4-1 附录一 物料能量衡算表

附录一 物料能量衡算表100万立方米/日含硫废气深度脱硫及绿色甲醇合成项目队员：钱绮明 谢犨纬 梁炜 李兴涛 莫春玲指导老师：何畅 杨祖金中山大学Sky团队 100万立方米/日含硫废气深度脱硫及绿色甲醇合成项目附录一 物料能量衡算表目录1.物料能量衡算任务12.物料能量衡算表12.1脱硫、脱碳工段12.1.1 塔设备(T0101T0104)12.1.2 闪蒸器(F0101F0104)62.1.3 泵(P0101P0104)122.1.4 混合器(M0101)172.1.5 分流器(S0101S0102)192.2制硫磺工段212.2.1 反应器(R0201R0203)212.3绿色合成甲醇工段252.3.1 反应器（R0301R0303）252.3.2 混合器（M0301）292.3.3 塔设备（T0301）312.4克劳斯尾气处理工段322.4.1 塔设备（T0401T0402）322.4.2 反应器（R0401）352.4.3 混合器（M0401）3638中山大学Sky团队1.物料能量衡算任务通过对系统整体以及部分主要单元的详细物料衡算，得到主、副产品的产量，原料的消耗量，“三废”的排放量以及最后产品的质量指标等关键经济技术指标，对所选工艺路线、设计流程进行定量评述，为后阶段的设计提供依据。2.物料能量衡算表2.1脱硫、脱碳工段2.1.1 塔设备(T0101T0104)表2-1 脱硫化氢塔(T0101)衡算InOut物流号S107S106S120S108S127温度40103010.397336.2612压力 MPa5.25.5955.3955.355.372气相分率100.9999710液相分率012.96E-0501体积流率l/min1200007876.373729.681079078131.73能量 kJ/kg-5043.34-511.013-5689.44-5278.13-414.451热容 J/(kgK)-5903.48-871.941-5213.81-6205.03-694.6质量流率kg/hr29194850691010446.3299248510057SELEXOL04989621.985850.00597024498964CO236018.77597.582652.4542152.84115.99H28.579210.03644770.2691418.870840.0139621H2O08.82E-062.53E-081.09E-078.76E-06N23903.3119.4019122.8174037.777.76655AR00000CH424279537.42637496.2825030128.1111H2S6549.39247.13496.64371.338336891.83O2001.38E-112.68E-130SO2009.54E-171.32E-130C2H61843.2731.975252.27731893.9933.5323C3H8830.06414.399123.5416852.90415.1003S00000S200000S300000S400000S500000S600000S700000S800000O3S00000S-S00000CH4O00000CO00000表2-2 提浓塔(T0102)衡算InOut物流号S118S129S130S119温度15.2695105103.323105.087压力 MPa5.45.8675.4225.4气相分率1001液相分率0110体积流率l/min3223.158828.388773.34987.34能量 kJ/kg-5046.7-247.59-218.972-5523.93热容 J/(kgK)-6527.11-210.353-219.873-4726.54质量流率kg/hr8455.3551005750806610446.3SELEXOL0.000205914989644989621.98585CO2757.2544115.992220.792652.45H20.2607710.01396210.005592320.269141H2O7.14E-108.76E-068.74E-062.53E-08N2118.3147.766553.26354122.817AR0000CH47503.4128.111135.24017496.28H2S0.04317176891.836795.2396.6437O20001.38E-11SO20009.54E-17C2H652.451833.532333.706952.2773C3H823.620215.100315.178923.5416S0000S20000S30000S40000S50000S60000S70000S80000O3S0000S-S0000CH4O0000CO0000表2-3 解吸塔(T0102)衡算InOut物流号S130S135S122温度103.323159.169104.282压力 MPa5.4220.10.5气相分率010.00267559液相分率100.997324体积流率l/min8773.31543609433.34能量 kJ/kg-218.972-1771.48-218.972热容 J/(kgK)-219.8731251.03-206.189质量流率kg/hr50806612357.5508066SELEXOL4989623507.13498962CO22220.792215.52220.79H20.005592320.005592310.00559232H2O8.74E-066.92E-068.74E-06N23.263543.263523.26354AR000CH435.240135.2435.2401H2S6795.236547.556795.23O2000SO2000C2H633.706933.680633.7069C3H815.178915.167115.1789S000S2000S3000S4000S5000S6000S7000S8000O3S000S-S000CH4O000CO000表2-4 脱二氧化碳氢塔(T0104)衡算InOut物流号S108S113S125S102S101温度10.397311.25941011.122211.9313压力 MPa5.355.35.2645.2225.2气相分率10001液相分率01110体积流率l/min1079077759.3331347.939447.5106857能量 kJ/kg-5278.13-373.584-469.836-508.97-5052.63热容 