江苏省泄漏检测与修复(LDAR)实施技术的指南

1省泄漏检测与修复（）实施技术指南号），1

适围用输点无项目2

规引文3

术和义油油产发VOCs）线10Pa101.3kPa）260℃/

3.4有OHAPs响和。液0.3VOCs组20%的液VOCs物料封体漏口阀道备漏控制浓泄漏泄/

LDAR。校参％响VOCs浓的恢复VOCs读的所需难/险面以外2致检净mol/mol（ppmv）。环mol/mol（ppmv）。4LDAR项建检图（PID析产品VOCs)的含于重量96.3kPa，/

备）录同一操作ZL-0227。PIDID漏测展LDAR的VOCs定量检OHAPs组2.5前测得的在(。/

4.3.2含μmol/mol2％4.3.3/蒸一/蒸一次4.3.4检或大5点1所示25数低于3装置边界检测位置1环境本底/

10cm/s2倍仪现设备表冒滴漏表列；/影表1：(单位，以)

漏4.4.1有检后5业4.4.2/

4.4.3日）漏密VOCs排放量大于6月测4.5.1用前浓4.5.2-校/10%施LDAR项5目量证控管管LDAR质量体5.2数/

数据2年：、所表3。、设、设。、不。、所、企图无、企施前泄施LDAR后泄漏VOCs与、所、采6LDAR项目申2、、表6，环境月10/

表A：VOCs和OHAPsCAS号

英文名

化学品

沸点（℃

蒸气压（20℃下，Pa

VOCsOHAPs1,1,1-trichloroethan71-55-61,1,1-三氯乙烷74.013055.56√√e1,1,2-trichloroethan79-00-51,1,2-三氯乙烷113.72351.98√√e1,2,3-Trichlorobenze87-61-61,2,3-三氯苯218-21932.63√√ne1,2-dichloroethane107-06-21,2-二氯乙烷83.48219.95√√(EDC)122-66-7106-99-0123-91-1540-84-179-46-983-32-975-07-060-35-575-05-898-86-2107-02-879-06-179-10-7107-13-1107-05-162-53-371-43-298-07-7100-44-792-52-4542-88-175-25-275-15-056-23-579-11-8

1,2-Diphenylhydrazine1,3-Butadiene1,4-Diethyleneoxide2,2,4-Trimethylpentane2-NitropropaneAcenaphtheneAcetaldehydeAcetamideAcetonitrileAcetophenoneAcroleinAcrylamideAcrylicacidAcrylonitrileAllylchlorideAnilineBenzeneBenzotrichlorideBenzylchlorideBiphenylBis(chloromethy1)etherBromoformCarbondisulfideCarbontetrachlorideChloroaceticacid

1,2-二苯肼1,3-丁二烯1,4二恶烷2,2,4-三甲基戊烷2-硝基丙烷苊乙醛乙酰胺乙腈苯乙酮丙烯醛丙烯酰胺丙烯酸丙烯腈3-氯丙烯苯胺苯三氯化苄苄基氯联苯双氯甲醚三溴甲烷二硫化碳四氯化碳一氯乙酸

229-4.5131.799.238119-122231.220.4221.1581.6201.753231.7116.477.341.6184.380.1219-223179.4255.2182.414946.276.5189

4.54E-02238833.783905.945107.681732.221.2099156.724.049568.5335.9229485.540.166372.0811447.1140226.0142.749945.2343.76123.101.692951.24538.2439237.8712057.8018.58

√√√√√√√√√√√√√√√√√√√√√√√√√

√√√√√√√√√√√√√√√√√√√√√√√√/

108-90-767-66-3126-99-8

ChlorobenzeneChloroformChloroprene

氯苯三氯甲烷2-氯1,3-二烯

131.761.159.1

1197.9019416.3423499.98

√√√

√√√Cresolandcresylic108-39-4间甲酚202.214.22√√acid(m-)106-44-598-82-877-78-1

Cresolandcresylicacid(p)CumeneDimethylsulfate

对-酚异丙基苯硫酸二甲酯

201.9152.392188

8.25436.1261.77

√√√

√√√Epichlorohydrin106-89-8(l-Chloro-2,3-epoxypropane)

环氧氯丙烷116.11655.43√√140-88-5100-41-475-00-3106-93-4107-21-175-21-875-34-3

EthylacrylateEthylbenzeneEthylchlorideEthylenedibromideEthyleneglycolEthyleneoxideEthylidenedichloride(1.l-Dichloroethane)

