【《氨分解催化剂研究进展文献综述》8400字】

氨分解催化剂研究进展文献综述目录TOC\o"1-3"\h\u9435氨分解催化剂研究进展文献综述 图1-5所示，CNF表面特有的边缘结构可改善了Ru的得电子性能，可以增强催化剂的氨分解活性。此外，催化剂上含氧基团的存在可以调节粒径大小，增加了催化剂的活性。Ru粒径范围在l-2.5nm以下时，氨分解活性随Ru颗粒粒径增大而增强。图1-SEQ图1-\*ARABIC5(a)CNFs和(b)CNTs的HTEM图Figure1-SEQFigure.1-\*ARABIC5HRTEMimagesof(a)CNFsand(b)CNTs.以上研究表明，催化剂上Ru的尺寸和分散对于氨分解活性具有重要影响。Wu等ADDINEN.CITE<EndNote><Cite><Author>Wu</Author><Year>2010</Year><RecNum>3027</RecNum><DisplayText><styleface="superscript">[66]</style></DisplayText><record><rec-number>3027</rec-number><foreign-keys><keyapp="EN"db-id="ft92tvr2f5pvtae0aecxdv2yatvxv9rda9ta"timestamp="1579229786">3027</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Wu,Xiaoman</author><author>Li,Xuefeng</author><author>Zhang,Hongbin</author></authors><translated-authors><author>武小满,</author><author>李学峰,</author><author>张鸿斌,</author></translated-authors></contributors><titles><title>PreparationofRu/CNTsNano-materialbyPolyolReduction-depositionMethodandItsCatalyticalPerformanceforAmmoniaDecomposition</title><secondary-title>PreciousMetals</secondary-title><translated-title>液相还原制备钌/碳纳米管及催化氨分解性能</translated-title></titles><periodical><full-title>PreciousMetals</full-title></periodical><pages>1-6</pages><volume>31</volume><number>3</number><dates><year>2010</year><pub-dates><date>2010</date></pub-dates></dates><isbn>1004-0676</isbn><accession-num>CSCD:3978918</accession-num><urls><related-urls><url><GotoISI>://CSCD:3978918</url></related-urls></urls><custom7>1004-0676(2010)31:3<1:yxhyzb>2.0.tx;2-u</custom7></record></Cite></EndNote>[66]通过乙二醇还原法得到了分散良好的4.2%Ru/CNTs催化剂，催化活性为浸渍法制备的5%Ru/CNTs催化剂的1.3倍。LiADDINEN.CITE<EndNote><Cite><Author>Li</Author><Year>2017</Year><RecNum>296</RecNum><DisplayText><styleface="superscript">[67]</style></DisplayText><record><rec-number>296</rec-number><foreign-keys><keyapp="EN"db-id="ft92tvr2f5pvtae0aecxdv2yatvxv9rda9ta"timestamp="1565686050">296</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Li,Gang</author><author>Kanezashi,Masakoto</author><author>Tsuru,Toshinori</author></authors></contributors><titles><title>CatalyticAmmoniaDecompositionoverHigh-PerformanceRu/GrapheneNanocompositesforEfficientCOx-FreeHydrogenProduction</title><secondary-title>Catalysts</secondary-title></titles><periodical><full-title>Catalysts</full-title></periodical><volume>7</volume><number>1</number><dates><year>2017</year><pub-dates><date>Jan</date></pub-dates></dates><isbn>2073-4344</isbn><accession-num>WOS:000395426100023</accession-num><urls><related-urls><url><GotoISI>://WOS:000395426100023</url><url>/catalysts/catalysts-07-00023/article_deploy/catalysts-07-00023.pdf?filename=&attachment=1</url></related-urls></urls><custom7>23</custom7><electronic-resource-num>10.3390/catal7010023</electronic-resource-num></record></Cite></EndNote>[67]也报道了通过乙二醇还原法在石墨烯纳米片上可以生长出高度分散的钌纳米颗粒。通过调整制备条件，可以很容易地从Ru的粒径、形貌和负载等方面调整Ru/石墨烯纳米复合材料的微观结构。并探讨了空速对活性的影响。如图所示，450°C下，随着空速从20,000mL.g.h-1增加到20,000mL.g.h-1，氨分解转化率由91%下降到62%，但氢气生成速率从20.3mmol·min−1·gcat−1增加到41.5mmol·min−1·gcat−1。