J/(kgK)-6205.03-854.667-867.775-863.514-6531.64质量流率kg/hr2992484992152.02E+062.53E+06273390SELEXOL0.005970244989622.00E+062.49E+060.00665774CO242152.85.2964821071.637987.924484.5H28.870841.18E-080.003783990.1822388.43161H2O1.09E-071.82E-064.19E-054.41E-052.31E-08N24037.771.23E-053.0379297.00953825.48AR00000CH42503011.41E-050.0480644187.131242610H2S1.33833247.675988.0971235.671.39588O22.68E-1301.35E-1300SO21.32E-1306.63E-1800C2H61893.990.026235514.253159.8761695.94C3H8852.9040.01181446.4184371.9955763.719S00000S200000S300000S400000S500000S600000S700000S800000O3S00000S-S00000CH4O00000CO000002.1.2 闪蒸器(F0101F0104)表2-5 高压二氧化碳闪蒸器(F0101)衡算InOut物流号S103S109S110温度11.122212.091212.0912压力 MPa5.2222.072.07气相分率010液相分率101体积流率l/min31558115.49231701.9能量 kJ/kg-508.97-5624.39-508.654热容 J/(kgK)-863.514-4779.06-852.899质量流率kg/hr2.03E+06125.4572.03E+06SELEXOL2.00E+061.14E-052.00E+06CO230390.331.995530358.3H20.1457910.009121690.136669H2O3.53E-057.25E-113.53E-05N277.60763.611873.9958AR000CH4149.70587.031262.674H2S988.5380.00111532988.536O2000SO2000C2H6127.9011.93635125.965C3H857.59640.87197856.7244S000S2000S3000S4000S5000S6000S7000S8000O3S000S-S000CH4O000CO000表2-6 中压二氧化碳闪蒸器(F0102)衡算InOut物流号S110S116S117温度12.091212.384912.3849压力 MPa2.071.11.1气相分率010液相分率101体积流率l/min31701.996.490531746.5能量 kJ/kg-508.654-6096.32-508.482热容 J/(kgK)-852.899-3509.4-849.623质量流率kg/hr2.03E+0662.21172.03E+06SELEXOL2.00E+061.06E-052.00E+06CO230358.324.474930333.9H20.1366690.007310410.129359H2O3.53E-055.54E-113.53E-05N273.99582.8115671.1842AR000CH462.67432.603530.0706H2S988.5360.000859095988.536O2000SO2000C2H6125.9651.59522124.369C3H856.72440.71835956.0061S000S2000S3000S4000S5000S6000S7000S8000O3S000S-S000CH4O000CO000表2-7 低压二氧化碳闪蒸器(F0103)衡算InOut物流号S117S115S114温度12.384911.789511.7895压力 MPa1.10.150.15气相分率001液相分率110体积流率l/min31746.531598.557337.5能量 kJ/kg-508.482-469.473-8776.7热容 J/(kgK)-849.623-849.648-122.48质量流率kg/hr2.03E+062.02E+069520.69SELEXOL2.00E+062.00E+060.00575315CO230333.921071.69262.25H20.1293590.003783990.125575H2O3.53E-053.53E-052.99E-08N271.18423.0379268.1463AR000CH430.07060.048064430.0225H2S988.536988.0980.437169O2000SO2000C2H6124.36914.253110.116C3H856.00616.4184349.5877S000S2000S3000S4000S5000S6000S7000S8000O3S000S-S000CH4O000CO000表2-8 解吸塔后气液分离器(F0104)衡算InOut物流号S133S132S126温度804949压力 MPa0.0950.0950.095气相分率0.91938610液相分率0.080613701体积流率l/min12213410635866.7282能量 kJ/kg-1991.78-2851.76-519.303热容 J/(kgK)706.0681107.35-773.374质量流率kg/hr12357.58211.194146.35SELEXOL3507.130.1369533507CO22215.52213.591.90922H20.005592310.005592265.19E-08H2O6.92E-064.90E-062.02E-06N23.263523.263484.17E-05AR000CH435.2435.245.52E-05H2S6547.555910.11637.441O2000SO2000C2H633.680633.67540.00528436C3H815.167115.16470.00237966S000S2000S3000S4000S5000S6000S7000S8000O3S000S-S000CH4O000CO0002.1.3 泵(P0101P0104)表2-9 P0101衡算InOut物流号S127S128温度36.261236.3741压力 MPa5.3725.872气相分率00液相分率11体积流率l/min8131.738127.6能量 kJ/kg-414.451-413.889热容 J/(kgK)-694.6-694.327质量流率kg/hr510057510057SELEXOL498964498964CO24115.994115.99H20.01396210.0139621H2O8.76E-068.76E-06N27.766557.76655AR00CH428.111128.1111H2S6891.836891.83O200SO200C2H633.532333.5323C3H815.100315.1003S00S200S300S400S500S600S700S800O3S00S-S00CH4O00CO00表2-10 