【《锌离子电池性能探析国内外文献综述》7600字】

锌离子电池性能研究国内外文献综述目录TOC\o"1-3"\h\u31082锌离子电池性能研究国内外文献综述 1205081绪论 1316161.1研究背景 1198671.2水系锌离子电池的工作原理 2292901.3锌负极材料存在的问题及改性方法 2109541.3.1锌负极材料存在的问题 2257741.3.2锌负极材料的改性方法 418347参考文献 121绪论1.1研究背景随着能源的需求不断增加和化石燃料的逐渐枯竭，能源储存问题已成为一个严重的社会问题。因此，我们迫切需要做出改变并找到创新性的解决方案。在过去的十年中，许多国家出台了法律和政策，鼓励开发和利用太阳能、风能、地热能和水力发电等绿色能源，以摆脱对化石燃料的依赖。同时，包括电池和电容器在内的储能系统得到了迅速发展和普及。锂离子电池由于其较高的能量密度、较长的使用寿命、强适应性、高可靠性和高效率的特点[ADDINCSL_CITATION{"citationItems":[{"id":"ITEM-1","itemData":{"DOI":"10.1016/j.partic.2020.12.003","ISSN":"22104291","abstract":"Lithiumionbatterieshaveachievedextensiveapplicationsinportableelectronicsandrecentlyinelectronicvehiclessinceitscommercializationin1990s.Thevastapplicationsoflithiumionbatteriesarenotonlyderivedfromtheinnovationinelectrochemistrybasedonemergingenergymaterialsandchemicalengineeringscience,butalsothetechnologicaladvancesinthepowdertechnologiesforelectrodeprocessingandcellfabrication.Revealingtheeffectsofpowdertechnologyonelectrodemicrostructureevolutionduringelectrodeprocessingiswithcriticalvaluetorealizethesuperiorelectrochemicalperformance.Thisreviewpresentstheprogressinunderstandingthebasicprinciplesofthematerialsprocessingtechnologiesforelectrodesinlithiumionbatteries.Theimpactsofslurrymixingandcoating,electrodedrying,andcalenderingontheelectrodecharacteristicsandelectrochemicalperformancearecomprehensivelyanalyzed.Conclusionandoutlookaredrawntoshedfreshlightsonthefurtherdevelopmentofefficientlithiumionbatteriesbyadvancingpowdertechnologiesandrelatedadvancedenergymaterials.","author":[{"dropping-particle":"","family":"Liu","given":"He","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Cheng","given":"Xinbing","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Chong","given":"Yan","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Yuan","given":"Hong","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Huang","given":"JiaQi","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Zhang","given":"Qiang","non-dropping-particle":"","parse-names":false,"suffix":""}],"container-title":"Particuology","id":"ITEM-1","issued":{"date-parts":[["2021"]]},"page":"56-71","publisher":"ChineseSocietyofParticuology","title":"Advancedelectrodeprocessingoflithiumionbatteries:Areviewofpowdertechnologyinbatteryfabrication","type":"article-journal","volume":"57"},"uris":["/documents/?uuid=8e0e6fec-e4e2-4c47-be16-fe5062ea7b0d"]}],"mendeley":{"formattedCitation":"¹","plainTextFormattedCitation":"1","previouslyFormattedCitation":"¹"},"properties":{"noteIndex":0},"schema":"/citation-style-language/schema/raw/master/csl-citation.json"}1]，被广泛应用于各种储能系统中。另外，水系充电电池具有成本低和安全性高等特点，也是一种最有前途的储能系统。近年来，电解液体系为中性或弱酸性的水系锌离子电池（ZIBs）受到了广泛的关注[ADDINCSL_CITATION{"citationItems":[{"id":"ITEM-1","itemData":{"author":[{"dropping-particle":"","family":"杜合平","given":"","non-dropping-particle":"","parse-names":false,"suffix":""}],"id":"ITEM-1","issued":{"date-parts":[["2020"]]},"title":"MnO_2电极的改性及其锌离子电池性能研究_杜合平_1_5.pdf","type":"article"},"uris":["/documents/?uuid=6f6d306a-ed0b-49d9-9ac2-85a6a8d66456"]}],"mendeley":{"formattedCitation":"²","plainTextFormattedCitation":"2","previouslyFormattedCitation":"²"},"properties":{"noteIndex":0},"schema":"/citation-style-language/schema/raw/master/csl-citation.json"}2]，锌负极具有比容量高（质量比容量820mAhg-1，体积比容量5855mAhcm-3）、资源丰富、还原电位低（相对于标准氢电极-0.76V）