有机化学试题库三——完成反应式题及解答(2023205448)

1、试题库三一一完成反响式题及解答(CH3)2C=CHCH3 HBr2.CH3OCH=CH2+ HBri3. CH3CH2CH=CH2 CH3CH2CH2CH2OH4. CH3CH=CH2 bhH6t5. (CH3)2C=CHCH2CH3O3 Zn粉，H2O6. CH2=CHCH2OH ClCH2CHCH2OHOH7. CH3CH2CH2C三CH+ HCl过量8. CH3CH2C三CH+HBr过量9. CH3CH2C三CCH3+ KMnO4 h + >10.CH3CH2C三 CCH3 + H2O H2S°4 .HgSO 411.CH2=CHCH= CH2 + CH2=CHCHO 八

2、十CH312.11+ HBr13.高温+ Cl2 "14._ + Cl2 15. CH2CH3QT + Br2CH(CH 3)216.QT + Cl2 高温 -17.| CH3 h2o 18.CH3CH=CH2 -3 . 2 H2O 19.ZKMnO 4 -CH=CH 220.| CH3 H2SO4 H2o + CH2Cl2 A©3 .CH3+ HNO 3FeSO3HOO +曲0 4 + C6H5CH2CICO9.40.41.CH2=CHCH 2Br + NaOC

3、 2H5CH=CHBr,CH2Br +AgNO3乙醇-室温| + Br2 KOH-乙醇厂CH2=CHCHO-ch2ciNaOH -H?O , CH3 ClOHH2OSn 2历程KOH-乙醇CH2=CHCH2ClCH2=CHCH2CN(CH3)3CCI + NaOH 2°(CH3)2CHCH2CH2OH + HBr -OH + HCI 无水ZnCI *匚OHIOCH31CH 2CH 2OCH3+ HI (过量)6.0+ Hl (过量)_CH

4、3(CH3)2CHBr + NaOC2H5CH3CH2CH2CH2CHCH 3OHKMnO4 OH_HI04CH3COOH + CH3CH2CHOhioVCH3COCH2CH2CH2CHOCH3OHCH3CH2CH2CHCH 2CH3 rOH浓 H2SO4分子内脱水CH3COCH2CH3 + H2N-OH C13CCH0 + H20 CH3CH2CHO+ KMnO 4 稀 NaOHC6H5COCH3 + C6H5MgBr H2Oh2nnhc 6h5(CH3)3CCHOH2NOH 浓 NaOH(CH3)2C(CH2OH)2无水HCI|-0 + Na2CrO7KMnO4 室温*Cl2, H20_O

5、H-CH2=CHCH2CH2COCH3+ HCl C6H5CHO + CH3COCH3 CH3COCHCO 2C2H5 稀+0H、CH3 H, H20CH3COCHCO 2CH3 浓 NaOH -CH2CO2CH3ch3ch2chcooh OHCO2CH3稀H+COCH 3CH3HO2CCH2COCCOOHCH3NaOH -H2OCH3CH2CHCOOH, 2 -Clch3chch 2coohOHNaOH-H2O5.H3CCH3CH3CH2CCOOH稀 H2SO4 OHch3ch2co

6、co 2HCH3CHCOCOIch3coOh稀 H2SO4 *2H COOHCOOHVi'、 NaOH,一汎宀O OH+, CH3CH2COOH + Cl 2P*Ba(OH) 2(CH 3)2CHOH + h3c_ COCl HOCH2CH2COOH 山耐件NCCH 2CH 2CN + H 2O Na°H.xChCOOH>ACH2COOHCH3COCI +(CH3CO)2O +CH3CH2COO C2H5Na0Et-CH3COOC2H5 + CH3CH2CH2OH CH3CH(COOH)28.99

7、.006.+ hoch2ch2oh2CH2COOC 2H5 NaOEtCH2CH2COOC 2H5(C2H5)3N + CH3CHBrCH3 (CH3)3NCH2CH2CH2CH3+C+ NaOH CH3CH2COCI + h3cnhch 3N(C2H5)2一 +hno2CH2CH2COOC2H5CH 2CH2COOC 2H5NaOC2H5 CH3CH2Br NaOH / H2O H+ / H2Och2ch2ch2cnOHH + / H2OH2O2OHCH3CH2CHO OH *NaBH农CHO + HS(CH 2)3SH NaBr / H2SO