图1-SEQ图1-\*ARABIC6不同空速下CS-60Ru/graphene催化剂氨分解性能ADDINEN.CITE<EndNote><Cite><Author>Li</Author><Year>2017</Year><RecNum>296</RecNum><DisplayText><styleface="superscript">[67]</style></DisplayText><record><rec-number>296</rec-number><foreign-keys><keyapp="EN"db-id="ft92tvr2f5pvtae0aecxdv2yatvxv9rda9ta"timestamp="1565686050">296</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Li,Gang</author><author>Kanezashi,Masakoto</author><author>Tsuru,Toshinori</author></authors></contributors><titles><title>CatalyticAmmoniaDecompositionoverHigh-PerformanceRu/GrapheneNanocompositesforEfficientCOx-FreeHydrogenProduction</title><secondary-title>Catalysts</secondary-title></titles><periodical><full-title>Catalysts</full-title></periodical><volume>7</volume><number>1</number><dates><year>2017</year><pub-dates><date>Jan</date></pub-dates></dates><isbn>2073-4344</isbn><accession-num>WOS:000395426100023</accession-num><urls><related-urls><url><GotoISI>://WOS:000395426100023</url><url>/catalysts/catalysts-07-00023/article_deploy/catalysts-07-00023.pdf?filename=&attachment=1</url></related-urls></urls><custom7>23</custom7><electronic-resource-num>10.3390/catal7010023</electronic-resource-num></record></Cite></EndNote>[67]，450°CFigure1-SEQFigure.1-\*ARABIC6CatalyticperformanceofCS-60Ru/graphenenanocompositesforammoniadecompositionat450°CunderdifferentGHSVs.碳材料负载钌时虽然能得到具有高活性的氨分解催化剂，但催化剂在500°C下活性出现较大衰减，因为石墨烯纳米片在H2气氛下受到了甲烷化和高温烧结增强的影响。需要进行更多研究以提高碳材料载体的稳定性。（2）金属氧化物载体虽然Yin等ADDINEN.CITE<EndNote><Cite><Author>Wang</Author><Year>2004</Year><RecNum>1135</RecNum><DisplayText><styleface="superscript">[68]</style></DisplayText><record><rec-number>1135</rec-number><foreign-keys><keyapp="EN"db-id="ft92tvr2f5pvtae0aecxdv2yatvxv9rda9ta"timestamp="1579140408">1135</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Wang,S.J.</author><author>Yin,S.F.</author><author>Li,L.</author><author>Xu,B.Q.</author><author>Ng,C.F.</author><author>Au,C.T.</author></authors></contributors><titles><title><styleface="normal"font="default"size="100%">InvestigationonmodificationofRu/CNTscatalystforthegenerationofCO</style><styleface="subscript"font="default"size="100%">X</style><styleface="normal"font="default"size="100%">-freehydrogenfromammonia</style></title><secondary-title>AppliedCatalysisB-Environmental</secondary-title></titles><periodical><full-title>AppliedCatalysisB-Environmental</full-title></periodical><pages>287-299</pages><volume>52</volume><number>4</number><dates><year>2004</year><pub-dates><date>Oct8</date></pub-dates></dates><isbn>0926-3373</isbn><accession-num>WOS:000223505100007</accession-num><urls><related-urls><url><GotoISI>://WOS:000223505100007</url></related-urls></urls><electronic-resource-num>10.1016/j.apcatb.2004.05.002</electronic-resource-num></record></Cite></EndNote>[68]的研究表明，TiO2，MgO和Al2O3等载体负载钌时催化剂氨分解活性不如CNTs。但通过多种手段提高催化剂氨分解反应的活性。如山东大学贾春江课题组ADDINEN.CITEADDINEN.CITE.DATA[69]通过胶体沉淀法在CeO2载体上成功制备了高分散的Ru团簇催化剂，通过钌团簇和二氧化铈载体之间的协同效应实现了中低温下高效制氢，如图所示，以单位质量活性组分氢气生成速率来看，催化剂在450°C下的氢生成速率达到了9924mmolH2gRu−1min−1。与Ru/CNT相比，催化性能提高了一个数量级。是目前以金属氧化物为载体时制备的活性最好的氨分解催化剂。图1-SEQ图1-\*ARABIC7团簇Ru/CeO2催化剂与Ru/MgOADDINEN.CITEADDINEN.CITE.DATA[70]、Ru/CNTsADDINEN.CITE<EndNote><Cite><Author>Wang</Author><Year>2004</Year><RecNum>1135</RecNum><DisplayText><styleface="superscript">[68]</style></DisplayText><record><rec-number>1135</rec-number><foreign-keys><keyapp="EN"db-id="ft92tvr2f5pvtae0aecxdv2yatvxv9rda9ta"timestamp="1579140408">1135</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Wang,S.J.