Powder-Coating-MSDS--Black.doc

Chemical product name:powder coatingDate:May-18-2010SAFETYDATASHEET COATING POWDER1IDENTIFICATIONOFTHEPREPARATIONANDCOMPANYProductionname:ThermosettingCoatingPowderSupplier:Tianjin Dongcheng Chemical Co.,Ltd Address:Beichen Liukuaizhuang Industrial Park,Beichen District，Tianjin，China Post code：300401Tel：+86-22-86843868Fax：+86-22-86843868Chemical use：Equipment protection,decoration2.COMPOSITION/INFORMATIONONINGREDIENTSSubstancespresentingahealthhazardwithinthemeaningoftheChemicals(HazardInformationandPackaging)Regulations1997:NameCAS NO%Poly25036-25-330%SMC2613-45-530%DL-benzoin579-44-23%Barium Sulfate7727-43-737%Carbon Black1333-86-41%3.HAZARDSIDENTIFICATIONThisproductcontainsTGICandisclassifiedastoxic.Possibleriskofheritablegeneticdamage.Maycausesensitisationbyskincontactandmaybeirritatingtoeyes.Harmfulbyinhalationandifswallowed.4.FIRSTAIDMEASURESGeneral:Inallcasesofdoubt,orwhensymptomspersist,seekmedicalattention.Nevergiveanythingbymouthtoanunconsciousperson.Inhalation：Removetofreshair,keepthepatientwarmandatrest.Ifbreathingisirregularorstopped,administerartificialrespiration.Givenothingbymouth.Ifunconscious,placeintherecoverypositionandseekmedicaladvice.Eyecontact：Contactlensesshouldberemoved.Irrigatecopiouslywithclean,freshwaterforatleast10minutes,holdingtheeyelidsapart,andseekmedicaladvice.SkinContact:Removecontaminatedclothing.Washskinthoroughlywithsoapandwateroruseaproprietaryskincleaner.DoNOTusesolventsorthinners.Ingestion:Ifaccidentallyswallowed,obtainmedicalattention.Keepatrest.DoNOTinducevomiting.5.FIREFIGHTINGMEASURESExtinguishingmedia:Recommended:water,extinguisheroffoam,PowderandCarbondioxide,waterspray/mist.Nottobeused:highpressureinertgas（e.g.CO2），waterjets.Recommendations:Firewillproducedenseblacksmokecontaininghazardousproductsofcombustion(seeSection10).Exposuretodecompositionproductsmaybeahazardtohealth.Appropriateself-containedbreathingapparatusmayberequired.Coolclosedcontainersexposedtofirewithwaterspray.Donotallowrun-offfromfirefightingtoenterdrainsorwatercourses.6.ACCIDENTALRELEASEMEASURESExcludesourcesofignitionandventilatethearea.Excludenon-essentialpersonnel.Avoidbreathingdust.RefertoprotectivemeasureslistedinSections7&8.Containandcollectspillagewithananti-electrostaticvacuumcleanerorbywetbrushingandplaceinaclosedcontainerfordisposalinaccordancewiththewasteregulations(seeSection13).Donotuseadrybrushorstaticelectricitycanbecreated.Donotallowtoenterdrainsorwatercourses.Iftheproductentersdrainsorsewers,thelocalwatercompanyshouldbecontactedimmediately;incaseofcontaminationofstreams,riversorlakes,therelevantenvironmentagency.7.HANDLINGANDSTORAGEHandling:Precautionsshouldbetakentopreventtheformationofdustsinconcentrationsaboveexplosiveoroccupationalexposurelimits.Electricalequipmentandlightingshouldbeprotectedtoappropriatestandardsandtopreventdustcomingintocontactwithhotsurfaces,sparksorotherignitionsources.Keepthecontainertightlyclosed.Excludesourcesofheat,sparksandopenflame.Avoidtheinhalationofdusts.Smoking,eatinganddrinkingshouldbeprohibitedinareasofstorageanduse.Operatorsshouldwearanti-staticfootwearandfloorsshouldbeelectricallyconductive.ForpersonnelprotectionseeSection8.Thecontainersofthisproductshouldbehandledinqualifieddepartment.Storage:Observethelabelprecaution.Storebelow35inadry,wellventilatedplaceawayfromsourcesofheat,ignitionanddirectsunlight.Nosmoking.Preventunauthorizedaccess.Containerswhichareopenedshouldbeproperlyreleasedanduprighttopreventleakage.8.EXPOSURECONTROLS/PERSONALPROTECTIONExposureLimits:SubstanceOccupationalExposureLimits8hrTWA（1）15minSTEL（2）mg/m3(3)mg/m3(3)TGIC0.1MELNotes:（1）Longtermexposurelimit8hourtimeweightedaverage（2）Shorttermexposurelimit15minutesreferenceperiod（3）“OES”indicatesanOccupationalExposureStandard.MELindicatesaMaximumExposureLimit.OELSaretakenfromthecurrentversionofEH40.ExposuretoTGICcanbemeasuredbythemethoddescribedinMDHS85(HSE).AnestimateofexposuretoTGICcanalsobecarriedoutbymeasuringexposuretototalinhalationparticulate(TIP),andthencalculatinghowmuchofthismaterialisTGIC.ForproductswithTGICcontentintherange0.1to5.0%exposuretoTIPbelow2mg/m3willmeanexposuretoTGICwillbebelowtheMELof0.1mg/m3.Personswithahistoryrespiratoryproblemsorallergicresponsesshouldonlybeexposedto,orhandle,thisproductunderappropriatemedicalsupervision.EngineeringMeasures:Avoidtheinhalationofdusts.Wherereasonablypracticablethisshouldbeachievedbytheuseoflocalexhaustventilationandgoodgeneralextraction.IftherearenotsufficienttomaintainconcentrationsofdustbelowtherelevantOccupationalExposureLimits,suitablerespiratoryprotectiveequipmentshouldbeworn(seepersonalprotectionbelow).PersonalProtection:AllPPE,includingRPE,usedtocontrolexposuretohazardoussubstancesmustbeselectedtomeettherelevantrequirements.RespiratoryProtection:Suitablerespiratoryprotectiveequipmentshouldbewornwhenthisproductissprayediftheexposureofthesprayerorotherpeoplenearbycannotbecontrolledtobelowtheoccupationalexposurelimitandtheengineeringcontrolsandmethodscannotreasonablybeimproved.HandProtection:Whereskinexposuremayoccur,adviceshouldbesoughtfromglovesuppliersonappropriatetypes.Eyeprotection:Eyeprotectiondesignedtoprotectagainstexposuretodustsshouldbewornwhenthereisalikelihoodofexposure.SkinProtection:Cottonorcotton/syntheticoverallsoroverallsarenormallysuitable.Careshouldbetakenintheselectionofprotectiveclothingtoensurethatinflammationandirritationoftheskinattheneckandwriststhroughcontactwiththepowderisavoided.9.PHYSICALANDCHEMICALPROPERTIESPhysicalstate:FinepowderSpecificGravity:1.21.9Solubilityinwater:insolubleMinimumignitiontemp:400Minimumignitionenergy:520mJMinimumexplosiveconcentration:2070g/m310.STABILITYANDREACTIVITYStableundertherecommendedstorageandhandlingconditions(SeeSection7).Inafire,hazardousdecompositionproductssuchassmoke,carbonmonoxide,carbondioxideandoxidesofnitrogenmaybeproduced.11.TOXICOLOGICALINFORMATIONThereisnodataavailableontheproductitself.Coatingpowderscancauselocalizedskinirritationinfoldsoftheskinorincontactwithtightclothing.12.ECOLOGICALINFORMATIONThereisnodataavailableontheproductitself.ThisproductcontainsTriglycidylIsocyanurate(TGIC)whichisclassifiedasharmfultoaquaticorganisms,andmaycauselong-termadverseeffectsintheaquaticenvironment.Theproductshouldnotbeallowedtoenterdrainsorwatercoursesorbedepositedwhereitcanaffectgroundorsurfacewaters.TheAirPollutionControlrequirementsofregulationsmadeundertheEnvironmentalProtectionActmayapplytotheuseofthisproduct.13.DISPOSALCONSIDERATIONSDonotallowintodrainsorwatercoursesordisposeofwheregroundorsurfacewatersmaybeaffected.Wastes,includingemptiedcontainers,arecontrolledwastesandshouldbedisposedofinaccordancewithregulationsmadeundertheControlofPollutionAct.14.TRANSPORTINFORMATIONAlwaystransportinclosedcontainersthatareuprightandsecure.Ensurethatpersonstransportingtheproductknowwhattodointheeventofaccidentorspillage.TheproductisnotclassifiedasdangerousforcarriageunderInternationalregulations.15.REGULATORYINFORMATIONThesafetyphrasesofthisproductisidentifiedinaccordancewiththerequirementsoftheChemicals(HazardInformationandPackagingforSupply)Regulations(1997)asfollows.ThisproductcontainsTriglycidylIsocyanurate(TGIC)andisclassifiedastoxic.R46MaycauseheritablegeneticdamageR43Maycausesensitisationbyskincontact.R36Irritatingtoeyes.R20/22HarmfulbyinhalationandifswallowedS24/25Avoidcontactwithskinandeyes.S45Incaseofaccidentorifyoufeelunwell,seekmedicaladviceimmediately(showthelabelwherepossible).S38Incaseofinsufficientventilationwearsuitablerespiratoryequipment.S53Avoidexposureobtainspecialinstructionsbeforeuse.Theinformationcontainedinthissafetydatasheetdoesnotconstitutetheusersownassessmentofworkplacerisksasrequiredbyotherhealthandsafetylegislation.TheprovisionsoftheHealthandSafetyatWorketcActandtheControlofSubstancesHazardoustoHealthRegulationsapplytotheuseofthisproductatwork.16.OTHERINFORMATIONTheinformationinthissafetydatasheetisprovidedinaccordancewiththerequirementsoftheChemicals(HazardInformationandPackaging)Regulations1997.ThefulltextoftheRphrasecontainedinSection2is:-R23/25Toxicbyinhalationandifswallowed.R41Riskofseriousdamagetoeyes.R43Maycausesensitisationbyskincontact.R46Maycauseheritablegeneticdamage.R48/22Harmful:dangerofseriousdamagetohealthbyprolongedexposureifswallowed.TheproductshouldnotusedforpurposesotherthanthoseshowninSection1withoutfirstreferringtothepowdersupplierandobtainingwrittenhandlingins