、析氢电位高、安全无毒等优点[ADDINCSL_CITATION{"citationItems":[{"id":"ITEM-1","itemData":{"DOI":"10.1002/eem2.12067","ISSN":"2575-0356","abstract":"Rechargeableaqueouszinc‐ionbatteries(ZIBs)featuringthemeritsoflowcost,eco‐friendliness,andenhancedsafetyhaveattractedextensiveinterestsandconsideredasthemostpromisingenergystoragesystem.However,mucheffortsaredevotedtothe…","author":[{"dropping-particle":"","family":"Li","given":"Canpeng","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Xie","given":"Xuesong","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Liang","given":"Shuquan","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Zhou","given":"Jiang","non-dropping-particle":"","parse-names":false,"suffix":""}],"container-title":"Energy&EnvironmentalMaterials","id":"ITEM-1","issue":"2","issued":{"date-parts":[["2020"]]},"page":"146-159","title":"IssuesandFuturePerspectiveonZincMetalAnodeforRechargeableAqueousZinc‐ionBatteries","type":"article-journal","volume":"3"},"uris":["/documents/?uuid=fe505ea8-4675-4e93-9fe8-f0c91ad9d20c"]}],"mendeley":{"formattedCitation":"³","plainTextFormattedCitation":"3","previouslyFormattedCitation":"³"},"properties":{"noteIndex":0},"schema":"/citation-style-language/schema/raw/master/csl-citation.json"}3]，但是在中性或弱酸性电解液中仍面临枝晶生长、界面副反应、腐蚀、库仑效率低[ADDINCSL_CITATION{"citationItems":[{"id":"ITEM-1","itemData":{"DOI":"10.1016/j.nanoen.2020.104523","ISSN":"22112855","abstract":"Thezincionbattery(ZIB)withmildaqueouselectrolytesisoneofthemostpromisingsystemsforthelarge-scaleenergystorageapplicationduetoitshighsafety,environmentalbenignity,lowcost,andhighenergydensity.Itexhibitsexcellentapplicationpotentialandhasattractedtheattentionofbatterydevelopersforgridenergystoragedemandsinrecentyears.ComparedwiththenumerousstudiesonthecathodematerialsforZIBs,theresearchontheenhancementoftheelectrochemicalperformanceofzincmetalanodeisstillinitsearlystage.ThecurrentchallengesforZnanodesaretheirpoorcyclabilityandlowCoulombicefficiency(CE)originatedfromtheseveredendritegrowth,self-corrosion,andirreversiblebyproductsformation.Toaddresstheintrinsicdrawbacksofzincmetalanodesinmildaqueouselectrolytes,someeffectivestrategies,includinginterfacialmodificationbetweenanodeandelectrolyte,structuraldesignforZnanodesandtheadoptionofnovelseparatorsandelectrolytes,havebeendevelopedrecently.ThisreviewaimstohighlighttherecentadvancesinZnanodeandoutlinefutureopportunitiesforthedevelopmentofhigh-performancezincmetalanodesinaqueousZIBs.","author":[{"dropping-particle":"","family":"Jia","given":"Hao","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Wang","given":"Ziqi","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Tawiah","given":"Benjamin","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Wang","given":"Yidi","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Chan","given":"CheukYing","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Fei","given":"Bin","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Pan","given":"Feng","non-dropping-particle":"","parse-names":false,"suffix":""}],"container-title":"NanoEnergy","id":"ITEM-1","issue":"October2019","issued":{"date-parts":[["2020"]]},"page":"104523","publisher":"ElsevierLtd","title":"Recentadvancesinzincanodesforhigh-performanceaqueousZn-ionbatteries","type":"article-journal","volume":"70"},"uris":["/documents/?uuid=faa80bbb-25bf-4afc-bfa5-fe07293e17ae"]}],"mendeley":{"formattedCitation":"⁴","plainTextFormattedCitation":"4","previouslyFormattedCitation":"⁴"},"properties":{"noteIndex":0},"schema":"/citation-style-language/schema/raw/master/csl-citation.json"}4]等问题，需进一步对其进行改性、修饰。