部分有机化合物在TCD上的校正因1.doc

附录四 部分有机化合物在TCD上的校正因子载气：H2 基准物：苯化合物SMSmfMfm化合物SMSmfMfm甲烷0.3571.732.800.581-丁烯0.811.131.230.88乙烷0.5121.331.960.75反-2-丁 烯0.851.191.180.84丙烷0.6451.161.550.86顺-2-丁 烯0.871.221.150.82丁烷0.8511.151.180.873-甲基-1-丁烯0.991.101.010.91戊烷1.051.140.950.882-甲基-1-丁烯0.991.101.010.91己烷1.231.120.810.891-戊烯0.991.101.010.91庚烷1.431.120.700.89新戊烷0.991.081.010.93辛烷1.601.090.630.922，2-二甲基丁烷1.161.050.860.95壬烷1.771.080.570.932，3-二甲基丁烷1.161.050.860.95癸烷1.991.090.500.922-甲基戊烷1.201.090.830.92十一烷1.980.990.511.013-甲基戊烷1.191.080.840.93十四烷2.340.920.421.092，2-二甲基戊烷1.331.040.750.96C20-C361.090.922，4-二甲基戊烷1.291.010.780.99异丁烷0.821.101.220.12，3-二甲基戊烷1.351.050.740.95异戊烷1.021.100.980.913，5-二甲基戊烷1.331.040.750.96丙烯0.651.201.540.832，2，3-三甲基丁烷1.291.010.78.99异丁烯0.821.141.220.882-甲基己烷1.361.060.740.943-甲基己烷1.331.040.750.96乙基苯1.290.950.781.053-乙基戊烷1.311.020.760.98间二甲苯1.310.960.761.042，2，4-三甲基戊烷1.471.010.680.99对二甲苯1.310.960.761.04乙烯0.481.342.080.75邻二甲苯1.270.930.791.081-甲基四氢萘1.580.840.631.19异丙苯1.420.920.701.091-乙基四氢萘1.700.830.591.20正丙苯1.450.950.691.05反十氢化萘1.500.850.671.181，2，4-三甲苯1.500.980.671.02顺十氢化萘1.510.860.661.161，2，3-三甲苯1.490.970.671.03环戊烷0.971.091.030.92对-乙基甲苯1.500.980.671.02甲基环戊烷1.151.070.870.931，3，5-三甲苯1.490.970.671.031，1-二甲基环戊烷1.240.990.811.01仲丁苯1.580.920.631.09乙基环戊烷1.261.010.790.99联二苯1.690.860.591.16反-2-戊烯1.041.160.960.86邻三联苯2.170.740.461.35顺-2-戊烯0.981.101.020.91间三联苯2.300.780.431.282-甲基-2-戊烯0.961.041.040.96对三联苯2.240.760.451.322，4，4-三甲基-1-戊烯1.581.100.630.91三苯甲烷2.320.740.431.35丙二烯0.531.031.890.97萘1.390.840.721.191，3-丁二烯0.801.161.250.86四氢萘1.450.860.691.16环戊二烯0.680.811.471.23叔丁醇0.961.021.040.982-甲基-1，3-丁二烯0.921.061.090.94顺-1，2-二甲基环戊烷1.251.000.801.001-甲基环己烯1.150.930.871.07反-1，3-二甲基环戊烷1.251.000.801.00甲基乙炔0.581.131.720.88顺-1，3-二甲基环戊烷1.251.000.801.00双环戊二烯0.760.781.321.28顺-1，反-2，顺-4-三甲基环戊烷1.360.950.741.054-乙烯基环己烯1.300.940.771.07顺-1，顺-2，反-4-三甲基环戊烷1.431.000.701.00环戊烯0.800.921.251.09环己烷1.141.060.880.94降冰片烯1.130.940.891.06甲基环己烷1.200.950.831.05降冰片二烯1.110.950.901.051，1-二甲基环己烷1.410.980.711.02环庚三烯1.040.880.961.141，4-二甲基环己烷1.461.020.680.981，3-环辛二烯1.270.910.791.10乙基环己烷1.451.010.690.991，5-环辛二烯1.310.950.761.05正丙基环己烷1.580.980.631.021，3，5，7-环辛四烯1.140.860.881.161，1，3-三甲基环己烷1.390.860.721.16环十二碳三烯（反，反，反）1.680.810.601.23氩0.420.822.380.86环十二碳三烯1.530.730.651.37氮0.421.162.380.86苯1.001.001.001.00氧0.400.982.501.02甲苯1.160.980.861.02二氧化碳0.480.852.081.18一氧化碳0.421.162.380.86乙酸乙丙脂1.210.930.831.08四氯化碳1.080.550.931.82乙酸正丁脂1.350.910.741.10羟基铁【Fe(CO)5】1.500.600.671.67乙酸正戊脂1.460.880.681.141.