</author><author>Yin,S.F.</author><author>Li,L.</author><author>Xu,B.Q.</author><author>Ng,C.F.</author><author>Au,C.T.</author></authors></contributors><titles><title><styleface="normal"font="default"size="100%">InvestigationonmodificationofRu/CNTscatalystforthegenerationofCO</style><styleface="subscript"font="default"size="100%">X</style><styleface="normal"font="default"size="100%">-freehydrogenfromammonia</style></title><secondary-title>AppliedCatalysisB-Environmental</secondary-title></titles><periodical><full-title>AppliedCatalysisB-Environmental</full-title></periodical><pages>287-299</pages><volume>52</volume><number>4</number><dates><year>2004</year><pub-dates><date>Oct8</date></pub-dates></dates><isbn>0926-3373</isbn><accession-num>WOS:000223505100007</accession-num><urls><related-urls><url><GotoISI>://WOS:000223505100007</url></related-urls></urls><electronic-resource-num>10.1016/j.apcatb.2004.05.002</electronic-resource-num></record></Cite></EndNote>[68]催化剂的氢气生成速率对比ADDINEN.CITEADDINEN.CITE.DATA[69]Figure1-SEQFigure.1-\*ARABIC7ComparisonofH2formationyields(mmolH2.gRu−1 min−1)overRu/CeO2catalystandRu/MgO,Ru/CNTscatalysts.此外，研究者对Pr6O10ADDINEN.CITE<EndNote><Cite><Author>Nagaoka</Author><Year>2014</Year><RecNum>2913</RecNum><DisplayText><styleface="superscript">[71]</style></DisplayText><record><rec-number>2913</rec-number><foreign-keys><keyapp="EN"db-id="ft92tvr2f5pvtae0aecxdv2yatvxv9rda9ta"timestamp="1579229786">2913</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Nagaoka,Katsutoshi</author><author>Eboshi,Takaaki</author><author>Abe,Naruhiko</author><author>Miyahara,Shin-ichiro</author><author>Honda,Kyoko</author><author>Sato,Katsutoshi</author></authors></contributors><titles><title><styleface="normal"font="default"size="100%">InfluenceofbasicdopantsontheactivityofRu/Pr</style><styleface="subscript"font="default"size="100%">6</style><styleface="normal"font="default"size="100%">O</style><styleface="subscript"font="default"size="100%">11</style><styleface="normal"font="default"size="100%">forhydrogenproductionbyammoniadecomposition</style></title><secondary-title>InternationalJournalofHydrogenEnergy</secondary-title></titles><periodical><full-title>InternationalJournalofHydrogenEnergy</full-title></periodical><pages>20731-20735</pages><volume>39</volume><number>35</number><dates><year>2014</year><pub-dates><date>Dec3</date></pub-dates></dates><isbn>0360-3199</isbn><accession-num>WOS:000347017200099</accession-num><urls><related-urls><url><GotoISI>://WOS:000347017200099</url></related-urls></urls><electronic-resource-num>10.1016/j.ijhydene.2014.07.142</electronic-resource-num></record></Cite></EndNote>[71]、Al2O3ADDINEN.CITE<EndNote><Cite><Author>Lamb</Author><Year>2019</Year><RecNum>1427</RecNum><DisplayText><styleface="superscript">[39]</style></DisplayText><record><rec-number>1427</rec-number><foreign-keys><keyapp="EN"db-id="ft92tvr2f5pvtae0aecxdv2yatvxv9rda9ta"timestamp="1579229638">1427</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