有机磷钻井液降粘剂研究与应用科技文献检索课程设计毕业论文.doc

科技文献检索课程设计文献检索与综述题 名: 有机磷型钻井液降粘剂的研究 英文题名:Organic vinyl drilling fluid viscosity of type agent 一、课题分析1、涉及技术领域：TE22钻井设计 、_ TE2钻井工程 、TE石油、天然气工业 _ _（提供涉及的不少于三种的技术领域，并表明该技术领域在中图分类法中的三级分类。）2、研究内容（包括要解决的关键性问题，字数在200-300字之间）：随着钻井液技术的发展,钻井液降粘剂己由无机磷酸盐、有机磷酸盐、磺化褐煤、铁铬木质素磺酸盐FCLS、磺化丹宁SMT发展到了聚合物。聚合物降粘剂具有降粘效果好、抗盐钙污染能力强和热稳定性好等优点,其开发受到了国内外的重视,应用日益广泛一“。为满足提高四川深井气藏钻井速度综合技术的需要,我们研制了聚合物降粘剂PT一1,该剂既可用作聚合物重泥浆降粘剂,又能作为分散泥浆降粘剂。 实验部分 一、PT一1的合成 将计量的顺丁烯二酸醉加入盛有水的反应瓶中,在一定温度下不断搅拌使之溶解,加入乙烯基单体和过氧化物引发剂,在60一90下反应4一8h得到的共聚物水溶液即为产物。钻井液降粘剂PT一1的主要技术指标如下:外观为桔红色透明液体,固含量35肠,1肠水溶液的pH6,20密度1 .20一1 .309/cm“,特性粘数2一3ml/g,对聚合物泥浆的降粘率夕90肠。3、中英文关键词（不得少于3个）：中文关键词：磷、钻井液、降粘剂英文关键词：phosphorus、Drilling fluid、Drop adhesive4、中英文逻辑检索表达式（提供检索表达式的组配方式不少于3种）：中文检索表达式： 磷 and 钻井液 ； 磷 and 降粘剂 ； 钻井液 and 降粘剂 ； 。英文检索表达式： phosphorus and Drilling fluid ； phosphorus and Drop adhesive ； Drilling fluid and Drop adhesive ； 。二、选择检索工具并检索、记录、整理检索结果1、检索工具及检索结果：（1）中国知网之中国学术期刊全文数据库（检索时间范围：2005-2012）检索过程：采用检索表达式，检索结果 5 篇；采用检索表达式，检索结果 2 篇；采用检索表达式，检索结果 69 篇；采用检索表达式，检索结果 篇。检索分析：通过检索结果的比较和分析，该课题的标准检索表达式为： 钻井液 and降粘剂 ，检索结果为 69 篇文献。 二次检索：由于检索的文献的数量比较多，应用检索词 磷 进行进一步限制检索：二次检索后获得检索结果为 0 篇。（2）中文科技期刊全文数据库（检索时间范围：2005-2012）检索过程：采用检索表达式，检索结果 3 篇；采用检索表达式，检索结果 1 篇；采用检索表达式，检索结果 79 篇；采用检索表达式，检索结果 篇。检索分析：通过检索结果的比较和分析，该课题的标准检索表达式为： 钻井液 and 降粘剂 ，检索结果为 79 篇文献。 二次检索：由于检索的文献的数量比较多，应用检索词 磷 进行进一步限制检索：二次检索后获得检索结果为 0 篇。（3）读秀知识库（检索时间范围：2005-2012，检索模式：内容检索）检索过程：采用检索表达式，检索结果 2525 篇；采用检索表达式，检索结果 684 篇；采用检索表达式，检索结果 1243 篇；采用检索表达式，检索结果 篇。检索分析：通过检索结果的比较和分析，该课题的标准检索表达式为： 磷 and钻井液 ，检索结果为 2525 篇文献。 二次检索：由于检索的文献的数量比较多，应用检索词 降粘剂 进行进一步限制检索：二次检索后获得检索结果为 1479 篇。（4）中国优秀硕士/博士论文全文数据库（检索时间范围：2005-2012）检索过程：采用检索表达式，检索结果 496 篇；采用检索表达式，检索结果 482 篇；采用检索表达式，检索结果 20 篇；采用检索表达式，检索结果 篇。检索分析：通过检索结果的比较和分析，该课题的标准检索表达式为： 磷 and 钻井液 ，检索结果为 496 篇文献。 二次检索：由于检索的文献的数量比较多，应用检索词 降粘剂 进行进一步限制检索：二次检索后获得检索结果为 0 篇。（5）中国知识产权局-专利检索（检索时间范围：时间不限）检索过程：采用检索表达式，检索结果 0 篇；采用检索表达式，检索结果 0 篇；采用检索表达式，检索结果 0 篇；采用检索表达式，检索结果 篇。检索分析：通过检索结果的比较和分析，该课题的标准检索表达式为： 钻井液 and 降粘剂 ，检索结果为 0 篇文献。 二次检索：由于检索的文献的数量比较多，应用检索词 磷 进行进一步限制检索：二次检索后获得检索结果为 0 篇。（6）国家科技成果数据库成果检索（检索时间范围：时间不限）检索过程：采用检索表达式，检索结果 1599 篇；采用检索表达式，检索结果 1460 篇；采用检索表达式，检索结果 208 篇；采用检索表达式，检索结果 篇。检索分析：通过检索结果的比较和分析，该课题的标准检索表达式为： 磷 and 钻井液 ，检索结果为 1599 篇文献。 二次检索：由于检索的文献的数量比较多，应用检索词 降粘剂 进行进一步限制检索：二次检索后获得检索结果为 39 篇。爱思唯尔英文期刊全文数据库（Elsevier SD）（检索时间范围：2005-2011）（7）检索过程：采用检索表达式，检索结果 1501 篇；采用检索表达式，检索结果 1527 篇；采用检索表达式，检索结果 727 篇；采用检索表达式，检索结果 篇。检索分析：通过检索结果的比较和分析，该课题的标准检索表达式为： phosphorus and Drop adhesive ，检索结果为 1527 篇文献。 二次检索：由于检索的文献的数量比较多，应用检索词 Drilling fluid 进行进一步限制检索：二次检索后获得检索结果为 102 篇。（8）施普林格学术期刊全文数据库（SPRINGERLINK）（时间范围：2005-2011）检索过程：采用检索表达式，检索结果 216 篇；采用检索表达式，检索结果 360 篇；采用检索表达式，检索结果 177 篇；采用检索表达式，检索结果 篇。