合成氨第4章 氨合成

1、3322221.50.51.50.5NHNHfpHNHNppKK Kpp lnffRTKG RTAyATCRTABPRTiiiiiii2055 . 03ln 0)1()1(2)1(5 . 145 . 125 . 0 rrrrr331.522(1)(1)NHpNHiyrKyyr 35233101008351. 7105646. 0 . 1371.221096147. 1/1 .358672543.233 .38313TTTPTTH 9 .1490298 H 132223123322HNHNHHNppkpppkr 5 . 125 . 1123322HNHNHHNppkpppkr 221HNppkr

2、 33333333333, 21, 2, 10, 1, 10, 2, 20, 11, 221)1)(1(11NHNHNHNHNHNHNHNHNHNHNHyynyyynyynyynynyna 产产氨氨速速率率)1(4 .2217)1(4 .2217)1)(1(4 .22173333333, 12,21,2, 10NHNHsNHNHsNHNHNHsyyVyyVyyyVG 图图 1.30图图 1.31TpyNH/5 .1099/906. 11856. 4lg*3 图图 1.34图图 1.37图图 1.38图图 1.40图图 1.393330,21iiNHiiNHiiNHiNNN yN yNy3301

3、,12,211NHNHNNyNy333333333333332,21,1,11,21,1,212,2,10,1,2111111NHNHNHNHNHNHNHNHNHNHNHNHNHNHnN yN yyNyN yyyyNNyyyNyy3NHn333333303,1,2/17 24/100017 24/100011NHNHNHNHNHngkmolm dVnTm dVNyTm dVyy3333303,1,222.4/17 24/22.4 100011ssNHNHNHNVNmm dVVygTm dyymimpipiV yV yGS33,2 22.4 100011726351mpNHppNHpVGGSVy

4、GGSVymVpVimipy yiS SG3,NHpy33,1263511NHpiipmimNHpipyGGSGSyVyyy33,1263511NHpiipmimNHpipySSyVyyymimipipV ySVy3,17122.4 1000pNHpV y331,1,12100%1NHNHinNyy 33333122111,1222212112,101)1NHNHttNHPNHtPNHHHHNyHnHHyHN CttytttHCy （）（）绝热温升为（332121,2()1NHtPNHytttHCy 也可处理为3333212,11,21,22,11()11)1NHtcPNHNHtcPNHytt

5、tHqCyyHqCy （,1,2ccq q33,1263511NHpiipmimNHpipySSyVyyymimipipV ySVy3,17122.4 1000pNHpV y4224CHArHNiCHAriiSSSSSSSSG CG HP4CHS223330.5675;3.963;1.4168ArHNSNmSNmSNm42233332.5801;0.5978;4.724;1.7829CHArHNSNm SNmSNm SNm33,1263511NHpiipmimNHpipySSyVyyymimipipV ySVy3,17122.4 1000pNHpV y3331,2311000000.17620.03811749.7/1 0.176211749.7 178.92 /22.4 1000NHNHNHynNy