Lamb,Krystina</author><author>Hla,SanShwe</author><author>Dolan,Michael</author></authors></contributors><titles><title><styleface="normal"font="default"size="100%">AmmoniadecompositionkineticsoverLiOH-promoted,alpha-Al</style><styleface="subscript"font="default"size="100%">2</style><styleface="normal"font="default"size="100%">O</style><styleface="subscript"font="default"size="100%">3</style><styleface="normal"font="default"size="100%">-supportedRucatalyst</style></title><secondary-title>InternationalJournalofHydrogenEnergy</secondary-title></titles><periodical><full-title>InternationalJournalofHydrogenEnergy</full-title></periodical><pages>3726-3736</pages><volume>44</volume><number>7</number><dates><year>2019</year><pub-dates><date>Feb5</date></pub-dates></dates><isbn>0360-3199</isbn><accession-num>WOS:000457952100026</accession-num><urls><related-urls><url><GotoISI>://WOS:000457952100026</url></related-urls></urls><electronic-resource-num>10.1016/j.ijhydene.2018.12.123</electronic-resource-num></record></Cite></EndNote>[39]、MgOADDINEN.CITEADDINEN.CITE.DATA[70]、ZrO2ADDINEN.CITE<EndNote><Cite><Author>Yin</Author><Year>2006</Year><RecNum>1829</RecNum><DisplayText><styleface="superscript">[72]</style></DisplayText><record><rec-number>1829</rec-number><foreign-keys><keyapp="EN"db-id="ft92tvr2f5pvtae0aecxdv2yatvxv9rda9ta"timestamp="1579229639">1829</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Yin,S.F.</author><author>Xu,B.Q.</author><author>Wang,S.J.</author><author>Au,C.T.</author></authors></contributors><titles><title><styleface="normal"font="default"size="100%">NanosizedRuonhigh-surface-areasuperbasicZrO</style><styleface="subscript"font="default"size="100%">2</style><styleface="normal"font="default"size="100%">-KOHforefficientgenerationofhydrogenviaammoniadecomposition</style></title><secondary-title>AppliedCatalysisA-General</secondary-title></titles><periodical><full-title>AppliedCatalysisa-General</full-title></periodical><pages>202-210</pages><volume>301</volume><number>2</number><dates><year>2006</year><pub-dates><date>Feb24</date></pub-dates></dates><isbn>0926-860X</isbn><accession-num>WOS:000235583100009</accession-num><urls><related-urls><url><GotoISI>://WOS:000235583100009</url></related-urls></urls><electronic-resource-num>10.1016/j.apcata.2005.12.005</electronic-resource-num></record></Cite></EndNote>[72]和La2O3ADDINEN.CITE<EndNote><Cite><Author>Huang</Author><Year>2019</Year><RecNum>2713</RecNum><DisplayText><styleface="superscript">[73]</style></DisplayText><record><rec-number>2713</rec-number><foreign-keys><keyapp="EN"db-id="ft92tvr2f5pvtae0aecxdv2yatvxv9rda9ta"timestamp="1579229785">2713</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Huang,Chuanqing</author><author>Yu,Yingzhi</author><author>Yang,Jinmei</author><author>Yan,Yue</author><author>Wang,Dashan</author><author>Hu,Feiyang</author><author>Wang,Xuewen</author><author>Zhang,Rongbin</author><author>Feng,Gang</author></authors></contributors><titles><title><styleface="normal"font="default"size="100%">Ru/La</style><styleface="subscript"font="default"size="100%">2</style><styleface="normal"font="default