检索分析：通过检索结果的比较和分析，该课题的标准检索表达式为： phosphorus and Drop adhesive ，检索结果为 360 篇文献。 二次检索：由于检索的文献的数量比较多，应用检索词 Drilling fluid 进行进一步限制检索：二次检索后获得检索结果为 29 篇。2、文献分析（每种来源数据库摘录文献不得多于两篇）：（1）在所检索文献中，下列文献为综述性文献（不少于3篇）： 题 名：废钻井液的处理技术综述作 者：周迅文献源：【期刊】油气田环境保护摘 要：通过对近年来国内外废钻井液无害化处理方法进行的综合分析,了解了目前处理现状,并在此基础上,详细介绍了水泥、水玻璃;磷石膏;水泥窑粉等固化技术及生物等治理技术。同时对废钻井液的无害化处理及未来的发展趋势进行了展望。来源数据库：中国知网之中国学术期刊全文数据库 题 名：我国钻井液用降粘剂的研究应用现状作 者：张高波； 王善举； 史沛谦文献源：【期刊】油田化学摘 要：本文是根据 80年代中期以来我国发表的期刊文献资料写成的一篇综述 ,分四大类介绍了这一期间研制和开发应用的钻井液降粘剂及对其作用机理的研究。这四大类降粘剂是 :以木质素、栲胶、单宁等天然原料为基础的降粘剂 (13种 ) ;聚合物降粘剂 ,包括含马来酸 (酐 )或丙烯酸的共聚物 (6种 ) ,含磺酸基团的共聚物 (3种 ) ,两性或阳离子型聚合物 (4种 ) ;无机降粘剂 (磷酸盐类 ,有机硅类 ) ;正电胶钻井液降粘剂来源数据库：中国知网之中国学术期刊全文数据库 题 名：钻井液降粘剂作 者：腐植酸 文献源： 腐植酸 2011年第1期 -页,共1页摘 要：申请(专利权)人:成都市川锋化学工程有限责任公司申请日期:2000.02.25申请(专利)号:CN00112708.X主分类号:C09K7/02本发明提供了一种石油天然气钻井作业中所使用的钻井液处理剂。由天然单宁抽提物、褐煤腐植酸抽提物、乙烯基单体和有机胺单体按以下来源数据库：中文科技期刊全文数据库 题 名： 作 者： 文献源： 摘 要： 来源数据库： （2）在所检文献中，下列文献为相关度较高的文献（不少于6篇）： 题 名：钻井液用降粘剂的合成与评价作 者：张民文献源：【硕士】中国石油大学摘 要：石油钻探过程中,随着特殊井、超深井和复杂井数量的增多,钻井深度增加,钻遇地层日趋复杂,特别是在钻遇泥页岩造浆地层钻井液的降粘、降切问题十分突出。作为造纸废弃物的木质素磺酸钙,其再利用具有废弃物资源化利用和环境保护的双重意义。本文通过聚阴离子电解质木质素磺酸钙与非离子单体AM进行接枝共聚反应生成共聚物LSGC。LSGC通过Mannich反应阳离子化,最终制备得到了两性木质素类降粘剂ALSGC。通过室内正交试验和单因素优化实验,确定了合成LSGC和ALSGC的最佳条件,并用特性粘度测定、红外光谱分析和裂解气相色谱-质谱分析表征了LSGC和ALSGC的结构特征。室内评价了ALSGC在各种钻井液泥浆中的降粘效果,分析讨论了ALSGC在各种钻井液泥浆中的降粘规律与机理。室内实验表明,ALSGC具有很好的抗温、抗盐和抗钙性能,抗温达180以上,抗盐可达饱和,在2%的含钙泥浆中仍有较好的降粘效果。通过与同类产品对比可以看出,ALSGC是一种“一剂多效”的降粘剂,既具有分散降粘剂的特性又具有抑制性,可用于高密度钻井液和聚合物不分散钻井液。现场试验结果表明,ALSGC具有与其它处理剂配伍性好、维护周期长及适用于高矿化度、高温条件下降低钻井液粘切等特性。更多来源数据库：中国知网之中国学术期刊全文数据库 题 名：钻井液用抗高温降粘剂的研究动态与进展作 者：向海东文献源：【期刊】中国石油和化工标准与质量摘 要：传统降粘剂(强分散剂)虽能降低钻井液的粘度和切力,但钻井液的稳定周期短,处理频繁,常常诱发井下事故或复杂情况。研究能提高深井钻井速度的高密度钻井液体系和工艺技术一直是国内外深井钻井工艺技术的难点和热点。 来源数据库：中国知网之中国学术期刊全文数据库 题 名：海洋天然气水合物地层钻井的钻井液研究作 者：涂运中文献源：中国地质大学摘 要：天然气水合物是由水分子和天然气分子在一定温度和压力下形成的似冰雪状结晶化合物,又称笼形水合物或“可燃冰”。由于形成天然气水合物的气体主要为甲烷,因而也被称为甲烷水合物。自然界中的天然气水合物主要分布在大陆边缘的海洋深水区和陆上永冻地区,前者占了已发现数量的绝大多数。天然气水合物研究已成为当代地球科学研究和能源工业发展的一大热点,该研究涉及新能源的勘探开发、温室效应、全球碳循环和气候变化、古海洋、海洋地质灾害、天然气储运、油气管道流动安全等,并有可能对地质学、环境科学和能源工业的发展产生深刻的影响。因而世界上许多国家都从各自的关注点对天然气水合物展开了广泛的调查研究。特别是近年来能源短缺日益加剧,油气价格居高不下,使得各国更加关注具有能量密度高、储量大和分布广等特点的天然气水合物,纷纷加大对其勘探和开发研究的力度。对于我国来说,本身油气资源就不足,加之经济的快速发展,导致能源缺口越来越大。因此,从我国能源战略安全和经济可持续发展的角度来说,也应加大天然气水合物勘探开发的力度。 要对赋藏在地下一定深处的天然气水合物进行勘探和开发,钻井是必不可少的重要手段。天然气水合物的相平衡性质决定了此类地层钻井与一般油.来源数据库：中国优秀硕士/博士论文全文数据库 题 名：稠油组分的结构分析及降粘剂的研制作 者：关润伶文献源：北京交通大学摘 要：稠油是指粘度高、相对密度大的原油，由于流动性差，用常规的石油开采技术难以有效开采。通过添加各类流动性改性剂以辅助解决稠油在开采、集输、炼制等过程中的流动性问题， 若改进稠油的流动性即降低稠油的粘度，必须对稠油的化学组成及其结构特点进行深入研究。本文通过紫外光谱与荧光光谱的测试，分析了王庄稠油中胶质、沥青质的主要组份。结果表明，稠油中的胶质和沥青质的主要组份是由芳香结构组成的，是由多环状的复杂组份构成。胶质、沥青质主要含有3-4个芳香环，沥青质含有少量5个芳香环。红外光谱分析结果表明，稠油中的沥青质、胶质存在大量的极性基团，如羟基、胺基、羧基、羰基等，这些极性基团的存在，使原油中胶质分子之间、沥青分子之间及二者相互之间产生强烈的氢键作用，具有很强的极性。