硫化氢0.380.882.631.14乙酸异戊脂1.450.870.691.10水0.331.423.300.70乙酸正庚脂1.700.840.591.19丙酮0.861.151.160.87乙醚1.101.160.910.86甲乙酮0.981.051.020.95异丙醚1.300.990.771.01二乙酮1.101.000.911.00正丙醚1.311.000.761.003-己酮1.230.960.811.04正丁醚1.600.960.631.042-己酮1.301.020.770.98正戊醚1.830.910.551.103,3-二甲基-2-丁酮1.180.810.851.23乙基正丁基醚1.300.990.771.01甲基正戊基酮1.380.910.751.102,5-己二醇1.270.840.791.19甲基正己基酮1.470.900.681.111,6-己二醇1.210.800.831.25环戊酮1.060.990.941.011,10-癸二醇1.080.480.932.08环己酮1.250.990.801.011,12-十二醇1.100.490.912.042-壬酮1.610.930.621.07正丁胺1.141.220.880.82甲基异丁基酮1.180.910.851.10正戊胺1.521.370.660.73甲基异戊基酮1.380.940.921.06正己胺1.040.800.961.25甲醇0.551.341.820.75吡咯0.861.001.161.00乙醇0.721.221.390.82二氢吡咯0.830.941.201.06丙醇0.831.091.200.92四氢吡咯0.911.001.091.00异丙醇0.851.101.180.91吡啶1.000.991.001.01正丁醇0.951.001.051.001，2，5，6-四氯吡啶1.030.960.971.04异丁醇0.961.021.040.98呱啶1.020.940.981.06仲丁醇0.971.031.030.97丙烯腈0.781.151.280.871-丙硫醇1.011.040.990.96丙腈0.841.201.190.833-甲基-1-戊醇1.070.980.931.02正丁腈1.051.190.950.842-戊醇1.100.980.911.02苯胺1.140.950.881.053-戊醇1.090.960.921.04喹啉1.941.160.520.862-甲基-2-丁醇1.060.940.941.06四氢呋喃0.830.901.201.11正己醇1.180.900.851.11噻吩烷1.030.910.971.093-己醇1.250.980.801.02硅酸乙酯2.080.790.481.272-己醇1.301.020.770.98乙醛0.651.151.540.87正庚醇1.280.860.781.162-乙氧基乙醇1.070.930.931.08癸醇-51.840.910.541.101-氟己烷1.240.930.811.08十二烷-2-醇1.980.840.511.191-氯丁烷1.110.940.901.06环戊醇1.090.990.921.012-氯丁烷1.090.910.921.10环己醇1.120.880.891.141-氯-2-甲基丙烷1.080.910.931.10乙酸乙酯1.110.990.901.012-氯-2-甲基丙烷1.040.880.961.14甲醇0.551.341.820.75吡咯0.861.001.161.00乙醇0.721.221.390.82二氢吡咯0.830.941.201.06丙醇0.831.091.200.92四氢吡咯0.911.001.091.00异丙醇0.851.101.180.91吡啶1.000.991.001.01正丁醇0.951.001.051.001，2，5，6-四氯吡啶1.030.960.971.04异丁醇0.961.021.040.98呱啶1.020.940.981.06仲丁醇0.971.031.030.97丙烯腈0.781.151.280.871-丙硫醇1.011.040.990.96丙腈0.841.201.190.833-甲基-1-戊醇1.070.980.931.02正丁腈1.051.190.950.842-戊醇1.100.980.911.02苯胺1.140.950.881.053-戊醇1.090.960.921.04喹啉1.941.160.520.862-甲基-2-丁醇1.060.940.941.06四氢呋喃0.830.901.201.11正己醇1.180.900.851.11噻吩烷1.030.910.971.093-己醇1.250.980.801.02硅酸乙酯2.080.790.481.272-己醇1.301.020.770.98乙醛0.651.151.540.87正庚醇1.280.860.781.162-乙氧基乙醇1.070.930.931.08癸醇-51.840.910.541.101-氟己烷1.240.930.811.08十二烷-2-醇1.980.840.511.191-氯丁烷1.110.940.901.06环戊醇1.090.990.921.012-氯丁烷1.090.910.921.10环己醇1.120.880.891.141-氯-2-甲基丙烷1.080.910.931.10乙酸乙酯1.110.990.901.012-氯-2-甲基丙烷1.040.880.961.141-氯戊烷1.230.910.811.101,1-二氯乙烷1.030.810.971.231-氯己烷1.340.870.751.141,2-二氯丙烷1.120.770.891.301-氯庚烷1.470860.681.16顺-1,2-二氯乙烯1.000.811.001.23溴代乙烷0.980.701.021.432-3-二氯丙烯1.100.770.911.301-溴丙烷1.080.680.931.47三氯乙烯1.150.690.871.452-溴丙烷1.070.680.931.47氟代苯1.050.850.951.181-溴丁烷1.190.680.841.47间二氟代苯1.070.730.931.372-溴丁烷1.160.660.861.52邻氟代甲苯1.160.830.861.201-溴-2-甲基丙烷1.150.660.871.52反十氢喹啉1.170.660.851.511-溴戊烷1.280.660.781.52正十氢喹啉1.170.660.851.51碘代甲烷0.960.531.041.89氨0.401.862.50.54碘代乙烷1.060.530.941.89环氧乙烷0.581.031.720.971-碘丙烷1.170.540.851.85环氧丙烷0.801.071.250.931-碘丁烷1.290.550.781.82硫化氢0.380.882.631.142-碘丁烷1.230.520.811.92甲硫醇0.590.961.691.041-碘-2-甲基丙烷1.220.520.821.92乙硫醇0.871.091.150.921-碘丙烷1.380.550.731.82对氟代甲苯1.170.830.851.20二氯甲烷0.940.871