氟硼酸钠MSDS英文.doc

Sodium tetrafluoroborate (cas13755-29-8) MSDSSAFETY DATA SHEETaccording to Regulation (EC) No. 1907/2006Version 5.2 Revision Date 20.03.2014Section 1 - Chemical Product MSDS Name:Sodium tetrafluoroborate Synonym:Sodium fluoboratSection 2 - HAZARDS IDENTIFICATION Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.Skin:Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.Ingestion:Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.Inhalation:Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.Notes to Physician:Risk Phrases: 34Hazard Symbols: CSecurity term S25; S36/37/39; S45Section 3 - COMPOSITION, INFORMATION ON INGREDIENTS3.1 SubstancesSynonyms : Sodium fluoroborateFormula : BF4NaMolecular Weight : 109,79 g/molCAS-No. : 13755-29-8EC-No. : 237-340-6Hazardous ingredients according to Regulation (EC) No 1272/2008Component Classification ConcentrationSodium tetrafluoroborateCAS-No. 13755-29-8 Skin Corr. 1B; H314 = 100 %EC-No. 237-340-6Hazardous ingredients according to Directive 1999/45/ECComponent Classification ConcentrationSodium tetrafluoroborateCAS-No. 13755-29-8 C, R34 = 100 %EC-No. 237-340-6For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.Skin:Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.Ingestion:Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.Inhalation:Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.Notes to Physician:Section 5 - FIRE FIGHTING MEASURES General Information:5.1 Extinguishing mediaSuitable extinguishing mediaUse water spray, alcohol-resistant foam, dry chemical or carbon dioxide.5.2 Special hazards arising from the substance or mixtureno data available5.3 Advice for firefightersWear self contained breathing apparatus for fire fighting if necessary.5.4 Further informationno data availableSection 6 - ACCIDENTAL RELEASE MEASURES General Information: 6.1 Personal precautions, protective equipment and emergency proceduresUse personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensureadequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.For personal protection see section 8.6.2 Environmental precautionsDo not let product enter drains.6.3 Methods and materials for containment and cleaning upPick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closedcontainers for disposal.Section 7 - HANDLING and STORAGE Handling:Avoid contact with eyes, skin, and clothing. Do not breathe dust, vapor, mist, or gas. Use and store under nitrogen. Use only in a chemical fume hood.Storage:Store in a cool, dry place. Store in a tightly closed container.Corrosives area.Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls:Appropriate engineering controlsHandle in accordance with good industrial hygiene and safety practice. Wash hands before breaks andat the end of workday.Personal protective equipmentEye/face protectionFace shield and safety glasses Use equipment for eye protection tested and approved underappropriate government standards such as NIOSH (US) or EN 166(EU).Skin protectionHandle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching gloves outer surface) to avoid skin contact with this product. Dispose ofcontaminated gloves after use in accordance with applicable laws and good laboratory practices.Wash and dry hands.The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC andthe standard EN 374 derived from it.Full contactMaterial: Nitrile rubberMinimum layer thickness: 0,11 mmBreak through time: 480 minMaterial tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)Splash contactMaterial: Nitrile rubberMinimum layer thickness: 0,11 mmBreak through time: 480 minMaterial tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail saleskcl.de,test method: EN374If used in solution, or mixed with other substances, and under conditions which differ from EN 374,contact the supplier of the CE approved gloves. This recommendation is advisory only and mustbe evaluated by an industrial hygienist and safety officer familiar with the specific situation ofanticipated use by our customers. It should not be construed as offering an approval for anyspecific use scenario.Body ProtectionComplete suit protecting against chemicals, The type of protective equipment must be selectedaccording to the concentration and amount of the dangerous substance at the specific workplace.Respiratory protectionWhere risk assessment shows air-purifying respirators are appropriate use a full-face particlerespirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineeringcontrols. If the respirator is the sole means of protection, use a full-face supplied air respirator. Userespirators and components tested and approved under appropriate government standards suchas NIOSH (US) or CEN (EU).Control of environmental exposureDo not let product enter drains.Section 9 - PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical propertiesa) Appearance Form: crystallineColour: colourlessb) Odour no data availablec) Odour Threshold no data availabled) pH no data availablee) Melting point/freezing point 384 Cf) Initial boiling point and boiling range no data availableg) Flash point not applicableh) Evapouration rate no data availablei) Flammability (solid, gas) no data availablej) Upper/lower no data availableflammability or explosive limitsk) Vapour pressure no data availablel) Vapour density no data availablem) Relative density 2,47 g/mL at 25 Cn) Water solubility solubleo) Partition coefficient: noctanol/water no data availablep) Auto-ignition temperature no data availableq) Decomposition temperature no data availabler) Viscosity no data availables) Explosive properties no data availablet) Oxidizing properties no data available9.2 Other safety informationBulk density 720 kg/m3Section 10 - STABILITY AND REACTIVITY Chemical Stability:Not available.Conditions to Avoid:Exposure to moist air or water.Incompatibilities with Other Materials:Strong bases, water, strong oxidizing agents, sensitive to moisture Hazardous Decomposition Products:Hydrogen fluoride gas, oxides of boron, sodium oxide, fluoride fumes.Hazardous Polymerization: Has not been reported.Section 11 - TOXICOLOGICAL INFORMATION RTECS#:CAS# 13755-29-8: ED2975000 LD50/LC50:Not available.Carcinogenicity:Sodium tetrafluoroborate, 98% - Not listed by ACGIH, IARC, or NTP.Other:See actual entry in RTECS for complete information.Section 12 - ECOLOGICAL INFORMATION12.1 Toxicityno data available12.2 Persistence and degradabilityno data available12.3 Bioaccumulative potentialno data available12.4 Mobility in soilno data available12.5 Results of PBT and vPvB assessmentPBT/vPvB assessment not available as chemical safety assessment not required/not conducted12.6 Other adverse effectsno data availableSection 13 - DISPOSAL CONSIDERATIONS 13.1 Waste treatment methodsPr