稠油中的重质组份胶质和沥青质的结构特点决定了王庄稠油的宏观性质，如粘度高，密度大等。 为了进一步探究王庄稠油粘度大的原因，分别研究了稠油中重金属含量、沥青质含量、胶质含量、温度及稀释剂对稠油粘度的影响。结果表明，重金属V、Ni的含量高是造成王庄原油粘度高的重要因素之一。沥青质的含量对王庄原油的粘度有很大的影响，通过回归分析，稠油的粘度随其中沥青质.来源数据库：中国优秀硕士/博士论文全文数据库 题 名：一种超高温钻井液降粘剂的合成及性能研究作 者：王利民文献源：化学与生物工程摘 要：研究了水基钻井液降粘剂磺化苯乙烯-衣康酸共聚物的合成方法。以N,N-二甲基甲酰胺为溶剂,在衣康酸与苯乙烯摩尔比为11.2、引发剂偶氮二异丁腈用量为0.6%、溶液共聚反应温度为90、共聚反应时间为5 h的条件下,得到苯乙烯-衣康酸共聚物,并用红外光谱对其结构进行了表征。该共聚物与过量20%发烟硫酸在50进行磺化反应2 h,生成降粘剂磺化苯乙烯-衣康酸共聚物（SSHIA）。在淡水钻井液中加入0.3%SSHIA,降粘率可达54%;且在260老化16 h后,降粘率仍达44%。来源数据库：中文科技期刊全文数据库 题 名：抗220高温的水基钻井液用降粘剂研究作 者：黄进军 蒲晓林 李建波 李春霞文献源：油田化学 CA CSCD 2003年第3期摘 要：根据已知分子设计理论，通过水溶液引发聚合，控制分子量在1010310104范围，制得了丙烯酸丙烯磺酸2-甲基-2-丙烯酰胺基丙磺酸小阳离子单体共聚物，推荐用作钻井液降粘剂，代号THIN。THIN可抗220高温，抗盐(NaCl)达320gL，抗钙(以CaCl2计)10gL，在水基粘土钻井液特别是高固相高密度钻井液中降粘效果优于常用降粘剂XY27和FCLS。THIN水溶液相对粘度在150老化后增大，在180和220老化后略有减小(老化16h)。THIN，XY27和FCLS的盐析浓度分别为324，200和270，析出沉淀时CaCl2浓度分别为10；005和50gL。在220滚动(16h)前后，05THIN在80淡水泥浆中的各项流变性(50)，均优于XY27和FCLS，THIN加量05即可使泥浆粘度和切力大幅度降低，且对老化后泥浆有降滤失作用；10THIN在高固相泥浆特别是高固相高密度泥浆中的降粘效果，从50下的AV，PV和Gel 1min看，均优于相同加量的XY27和FCLS.表5参3来源数据库：中文科技期刊全文数据库（3）在所检文献中，下列文献为英文文献（不少于3篇） 题 名：International Journal of Adhesion and Adhesives 作 者：R.P. Narain, D. Kumar 文献源：University of Gorakhpur, India摘 要：By the reaction of phosphorus oxychloride, thiophosphoryl chloride and phosphorus trichloride with tetraethoxysilane, compounds containing SiOP linkages have been synthesized. The adhesive properties of these compounds have been measured. A probable mechanism for their formation is also suggested来源数据库：爱思唯尔英文期刊全文数据库（Elsevier SD） 题 名：Novel tetrapotassium azo diphosphonate (INAZO) as flame retardant for polyurethane adhesives 作 者：Teija Tirria, Melanie Auberta, Carl-Eric Wilna, , , Rudolf Pfaendnerb, Holger Hoppe 文献源：/10.1016/j.polymdegradstab.2011.12.005, How to Cite or Link Using DOI Cited by in Scopus (0)摘 要：An inorganic azo diphosphonate (INAZO), (KO)2(O)P-NN-P(O)(OK)24H2O, was synthesized and tested as a novel type of flame retardant additive forcastor oil and oligomeric methylene diphenyl diisocyanate (PMDI) based two component polyurethane adhesive with or without using dolomite (CaMg(CO3)2) as filler. Flammability according to UL 94 test and performance under forced-flaming conditions (cone calorimeter) were investigated at the additive loadings of 5, 10 and 20wt %. It was shown that INAZO improves flame retardancy by significantly reducing heat release rate (HRR), maximum average rate of heat emission (MARHE) and total smoke release (TSR) values in comparison to CaMg(CO3)2 filled polyurethane adhesives. The macroscopic structure of the sample residues after cone calorimeter measurement