（16）烃类—蒸汽转化制氢装置年度汇编

1、355一、装置概况表1序号厂名(装置简称)加工能力2008年开工天数建设日期设计单位占地面积投资目前主要设备概况初建设计2008年止改造后2008年度产氢量负荷率投产改造初建设计改造设计初建改造投资塔加热炉冷换设备反应器机泵容器万吨/年万吨/年吨/年%天年 月年 月m2万元万元座座台台台台合计68.073.036976857.44263.6上市67.672.636831557.52260.6非上市0.40.4145340.36353.01燕山 ()1.51.51044868.34349.02001.05洛阳院567111976921041427 ()3.83.83152484.05356.02

2、007.06202901116443582天津 ()1.42.3未开工1999.042008.09北京院13500111441648 ()1.41.4864161.72252.01998.11北京院135001114516493石家庄1.01.0630463.04337.02002.042005.06北京院399010390102548264沧州 0.70.7208228.92285.02001.12北京院540014000425512375济南 1.51.5未开工2002.12北京院540014000221045336齐鲁 ()1.52.92152774.75349.01982.041999

3、.10齐鲁石化齐鲁石化830074001133384547 ()3.13.52879681.44351.01991.042005.03本单位华西所1080087003230627697胜石化0.50.7217833.15324.01996.072003.06兰州院洛阳院512025001508921055218金陵 ()1.82.31005844.70249.01986.092003.12洛阳院大连天邦.金陵院6300247010003225622259扬子 5.35.321820135.08328.31990.01西德鲁奇196201285613308155910 武汉 ()0.40.649

4、0976.61333.01997.011999.12兰化院北京院480020001129629611 荆门 2.83.41317838.87361.02002.092002.05北京院洛阳院1200120084375294212 长岭 1.41.4490334.32316.01989.101994.11北京院本单位120004570650733574819356续表1序号厂名(装置简称)加工能力2008年开工天数建设日期设计单位占地面积投资目前主要设备概况初建设计2008年止改造后2008年度产氢量负荷率投产改造初建设计改造设计初建改造投资塔加热炉冷换设备反应器机泵容器万吨/年万吨/年吨/年%

5、天年 月年 月m2万元万元座座台台台台13 高桥 ()1.451.45502734.67183.92002.05北京院11145221441633 ()2.92.9992634.23176.12004.10北京院1849711125109 ()1.91.9844944.47225.42008.04北京院12328200551215462914 上海石化3.13.12141668.64335.01984.012003.09德国鲁奇四川天一132361132 ()2.32.32061090.17311.02002.0811182162515 镇海 ()1.82.219208.8942.01993.

6、052001.08洛阳院洛阳院980052272000322162121 ()1.82.21233457.10341.01993.052001.08洛阳院洛阳院98005227200032206212216 广州 ()2.62.61949774.27326.22006.08东华工程公司11114121561010 ()4.94.94684496.09361.32006.11东华科技500007326815817 茂名 ()1.81.8未开工1982.10洛阳院67384000233262023 ()1.81.8未开工1982.11洛阳院67884500433472226 ()4.34.3294

7、5968.96366.01999.11洛阳院1050028140121315222618 杭州 0.40.4145340.36353.02003.06洛阳院27454000927571319 塔河 1.81.8506027.65366.02004.1111946820 西安 0.30.3未开工2004.08洛阳院924621 海南 4.54.51334229.65360.02006.08洛阳院1482025935151214204822 青岛炼化2.42.4806333.86235.02008.04宁波工程公司1127411841114357二、原料、成品、半成品理化性质1.原料理化性质（液体

8、）(1)表2-1序号厂名(装置简称)原料名称密度(20)馏程族组成总含硫量杂质含量HK10%30%50%70%90%KK烷烃环烷烃芳烃烯烃AsCl-kg/m3%ppmppmppm1天津 ()石脑油705.033651081441684.100.751812齐鲁 ()拔头油648.226324043516311899.600.300.101001 ()石脑油642.32834404551677899.300.700.001023扬子 轻石脑油639.3313640455259642.534荆门 轻石脑油695.0303545528010114552.7243.403.200.50205高桥 ()

