传质系数的测定(共6页)

1、液液传质系数(xsh)的测定实验记录(jl)与处理表1 50醋酸(c sun)在水相和酯相中的平衡浓度(W%)酯相04.9610.8713.1316.6318.9722.0524.224.5水相05.378.6710.714.8719.7320.4924.0824.5表2 纯物系性质表物系水醋酸乙酸乙酯密度（kg/m3）997.11049901表3 50醋酸在水相和酯相中的平衡浓度水相(mol/L)00.9388551.5158051.8707166672.5997716673.4494623.5823354.2099874.283417酯相(mol/L)00.8671733331.90043

2、83332.2955616672.9074783333.3165883.8550754.2309674.283417计算范例：浓度c=p*w/MC单位mol/L M单位 g/mol P 单位g/L由图可知：平衡分配系数m=1.0366表4 水相处理(chl)数据实验序号时间/min样品质量/gNaOH的体积/mlCw(mol/L)Co*(mol/L) (mol/L)瓶重/g总重/g净重/g1510.32810.93150.603520.3304390.3425332108.1298.480.3511.50.4261110.4417073 0158.4828.9060.4242.60.61142

3、90.6338084209.1579.6960.5393.10.5734710.594465257.6948.21210.51813.30.6350960.658346309.98610.38130.39532.60.6558210.6798247 03510.70511.05620.351220.5678250.588607计算(j sun)范例：以5min为例 水的密度(md)p=997.1g/L水相溶质的物质的量 nw=v(NaOH)*0.1/1000=2*0.1/1000=0.0002mol 水相溶质的浓度Cw=Nw*p水/m总=0.0002*997.1/0.6035=0.330439

4、mol/L 与之平衡的酯相浓度Co*=m*Cw=1.0366*0.330439=0.34253mol/L表5 酯相处理数据序号时间/min样品质量/gNaOH的体积/ml酯相瓶重/g总重/g净重/gCo(mol/L)Cw*(mol/L)008.6519.70811.057119.21.6364771.5786971510.03910.5670.5288.81.5016671.4486462108.5939.14450.55158.31.3559931.30811631510.2310.540.314.81.3950971.3458394207.4177.9180.5016.51.1689621

5、.1276895258.9489.60710.65918.91.216644196511.4550.496.41.1768161.1352667358.1958.73560.54066.51.0833331.045083计算范例：以5min为例乙酸乙酯的密度p=901kg/m3=901g/L酯相溶质的物质的量nw=v(NaOH)*0.1/1000=0.00088mol酯相溶质的浓度Co=nw*p/m总=0.00088*901/0.528=1.5016647mol/L与之平衡的水相浓度Cw*=Co/m=1.5016647/1.0366=1.578697mol/L表6 酯

6、相与(xingy)水相浓度关于时间的关系表时间/minCo(mol/L)Cw(mol/L)01.636477051.5016670.330439101.3559930.426111151.3950970.611429201.1689620.573471251.2166440.635096301.1768160.655821351.0833330.567825表6 水相处理(chl)数据水相体积(tj)Vw=400mL=0.0004m3 接触(jich)面积A=6*3.8cm3=0.00228m3酯相体积Vo=400mL=0.0004m3 序号时间/min样品净重/gNaOH的体积/mlCw(m

7、ol/L)Cw*(mol/L)Cw*-Cw(ln)Kw(m/min)0001.578696851.57869700150.603520.3304391051.4486462151.118207-0.344870.0121012100.3513.20.4261111111.3081157120.882005-0.582160.0102133150.4243.20.6114292451.3458390640.73441-0.765290.0089514200.5393.10.5734712431.1276886710.554217-1.04680.0091825250.51813.30.63509

8、55411.1736869650.538591-1.07540.0075476300.39532.60.6558208961.1352656050.479445-1.191730.0069697350.35122.50.5678246011.0450832850.477259-1.19630.005996计算范例：以5min为例lnCw*t-Cw(t)Cw*0-Cw(0）=ln1.448646215-0.3304391051.57869685-0=-0.34487Kw=-VwAt lnCw*t-Cw(t)Cw*0-Cw(0）=-0.00040.00228*5*(-0.34487) = 0.01

9、2101m/min表7 酯相处理(chl)数据(shj)序号时间/min样品净重/gNaOH的体积/mlCo(mol/L)Co*(mol/L)Co*-Co(mol/L)(ln)Ko(m/min)001.057119.21.6364771540-1.6364800150.5288.81.5016666670.342533176-1.15913-0.344870.0121008112100.55158.31.3559927470.441706778-0.91429-0.582160.0102132943150.314.81.3950967740.633807556-0.76129-0.765290.0089507344200.5016.51.1689620760.594460291-0.5745-1.04680.0091824385250.65918.91.2166439080.658340038-0.5583-1.07540.0075466516300.496.41.1768163270.67982394-0.49699-1.191730.006969167350.54066.51.0833333330.588606982-0.49473-1.19630.005996473计算(j sun)范例