Phostech’s advanced C-LiFePO4 cathode for EV PHEV HEV Challenges and Opportunities.pptx

phostech sadvancedc lifepo4cathodeforev phev hev challengesandopportunities michelgauthierpresident phostechlithiuminc researcher d partementdechimie universit demontr al li e we clic6 lifepo4fepo4 e c lifepo4andli batteries phostech shistoryandip phostechproductsandprocesses lifepower customersandapplications challengesandopportunities phostech sadvancedc lifepo4 fcl krxern henear ds bh ub mt uq sg rf hs uu db os np bemg casrba ra hlina krbcs fr tizrhf zncdhg vnbta crmow mntcre feruos corhir nipdpt cuagau gaintl gesnpb bal csi assbbi setepo briat scyla ac freeenergyofreaction storagecapacityg nfe speci cenergy wh kg nfe rwtspeci cpower w kg vi rwt whyalithiumbattery licoo2 lifepo4 stableli reversiblestructurewidelyavailableelementshighvoltage 3 4v withfe covalentp obound noo2two phase atvoltagelowelectronicconductivitylowli iondiffusion periodictableoftheelements transition organicleli mos2rech li mno2rech polymerelectrolyteli voxli lifepo4 hq argo tech avestor bathiumorganiclelic6 licoo2lic6 li comnni o2lic6 lifepo4rocking chairli5ti4o12 limpo4li5ti4o12 limn2o4 moltenelec solidelec 50yearsoflithiumbatteryevolutionprimarycellsli mno2li so2 socl2 lithiumbatteryfastgrowingbusiness polymerelectrolyteli voxli lifepo4 organicleli mos2rech li mno2rech moltenelec solidelec qu bec canadastartearlyprimarycellsli mno2li so2 socl2 willtheyremainintherace hq argo tech avestor bathiumcaudm phostech2000organiclelic6 licoo2lic6 li comnni o2lic6 lifepo4rocking chairli5ti4o12 limpo4li5ti4o12 limn2o4 speci cpower w kg ele hc ei c iv ctr v i le ule 1000 100speci cenergy wh kg 10 10010 120km h 30km h 60 1000 edisonandtheelectricvehicle li h ev energysourcesfortransportation speci cpower energyrepresentationofvehiclespeedandrange ragone nomajorprogressfrom1913to 1970 thechallengesoflargelithiumbatteries thesolution lifepower c lifepo4 challenges statusoflithium ionbatteries 1234567 speci cenergy wh kg speci cpower w kg cyclability 2000 100 dod safety cellandbatterysystem sustainability environmentcompatibility 10yearslife 30to60oc shocks material manufacturingcosts kwhor kw 3 4timestheleadaciddemonstratedsustained pulse regenpowerachieveddemonstratedatcelllevelachievedatthecelllevelnon toxicandavailableelements recycling materialthermal chemical physicalstability components design processoptimizationneedthebene toflargescaleproduction c lifepo4andli batteries phostech shistoryandip phostechproductsandprocesses lifepower customersandapplications challengesandopportunities phostech sadvancedc lifepo4 historyparti phostech shistoryandip historypartii 2006200720082009 phostech2ndmanufacturingplant p1 inqu bec st bruno s d chemieacquiressgfsharesintophostechaftersgfdeclinesitsoptiontoinvestina2400t ymanufacturingplantincandiacphostechcontractsengineeringstudytogenivarfora2400t yp2plantandpurchasesgreenfieldincandiactobuildplants d chemiebecomes100 ownerofphostechapplicationtoinvestissementqu becforthep2plant delayed phostech crsngsupportanindustrialchairatudemapplicationtosdtcforthecandiacplant postponed doeputsinplacea2 4b grant evbatteryandcomponentmanufacturinginitiative phostech shistoryandipphostech1stmanufacturingplant p1 inqu bec boucherville 2005s d chemie1stinvestmentintophostech ep1049182ep1796189ca2 307 119 1 23 jpexaminationcore3 carbondeposit2 