msds 合成树脂 711F(无三苯).doc

物 品 安 全 资 料 表Product Safety Data Sheet一、物品名称与厂商资料Identification of the substance/preparation and company物品名称Product Information: 无三苯PVC处理剂 Primer物品编号Product Number:PVC711F制造商或供应商名称地址及电话Information on Producer/Supplier Name, Addresses Phone:广东南海霸力化工制品有限公司BALI Chemical Co., LTD南海里水沙涌工业区Sachong District Lishui Nanhai Guangdong Provice/Tel急电话/传真Emergency phone/Fax:0757-85635944制表单位Make Unit名称Name：品管部 QC department.制表人：Lister：何云帆HE YUN FAN制表日期：Make Date：2010/5/18May,2010文件类别Document type非控制文件Uncontrolled Document二、成分辨识资料Composition/Information on Ingredients纯物质Single中英文名称English Name: 合成树脂 Synthetic Resin化学文摘社登记号码Chemical Abstracts Number(CAS No.):N/A危害物质成分百分比Percentage for Chemical Ingredient(%): 95混合物Mixing:化学性质 Chemical Character危害物质成份Hazardous Components化学式Chemical Formula含量(成分百分比)%Content(Percentage)危规号Number of Hazard聚氨酯树脂Ployurethane2.0%3.0%32196丙酮AcetoneC3H6O10%30%31025丁酮MEKC4H8O15%35%32073环己酮CyclohexanoneC6H10O15%35%32163三、危害辨识资料Hazard Identification:最重要危害效应Major hazard effect*健康危害效应Hazard Warning For Health:1. 头痛、晕眩、困倦、呕吐。1. Headache dizziness drowsiness and vomit.2. 眼睛、鼻子、喉咙之刺激感。2May imitate eyes skin and to respiratory tract.*环境影响：空气污染和水源污染。 Hazard warnings for Environment: Air pollution and water pollution.*物理性及化学性危害Physical and Chemical Danger:易燃性Flammable.特殊性及化学性危害Special Harm; 易燃 Flammable.主要症状：在浓度高为200ppm的环境下8小时，会引起疲劳，虚弱和头昏目眩Major state: 200ppm for 8 hours may result in fatigue weakness and dizziness.在浓度为600ppm的环境下8小时，会引起兴奋、头痛、头晕和恶心。600ppm for 8 hour may result in excitation, headache, dizziness and nausea.如果接触眼睛会有刺激，但48小时后会恢复。If contact with eyes may cause irritation but will recover in 48 hours. 物品危害分类： Hazard category:四、急救措施First Aid Measures不同暴露途径之急救方法Emergency and first aid procedure *吸入: 移至空气清新处，若呼吸停止，应进行人工呼吸，保持温暖，尽速送医院治疗。Inhalation: remove to well-ventilated area if breathing is difficult, supply artificial. Respiration. If not breathing, institute CPR and get medical advice. *皮肤接触:用肥皂或温和的清洁剂及水清洗，去除污染衣物，若刺激仍在应立即送医。Skin contact: remove contaminated clothing immediately flush the contaminated skin With soap and water. Get medical attention.*眼睛接触:用大量清水冲洗，偶尔翻开眼睑，若刺激仍在，应立即送医。Eye contact: immediately flush with water. Get medical attention.*食入:用水漱口，饮足量温水，不要催吐，应立即送医。Ingestion: do not induce vomiting. Seek urgent medical advice.最重要症状及危害效应：Major Disease And Harm Effect对急救人员之防护：穿戴供压式或正压式全面自压呼吸器。First-aid personal protection: Wear respirator, rubber gloves, goggles and protective clothing.对医师之提示：Prompt to doctor: 五、灭火措施Fire Fighting Measure适用灭火剂：二氧化碳，化学干粉，泡沫灭火器。 Suitable extinguishing media: carbon dioxide. dry chemical foam.灭水时可能遭遇之特殊危害：产生一氧化碳。Special exposure hazards: Formation of carbon monoxide.特殊灭火程序Special extinguishing procedure: None.消防人员之特殊防护设备：穿戴防毒面具和防火衣物。 Special protection equipment: Wear respiratory protection equipment and fireproof clothes. 