8、4CH3CH2OH4 Mg /乙醚H2O +H CH3CHO我0 Na2Cr2O7. HOCH 2CH2OH25.OHC6H5CHO + CH3CH2CH2CHO H2S +1:1OKMnO 4"OHCH3COCH3 H2/Pd1 I Al2O3 ch3ch2ch2cho + h2nP + Br2(CH 3)2CHCH 2COOH JCh2oO2+ clHOOHNO3»O CH3H2SO4J O + HCN >CH2CHN

9、Me2 -CH2CH3CH3CH2CH2CHO + NaHSO3Na2CO3CH3hno3H2SO4 OCH3CHO + CH3CH2OH 无水 HCli(CH 3CH2)3NCH 2CH 2COCH 3OH_sNCOOHCOOH-coZn-HgHCl COOH I 丨 COOH 41.142.(CH3CH2CO)2OzoCH3(CH2)4CClH2NNHCONH 2C6H5COCH 3CICH2CH2NMe2OHCH2CH3#COOH SOCI2L 一aici3CHCOO

10、HHNaOHCHO3 c6h5hnnh 2 .CH2OHMgC6H5CH2C1 干醚 co2 H2OSOCI2-H3CNHCOCH 3+ HNO 3 HOACCOOHCH3(CH2)4COCINa OH(ch3)2Ch?hch3OH 乂 + N(CH3)3COOHS COCH 3HO&NH3CH2CIC 二OICH2CIHCNNaCN1H2OANH2+ ch3SO2CINaCH-143.144.145.COOHch2ch3右CF3dHNO3 h2so4 HNO 3*HNO3H 2SO4 146.OH+ (CH3CO)2O 147.OHch2cooh 148. CH2COOHCH2COO

11、H? ZHHg aAlCl 3? HClSOC»149.nh2NaNO2 + HClv 5CI OHOH150.HOCHOAg(NH 3)2 +OH151.COOHPCI5152.+phCH2CH-NMe2CH3O-153.ch2shCHSH + HgOCH2SH154.KMnO4155.OCHO+ H2NNHCNH2 H°Ac.156.CHO+ ch3cho稀OH157.|'| ° CH3Mg H3O+H 2SO4： B2H6 h2o26O3158.hno3CH3CH2CH2CH2SH HNO3O1HOAc159. CH3CH2CCH3 + O2N- .

12、 ANHNH2hcch2ch2chc hcnCH 3CH 3CH3CH-CHCH 3CH3C1FeKOH -乙醇H3O+-P2O5(CH 3CO) 2OO3CH2=CH-CH=CH 2 + CF3-CF=CF2180C*CH2=CH-CH=CH 2 + CH=CHCN CH3CH2=CH-CH=CH 2+ CH=CHCHO»+ ? + ?HCHO : HCI -Zn CI2CH 3CH2CH-CCH +ICH3CH3CH2OCHCH3 + HI(过量)CH3HNO3H2SO4H2OznZnCl260 C?亠葺Fe HgSO 4H2° H2SO4?+ HBrCH3CH3CH-

13、CH-C-CH 3 2HQ4.OH OH OHCH毛CH 2CH2CH2CH3 些？液氨*CH3CH2Br 戸 液氨NaCH3c毛h药氨Na 亠CH3c 53 + 也 k ?Na -HMg乙醚CH3C 三 CH-CH3I HPd / BaSq液氨93.194.195.H2CCHCH2CH3 H2° /°NaOH

14、Et°H+COCl 无水 AICl3OCH=CHBrCH2CIKCN，：丫 CH=CHBr NaOC2H5ClI 1 OCH2CH3+ HIOO+ L。OHICHHI80 CH2O3 _ Zn/H2O fHIO4一:=CH2B2H6 严H2O2/OH-99.200.201008.209.211.CH3CH=CHCH 2CH2CH2OH + KMnO4 Mg干醚BrClh2oHBrClBrMg干醚Mg干醚CH 3COOHCH2BrCH(CH3)2| l| + CH2=CHCH 3亘110120 C0.4MPaH2

15、O/ h+_8090 C c+ ?-+H3C ch 3AlCl 3CH(CH3)26H2OBr2CH(CH 3)2+ hno3H2SO4 CH 三CCH 2CH=CH 2 + Br2 (1mol)KMnO 4H+H2.H2/Ni yC80 CCH=CH 2 + Br2CCl4 MgCH 2HBrMg乙醚Cl2D2。KOH 一乙醇26.o + CH2=CH-COOEtL_l + Br2(CH 3)2C=CH 2 + HCl(CH 3)2C=CH 2 + HCl 过氧化物CH2