hq udm cnrsco ownership us7 457 018kr100879839cn100421289 jp epandcaexaminationnecessary freetooperate lifepo4materialip multicore material intellectualpropertycore1 lifepo4 hq ut us5 910 382c1us6 514 640c1ca2 251 709ep0904607core2 carbondeposit1 acep udm cnrsco ownership us6 962 666us7 344 659 successfulreexaminationofus5 910 382 lifepo4applicationascathodematerials successfulreexaminationofus6 514 640 optionallydoped mg nb intellectualpropertyimportantmilestone ippositionreinforcedafterpositivereexamination dr johnbannistergoodenough lithiummetalphosphatecathodeinventorjapanprize2001forhisworksonbatteriesu s presidentialenricofermiaward 2009 professorattheuniversityoftexasataustin pyrolysisofmostorganicmaterialsduringorafterlifepo4synthesisleavesaconductivecdepositorganicprecursorcanbesolid liquidorgas co carbondepositisbondedon elementaryparticlesoronagglomerates c lifepo4pcdcontrolssinteringandhelpspreservefeprecursororlifepo4size shape e g 50nmto15 200nmlifepo4 100nmcarbondeposit 2 agglomerate pyrolyticcarbondeposit pcd pyrolyticcarbondeposit pcd symbiosewithlifepo4isthekeytomaterialpower optimalenergyandcyclability nouvelles nergieslachinemalplac edanslecombatdebrevetsurlesbatterieslithiumhttp www bulletins thechineseacademician chenliquan toldsreporterthat inthe eldofthelithiumironphosphatebatteryandmaterials twocorepatentsareimpossibletobypass oneisthecarboncoatingpatent theotheristhecarbothermicreduction thecarboncoatingpatenthasbeenappliedinchinaandphostechisthesolelicensee thecarbon thermicpatentbelongstovalence butisnotappliedinchina citationfrom chinaautomobilenews phostech shistoryandippyrolyticcarbondeposit lifepo4patentisrecognizedinchinaasablockingpatent newippositionfromissuedc lifepo4patents c lifepo4andli batteries phostech sadvancedc lifepo4 phostech shistoryandipsynthetictriphyliteudm 1000ocphostechproductsandprocesseslifepower customersandapplicationschallengesandopportunities triphylite heterosite lifepo4olivinecathodematerial li extractionwithpreservationofstructureandspeci cvolume highcyclestability theoreticalcapacity 169mah gpracticalcapacity 155mah g 10 li surplusincell hightoleranceversusover chargecellvoltage 3 45vvs li metal 3 20vvs graphite lesselectrolyteaging at voltagedischargecurve1 dim li conduction1 dim e conduction lowbulkconductivitylifepo4isthecathodeforlargeli ionandhev lifepower lifepo4marketmainadvantagesphostechlithiumintroducedlifepo4onmarketwithaspeci cbrandname signi cantlymorestableandthereforesaferthanconventionalcathodematerials morecost effectiveasnoveryrareandexpensivecobalt high power fast chargecapabilities widetemperaturetoleranceensuresperformanceat 40 clifepower qualityrecognizedbybatteryindustry phostechproductionprocesses processgradestatus solidstateenergycommercialp1 wetprocesspowercommercialp2 meltalternativep3pilotscale 250t y 2400t ycandiac phostechlithiumcontrolseveralsynthesisprocessestoful llneedsofpresent futurecustomersandmarkets p2 powergradenanosized p1 energygrademicro aggregates phostechcommercialproducts productsareunderdevelopmenttoful llcustomer sneedsstrongr dinvestmenttocontinuouslyimprovedproducts lifepo4processfamilies processestomakelifepo4canbegroupedintotwofamilies phostechhasexpertiseonbothprocessfamilies 1 solidstateprocess ssp 2 liquidphaseprocess lpp mostlifepo4producersareusing sspprocesseswiththeirpros cons afewuselppprocesses