01-高分子科学导论-高分子的合成

1、1 2 Structure Monomer Synthesize Polymer Characterization & Analysis Properties ProcessingProducts Molecular design Polymer Chemistry Polymer Engineering Polymer Physics 3 4 5 6 7 8 9 C O OC O OC O O2 CHH2C+C O OC O OCHCH2 ka 10 CHH2C C O OCHCH2 kp1 C O OCHCH2CHCH2 CHH2C kp2 C O OCHCH2CHCH2 ()2 CHH2

2、C kp3 11 C O OCHCH2CHCH2 ()x C O OCH2CHCH2CH ()y + C O OCH2CHCH2CH ()y C O OCHCH2CHCH2 ()x ktc 12 C O OCHCH2CHCH2 ()x C O OCH2CHCH2CH ()y + C O OCHCH2CH2CH2 ()x C O OCH2CHCH2CH ()y + ktd 13 kp1 +SH C O OCHCH2CH2CH2+S C O OCHCH2CHCH2 ()x 14 15 Ti Cl Cl Cl H3C Cl Al CH3 CH3 CH2CH2 Ti Cl Cl Cl H3C Cl A

3、l CH3 CH3 CH2CH2 Ti Cl Cl Cl H3C Cl Al CH3 CH3 CH2CH2 Ti Cl Cl Cl H2C Cl Al CH3 CH3 CH2CH3 CH2CH2 16 Lac2Zn + HO-R Lac2Zn OR H O O O Lac2Zn OR H O O O Lac2Zn O H CH2CH2OCH2 O COR 17 18 C O OHC O HOCH2CH2OHHO+ C O OC O OHCH2CH2OH nn n +2n-1 H2O C O OCH3C O CH3OCH2CH2OHHO+ C O OC O OCH3CH2CH2OH nn n +

4、2n-1 CH3OH 19 HO(CH2)4OHN(CH2)6NCOCO+nn O(CH2)4OC O NH(CH2)6NHC O n 20 21 。 22 23 Structure Chemical Structure Chain Structure Aggregate Structure Morphology Properties Molecular design Copolymerization Branching Cross-linking 24 25 26 S SS S SS SS () Sn Sn Sn Sn 27 28 O O O O O O O O OCH2C O OCHC O CH3 () () xy + 29 OHHOOCN-R-NCO OO O NH-R-NCO O NCO-R-HN HO-R-OH OO O N-