1.2水系锌离子电池的工作原理水系锌离子电池的正极为能储存锌离子的宿主材料，负极为金属锌，电解液为含有锌离子的中性或弱酸性水溶液。其中正极材料主要包括锰基氧化物、钒基氧化物、普鲁士蓝类似物等。电解液主要包括ZnSO4和Zn(CF3SO3)2等弱酸性或中性锌盐[ADDINCSL_CITATION{"citationItems":[{"id":"ITEM-1","itemData":{"DOI":"10.6023/A20090409","ISBN":"2020203081","author":[{"dropping-particle":"","family":"张璐;王文凤;张洪明;韩树民;王利民.","given":"","non-dropping-particle":"","parse-names":false,"suffix":""}],"container-title":"化学学报","id":"ITEM-1","issued":{"date-parts":[["2021"]]},"title":"水系锌离子电池研究进展和挑战","type":"article-journal"},"uris":["/documents/?uuid=5238c89d-9d11-4832-ac2a-7b4c2ff3ff97"]}],"mendeley":{"formattedCitation":"⁵","plainTextFormattedCitation":"5","previouslyFormattedCitation":"⁵"},"properties":{"noteIndex":0},"schema":"/citation-style-language/schema/raw/master/csl-citation.json"}5]。水系锌离子电池的储能机制是以Zn2+为载体，通过其在负极溶解/沉积和在正极嵌入/脱嵌来实现电能的可逆储存与释放（如图1.1）。值得注意的是，相比于传统锌基电池的碱性电解液，弱酸性或中性电解液可以有效减少锌枝晶、ZnO和Zn(OH)2及其他钝化层的形成，以实现快速、可逆的锌溶解/沉积。图1.1水系锌离子电池的储能机理图[4]1.3锌负极材料存在的问题及改性方法1.3.1锌负极材料存在的问题水系锌离子电池锌负极材料存在如下问题：枝晶生长在水系锌离子电池的循环过程中，锌具有较高的活性，而且溶解/沉积过程通常是不均匀的[ADDINCSL_CITATION{"citationItems":[{"id":"ITEM-1","itemData":{"DOI":"10.1016/j.nanoen.2020.104523","ISSN":"22112855","abstract":"Thezincionbattery(ZIB)withmildaqueouselectrolytesisoneofthemostpromisingsystemsforthelarge-scaleenergystorageapplicationduetoitshighsafety,environmentalbenignity,lowcost,andhighenergydensity.Itexhibitsexcellentapplicationpotentialandhasattractedtheattentionofbatterydevelopersforgridenergystoragedemandsinrecentyears.ComparedwiththenumerousstudiesonthecathodematerialsforZIBs,theresearchontheenhancementoftheelectrochemicalperformanceofzincmetalanodeisstillinitsearlystage.ThecurrentchallengesforZnanodesaretheirpoorcyclabilityandlowCoulombicefficiency(CE)originatedfromtheseveredendritegrowth,self-corrosion,andirreversiblebyproductsformation.Toaddresstheintrinsicdrawbacksofzincmetalanodesinmildaqueouselectrolytes,someeffectivestrategies,includinginterfacialmodificationbetweenanodeandelectrolyte,structuraldesignforZnanodesandtheadoptionofnovelseparatorsandelectrolytes,havebeendevelopedrecently.ThisreviewaimstohighlighttherecentadvancesinZnanodeandoutlinefutureopportunitiesforthedevelopmentofhigh-performancezincmetalanodesinaqueousZIBs.","author":[{"dropping-particle":"","family":"Jia","given":"Hao","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Wang","given":"Ziqi","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Tawiah","given":"Benjamin","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Wang","given":"Yidi","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Chan","given":"CheukYing","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Fei","given":"Bin","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Pan","given":"Feng","non-dropping-particle":"","parse-names":false,"suffix":""}],"container-title":"NanoEnergy","id":"ITEM-1","issue":"October2019","issued":{"date-parts":[["2020"]]},"page":"104523","publisher":"ElsevierLtd","title":"Recentadvancesinzincanodesforhigh-performanceaqueousZn-ionbatteries","type":"article-journal","volume":"70"},"uris":["/documents/?uuid=faa80bbb-25bf-4afc-bfa5-fe07293e17ae"]}],"mendeley":{"formattedCitation":"⁴","plainTextFormattedCitation":"4","previouslyFormattedCitation":"⁴"},"properties":{"noteIndex":0},"schema":"/citation-style-language/schema/raw/master/csl-citation.json"}4]。