16、CH2CH3 NBS KMnO 4Me3COKKMnO4冷稀KMnO 4厂KMnO 4CH3竺H2O2"OH-"CH3+ CH3CH=CH 2 无水 AlCl 3 >KOH醇PhCH2CH2CH3-Cl2OCH3CHMe2+ CH2=CMe2 无水 AlCl 3 CH3HIOC2H5CH3CH2C 毛H HOBiCH3CH=CH 2 + HOCl227. |+ CH?=CHCN228.浓 H2SO4,060 C229.CH3CH2CMXH 2CH3 + H2Na液氨230. CH3CH2CH=CH2 + CI2 500C 231.CH3O3 Zn ,2O232.0NB

17、S233.NBSCH毛H234.+ HCN逬込235.127 cCH3CH2CH2CH3+ Br2236.237 CHgCHzCHzBr + ?OH-CH3CHCH3 OH醇Qh2o也亠 CH3CH2COOH238.ch3cho + ?乙醚CH3CH-CHCH 3Oh ch3239.NO2+ N3HCO3 H2°十3240.241.Mg干醚+ Na2CO3 H2O .Br B2H6 H2°2/OHH2SO4242.CH3CH-C-CH 2CH3CH3CH3243.H2OOH + B2CH3244.Cl2光 NaCN h3o+245.AlCl 3246.:_ : _ N6hn

18、o3H2SO4 “247.CH3Cl 1C Cl I1 11HBrCH 3-C-CH 2OH +CH3CH3248.CH3CH2-C-CH3H +OhI ' |- CH2CH2CH2CHCH3-Cl试题库二：完成反响式答案1. (CH3)2C-CH2CH3Br3 B2% H2O2 于 HBr H2O3. 或oh*5. (CH3)2C=O + CH3CH2CHO7. CH3CH2CH2CCI2CH39. CH3CH2COOH + CH3COOH2. CH3OCHCH3 Br4. CH3CH2CH2OH6. CI2+H2O8. CH3CH2CH2CBr2CH310.cH3CH2CCH2CH

19、3 + CH3CH2CH2CCH3oOCl12.14.OCH3Br13.15.CH2CH3Br16.C(CH 3)2Cl17. CH3-C-CH2CH2CH2CH2CHOO18. ch3CHO19COOH20.。0；3CH 3no223.SO3H22.so3h25.HOOC26. ? CH-CH 2 Cl Cl27. C6H5CH2MgClC6H5CH2C OOMgClC6H5CH2COOH28. CH2=CHCH 2OC2H5CH=CHBr29.CH2ONO230.CHOOH35.31.33.CH 2OHOHCH3HO34.36.37. (CH3)3C-OH39. )-ci41 I L CH

20、2CH2143. (CH3)2CH- O-C2H545 CH3CH2CH-CCH 3i aOH OCH3OHN OH卄49- CH2CCH2CH350. Cl3CCH(OH)2OMgBr53. C6H5-C-C6H5CH3OHfC6H5-C-C6H5CH355.( ln-oh(CH3)3CCH2OHH257.oCH3C CH3H2NaCN乙醇，38. (CH3)2CHCH2CH2Br6.ch2ch2ch2ch2chch3CH3CH2CH2CH2CCH3CH3OHOH48. CH3CH2CH=CHCH2CH351.HOOCCOOH52. CH3cH2-CH-CHCHOOH C

21、H354.NNHC 6H556. (CH3)3CCOOH +58. HOOCCH2CH2CH2COOH59.|-COOH60.61.02-CCH2CI62.64.63.C6H5CH(OH)CH2COCH30H 2C Cz65.0H2C c2 066.67.:>COCH 368.69.CH3CH2CHCOONa170OHCH371.CH2CHCH2COONa172.OH74.73.CH 3CH2CHO + CO2O C76.75.0C 077.CH3CHCOOH78.ClH3CCOO + chci3CH3CH(CI)CH 2CH2COCH3ch3cochcoohCH3h3ch2chc0O