9、轻石脑油710.03616363.8528.857.300.000.5 ()轻石脑油710.03616363.8528.857.300.000.56上海石化()轻石脑油640.0242840616691.806.861.350.001.0 ()LPG0.467广州 ()0.00 ()石脑油650.13012050.8643.126.020.0015.408茂名 ()轻石脑油0.009杭州 轻石脑油700.05016097.002.001.152010 海南 轻石脑油634.03133415052670.040.70303581.原料理化性质（气体）(2)表2-2序号厂名(装置简称)原料名称分子

10、量氢碳比H/C组成总SH2CH4C2H6大于C2COCO2O2烯烃%(v)%(v)%(v)%(v)%(v)%(v)%(v)%(v)%(v)1燕山 ()天然气164.000.0091.882.850.610.001.800.960.000.00 ()天然气173.980.0495.500.600.120.000.010.000.000.012天津 ()干气124.2047.6812.4315.270.000.000.000.003石家庄焦化干气223.3113.8044.6425.4011.320.000.000.005.280.004沧州 焦化干气+加氢干气287.9349.1710.8125

11、.548.985齐鲁 ()瓦斯气+天然气153.4029.0239.6710.0418.450.001.080.290.300.00 ()天然气+炼厂净化气193.7933.8345.444.1012.000.601.400.706胜石化混合干气203.3332.0015.0011.5023.000.720.770.909.500.027金陵 ()加氢干气124.7271.5010.401.9016.200.000.008扬子 天然气94.731.970.561.009武汉 ()催化干气27.3637.7712.264.321.231.0312.9316.880.0210 荆门 252.201

12、3.4043.5013.487.050.810.120.503.900.0211 长岭 焦化干气173.6724.9051.8017.543.3712 高桥 ()混合干气223.4238.1618.6014.5123.430.000.011.171.790.00 ()混合干气223.4238.1618.6014.5123.430.000.011.171.790.00 ()干气2028.8233.7617.8413.120.000.000.902.7413 上海石化()液化气570.8599.150.601.00 ()甲烷氢164.219.4990.030.50359续表2-2序号厂名(装置简称

13、)原料名称分子量氢碳比H/C组成总SH2CH4C2H6大于C2COCO2O2烯烃%(v)%(v)%(v)%(v)%(v)%(v)%(v)%(v)%(v)14 镇海 ()干气+天然气144.2753.6623.8310.1012.410.170.000.001.96 ()干气+天然气213.5130.0819.749.4940.690.000.000.000.040.0015 广州 ()加氢尾气+焦化、重催干气+中压瓦斯183.7132.8933.3312.436.090.000.000.117.700.09 ()加裂尾气1155.6735.724.863.750.000.000.000.000

14、.0016 茂名 ()加氢干气124.5760.2020.917.7911.100.010.020.250.0117 杭州 催化干气2142.0025.0012.000.0013.000.0018 塔河 天然气183.8288.283.910.100.480.000.0019 海南 重整氢PSA尾气70.0012.507.908.000.005.0020 青岛炼化天然气183.760.1094.202.880.270.001.210.460.880.003602.成品、半成品组成表2-3序号厂名(装置简称)成品、半成品名称组成氢气甲烷一氧化碳二氧化碳%(v)%(v)ppmppm1燕山 ()99

15、.900.000.500.20 ()氢气99.900.1020.001.002天津 ()氢气99.990.752.613石家庄99.990.004.500.404齐鲁 ()工业氢气97.002.808.206.50 ()产品氢气99.905.0011.0014.005胜石化工业氢99.900.0210.0020.006金陵 ()95.104.901.0039.007扬子氢气99.99 转化气79.014.197.908.90 高变气80.424.100.8614.628武汉 ()中变气74.763.530.9616.029荆门 工业氢97.803.200.000.0010 长岭 甲醇原料气75

16、.402.1010.7011.8011 高桥 ()99.900.1010.0010.00 ()99.900.1010.0010.00 ()99.990.003.165.8512 上海石化()氢气99.990.0156361续表2-3序号厂名(装置简称)成品、半成品名称组成氢气甲烷一氧化碳二氧化碳%(v)%(v)ppmppm ()氢气99.992.814.4513 镇海 ()96.583.421.0012.95 ()96.653.353.0010.8014 广州 ()99.920.011.125.21 ()95.624.383.121.0215 茂名 ()工业氢99.900.0085.1220.