P0102衡算InOut物流号S104S105温度11.122211.2073压力 MPa5.2225.6气相分率00液相分率11体积流率l/min7889.57886.82能量 kJ/kg-508.97-508.555热容 J/(kgK)-863.514-863.295质量流率kg/hr506910506910SELEXOL498962498962CO27597.587597.58H20.03644770.0364477H2O8.82E-068.82E-06N219.401919.4019AR00CH437.426337.4263H2S247.134247.134O200SO200C2H631.975231.9752C3H814.399114.3991S00S200S300S400S500S600S700S800O3S00S-S00CH4O00CO00表2-11 P0103衡算InOut物流号S115S124温度11.789512.9588压力 MPa0.155.269气相分率00液相分率11体积流率l/min31598.531449.5能量 kJ/kg-469.473-463.814热容 J/(kgK)-849.648-846.635质量流率kg/hr2.02E+062.02E+06SELEXOL2.00E+062.00E+06CO221071.621071.6H20.003783990.00378399H2O3.53E-053.53E-05N23.037923.03792AR00CH40.04806440.0480644H2S988.098988.098O200SO200C2H614.25314.253C3H86.418436.41843S00S200S300S400S500S600S700S800O3S00S-S00CH4O00CO00表2-12 P0103衡算InOut物流号S112S113温度1011.2594压力 MPa0.2055.3气相分率00液相分率11体积流率l/min7794.237759.33能量 kJ/kg-379.418-373.584热容 J/(kgK)-858.444-854.667质量流率kg/hr499215499215SELEXOL498962498962CO25.296485.29648H21.18E-081.18E-08H2O1.82E-061.82E-06N21.23E-051.23E-05AR00CH41.41E-051.41E-05H2S247.675247.675O200SO200C2H60.02623550.0262355C3H80.01181440.0118144S00S200S300S400S500S600S700S800O3S00S-S00CH4O00CO002.1.4 混合器(M0101)表2-12 M0101衡算InOut物流号S123S121S111温度25241.355240.14压力 MPa0.210.1310.21气相分率000液相分率111体积流率l/min55.688411288.511318.6能量 kJ/kg-347.496251.788247.578热容 J/(kgK)-751.595729.777721.363质量流率kg/hr3507.15495708499215SELEXOL3507.15495455498962CO205.296485.29648H201.18E-081.18E-08H2O01.82E-061.82E-06N201.23E-051.23E-05AR000CH401.41E-051.41E-05H2S0247.675247.675O2000SO2000C2H600.02623550.0262355C3H800.01181440.0118144S000S2000S3000S4000S5000S6000S7000S8000O3S000S-S000CH4O000CO0002.1.5 分流器(S0101S0102)表2-12 S0101衡算InOut物流号S134S131S101温度11.931311.931311.9313压力 MPa5.25.25.2气相分率111液相分率000体积流率l/min1101623304.86106857能量 kJ/kg-5052.63-5052.63-5052.63热容 J/(kgK)-6531.64-6531.64-6531.64质量流率kg/hr2818458455.35273390SELEXOL0.006863650.000205910.00665774CO225241.8757.25424484.5H28.692380.2607718.43161H2O2.38E-087.14E-102.31E-08N23943.79118.3143825.48AR000CH42501147503.41242610H2S1.439060.04317171.39588O2000SO2000C2H61748.3952.45181695.94C3H8787.33923.6202763.719S000S2000S3000S4000S5000S6000S7000S8000O3S000S-S000CH4O000CO000表2-13 S0102衡算InOut物流号S102S103S104温度11.122211.122211.1222压力 MPa5.2225.2225.222气相分率000液相分率111体积流率l/min39447.5315587889.5能量 kJ/kg-508.97-508.97-508.97热容 J/(kgK)-863.514-863.514-863.514质量流率kg/hr2.53E+062.03E+06506910SELEXOL2.49E+062.00E+06498962CO237987.930390.37597.58H20.1822380.1457910.0364477H2O4.41E-053.53E-058.82E-06N297.009577.607619.4019AR000CH4187.131149.70537.4263H2S1235.67988.538247.134O2000SO2000C2H6159.876127.90131.9752C3H871.995557.596414.3991S000S2000S3000S4000S5000S6000S7000S8000O3S000S-S000CH4O000CO0002.2制硫磺工段2.2.1 反应器(R0201R0203)表2-21 R0201衡算InOut物流号S313S312S301温度2561.46841148.89压力 MPa0.1723690.0950.0881052气相分率111液相分率000体积流率l/min1115495643214.17E+06能量 kJ/kg-0.518115-2930.92-1220.79热容 