffectiveness低成本ImprovedFlexibility提高弹性Acidresistance耐酸性Fatigueresistance耐疲劳性,APPLICATIONPROFILE应用解析,28,IntroducingNewAmodelLowTmPPA低熔点AmodelPPA,ImprovedProcessingvs.AmodelEXT-1800改善加工vs.AmodelEXT-1800SimilartypechemistryasEXT-1800与EXT-1800类似的化学性能Muchwiderextrusionwindow更加宽的加工窗口ExtrudesinthesamerangeasETFE(290-310oC)与ETFE(290-310oC)相同的挤出温度DesignedforCo-extrusionwithPA11/12可以与PA11/12共挤Performance性能Highelongation(100%)高延展性大于100%)Highimpact(NoBreak-40oC)高冲击（不断-40oC)Excellentthermalaging(125oC)卓越的耐热老化(125oC)Lowpermeation(1.0g.mm/m2.day)低渗透(1.0g.mm/m2.day),29,Co-extrusionofAmodelLowTmPPAwithPA11andPA12低熔点PPA与PA11和PA12共挤Twolayersystem2层管Notielayerisrequired无需粘接层Benefits优点Lowercostthan3to6layersystems低成本VS3或6层管Nopatentissues无专利限制Reductionofstiffnessofmono-layer更加柔软VS单层管LowcostETFEReplacement低成本VSETFE管,AmodelLowTmPPA低熔点PPA,PA11or12,LowTmPPA,30,BlowMoldedApplications吹塑应用,31,IntroductionofIxefPAMXD6BarrierTechnology,Polymerwithmeltpoint235oC熔点235oCGoodmeltviscosityandmeltelasticity好的熔融粘度和熔体弹性Exceptionalmeltstability(superiortoEVOH)较好的熔体稳定性（优于EVOH）Wideprocessingwindow(likePA6)较宽的加工范围（类似PA6)Lowpermeation(similartoEVOH)低渗透（类似EVOH)Pinchoffdirectlyonbarrierlayer直接在阻挡层修剪Canbeusedindirectfuelcontact可直接与燃油接触ExcellentadhesiontoPEwithtielayer与PE和粘接层的优异的粘接性Highimpactformulationavailable可提供抗冲击牌号Laboratoryvalidationofthemulti-layerblowmoldingprocessiscomplete实验室证明可以多层吹塑成型,32,PermeationonMulti-layerPolyethyleneConstruction,Construction结构1LiterClosedBottle1公升容量的密封瓶5Layers5层WallSection刨面结构Soak浸泡Sealed密封40oC3,360hoursFuelCE10Testing测试Mini-SHED40oC24hoursisothermal24小时恒温HydrocarbonemissionanalysisbyFIDFID检测碳氢挥发物Propanereferencestandard参考标准丙烷,2mm,PEPE,BARRIER,0.06mm,Results结