17、5116 杭州 99.9917 海南 99.900.010.0015.6018 青岛炼化99.900.006.304.78362三、主要操作条件1、操作条件（1）表3-1序号厂名(装置简称)原料预热炉加氢反应器脱硫反应器转化反应器（炉）工业废热锅炉入出口油温度(入/出)炉管压降烟气温度入出口油温度(入/出)床层压降干气空速入出口油温度(入/出)床层压降干气空速出口气含H2S量入口温度出口温度入口压力床层压降总碳空速水碳比入口温度出口温度入口压力KPaKPah-1KPah-1ppmMPaKPah-1H2O/CMPa1燕山 ()75/38045170375/36510.0355/32020.00.

18、25068032.62180599.73.65 ()333/3288.01049328/32311.0482.00.55008052.60300708.03.908003302.302天津 ()247/360128158359/3496.01500349/3357.0330.00.34727702.78190420.03.897803402.603石家庄84/3042263110.01335/32830.014707601.7290465.03.658003501.714沧州 65/267213240/3121.85307/2822.040.00.54597632.1760300.05.335

19、齐鲁 ()60/355310350335/35020.0910345/34028.0460.00.54907601.80180780.05.007603451.80 ()220/320500400323/31546.0696315/301100.0343.004807802.90495.04.807703442.446胜石化240/3501.6300350/3002.8200.004907601.54160420.05.506803401.387金陵 ()20/28230282/357100357/32150.00.54477791.81192392.84.507793801.628扬子355

20、.4/349.5/4827442.514.52 352.7/347.9/4837252.444.219武汉 ()220/350300/3300.54757401.601205.0074035010 荆门 60/34050435320/35020.070332/27920.025.00.34707801.605050.05.207803301.5511 长岭 40/23540195235/37022.0145350/30526.063.80.35107151.26100315.03.907153301.2612 高桥 ()300/330320/3100.55107702.261403.80 ()

21、310/350340/3300.55307902.463003.70 ()293/3496.0360349/3355.0346.40.54997702.351534.107703292.113 上海石化355/357348/34414397872.81583.107803602.50363续表3-1序号厂名(装置简称)原料预热炉加氢反应器脱硫反应器转化反应器（炉）工业废热锅炉入出口油温度(入/出)炉管压降烟气温度入出口油温度(入/出)床层压降干气空速入出口油温度(入/出)床层压降干气空速出口气含H2S量入口温度出口温度入口压力床层压降总碳空速水碳比入口温度出口温度入口压力KPaKPah-1KP

22、ah-1ppmMPaKPah-1H2O/CMPa ()311/33917.211565287872.62124599.23.6414 镇海 ()36/36750390367/35520.0423355/32320.00119.4814827541.90140626.74.107543301.97 ()33/37060413370/36025.0431360/32920.00121.7814697371.90190622.24.017373221.9715 广州 ()282/38899.0375/3520.55058003.062403.918003442.82 ()70/380182380/3

23、78365/34520.120.54908003.11604.127983902.7516 茂名 ()335/354354/3440.55107352.78100287.04.5017 杭州 25/36013260/3300.5345/36005007252.45600.06.006683162.1618 塔河 316/30110.0665295/26940.00317.000.185477382.43374614.03.507383742.0619 海南 360/35510.0600355/34010.00600.000.55007202.1560300.05.507403422.1020

24、青岛炼化320/3603.0380320/3003.00150.0000.15007402.3080350.03.808003302.203642、操作条件（2）表3-2序号厂名(装置简称)生产蒸汽中变反应器低变反应器甲烷化反应器压力产量温度入口温度出口温度入口压力床层压降干气空速CO含量(入/出）入口温度出口温度入口压力床层压降干气空速CO含量(入口)入口温度出口温度床层热点温度入口压力床层压降入CO+CO2出CO+CO2干气空速MPat/hMPaKPah-1%MPaKPah-1%MPaKPa%ppmh-11燕山 ()3.8725.004103604082.3010.008.05/12.98

25、 ()3.5075.003903223702.2563.00151110.01/16.012天津 ()3.5035.004103513962.3056.002256.5/16.73石家庄3.6616.004453503921.716304沧州 3.009.182343383632.141.70755齐鲁 ()2.5048.002333453951.6065.0010151902001.499251.502852912931.450.0316.321490 ()3.3053.002403463812.322002508.8/0.96胜石化1.807.002303403801.3710015001