J/(kgK)-87.87611179.13280.25质量流率kg/hr14817.941934.556752.4SELEXOL000CO2011481.211481.2H2000H2O0280.91912501.6N2661.63316.6645678.297AR000CH4000H2S030155.77036.34O214156.34.31E-080SO200.006450466613.22C2H6000C3H8000S0018441.8S2000S3000S4000S5000S6000S7000S8000O3S000S-S000CH4O000CO000表2-22 R0202衡算InOut物流号S304S305温度193.33333.903压力 MPa0.08460520.0816052气相分率11液相分率00体积流率l/min9805071.28E+06能量 kJ/kg-7744.82-7744.83热容 J/(kgK)420.345515.404质量流率kg/hr38352.438352.4SELEXOL00CO211481.111481.1H200.0353976H2O12457.815078N2678.297678.297AR00CH401.25E-11H2S7036.272078.71O201.74E-23SO26613.161954.29C2H600C3H800S3.82E-204.71E-13S20.052696264.4318S30.0052846710.8408S40.004452289.84228S50.654213125.955S617.70031822.21S78.038881320.48S859.26533728.16O3S00S-S00CH4O00CO00.00629459表2-23 R0203衡算InOut物流号S307S308温度165.556221.425压力 MPa0.07860520.0756052气相分率11液相分率00体积流率l/min9343961.08E+06能量 kJ/kg-9889.11-9889.13热容 J/(kgK)-160.853-115.632质量流率kg/hr31259.331259.3SELEXOL00CO211481.111481.1H20.03539760.00150318H2O15047.815930.5N2678.297678.297AR00CH409.64E-14H2S2078.7409.446O203.03E-30SO21954.29384.863C2H600C3H800S02.92E-18S20.008561750.567886S30.0007687380.0869198S40.0006249310.0999173S50.13267310.8389S63.87971336.873S71.59268230.291S813.39921796.31O3S00S-S00CH4O00CO0.006294594.28E-052.3绿色合成甲醇工段2.3.1 反应器（R0301R0303）表2-31 R0301衡算InOut物流号S302S306温度210229.546压力 MPa4.994.96气相分率11液相分率00体积流率l/min472454484208能量 kJ/kg-887.621-887.621热容 J/(kgK)-5112.92-5010.99质量流率kg/hr115443115443SELEXOL00CO223564.98333.95H266839.764755H2O473.5336708.29N29438.079438.07AR00CH45166.945166.94H2S00O200SO200C2H600C3H800S00S200S300S400S500S600S700S800O3S00S-S00CH4O4257.3815280.5CO5702.045759.77表2-32 R0302衡算InOut物流号S304S307温度210229.546压力 MPa4.994.96气相分率11液相分率00体积流率l/min472454484208能量 kJ/kg-887.621-887.621热容 J/(kgK)-5112.92-5010.99质量流率kg/hr115443115443SELEXOL00CO223564.98333.95H266839.764755H2O473.5336708.29N29438.079438.07AR00CH45166.945166.94H2S00O200SO200C2H600C3H800S00S200S300S400S500S600S700S800O3S00S-S00CH4O4257.3815280.5CO5702.045759.77表2-33 R0302衡算InOut物流号S305S308温度210229.546压力 MPa4.994.96气相分率11液相分率00体积流率l/min472455484208能量 kJ/kg-887.621-887.621热容 J/(kgK)-5112.92-5010.99质量流率kg/hr115443115443SELEXOL00CO223564.98333.96H266839.764755H2O473.5336708.29N29438.079438.07AR00CH45166.945166.94H2S00O200SO200C2H600C3H800S00S200S300S400S500S600S700S800O3S00S-S00CH4O4257.3815280.5CO5702.045759.772.3.2 混合器（M0301）表2-34 M0301衡算InOut物流号S315S316S322S311温度22022035.891445.7841压力 MPa4.995554.995气相分率1111液相分率0000体积流率l/min14059.556416.3860854934722能量 kJ/kg-8714.292803.36-1477.19-2345.65热容 J/(kgK)-236.769-8922.58-10370.9-8800.43质量流率kg/hr46409.78200291718346328SELEXOL0000CO245969.3024725.570694.8H208200192319200519H2O001420.61420.6N2283.831028030.428314.2AR0000CH4156.565015344.215500.8H2S0000O20000SO20000C2H60000C3H80000S0000S20000S30000S40000S50000S60000S70000S80000O3S0000S-S0000CH4O0012772.112772.1CO0017106.117106.12.3.3 塔设备（T0301）表2-35 T0301衡算InOut物流号S323S324S325温度-23.190765.202991.3519压力 MPa0.1140.10.114气相分率010液相分率101体积流率l/min964.272412212376.329能量 kJ/kg