在碱性介质中，Zn2+首先沉积在Zn浓度较高的区域，并且由于其较大的表面能，随后的Zn会在已经形成的隆起处自发成核生长，进而在负极表面上形成小的尖端，诱导尖端效应，吸引更多的锌酸盐聚集，在重复充放电过程中逐渐形成枝晶[ADDINCSL_CITATION{"citationItems":[{"id":"ITEM-1","itemData":{"DOI":"10.1016/j.jcis.2020.10.099","ISSN":"10957103","PMID":"33148452","abstract":"Duetotheirlowcost,highsafety,environmentalfriendliness,andimpressiveelectrochemicalperformances,aqueouszinc-ionbatteriesareconsideredpromisingalternativetechnologiestolithium-ionbatteriesforuseinlarge-scaleapplications.However,existingaqueouszinc-ionbatteriesusuallysufferfrompoorcyclabilityandcannotoperateatsubzerotemperatures.Herein,tosolvetheseproblems,theelectrolyteinaqueouszinc-ionbatterieisoptimizedbyaddingtheappropriateamountsofdiethyletherandethyleneglycol.Resultsshowthattheadditionof1%diethylethercontributestothebestcyclabilityat25°C.Furthermore,theadditionof30%ethyleneglycolresultsinthebestelectrochemicalperformancesat0and−10°C.Thissignificantperformanceimprovementatlowtemperaturesisascribedtothehighionicconductivityofthemodifiedelectrolyteandthelowchargetransferimpedanceofthebatterywiththemodifiedelectrolyteat0and−10°C.Itisalsoshownthatthemodifiedelectrolytecandecreasethenucleationoverpotentialofzincplating,enhancetheinterfacialstabilitybetweenthezincmetalandelectrolyte,suppressthezincdendriticgrowthandsidereactions,anddecreasetheself-corrosionrateofthezincanode.Thisworkoffersafacilestrategytorealizeaqueouszinc-ionbatterieswithexcellentcyclabilityandantifreezingabilityandmayinspireresearchonotheraqueousenergystoragesystems.","author":[{"dropping-particle":"","family":"Wang","given":"Anran","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Zhou","given":"Weijun","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Huang","given":"Aixiang","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Chen","given":"Minfeng","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Tian","given":"Qinghua","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Chen","given":"Jizhang","non-dropping-particle":"","parse-names":false,"suffix":""}],"container-title":"JournalofColloidandInterfaceScience","id":"ITEM-1","issued":{"date-parts":[["2021"]]},"page":"362-370","publisher":"ElsevierInc.","title":"Developingimprovedelectrolytesforaqueouszinc-ionbatteriestoachieveexcellentcyclabilityandantifreezingability","type":"article-journal","volume":"586"},"uris":["/documents/?uuid=e5f91ab0-6569-47ec-850f-a16f658f8a92"]}],"mendeley":{"formattedCitation":"⁶","plainTextFormattedCitation":"6","previouslyFormattedCitation":"⁶"},"properties":{"noteIndex":0},"schema":"/citation-style-language/schema/raw/master/csl-citation.json"}6]。枝晶的生长取决于正极和负极之间的局部过电位。