was also analysed. The action mechanism of the developed INAZO flame retardant is suggested to be mainly in the condensed phase. UL 94 V-0 rating was achieved in the vertical burning test when 10wt % loading of INAZO was used, whereas the reference flame retardant ammonium polyphosphate (APP) required a loading of 20wt % to reach the V-0 classification来源数据库：爱思唯尔英文期刊全文数据库（Elsevier SD） 题 名：Adhesive/Dentin Interface: The Weak Link in the Composite Restoration作 者：Paulette Spencer, Qiang Ye, Jonggu Park, Elizabeth M. Topp, Anil Misra, Orestes Marangos, Yong Wang, Brenda S. Bohaty, Viraj Singh and Fabio Sene文献源：From the issue entitled Special Issue: Interfacial Bioengineering; Guest Editor: Michael Detamore摘 要：Results from clinical studies suggest that more than half of the 166 million dental restorations that were placed in the United States in 2005 were replacements for failed restorations. This emphasis on replacement therapy is expected to grow as dentists use composite as opposed to dental amalgam to restore moderate to large posterior lesions. Composite restorations have higher failure rates, more recurrent caries, and increased frequency of replacement as compared to amalgam. Penetration of bacterial enzymes, oral fluids, and bacteria into the crevices between the tooth and composite undermines the restoration and leads to recurrent decay and premature failure. Under in vivo conditions the bond formed at the adhesive/dentin interface can be the first defense against these noxious, damaging substances. The intent of this article is to review structural aspects of the clinical substrate that impact bond formation at the adhesive/dentin interface; to examine physico-chemical factors that affect the integrity and durability of the adhesive/dentin interfacial bond; and to explore how these factors act synergistically with mechanical forces to undermine the composite restoration. The article will examine the various avenues that have been pursued to address these problems and it will explore how alterations in material chemistry could address the detrimental impact of physico-chemical stresses on the bond formed at the adhesive/dentin interface.来源数据库：Hydroxyapatite Ca10(PO4)6(OH)2 has attracted widespread interest from both orthopedic and dental fields due to its excellent biocompatibility and tissue bioactivity properties. Since nanophase materials can mimic the dimensions of constituent components of natural tissues, the implants developed from nanophase material could serve as a successful alternative. However, the defects of hydroxyapatite ceramics, mainly brittleness and low