22、CHCH 2CH3c 230CH 3ch3coch、CH3CH3CH二CHCOOHCH3CH3CH2C=O + HCOOHCH3CHCHO + CO2CH3CH2CH2COONaOH79.COOCHMe 281.NaOOCCH 2CH 2COONa HOOCCH 2CH 2COOH82.O84.OCOCH386.CH3COOCH2CH2CH3 + CH3CH2OH88.Cl:A COOH90.CH2OH92.OCOOEt94.(C2H5)3NCHMe2+Br-COOHCOOH80. HOCH2CH2CH2OHCH383.COCH 3O85. CH3CH2CCHCOOEtCH387.CH3CH2

23、COOH + CO289.91.93.COOCH 2CH2OOCOOCHCOO-+ nh395. (CH3)3NCH2CH2CH2CH3+Na+Cl +0HN(C 2H5)296. H3CNCCH2CH3CH3 O97.NOCOOC2H5 rO2 5099. CH2CH2COHcooc2h5OHNaC2H5OOC CH2CH3CH 2-CH 2HOOC CH2CH30014.116.120.CH2 c 0)CH2CH3100. CH3SCH3JIO101.H3CCOONah3CCH2OHCOOH102.COOHCH3CH2CH=CCHOJOH C

24、H 3 OHa CN a COOHCH3CH2CH=CCH2OHCH 3CHsCHzMgBr CH3CH2CHCH3HSCH2CH2OHCOOHCOOHCH=CH 2118.COOHCH3O NO2122. CH2=CHCOCH3124.BrCH3OHch3ch2ch2ch=n105.126.linhcoch2ch3128.C6H5C=NNHCONH2CH3COCICH3CH2CHCH3* O OCH2-CH2O107. C6H5CH=C-CHOCh 2ch3109.oh0 C ch3U 3 OH J 063111.113.(CH3)2CHCHCOOHBrCH3O2NO0HCNZOH117.

25、CH3CH2CH2CHSO3Na115.119.?爭一CH2NH2OCH3121.CH3CHOCH3123.C00HN125."COOH127.CH3(CH2)4NH2129.ClCH=CH2CHC 0II ：OCHCCH3CH2CH2CHO132.CH3H133.CONH2NH2134.CH 二 NNHph= NNHphCH2OH135. C6H5CH2MgCl C6H5CH2COOH C6H5CH2COCI136. H3C-Q-NHCOCH3NO2138.o2nCOCH 3137. (CH3)2CHC=CH 2139.O140. CH3(CH2)4CONH2 CH3(CH2)4N

26、H2141.ch2ciIHOC CNIch2cich2ciIHO C COOHIch2cich2cnIHO C COOHI ch2cnch2coohIHOC COOHIch2cooh142. CH3>SO2N CH3>SO2 NNa+143.CF3COOH144.145.OCOCH3146.NH2CH2C ICH2CNO2148.宀 L CCH2CH2COOH 0八 |-CH2CH2CH2COOHCtch2ch2ch2coci0COOH149.QrN2 ci-：yN=NOH150.HO严2 COCI151.CH2S.153. CHS HgCH2SH152.phCH2CH=CH2CO

27、OH155.OCH二NNHCNH154.156.N| CHCH2CHOOH/OH157.CH3I I CH3OCH3OHCH3O158. CH3CH2CH2CH2SO3Hno2COOHOOc 心C； O162.COOHCO'0163.CH3C=CHCHH3C3CH 3H3C165.CN167.H-C-H flHClIII 0161.C 0、JOOCOOHV'-COOHCHCH 3CH 3-C-CH 3IIO160.HNO 3H2SO4CH3CHO169.CH3CH2CH-C-CH 3111CH3O173.171.175.CH 3CHO + HCOOH+ CH3-C-CH 317

28、6.CO3；反-2-戊烯177.CH3CCNaCH3C 宅CHCH3CH2CH32CH3：c=c： 2 3HH179.CH3CH2CHOH CH 2OH; CH3CH2CHO+HCHO180.182.CH=CHCNCH2Cl184.OH+ ch3ch2iOHHOCH2CH2CH CNnh2CH3168.CH2Br172.174.CH3166.-OH00NHCOCH3CH3CNF164.FCF3FCH3nh2CNCH3no2CH2CI CH2CICH2Cl CH2OHCH 3CI 3CI 0170.ClCH3CH2I(CH3)2CHICH2MgBrCH3 CH3C CMgBrch2ohClCH-CH 2CH3BrCH 3CH 2C 三 CNa; CH3CH2C 三 C178.181.ch3hc=cHCH3COch=choc2h5CH3183.+ CH3I189.0OO192. CH3CH2CH3194. (CH3)2C - C-CH 3Br CH 3196