26、4/207金陵 ()3.7726.304273804191.5950.0017565.2/1.71861961.395017471.703033103101.21500.1+0.11+398扬子3523912.36 3583982.329武汉 ()1.903503901.6010 荆门 2.0020.002303303801.5520.003508.14/1.641801921.50203500.012703203451.30200.020.00372011 长岭 1.678.6020512 高桥 ()3.4029.003803603652.1212.0010/1.63904504502.33

27、43 ()3.4062.004083803802.1810/2.24004604602.62100 ()3.1045.002403293622.11502878.92/1.0913 上海石化3.5020.00320330390365续表3-2序号厂名(装置简称)生产蒸汽中变反应器低变反应器甲烷化反应器压力产量温度入口温度出口温度入口压力床层压降干气空速CO含量(入/出）入口温度出口温度入口压力床层压降干气空速CO含量(入口)入口温度出口温度床层热点温度入口压力床层压降入CO+CO2出CO+CO2干气空速MPat/hMPaKPah-1%MPaKPah-1%MPaKPa%ppmh-1 ()3.50

28、49.6040034338720.3312859.87/1.6814 镇海 ()3.8227.082543273721.6010.0012969.30/1.341912001.501011981.342802942971.25200.2428.203066 ()3.8725.222523143621.6010.0017228.39/1.461891951.501315911.462802922941.25200.2110.80220315 广州 ()6.9750.222903443822.8160.129.82/1.582022052.746.111.58 ()7.2850.652903904

29、292.75120.121952102.7110.22822983002.53100.302.3016 茂名 ()3.6275.004283433892.59100102310/1.42102192.565011301.4017 杭州 3353253352.1215018 塔河 3.617.304283734062.0460.0012808/0.9619 海南 3.5035.004103453802.1020.008009/1.120 青岛炼化3.6013.004003353752.2035.003001.53663、操作条件（3）表3-3序号厂名(装置简称)脱CO2塔再生塔总碱度K2CO3K

30、HCO3总钒入口温度出口温度入口压力压降出口气中CO2含量吸收能力富液入口温度塔顶出口温度塔底压力贫液转化率(相对)半贫液转化率(相对)富液半贫液贫液富液半贫液贫液富液半贫液贫液富液半贫液 贫液MPaKPa%CO2Nm3/m3MPa%1燕山 ()0.002齐鲁 ()95651.44180.0526.0098910.04 22.0041.012.9021.3013.197.070.693金陵 ()115621.26500.10109960.1125.2138.7121.1510.331.444荆门 106881.3200.017.0099940.15 95.0095.01251301.101.0

31、1.15镇海 ()111631.3300.0896890.0317.1236.2722.7421.9623.499.3214.3219.4019.45 11.085.923.163.15 () 108661.22350.0594890.0811.5343.2912.2622.3625.449.3312.6822.5119.35 14.034.250.596广州 ()71822.55 0.80.030.0615.1233.35195.18 220.16192.35 275.7894.68 48.326.157.08367 4、操作条件（4）表3-4序号厂名(装置简称)V+5三乙醇胺二乙醇三胺总铁

32、再生度泡沫高度消泡时间富液半贫液贫液富液半贫液贫液富液半贫液贫液富液半贫液贫液富液半贫液贫液富液半贫液贫液富液半贫液贫液消泡时间%ppmppmppm%cmcmcmsss1齐鲁 ()0.391.301.6041.051.501.801.601.902金陵 ()0.752.1436.707.803.003荆门 0.840.830.8417.0022.0024.001.351.104镇海 ()0.402.0938.255.583.428.453.612.164.39 ()0.362.1130.307.505.503.003.502.201.005广州 ()2.782.3520.3869.120.51

33、1.00368四、物料平衡表4序号厂名(装置简称)进料量百分率出料量产品产率原料水蒸汽配氢气合计原料水蒸汽配氢气合计工业氢二氧化碳或PSA废气排出凝水工业氢二氧化碳或PSA废气排出凝水吨/年吨/年吨/年吨/年%吨/年吨/年吨/年%合计100619144515603705.218.3781.260.07370388.63736299.22904791.236.7613.4453.03上市999588.9544105583328.218.4181.230.06368935.63726174.22868387.236.7913.3752.83非上市66024100237713.7685.450.79