usuallywaterbased hydrothermal orsolventassisted butalsomolten lifepo4processfamiliessimpli edrepresentation phostechproducesbothp1andp2commerciallyanddevelopp3 process1 solidstate exemples 2 liquidphase solvent e g h2o 3 liquidphase molten reactionfepo4 li2co3 copolymerfe2o3 li2co3 cfe2c2o4 li2c2o4 li2co3 fe po4 lioh solubles fe po4 li nonspeci c characteristics simplicity onestep reactantcost mixingsolids 100 liquidreactivemedia nanoprecipitation lowcostreactants capitalintensive liquidreactivemedia commodityprices powderization steelindustry p3meltcasting closetowellknownmetallurgicalprocess c lifepo4andli batteries phostech shistoryandip phostechproductsandprocesses lifepower customersandapplications challengesandopportunities phostech sadvancedc lifepo4 korea china japan europe us phostechc lifepo4isusedandevaluatedbynumerouscompanies pt hev phev ev ups phostechlithium otherscustomers current a 1 510 50 uncompromisedqualitykeytosuccesscontinuousdischargeofvl10vfeandvl12vfecellsat25 c750a43 532 52 0 2 4 68 10 12 superphosphatevl10vfeoldervl10vfevl12v capacity ah source saft11thelectrochemicalpowersourcesr dsymposium july2009 closecollaborationwithcustomershelpimproveperformance saft superphosphate lineofbatteries high qualitylifepo4 saftengineering superphosphatebrand 11to40ahcylindricalcells57to132wh kg 0 17to4 5kw kg continuous source saft11thelectrochemicalpowersourcesr dsymposium july2009 wh kg ragoneplotoflifepower cells1301201101009080706050 10 100 1000 10000 w kgk2energysolution market2010 market2010 buildtoorder lifepoweredelectricvehiclesmicrocar lifepower productsexpandsmarketacceptance capacity ah 2 0 500 2000 1000 1500 cyclesanyhesitationforyourhevbatteries howdoeslifepower lfpcomparetonca 10nca100 dod8nca80 dod6lifepo4100 dod4 ifonewanttoachievethesamelifecycleas lfp dodhavetobereducedto80 fornca whichnearlycompensatesfortheenergydensity gapbetweenbothchemistriesoncelllevel 0 capacityloss impedancegain safthighenergycellcalendarlifetesting100 soc45 c 80 70 60 50 40 30 20 10 110 100 90 0 50 100 150 200 250 300 350 400 450 60 50 40 30 20 10 0 10 90 80 70 lifepo4capacityncacapacityllifepo4impedancencaimpedance uncompromisedqualitykeytosuccess dayssource saft11thelectrochemicalpowersourcesr dsymposium july2009 minimalimpedancegrowth everthoughtofthecostofabatteryrecallforaphev costtosonyofali ionbatteriesrecallforlaptopwas 300m howtodiscriminatecathodethermalstability locatedoverthemechanicalventrecords 150 cventgastemperature resultingventspray leftcarbonresidueonthemodulethatwasundamaged undamagedthermocouple mechanicalvent adjacentcellswereundamagedandremainedatfullcharge approximateskintemperaturesreached125 c ventedgas noflame nopropagation highrateoverchargeispossiblythemostabusivetestforli ion highrateoverchargeofonevl10vfecelltestcellinmoduleconfigurationwiththermocouplelocatedoverthe c lifepo4andli batteries phostech shistoryandip phostechproductsandprocesses lifepower customersandapplications challengesandopportunities phostech sadvancedc lifepo4 thechallengeoffutureevmarket highbatterycostamortizeduringwholelifeofev s favorabletcoofev s pro tabilityofbatterypackleasingbusinessimpliedlong lifebatteries highqualitylifepo4businesseconomicstronglylinktoquality tcoreasoningdif culttosoldtoconsumersolution leasingofevand orbatterypack secondlifeofbattery storage thechallengeofthecompeti