人造金刚石方法总结

ManMadeDiamonds

人造金刚石NO.32梁剑文张晶晶陈桂焕王黎丽王文亮樊龙1、Man-madediamonds.(HTHP)Drs.F.P.Bundyetal.Nature

1955

178,51-572、Diamondsindetonationsoot.(爆炸法)N.RoyGreineretal.Nature1988,333,440-4423、Epitaxialsynthesisofdiamondinthemetastableregion.(CVD)B.V.Deryagin,etal.,RussianChemicalReviews,19704、Hydrothermalgrowthofdiamondinmetal-C-H2Osystems.（水热法）Xing-ZhongZhao,etal.Nature1997,385,612341、高温高压法2、爆炸法VadymN.Mochalin,etal.NatureNanotechnology

2011.PUBLISHEDONLINE:18DECEMBER2011 | DOI:10.1038黑金刚石Whyitwouldbethat?

3、CVDH*0.5H2

△(G1)TP=-112.72KJC(gra)C(dia)

△(G1)TP=6.96KJT激活

=2400K，T=1200K，P=10KPaPaulW.May,Phil.Trans.R.Soc.Lond.A

2000,358,473-495王季陶，现代热力学及热力学学科全貌（M),2005，123-130HotFilamentCVDMicrowavePlasma-AssistedCVDPlasmaTorchCVD(LaserAssisted)CombustionCVDHGCTRhigh-qualitydiamondcrystalsweregrownonsiliconsubstrateswithahighgrowthrateat∼139μm/h.ZhiqiangXie,etal.Crystal.Growth&Design.2010,10,1762–1766.RussellJ.Hemleyetal.USPatent,NO.007883684B22011.JimmyXuetal.,NanoLett.

2010,10,3272-–3276△P=2γ/r4、水热法Xing-ZhongZhao,etal.Nature

1997,385,6耐高压钢管H2O<0.25umDiamondSeedsMetal&CYadongLi,etal.Nature1998,282,246-248QianwangChenetal.,J.AM.CHEM.SOC.2003,125,9302-93032%的产率确实的温度？确实的压力？可重复性1、Drs.F.P.Bundyetal.Nature

1955

178,51-572、N.RoyGreineretal.Nature1988,333,440-4423、B.V.Deryagin,etal.,RussianChemicalReviews,19704、Xing-ZhongZhao,etal.Nature1997,385,65、VadymN.Mochalin,etal.NatureNanotechnology2011.DOI:10.10386、PaulW.May,Phil.Trans.R.Soc.Lond.A

2000,358,473-4957、王季陶,现代热力学及热力学学科全貌(M),2005,123-1308、ZhiqiangXie,etal.Crystal.Growth&Design.2010,10,1762–17669、RussellJ.Hemleyetal.USPatent,NO.007883684B22011.10、JimmyXuetal.,NanoLett.

2010,10,3272—327611、Xing-ZhongZhao,etal.Nature

1997,385,612、YadongLi,etal.Nature1998,282,246-248