34、1453.0010125.0036404.003.0321.1075.871燕山 ()3985711620333615639325.4874.300.22100.0010448.0028753.00117195.006.6818.3974.94 ()9037142320952994317.0579.863.09100.0031524.00258132.005.9548.712天津 ()22509100.008641.001156.003石家庄153986304.009043.0040.9458.730.004沧州 5270.9553324593.259188.158.990.091.00100

35、.002081.616167.004987.593.5210.428.435齐鲁 ()5978337777648043803913.6586.240.11100.0021527.0045100.00208000.004.9110.3047.48 ()7736348886471756694413.6486.230.13100.0028796.0025336.00296500.005.084.4752.306胜石化727954470756182411.7788.100.13100.002178.0028358.0031288.003.5245.8750.617金陵 ()18008116726013

36、473413.3786.630.00100.0010058.0048621.6076054.407.4736.0956.458扬子 7137450502161357700821820.0049772.003.788.639武汉 ()187614909.0013537.0010 荆门 209801448002016580012.6587.330.02100.0013178.0053688.0098934.007.9532.3859.6711 长岭 12744537611636666835.350.284903.0037376.307.350.0056.0612 高桥 ()143868617001

37、0055614.3185.690.00100.005027.0024662.0070455.005.0024.5370.07 ()28723150017017874016.0783.930.00100.009926.0049621.00118072.005.5527.7666.06369续表4序号厂名(装置简称)进料量百分率出料量产品产率原料水蒸汽配氢气合计原料水蒸汽配氢气合计工业氢二氧化碳或PSA废气排出凝水工业氢二氧化碳或PSA废气排出凝水吨/年吨/年吨/年吨/年%吨/年吨/年吨/年% ()2849816188219038014.9785.03100.008449.0038770.0014

38、2939.004.4420.3675.0813 上海石化()8319325021416.00 ()61824208400027022422.8877.120.00100.0020609.5919445.00119968.007.637.2044.4014 镇海 ()37381757402131229.8970.11100.001920.008455.3610936.569.0139.6751.32 ()23356143566.01016692213.9986.010.00100.0012334.0059346.22146519.477.3935.5587.7815 广州 ()592582316

39、991029096720.3779.630.00100.0019497.1752653.15218816.586.7018.1075.20 ()958793950211049091119.5380.470.00100.0046844.0047889.00396177.609.549.7680.7016 茂名 ()5523523816729340218.8381.17100.0029459.0022642.00128650.0010.047.7243.8517 杭州 6602410023774798113.7685.450.79100.001453.0010125.0036404.003.032

40、1.1075.8718 塔河 1650961548617811821.1378.790.08100.005680.9932690.1939746.737.2741.8550.8819 海南 43219248054029127314.8485.160.00100.0013342.2750181.68205610.004.5817.2370.5920 青岛炼化26073134306016037916.2583.750.00100.008063.0010287.00142029.005.036.4188.56370五、主要技术经济指标表5序号厂名(装置简称)轻油动力消耗能耗催化剂消耗现金操作费用单位

41、加工费含油污水含油排污合格率非计划停工馏出口合格率上报事故电蒸汽工业净水(新鲜水)循环水脱盐水燃料气总天数 总次数t/km3kw.h/km3t/km3t/km3t/km3t/km3kg/km3千克标油/千米3kg/km3元/吨元/吨mg/l%天次%次合计0.3856.70-0.170.0511.932.29126.14127.730.2715.999.9685699.791上市0.3856.86-0.170.0511.932.29126.64127.730.2716.699.9585699.781非上市21.0010.00125.000.000.01000010001燕山 ()11.99-0.

42、150.001.222.2882.190.01000095.780 ()59.08-0.630.004.28141.8198.900.000.11001110012天津 ()56.200.140.1834.320.00118.5065.0820.01000099.1803石家庄13.18-25.090.002.834.2586.0481.174.179.299.000099.9704沧州 192.1410.85111.35184.68100.010081410005齐鲁 ()0.0369.42-0.030.002.432.16171.56141.790.10001000 ()1.76100.001.520.0015.601.77105.50103.600.070010006胜石化2