"size="100%">O</style><styleface="subscript"font="default"size="100%">3</style><styleface="normal"font="default"size="100%">catalystforammoniadecompositiontohydrogen</style></title><secondary-title>AppliedSurfaceScience</secondary-title></titles><periodical><full-title>AppliedSurfaceScience</full-title></periodical><pages>928-936</pages><volume>476</volume><dates><year>2019</year><pub-dates><date>May15</date></pub-dates></dates><isbn>0169-4332</isbn><accession-num>WOS:000459458600110</accession-num><urls><related-urls><url><GotoISI>://WOS:000459458600110</url></related-urls></urls><electronic-resource-num>10.1016/j.apsusc.2019.01.112</electronic-resource-num></record></Cite></EndNote>[73]等催化剂的研究也实现了较高的氨分解活性和稳定性。综合以上研究发现，具有较强碱性的金属氧化物载体负载钌时往往具有更好的氨分解活性。并且可以通过优化制备方法、以及助剂改性等策略，提高Ru颗粒组分的分散度以及增强金属-载体的相互作用以提高催化性能。为探究制备方法对氨分解活性的影响，Ju等ADDINEN.CITEADDINEN.CITE.DATA[70]对比了等体积法以及沉积-沉淀法制备的Ru/MgO氨分解性能，结果表明，沉积-沉淀法制得的样品具有较高的比表面积和大量的介孔的增加了Ru颗粒的分散性，催化活性远高于等体积浸渍法制得的样品。WangADDINEN.CITE<EndNote><Cite><Author>Wang</Author><Year>2019</Year><RecNum>812</RecNum><DisplayText><styleface="superscript">[74]</style></DisplayText><record><rec-number>812</rec-number><foreign-keys><keyapp="EN"db-id="ft92tvr2f5pvtae0aecxdv2yatvxv9rda9ta"timestamp="1578921426">812</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Wang,Ziqing</author><author>Qu,Yingmin</author><author>Shen,Xiaolong</author><author>Cai,Zhifeng</author></authors></contributors><titles><title><styleface="normal"font="default"size="100%">RutheniumcatalystsupportedonBamodifiedZrO</style><styleface="subscript"font="default"size="100%">2</style><styleface="normal"font="default"size="100%">forammoniadecompositiontoCO</style><styleface="subscript"font="default"size="100%">X</style><styleface="normal"font="default"size="100%">-freehydrogen</style></title><secondary-title>InternationalJournalofHydrogenEnergy</secondary-title></titles><periodical><full-title>InternationalJournalofHydrogenEnergy</full-title></periodical><pages>7300-7307</pages><volume>44</volume><number>14</number><dates><year>2019</year><pub-dates><date>Mar15</date></pub-dates></dates><isbn>0360-3199</isbn><accession-num>WOS:000462102000025</accession-num><urls><related-urls><url><GotoISI>://WOS:000462102000025</url></related-urls></urls><electronic-resource-num>10.1016/j.ijhydene.2019.01.235</electronic-resource-num></record></Cite></EndNote>[74]使用溶胶-凝胶法制备了Ru/Ba-ZrO2催化剂。该方法制备的样品中Ru纳米颗粒具有更好的分散性，并且生成了BaZrO3相，自由电子可从BaZrO3转移到Ru颗粒表面，促进N在Ru颗粒上的缔合脱附，从而充分提高氨分解活性。Nagaoka等ADDINEN.CITEADDINEN.CITE.DATA[71,75]则探究了在Ru/Pr6O11中加入碱金属氧化物、碱土金属氧化物和稀土氧化物等助剂对氨分解性能的影响。结果表明，Ru/Pr6O11掺杂碱金属氧化物后，NH3转化率均高于未掺杂的Ru/Pr6O11(Li2O除外)，Cs2O是最有效的掺杂剂。如图所示，其他碱度低于碱金属氧化物的助剂掺杂后氨转化率更低。此外，碱氢氧化物对氨分解反应也有促进作用，但要注意助剂覆盖在Ru颗粒上导致的传质限制ADDINEN.CITE<EndNote><Cite><Author>Bajus</Author><Year>2016</Year><RecNum>1561</RecNum><DisplayText><styleface="superscript">[76]</style></DisplayText><record><rec-number>1561</rec-number><foreign-keys><keyapp="EN"db-id="ft92tvr2f5pvtae0aecxdv2yatvxv9rda9ta"timestamp="1579229638">1561</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Bajus,S.</author><author>Agel,F.</author><author>Kusche,M.</author><author>Bhriain,N.Ni</author><author>Wasserscheid,P.