fracture toughness, have been overcome by the use of nanophase hydroxyapatite coatings on the implant surfaces that integrate the good mechanical properties of metals and the bioactivity of hydroxyapatite. In the present investigation, Solgel hydroxyapatite was prepared from two different phosphorus precursors such as triethyl phosphate and phosphorus pentoxide respectively with calcium nitrate tetrahydrate as a calcium precursor. The effects of pH and liquid P31 Nuclear Magnetic Resonance spectroscopy for the solution aged at different periods were investigated and the synthesized hydroxyapatite powder was characterized by Transmission electron microscopy, X-ray Powder Diffraction, Fourier transform infrared spectroscopy and thermal analysis respectively. In order to fully understand the bioactivity of the synthesized materials, they were coated on 316L Stainless Steel implant surface by spin coating method at the spin speed of 2,000 Revolutions per minute. The effect of nanoparticles on the surface of 316L Stainless Steel implant was studied by adhesive strength measurements. The corrosion resistance property of the hydroxyapatite coatings was evaluated by electrochemical impedance analysis. From the results, it was observed that the hydroxyapatite coatings obtained from different precursors have very high resistance to corrosion with higher adhesive strength三、英文文献摘要及翻译1、密切相关英文文献： 题 名：Influence of process parameters on the solgel synthesis of nano hydroxyapatite using various phosphorus precursors作 者：U. Vijayalakshmi and S. Rajeswari文献源：The International Sol Gel Society摘 要：Hydroxyapatite Ca10(PO4)6(OH)2 has attracted widespread interest from both orthopedic and dental fields due to its excellent biocompatibility and tissue bioactivity properties. Since nanophase materials can mimic the dimensions of constituent components of natural tissues, the implants developed from nanophase material could serve as a successful alternative. However, the defects of hydroxyapatite ceramics, mainly brittleness and low fracture toughness, have been overcome by the use of nanophase hydroxyapatite coatings on the implant surfaces that integrate the good mechanical properties of metals and the bioactivity of hydroxyapatite. In the present investigation, Solgel hydroxyapatite was prepared from two different phosphorus precursors such as triethyl phosphate and phosphorus pentoxide respectively with calcium nitrate tetrahydrate as a calcium precursor. The effects of pH and liquid P31 Nuclear Magnetic Resonance spectroscopy for the solution aged at different periods were investigated and the