丙烯酸乙酯乙苯氯乙烷1,2-二溴乙烷乙二醇环氧乙烷亚乙基二氯(1,1-氯乙烷)

100136.18612.2130.2197.210.3183.70

3909.83950.87133708.041346.057.57145672.5724288.18

√√√√√√√

√√√√√√√50-00-087-68-367-72-1110-54-378-59-1108-31-667-56-1

FormaldehydeHexachlorobutadieneHexachloroethaneHexanelsophoroneMaleicanhydrideMethanol

甲醛六氯丁二烯六氯乙烷正己烷异佛尔酮马来酸酐甲醇

-19.5231185.6121.24215.2119.364.6

440037.9919.6161.9416214.8840.8833.6412758.04

√√√√√√√

√√√√√√√78-93-3

Methylethylketone

甲乙酮(丁酮)202

9970.24

√

√(2-Butanone)108-10-1Methylisobutylketone(Hexone)

甲基异丁基酮94.21966.95√√624-83-9

Methylisocyanate

基异氰酸盐3549747.50

√

√80-62-61634-04-4

MethylmethacrylateMethyltert-butyl

甲基丙烯酸甲酯100.3甲基叔丁基醚55.2

3915.4426768.56

√√

√√ether74-83-9Methylbromide(Bromomethane)74-87-3Methylchloride(Chloromethane)

溴甲烷3.5183474.29√√氯甲烷-24.3492691.51√√/

75-09-2Methylenechloride(Dichloromethane)

二氯甲烷39.846735.69√√121-69-7

N,N-dimethylaniline

N,N-二甲基苯胺193.5

66.20

√

√68-12-2

N,N-dimethylformamid

N,N-二甲基甲酰

153

372.03

√

√e

胺98-95-395-48-7

Nitrobenzeneo-Cresoland

硝基苯邻甲酚

210.6191

22.1725.87

√√

√√cresylicacid95-47-6106-46-7127-18-4

o-xylenep-DichlorobenzenePerchloroethylene

邻二甲苯对-氯苯四氯乙烯

144.411174.1121.1

647.14166.401870.84

√√√

√√√108-95-275-44-5106-50-3

PhenolPhosgenep-Phenylenediamine

苯酚氯代甲酰氯对苯二胺

181.88.2267.4

47.45158376.420.34

√√√

√√√57-57-8

Propiolactone(beta-)丙酯

162

158.43

√

√123-38-6

Propionaldehyde

丙醛

47.93

34003.01

√

√78-87-5

Propylenedichloride1,2-二氯丙烷

96.3

16723.19

√

√75-56-9106-42-3100-42-579-34-5

Propyleneoxidep-xylenesStyreneTetrachloroethanes

环氧丙烷对二甲苯苯乙烯1,1,2,2-四氯乙

34.3138.351145.14146.20

58030.90874.56592.25436.03

√√√√

√√√√烷108-88-379-01-6121-44-8108-05-475-01-476-13-1

TolueneTrichloroethyleneTriethylamineVinylacetateVinylchloride1,1,2-Trichlorotrifl

甲苯三氯乙烯三乙胺醋酸乙烯酯氯乙烯氟利昂-113

110.62587.289.573-13.447.5

2887.937688.747125.3111932.88339701.7635856.15

√√√√√√

√√√√√uoroethane96-18-41,2,3-trichloropropane120-82-11,2,4-Trichlorobenzene108-70-31,3,5-Trichlorobenzene

1,2,3-三氯丙烷156.8355.31√1,2,4-三氯苯211.440.43√1,3,5-三氯苯211.349.92√107-88-0106-98-9109-67-1104-76-7

1,3-butyleneglycol1-butene1-pentene2-ethylhexanol

1,3-丁二醇正丁烯1-戊烯2-乙基己醇

207-6.2629.968184.6

1.53255858.4870783.2910.54

√√√√/

2807-30-92-propoxy-ethano105-57-7Acetal

乙二醇单丙醚1,1-二乙氧基乙

258.2103.6

294.592732.41

√√烷64-19-7108-24-767-64-175-86-575-36-574-86-2107-18-698-83-9111-41-1

AceticacidAceticanhydrideAcetoneAcetonecyanohydrinAcetylchlorideAcetyleneAllylalcohola-methylstyreneAminoethylethanolami