</author></authors></contributors><titles><title>Alkalihydroxide-modifiedRu/gamma-Al2O3catalystsforammoniadecomposition</title><secondary-title>AppliedCatalysisA-General</secondary-title></titles><periodical><full-title>AppliedCatalysisa-General</full-title></periodical><pages>189-195</pages><volume>510</volume><dates><year>2016</year><pub-dates><date>Jan25</date></pub-dates></dates><isbn>0926-860X</isbn><accession-num>WOS:000369214300020</accession-num><urls><related-urls><url><GotoISI>://WOS:000369214300020</url></related-urls></urls><electronic-resource-num>10.1016/j.apcata.2015.11.024</electronic-resource-num></record></Cite></EndNote>[76]。图1-SEQ图1-\*ARABIC8350°C下NH3的转化随掺杂剂部分电荷的变化（部分电荷越小时碱性越强）Figure1-SEQFigure.1-\*ARABIC8NH3conversionsat350°Casafunctionofthepartialchargeofthedopants(smallervaluesmeanthattheoxideismorestronglybasic).（3）其他载体此外，还研究了诸如核壳结构载体ADDINEN.CITE<EndNote><Cite><Author>Li</Author><Year>2010</Year><RecNum>1750</RecNum><DisplayText><styleface="superscript">[77]</style></DisplayText><record><rec-number>1750</rec-number><foreign-keys><keyapp="EN"db-id="ft92tvr2f5pvtae0aecxdv2yatvxv9rda9ta"timestamp="1579229639">1750</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Li,Yanxing</author><author>Yao,Lianghong</author><author>Song,Yanyan</author><author>Liu,Shunqiang</author><author>Zhao,Jing</author><author>Ji,Weijie</author><author>Au,Chak-Tong</author></authors></contributors><titles><title><styleface="normal"font="default"size="100%">Core-shellstructuredmicrocapsular-likeRu@SiO</style><styleface="subscript"font="default"size="100%">2</style><styleface="normal"font="default"size="100%">reactorforefficientgenerationofCO</style><styleface="subscript"font="default"size="100%">X</style><styleface="normal"font="default"size="100%">-freehydrogenthroughammoniadecomposition</style></title><secondary-title>ChemicalCommunications</secondary-title></titles><periodical><full-title>ChemicalCommunications</full-title></periodical><pages>5298-5300</pages><volume>46</volume><number>29</number><dates><year>2010</year><pub-dates><date>2010</date></pub-dates></dates><isbn>1359-7345</isbn><accession-num>WOS:000279911000027</accession-num><urls><related-urls><url><GotoISI>://WOS:000279911000027</url></related-urls></urls><electronic-resource-num>10.1039/c0cc00430h</electronic-resource-num></record></Cite></EndNote>[77]ADDINEN.CITE<EndNote><Cite><Author>Yao</Author><Year>2011</Year><RecNum>1713</RecNum><DisplayText><styleface="superscript">[78]</style></DisplayText><record><rec-number>1713</rec-number><foreign-keys><keyapp="EN"db-id="ft92tvr2f5pvtae0aecxdv2yatvxv9rda9ta"timestamp="1579229639">1713</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Yao,Lianghong</author><author>Shi,Tianbao</author><author>Li,Yanxing</author><author>Zhao,Jin</author><author>Ji,Weijie</author><author>Au,Chak-Tong</author></authors></contributors><titles><title>Core-shellstructurednickelandrutheniumnanoparticles:VeryactiveandstablecatalystsforthegenerationofCOx-freehydrogenviaammoniadecomposition</title><secondary-title>CatalysisToday</secondary-title></titles><periodical><full-title>CatalysisToday</full