synthesized hydroxyapatite powder was characterized by Transmission electron microscopy, X-ray Powder Diffraction, Fourier transform infrared spectroscopy and thermal analysis respectively. In order to fully understand the bioactivity of the synthesized materials, they were coated on 316L Stainless Steel implant surface by spin coating method at the spin speed of 2,000 Revolutions per minute. The effect of nanoparticles on the surface of 316L Stainless Steel implant was studied by adhesive strength measurements. The corrosion resistance property of the hydroxyapatite coatings was evaluated by electrochemical impedance analysis. From the results, it was observed that the hydroxyapatite coatings obtained from different precursors have very high resistance to corrosion with higher adhesive strength来源数据库：Hydroxyapatite Ca10(PO4)6(OH)2 has attracted widespread interest from both orthopedic and dental fields due to its excellent biocompatibility and tissue bioactivity properties. Since nanophase materials can mimic the dimensions of constituent components of natural tissues, the implants developed from nanophase material could serve as a successful alternative. However, the defects of hydroxyapatite ceramics, mainly brittleness and low fracture toughness, have been overcome by the use of nanophase hydroxyapatite coatings on the implant surfaces that integrate the good mechanical properties of metals and the bioactivity of hydroxyapatite. In the present investigation, Solgel hydroxyapatite was prepared from two different phosphorus precursors such as triethyl phosphate and phosphorus pentoxide respectively with calcium nitrate tetrahydrate as a calcium precursor. The effects of pH and liquid P31 Nuclear Magnetic Resonance spectroscopy for the solution aged at different periods were investigated and the synthesized hydroxyapatite powder was characterized by Transmission electron microscopy, X-ray Powder Diffraction, Fourier transform infrared spectroscopy and thermal analysis respectively. In order to fully understand the bioactivity of the synthesized materials, they were coated on 316L Stainless Steel implant surface by spin coating method at the spin speed of 2,000 Revolutions per minute. The effect of nanoparticles on the surface of 316L Stainless Steel implant was studied by adhesive strength measurements. The corrosion resistance property of the hydroxyapatite coatings was evaluated by electrochemical impedance analysis. From the results, it was observed that the hydroxyapatite coatings obtained from different precursors have very high resistance to corrosion with higher adhesive s