乙酸乙酸酐丙酮丙酮氰醇乙酰氯乙炔丙烯醇α-甲基苯乙烯羟乙基乙二胺

117.913956.2167.351-84.054.3165-169215.98

1559.41330.4224390.56104.7730793.484328141.932537.19252.440.11

√√√√√√√√√ne628-63-7110-58-7543-59-9100-66-3100-52-765-85-0100-47-0100-51-698-87-3100-46-9108-99-6107-92-6106-31-0109-74-0105-60-2558-13-475-45-675-72-9

amylacetateAmylamineAmylchlorideAnisoleBenzaldehydeBenzoicacidBenzonitrileBenzylalcoholBenzyldichlorideBenzylamineb-picolineButyricacidButyricanhydrideButyronitrileCaprolactamCarbontetrabromideChlorodifluoroethaneChlorotrifluorometha

乙酸戊酯1-氨基戊烷1-氯戊烷苯甲醚苯甲醛苯甲酸苯甲腈苯甲醇二氯苄苄胺3-甲基吡啶丁酸丁酸酐丁腈己酰胺四溴化碳一氯二氟甲烷氯三氟甲烷

149.2105.5107-108153.6178.7250191204.699214185143.5163.27198.3118180181.2-40.826.8

330.723018.553356.58344.88110.263.58E-0171.426.6648.2259.32587.6784.9824.271959.200.5085.65893928.813178608.49

√√√√√√√√√√√√√√√√√√ne80-15-9Cumenehydroperoxide

过氧化羟基异丙苯

253.73.49E-01√506-77-4110-82-7108-93-0108-94-1110-83-8108-91-8

CyanogenchlorideCyclohexaneCyclohexanolCyclohexanoneCyclohexeneCyclohexylamine

氯化氰环己烷环己醇环己酮环己烯环己胺

13.880.738159.6155.682.979134.5

134561.5510367.1965.46345.049295.60990.80

√√√√√√/

111-78-4112-30-1123-42-275-71-8

CyclooctadieneDecanolDiacetonealcoholDichlorodifluorometh

1,5-环辛二烯1-癸醇甲基戊酮醇氟里昂-

125230168.1-29.8

479.236.22E-01162.33560905.07

√√√√ane101-83-7111-46-6

DicyclohexylamineDiethyleneglycol

二环己胺二甘醇

256.1246

2.824.39E-01

√√112-36-7

Diethyleneglycol

二乙二醇二乙醚190.2

47.30

√diethylether111-96-6

Diethyleneglycol

二乙二醇二甲醚159.8

281.95

√dimethylether112-15-2

Diethyleneglycol

乙二醇一甲醚221.8

13.14

√monoethylether112-15-2Diethyleneglycolmonoethylether

乙二醇一甲醚162.713.14√111-77-3

Diethyleneglycol

二乙二醇单甲醚226.927

14.84

√monomethyl75-37-6674-82-875-18-367-68-5101-84-825265-71-

DifluoroethaneDiketeneDimethylsulfideDimethylsulfoxideDiphenyloxideDipropyleneglycol

1,1-二氟乙烷二乙烯酮二甲基硫二甲基亚砜二苯醚一缩二丙二醇

-25106.638189.0258230.5

563101.621055.4653488.0956.543.752.72

√√√√√√864-17-560-29-7141-78-6141-97-974-96-475-04-7105-56-674-85-1

EthanolEtherEthylacetateEthylacetoacetateEthylbromideEthylamineEthylcyanoacetateEthylene

乙醇乙醚乙酸乙酯乙酰乙酸乙酯溴乙烷乙胺氰乙酸乙酯乙烯

78.334.4873.9236.338.316.5206.0-103.71

5830.290.589632.1771.8751046.70114501.225.056261415.60

√√√√√√√√107-07-3

Ethylenechlorohydrin2-氯乙醇

128.6

692.93

√111-55-7

Ethyleneglycol

乙二醇二乙酸酯168

5.68

√diacetate110-71-4Ethyleneglycoldimethylether

乙二醇二甲醚637916.43√111-15-9Ethyleneglycolmonethylether111-76-2Ethyleneglycolmonobutylether