-title></periodical><pages>112-118</pages><volume>164</volume><number>1</number><dates><year>2011</year><pub-dates><date>Apr30</date></pub-dates></dates><isbn>0920-5861</isbn><accession-num>WOS:000289716300020</accession-num><urls><related-urls><url><GotoISI>://WOS:000289716300020</url></related-urls></urls><electronic-resource-num>10.1016/j.cattod.2010.10.056</electronic-resource-num></record></Cite></EndNote>[78]、层状双氢氧化物ADDINEN.CITE<EndNote><Cite><Author>Zhao</Author><Year>2019</Year><RecNum>1387</RecNum><DisplayText><styleface="superscript">[79]</style></DisplayText><record><rec-number>1387</rec-number><foreign-keys><keyapp="EN"db-id="ft92tvr2f5pvtae0aecxdv2yatvxv9rda9ta"timestamp="1579229638">1387</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Zhao,Jiawen</author><author>Xu,Shuang</author><author>Wu,Hongjie</author><author>You,Zhixiong</author><author>Deng,Lidan</author><author>Qiu,Xinhong</author></authors></contributors><titles><title><styleface="normal"font="default"size="100%">Metal-supportinteractionsonRu/CaAlO</style><styleface="subscript"font="default"size="100%">X</style><styleface="normal"font="default"size="100%">catalystsderivedfromstructuralreconstructionofCa-Allayereddoublehydroxidesforammoniadecomposition</style></title><secondary-title>ChemicalCommunications</secondary-title></titles><periodical><full-title>ChemicalCommunications</full-title></periodical><pages>14410-14413</pages><volume>55</volume><number>96</number><dates><year>2019</year><pub-dates><date>Dec14</date></pub-dates></dates><isbn>1359-7345</isbn><accession-num>WOS:000499480200032</accession-num><urls><related-urls><url><GotoISI>://WOS:000499480200032</url></related-urls></urls><electronic-resource-num>10.1039/c9cc05706d</electronic-resource-num></record></Cite></EndNote>[79]ADDINEN.CITE<EndNote><Cite><Author>Su</Author><Year>2018</Year><RecNum>359</RecNum><DisplayText><styleface="superscript">[80]</style></DisplayText><record><rec-number>359</rec-number><foreign-keys><keyapp="EN"db-id="ft92tvr2f5pvtae0aecxdv2yatvxv9rda9ta"timestamp="1565686052">359</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Su,Q.</author><author>Gu,L.L.</author><author>Zhong,A.H.</author><author>Yao,Y.</author><author>Ji,W.J.</author><author>Ding,W.P.</author><author>Au,C.T.</author></authors></contributors><titles><title><styleface="normal"font="default"size="100%">LayeredDoubleHydroxideDerivedMg</style><styleface="subscript"font="default"size="100%">2</style><styleface="normal"font="default"size="100%">Al-LDOSupportedandK-ModifiedRuCatalystforHydrogenProductionviaAmmoniaDecomposition</style></title><secondary-title>CatalysisLetters</secondary-title></titles><periodical><full-title>CatalysisLetters</full-title></periodical><pages>894-903</pages><volume>148</volume><number>3</number><dates><year>2018</year><pub-dates><date>Mar</date></pub-dates></dates><isbn>1011-372X</isbn><accession-num>WOS:000426067700010</accession-num><urls><related-urls><url><GotoISI>://WOS:000426067700010</url><url>/content/pdf/10.1007%2Fs10562-017-2195-1.pdf</url></related-urls></urls><electronic-resource-num>10.1007/s10562-017-2195-1</electronic-resource-num></record