六、泄漏处理方法Accidental Release Measures个人应注意事项：穿戴供压式或正压式全面自动式呼吸器。 Personal protection: Keep people without protective equipment away.环境注意事项：保持泄漏地区的通风和移开热源及火源。Environmental protection: keep away from sources of ignition.清理方法：尽可能回收沙子,锯屑等吸收外泄物,并避免流入下水道以免阻塞。Methods for cleaning up: Absorb the spilt liquid with tissue paper or sand, or collect it back for reuse. Prevent entry into the sewage system, risk of blockage due to polymer deposits. 七、安全处理与储存方法Handling and Storage 处置：应在良好的通风处并有保护装置的情况下操作。 Handling: keep ventilation well and wear protective equipment.储存：存储凉，干燥、通风好的地区，远离火源，热源、气化剂。 Storage: keep ventilation well and keep away from sources of ignition.八、暴露预防措施Exposure Control/Personal Protection工程控制：Engineering control:控制参数：Control factor:*八小时日时量平均容许浓度/短时间时量平均容许浓度/最高容许浓度物质：Substances8小时日时量平均容许浓度TWA短时间时量平均容许浓度STEL最高容许浓度CEILING丙酮:Acetone400 mg/m3丁酮:MEK250 mg/m3碳酸二甲酯DMC500 mg/m3*生物指标Biotic index:丙酮Acetone:LD50（rat）Oral: 510ml/kg丁酮:MEKLD50（mouse）Oral:3980mg/kg碳酸二甲酯DMCLD50（mouse）Oral:6500mg/kg个人防护设备：Personal protection equipment:*呼吸防护Respiratory protection：戴防护口罩。Wear air- supplied respirator*手部防护Hand protection：戴手套。Wear goggles*眼睛防护Eye protection:戴防毒面具。Wear goggles*皮肤及身体防护Skin& body protection：穿防护衣。Wear protective clothing.卫生措施：遵循一般防范措施，衣物被污染须立即更换，工作后洗手。Hygiene procedures: Observe the common precautionary measures, contaminated clothes must be changed immediately. Wash hands after work is completed. 九、物理及化学性质Physical and Chemical Properties/Characteristics物质状态：无色透明液体。Appearance: Colorless liquid.形状:液态Form : liquid颜色:无色Color: Colorless气味：酮类气味 Odor: Ketone odor.Ph值PH value：沸点/沸点范围：5680Boiling Point/Boiling Range：5680分解温度：Decomposition. Temperature:闪火点Flash Point：-10-5.6测试方法Test Method:开杯Open Cup 闭杯Closed Cup自燃温度：Ignition temperature:420爆炸界限Explosion Limits：1.8112.8%蒸汽密度: vapor density:2.0-3.0饱和蒸汽：vapor pressure: 72-170mmHg psi相对密度（水=1）relative gravity 0.80.9g/ml溶解度：不溶于水solubility in water insoluble 十、安定性及反应性Stability and Reactivity安定性:stability 正常情况下安定：Stable特殊状况下可能之危害反应:Special conditions of hazardous reaction应避免之状况：远离火源。Conditions to avoid: Keep away from flame.应避免之物质：Incompatibility 强氧化剂 strong oxidizer.危害分解性：着火时释放出有毒蒸汽和气体。Hazardous decomposition products: when ignited produce toxic vapor and gas.十一、毒性资料Toxicological Information急毒性：Acute toxicity:吸入：可能引致呼吸系统不适，咳嗽。过久或重复吸入可引致过敏。INHALATION:May irritation to respiratory tract Exposure to high concentrations may result in cough prolonged or repeated inhalation may cause allergy.皮肤接触：对皮肤产生刺激。SKIN: May irritate skin.眼睛接触：对眼睛产生刺激。EYES: May irritate eyes吞食：引起刺激、无力、头痛、头晕。INGESTION: May cause irritation, weakness and headache, dizziness局部效应 Local effects:致敏感性Sensitive:慢毒性或长期毒性：神经系统障碍、迟缓。Chronic: Nervous breakdown.特殊效应 Exceptional effect:十二、生态资料Ecological Information可能之环境影响/环境流布：污染水源、勿排入河川、沟渠或地表。Possibility of Environmental Impact/Move: Hazardous to water, must not enter waters, drains