乙二醇乙醚醋酸酯乙二醇单丁醚

156.4217.71√151.57977.60√/

110-80-5Ethyleneglycolmonoethylether109-86-4Ethyleneglycolmonomethylether

乙二醇单乙醚221499.68√乙二醇甲醚124.6853.24√107-15-375-12-764-18-698-01-156-81-5

EthylenediamineFormamideFormicacidFurfuralGlycerol

乙二胺甲酰胺甲酸糠醛甘油

117.2210.5100.6161.898.3

1162.754.954402.66208.581.17E-02

√√√√√629-11-8124-09-4

Hexamethyleneglycol1,6-己二醇Hexamethylenediamine1,6-己二胺

239.7226.4

7.01E-0210.00

√√74-90-8123-92-278-83-1110-19-0115-11-778-84-279-31-225339-17-

HydrogencyanideIsoamylacetateIsobutanolIsobutylacetateIsobutyleneIsobutyraldehydeIsobutyricacidIsodecanol

氰化氢乙酸异戊酯异丁醇乙酸异丁酯异丁烯异丁醛异丁酸异癸醇

25.7142.0107.8116.8-6.967.1154.7213.4

81251.18510.23947.811766.52262095.5818299.20167.341.62

√√√√√√√√778-78-478-79-567-63-0108-21-475-29-675-31-0463-51-4108-42-9108-41-8541-73-1141-79-7

IsopentaneIsopreneIsopropanolIsopropylacetateIsopropylchlorideIsopropylamineKetenem-chloroanilinem-chlorotoluenem-dichlorobenzeneMesityloxide

2-甲基丁烷异戊二烯异丙醇乙酸异丙酯2-氯丙烷异丙胺乙烯酮3-氯苯胺3-氯甲苯1,3-二氯苯4-甲基-烯

303482.288.235-3648.6-56227.8161.6173132.7

76218.3360574.734409.226199.0858495.5762683.391214927.625.58307.50206.041085.48

√√√√√√√√√√√-2-酮79-41-4563-47-3

MethacrylicacidMethallylchloride

甲基丙烯酸3-氯-甲基丙

162~16372.5

87.8111237.64

√√烯79-20-9105-45-3107-31-3108-11-2

MethylacetateMethylacetoacetateMethylformateMethylisobutyl

醋酸甲酯乙酰乙酸甲酯甲酸甲酯4-甲基-戊醇

56.9169.431.7133.5

22648.4680.7363434.35489.07

√√√√carbinol/

74-89-5108-87-213952-84-

MethylamineMethylcyclohexaneMethylpropylamine

甲胺甲基环己烷仲丁胺

-6.4100.93462.9

294402.284753.2318839.90

√√√6110-91-8115-10-671-41-0123-86-4141-32-271-36-3109-73-9123-72-875-98-979-24-375-52-5100-61-8109-66-071-23-895-51-288-73-395-49-895-50-1123-63-7106-47-8100-00-5106-43-4110-85-0156-43-479-09-4540-54-5107-10-8115-07-157-55-6110-86-169-72-778-92-2110-15-675-65-075-64-9

MorpholineN,N-dimethylethern-Amylalcoholn-butylacetaten-butylacrylaten-butylalcoholn-butylaminen-butyraldehydeNeopentanoicacidNitroethaneNitromethanen-methylanilinen-pentanen-propylalcoholo-chloroanilineo-chloronitrobenzeneo-chlorotolueneo-dichlorobenzeneParaldehydep-chloroanilinep-chloronitrobenzenep-chlorotoluenePiperazinep-phenetidinePropionicacidPropylchloridePropylaminePropylenePropyleneglycolPyridineSalicylicacids-butylalcoholSuccinicacidt-butylalcoholt-butylamine

吗啡啉甲醚1-戊醇乙酸丁酯丙烯酸丁酯正丁醇正丁胺丁醛特戊酸硝基乙烷硝基甲烷N-甲基苯胺正戊烷正丙醇邻氯苯胺邻氯硝基苯邻氯甲苯1,2-二氯苯三聚乙醛对氯苯胺对硝基氯苯对氯甲苯哌嗪对氨基苯乙醚丙酸1-氯丙烷丙胺丙烯1,2-丙二醇吡啶水酸仲丁醇丁二酸叔丁醇叔丁胺

128.9-24.9137.8126.6221.938117.777.477.6166.209109.2100-102200.430.07497.2208.8245.5159.5180.4233.9208.8242162.2149.324254140.8346.648.6-47.7187.3115-11621199.5236.182.444.4