></Cite></EndNote>[80]、碱交换Y沸石分子筛ADDINEN.CITE<EndNote><Cite><Author>Cha</Author><Year>2021</Year><RecNum>3202</RecNum><DisplayText><styleface="superscript">[81]</style></DisplayText><record><rec-number>3202</rec-number><foreign-keys><keyapp="EN"db-id="ft92tvr2f5pvtae0aecxdv2yatvxv9rda9ta"timestamp="1618993276">3202</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Cha,Junyoung</author><author>Lee,Taeho</author><author>Lee,Yu-Jin</author><author>Jeong,Hyangsoo</author><author>Jo,YoungSuk</author><author>Kim,Yongmin</author><author>Nam,SukWoo</author><author>Han,Jonghee</author><author>Lee,KiBong</author><author>Yoon,ChangWon</author><author>Sohn,Hyuntae</author></authors></contributors><titles><title>Highlymonodispersesub-nanometerandnanometerRuparticlesconfinedinalkali-exchangedzeoliteYforammoniadecomposition</title><secondary-title>AppliedCatalysisB-Environmental</secondary-title></titles><periodical><full-title>AppliedCatalysisB-Environmental</full-title></periodical><volume>283</volume><dates><year>2021</year><pub-dates><date>Apr</date></pub-dates></dates><isbn>0926-3373</isbn><accession-num>WOS:000600017400002</accession-num><urls><related-urls><url><GotoISI>://WOS:000600017400002</url></related-urls></urls><custom7>119627</custom7><electronic-resource-num>10.1016/j.apcatb.2020.119627</electronic-resource-num></record></Cite></EndNote>[81]、钙钛矿和钙酰胺ADDINEN.CITE<EndNote><Cite><Author>Kishida</Author><Year>2018</Year><RecNum>353</RecNum><DisplayText><styleface="superscript">[82]</style></DisplayText><record><rec-number>353</rec-number><foreign-keys><keyapp="EN"db-id="ft92tvr2f5pvtae0aecxdv2yatvxv9rda9ta"timestamp="1565686052">353</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Kishida,Kazuhisa</author><author>Kitano,Masaaki</author><author>Inoue,Yasunori</author><author>Sasase,Masato</author><author>Nakao,Takuya</author><author>Tada,Tomofumi</author><author>Abe,Hitoshi</author><author>Niwa,Yasuhiro</author><author>Yokoyama,Toshiharu</author><author>Hara,Michikazu</author><author>Hosono,Hideo</author></authors></contributors><titles><title>LargeOblateHemispheroidalRutheniumParticlesSupportedonCalciumAmideasEfficientCatalystsforAmmoniaDecomposition</title><secondary-title>Chemistry-aEuropeanJournal</secondary-title></titles><periodical><full-title>Chemistry-aEuropeanJournal</full-title></periodical><pages>7976-7984</pages><volume>24</volume><number>31</number><dates><year>2018</year><pub-dates><date>Jun4</date></pub-dates></dates><isbn>0947-6539</isbn><accession-num>WOS:000434216600025</accession-num><urls><related-urls><url><GotoISI>://WOS:000434216600025</url><url>/doi/pdf/10.1002/chem.201800467</url></related-urls></urls><electronic-resource-num>10.1002/chem.201800467</electronic-resource-num></record></Cite></EndNote>[82]等材料作为载体负载Ru时氨分解反应的活性。有趣的是，对Ru/Ca(NH2)2上的研究表明，当Ru粒径从1.5nm增加到8.4nm时，Ru/Ca(NH2)2的周转频率增加了两个数量级。这与Garcia-Garcia等ADDINEN.CITE<EndNote><Cite><Author>Garcia-Garcia</Author><Year>2009</Year><RecNum>3287</RecNum><DisplayText><styleface="superscript">[56]</style></DisplayText><record><rec-number>3287</rec-number><foreign-keys><keyapp="EN"db-id="ft92tvr2f5pvtae0aecxdv2yatvxv9rda9ta"time