这说明当过电位较大时，枝晶生长的起始时间较短，枝晶生长速度较快[ADDINCSL_CITATION{"citationItems":[{"id":"ITEM-1","itemData":{"DOI":"10.1016/j.nanoen.2020.104523","ISSN":"22112855","abstract":"Thezincionbattery(ZIB)withmildaqueouselectrolytesisoneofthemostpromisingsystemsforthelarge-scaleenergystorageapplicationduetoitshighsafety,environmentalbenignity,lowcost,andhighenergydensity.Itexhibitsexcellentapplicationpotentialandhasattractedtheattentionofbatterydevelopersforgridenergystoragedemandsinrecentyears.ComparedwiththenumerousstudiesonthecathodematerialsforZIBs,theresearchontheenhancementoftheelectrochemicalperformanceofzincmetalanodeisstillinitsearlystage.ThecurrentchallengesforZnanodesaretheirpoorcyclabilityandlowCoulombicefficiency(CE)originatedfromtheseveredendritegrowth,self-corrosion,andirreversiblebyproductsformation.Toaddresstheintrinsicdrawbacksofzincmetalanodesinmildaqueouselectrolytes,someeffectivestrategies,includinginterfacialmodificationbetweenanodeandelectrolyte,structuraldesignforZnanodesandtheadoptionofnovelseparatorsandelectrolytes,havebeendevelopedrecently.ThisreviewaimstohighlighttherecentadvancesinZnanodeandoutlinefutureopportunitiesforthedevelopmentofhigh-performancezincmetalanodesinaqueousZIBs.","author":[{"dropping-particle":"","family":"Jia","given":"Hao","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Wang","given":"Ziqi","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Tawiah","given":"Benjamin","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Wang","given":"Yidi","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Chan","given":"CheukYing","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Fei","given":"Bin","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Pan","given":"Feng","non-dropping-particle":"","parse-names":false,"suffix":""}],"container-title":"NanoEnergy","id":"ITEM-1","issue":"October2019","issued":{"date-parts":[["2020"]]},"page":"104523","publisher":"ElsevierLtd","title":"Recentadvancesinzincanodesforhigh-performanceaqueousZn-ionbatteries","type":"article-journal","volume":"70"},"uris":["/documents/?uuid=faa80bbb-25bf-4afc-bfa5-fe07293e17ae"]}],"mendeley":{"formattedCitation":"⁴","plainTextFormattedCitation":"4","previouslyFormattedCitation":"⁴"},"properties":{"noteIndex":0},"schema":"/citation-style-language/schema/raw/master/csl-citation.json"}4]。而且，枝晶还有可能穿透电池中的隔膜，导致内部短路，使电池破坏[ADDINCSL_CITATION{"citationItems":[{"id":"ITEM-1","itemData":{"DOI":"10.1002/adsu.202000082","ISSN":"23667486","abstract":"Aqueouszinc-ionbatteries(AZIBs)haveattractedincreasingattentionasanext-generationenergystoragesystembecauseoftheirinherentsafety,highcapacity,andcosteffectiveness.However,thepoorcyclingdurabilityandlowcoulombicefficiencyofzincanodessubstantiallyrestricttheirfurtherdevelopment,whichshouldbeattributedtotheseveredendritegrowth,shapechange,surfacepassivation,self-corrosion,andbyproductformationacrosstherepeatedplating/strippingprocesses.Toaddressthesecriticalissues,greateffortshavebeendedicatedtotherationaldesignofzincanodes.Inthisreview,differentstrategiesfortheperformanceimprovementofzincanodesaresummarizedaswellasrecentresearchthatbooststheirdevelopment.Thesemethodsincludethesurfacemodification,novelhost-anodedevelopmentforzinc,electrolyteformulation,andseparatordesign.Theirrespectiveadvantagesanddefectsarecomparedanddiscussedindetail.Thechallengesandfurtherprospectsinthisfieldarealsoaddressed.Thisworkisdesignedtoshedlightonadvancedzincanodeconstructionsforhigh-performanceAZIBsassembly.","author":[{"dropping-particle":"","family":"Yu","given":"Yanxia","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Xu","given":"Wei","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Liu","given":"Xiaoqing","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Lu","given":"Xihong","non-dropping-particle":"","parse-names":false,"suffix":""}],"container-title":"AdvancedSustainableSystems","id":"ITEM-1","issue":"9","issued":{"date-parts":[["2020"]]},"page":"1-15","title":"ChallengesandStrategiesforConstructingHighlyReversibleZincAnodesinAqueousZinc-IonBatteries:RecentProgressandFuturePerspectives","type":"article-journal","volume":"4"},"uris":["/documents/?uuid=9641bb6c-b724-465a-9859-66bfd85d3bdb"]}],"mendeley":{"formattedCitation":"⁷","plainTextFormattedCitation":"7","previouslyFormattedCitation":"⁷"},"properties":{"noteIndex":0},"schema":"/citation-style-language/schema/raw/master/csl-citation.json"}7]。这种机理也适用于中性或弱酸性电解液，但在中性或弱酸性电解液中以Zn2+为电荷载体，枝晶的化学组成仅为金属锌。腐蚀水系锌离子电池中腐蚀有自腐蚀和电化学腐蚀，自腐蚀主要存在于碱性锌离子电池中。腐蚀微观本质可以解释为具有非均匀表面的锌电极不同区域的电位不同，构成了无数的腐蚀微区。析氢反应将在一些局部高能区进行，并产生OH-，这将消耗有限的锌负极溶解而产生氧化锌和锌酸盐副产物（如图1.2）。因此，腐蚀使电池自放电，降低了锌负极的利用率和容量。此外，在密封环境中，腐蚀过程产生氢气进而导致电池的内压增加，电解液在一定程度上积聚压力后开始泄漏。因此，这些副反应将消耗锌负极和电解液，使电池容量严重衰减。钝化在中性或弱酸性电解质中，锌负极表面会形成钝化层。以ZnSO4电解液为例，在重复充放电循环过程中，难溶的ZnSO4(OH)6·H2O会在负极表面沉淀[ADDINCSL_CITATION{"citationItems":[{"id":"ITEM-1","itemData":{"DOI":"10.1002/adsu.202000082","ISSN":"23667486","abstract":"Aqueouszinc-ionbatteries(AZIBs)haveattractedincreasingattentionasanext-generationenergystoragesystembecauseoftheirinherentsafety,highcapacity,andcosteffectiveness.However,thepoorcyclingdurabilityandlowcoulombicefficiencyofzincanodessubstantiallyrestricttheirfurtherdevelopment,whichshouldbeattributedtotheseveredendritegrowth,shapechange,surfacepassivation,self-corrosion,andbyproductformationacrosstherepeatedplating/strippingprocesses.Toaddressthesecriticalissues,greateffortshavebeendedicatedtotherationaldesignofzincanodes.Inthisreview,differentstrategiesfortheperformanceimprovementofzincanodesaresummarizedaswellasrecentresearchthatbooststheirdevelopment.Thesemethodsincludethesurfacemodification,novelhost-anodedevelopmentforzinc,electrolyteformulation,andseparatordesign.Theirrespectiveadvantagesanddefectsarecomparedanddiscussedindetail.Thechallengesandfurtherprospectsinthisfieldarealsoaddressed.Thisworkisdesignedtoshedlightonadvancedzincanodeconstructionsforhigh-performanceAZIBsassembly.","author":[{"dropping-particle":"","family":"Yu","given":"Yanxia","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Xu","given":"Wei","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Liu","given":"Xiaoqing","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Lu","given":"Xihong","non-dropping-particle":"","parse-names":false,"suffix":""}],"container-title":"AdvancedSustainableSystems","id":"ITEM-1","issue":"9","issued":{"date-parts":[["2020"]]},"page":"1-15","title":"ChallengesandStrategiesforConstructingHighlyReversibleZincAnodesinAqueousZinc-IonBatteries:RecentProgressandFuturePerspectives","type":"article-journal","volume":"4"},"uris":["/documents/?uuid=9641bb6c-b724-465a-9859-66bfd85d3bdb"]}],"mendeley":{"formattedCitation":"⁷","plainTextFormattedCitation":"7","previouslyFormattedCitation":"⁷"},"properties":{"noteIndex":0},"schema":"/citation-style-language/schema/raw/master/csl-citation.json"}7]，形成绝缘层，防止放电产物的迁移，从而防止进一步放电[ADDINCSL_CITATION{"citationItems":[{"id":"ITEM-1","itemData":{"DOI":"10.1021/acsnano.0c07041","ISSN":"1936086X","abstract":"AqueousZn-ionbatteries(ZIBs)arepromisingsafeenergystoragesystemsthathavereceivedconsiderableattentioninrecentyears.BasedontheelectrochemicalbehaviorofZn2+inthecharginganddischargingprocess,hereinwereviewtheresearchprogressonanodematerialsforuseinaqueousZIBsbasedontwoaspects:ZndepositionandZn2+intercalation.Todate,Zndendrite,corrosion,andpassivationissueshaverestrictedthedevelopmentofaqueousZIBs.However,manystrategieshavebeendeveloped,includingstructuraldesign,interfaceprotectionoftheZnanode,Znalloying,andusingpolymerelectrolytes.ThemainaimistostabilizetheZnstripping/platinglayerandlimitsidereactions.Zn2+-intercalatedanodes,withahighZn2+storagecapacitytoreplacethecurrentmetalZnanode,arealsoapotentialoption.Finally,somesuggestionshavebeenputforwardforthesubsequentoptimizationstrategy,whichareexpectedtopromotefurtherdevelopmentofaqueousZIBs.","author":[{"dropping-particle":"","family":"Wang","given":"Tingting","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Li","given":"Canpeng","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Xie","given":"Xuesong","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Lu","given":"Bingan","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"He","given":"Zhangxing","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Liang","given":"Shuquan","non-dropping-particle":"","parse-names":false,"suffix":""},{"dropping-particle":"","family":"Zhou","given":"Jiang","non-dropping-particle":"","parse-names":false,"suffix":""}],"container-title":"ACSNano","id":"ITEM-1","issue":"12","issued":{"date-parts":[["2020"]]},"page":"16321-16347","title":"AnodeMaterialsforAqueousZincIonBatteries:Mechanisms,Properties,andPerspectives","type":"article-journal","volume":"14"},"uris":["/documents/?uuid=b215c77d-47bb-4a18-8b39-949d221e7414"]}],"mendeley":{"formattedCitation":"⁸","plainTextFormattedCitation":"8","previouslyFormattedCitation":"⁸"},"properties":{"noteIndex":0},"schema":"/citation-style-language/schema/raw/master/csl-citation.json"}8]。析氢adcb锌金属电极在被置于含水硫酸锌电解液中的过程中容易被氧化，形成疏松的硫酸锌表面层并产生氢气，导致内部电阻增加和电池溶胀问题，最终导致电池故障。由研究可知，在弱酸性环境中，Zn/Zn2+的标准还原电位（−1.26V）远低于析氢电位。虽然Zn在水系环境中拥有较高的析氢过电位，可以在一定程度上抑制析氢反应，但是在水系锌离子电池运行期间氢气的析出是无法避免的，所以在电池循环过程中也会消耗电解液和锌负极，导致锌电极的库仑效率降低[ADDINCSL_CITATION{"citationItems":[{"id":"ITEM-1","itemData":{"DOI":"10.1016/j.nanoen.2019.05.059","ISSN":"22112855","abstract":"Featuringwithlowcost,exceptionalinherentsafetyanddecentelectrochemicalperformance,rechargeableZn-basedbatteries(RZBs)haveattractedincreasedattentionandrevivedresearcheffortsrecentlyasacompellingalternativebatterychemistrytoLi-ion.However,somechallengesstillstandinthewayofthedevelopmentoftheseenergystoragesystems,suchaslowoperationvoltage,instabilityofcathodematerialsaswellasdissolutionofZnelectrode,etc.Inthisreview,wepresentacomprehensiveoverviewofrecentprogressindifferentRZBssystemsincludingmildelectrolyteRZBs,alkalineRZBs,hybridRZBs,Zn-ioncapacitorsandZnairbatteries.ThefundamentalchemistryofvariousRZBsystems,differentcathodematerials,optimizationofZnanodeaswellasvarioustypesofelectrolytesandtheirinfluenceonthebatteryperformancearesummarized.Themajorissuesofdifferentcomponentsalongwithrespectivestrategiestoalleviatethemarediscussed,aimingatprovidingageneralguidefordesignandconstructionofhigh-performanceRZBs.Additionally,thedevelopmentofRZBswithdifferentfeaturesinthelastfewyearsaresummarized.Finally,wediscussthelimitationsandchallengesthatneedtobeovercome,providingpotentialfutureresearchd