986.87507144.60218.511022.21530.83648.969456.6311626.2652.742081.653640.1341.0656259.461973.2117.671.81339.36127.321072.526.352.33264.38330.138.49E-01347.9837183.8232792.571015268.1910.592080.711.01E-011719.785.14E-043977.9140154.76

√√√√√√√√√√√√√√√√√√√√√√√√√√√√√√√√√√√/

119-64-2Tetrahydronaphthalene

1,2,3,4-四氢萘210.333.25√584-84-9Toluene-2,4-diisocyanate75-69-4Trichlorofluoromethane

甲苯-，4-二异氰酸酯三氯氟甲烷

115-1201.08√26.888844.64√112-49-2Triethyleneglycoldimethylether

三乙二醇二乙醚197.23.28√75-50-375-35-4

TrimethylamineVinylidenechloride

三甲胺过氯乙烯

2.931.6

182229.2165938.58

√√86-57-7

1-Nitronaphthalene

1-硝基萘

—

—

√95-95-4

2,4.5-Trichloropheno

2,4,5-三氯苯酚—

—

√l95-80-781-16-3

2,4-Toluenediamine2,l-Naphthylamine

2,4-甲二胺2-萘胺-磺酸

——

——

√√sulfonicacid532-27-4

2-Chloroacetophenone2-氯苯乙酮

—

—

√101-77-9

4.4'-Methylenedianil

4,4'-亚基二

—

—

√ine

苯胺100-02-7

4-Nitrophenol

4-硝基苯酚

——

√72-48-0

Alizarin

1,2-二羟基蒽醌—

—

√120-12-784-65-127497-51-

AnthraceneAnthraquinoneBromonaphthalene

蒽蒽醌溴萘

———

———

√√√4218-01-9

Chrysene

1,2-苯并菲——

√91-94-1

Dichlorobenzidine

3,3-对二氯联苯—

—

√(33-)111-44-4

Dichloroethylether

氯甲醚((2-—

—

√(Bis(2chloroethyl)ether)

氯乙基))26952-23-

Dichloropropene

二氯丙烯

—

—

√8111-42-2

Diethanolamine

乙醇胺

—

—

√(2,2)64-67-5

Diethylsulfate

硫酸二乙酯

—

—

√131-11-3

Dimethylphthalate

苯二甲酸二甲酯—

—

√119-93-7

Dimethylbenzidine

3,3'-二基联

—

—

√(3.3-)

苯胺57-14-7

Dimethylhydrazine

1,1-二甲基肼

—

—

√51-28-5

Dinitrophenol

2,4-二硝基苯酚—

—

√/

25321-14-6

Dinitrotoluene

二硝基甲苯混)——√206-44-0118-74-1123-31-960-34-4101-68-8

FluorantheneGlycolethersHexachlorobenzeneHydroquinoneMethylhydrazineMethylenediphenyl

荧蒽乙二醇醚系列六氯苯对苯二酚甲基联胺苯基甲烷二异氰

——————

——————

√√√√√√diisocyanate(4,4'-)(MDI)

酸酯120-18-3

Naphthalenesulfonic

β-萘磺酸

—

—

√acid(p)85-47-2

Naphthalenesulfonic

α-萘磺酸

—

—

√acid(a)90-15-3135-19-3

Naphthol(a)Naphthol(p)

α-萘酚β-萘酚

——

——

√√567-18-0

Naphtholsulfonicacid1-萘酚磺酸

—

—

√(1-)134-32-791-59-884-86-6

Naphthylamine(1-)1-萘胺Naphthylamine(2-)2-萘胺Naphthylamine4-萘胺磺酸

———

———

√√√sulfonicacid(1,4-)90-04-0

O-Anisidine

邻-氧苯胺

—

—

√31055.00Phenanthrene

菲

—

—

√85-44-9129-00-0106-51-4

PhthalicanhydridePyreneQuinone

苯酐芘对苯醌

———

———

√√√或CAS录B：1施定了编/

（1M01；（2（301F（4；V；S；OEL；C-（5(质液质液)；（6(0：否)。/

：实施LDAR挥、层

pmv数量v数量

（kg/hr/source）

（d/

、层设备元件

流体种类

排放因子（kg/hr/source）石化(化工)类筛选值围ppmv）0-10001001-9999≥10000

炼油类筛选值围(ppmv)0-10001001-9999≥10000液体0.00014

0.001650.0451

0.00010.0048