冶金物理化学 (张家芸 宋波 郭兴敏) 课后答案[1-7章].khdaw.pdf

1 4 1000k MnO 38493076 36 fG TJ mol Mn2O3 969640254 18 fG TJ mol MnO2 52300201 67 fG TJ mol Mn3O4 1384900350 62 fG TJ mol 1 38493076 36 fG TMnO J mol 2Mn O2 2 MnO 1mol O222 3849076 36 MnOfMnO GGT T 1000K 617 140 61 7 MnO GJ molKJ mol 2 3 2 Mn2O3 2Mn O2 Mn2O3 4 3 Mn O2 3 2 Mn2O3 1mol O2 2323 22 969640254 18 33 Mn OfMn O GGT J mol T 1000K 23 47 7 Mn O GKJ mol 3 1mol O2 MnO2Mn O2 MnO2 22 52300201 76 MnOfMnO GGT T 1000K 2 14 9 MnO GKJ mol 4 3 2 Mn3O4 Mn O2 1 2 Mn3O4 1mol O2 3434 11 1384900350 62 22 Mn OfMn O GGT T 1000K 34 51 7 Mn O GKJ mol 1molO2 MnO G MnO 1 5298 398KAlAl2O3 3 298 1673600 Al O HJ mol 2O O3 3 2323 2222 3333 Mn OMn O 232323 fMn O 33 fMn O 2222 Mn OMn OfMn O G G fMn OfMn O 2222 G G 222222 J molKJ molJ molKJ mol617 140 61 7 617 140 61 7 617 140 61 7 3 Mn O O2 2 3 3 2 Mn 2222 969640254 18 969640254 18 3333 23 fMn O 33 23 2222 969640254 18 969640254 18 fMn O 2323 Mn OMn O 232323 G GMn O Mn OMn OMn O G GMn O Mn O MnO MnO2 MnOfMnO GG MnOfMnO GGGG MnOfMnO T 1000K T 1000K 3 Mn 3 298 51 04 Al O SJKmol 298 28 33 Al SJKmol 2 298 205 13 O SJKmol 32 3 114 77 12 80 10 p Al Os cT JKmol 3 20 67 12 39 10 p Al s cT JKmol 2 3 29 964 19 10 p Os cT JKmol 2 2 1 p cabTcTc T 2Al 3 2 O2 Al2O3 32322 3 2 2 p Al Op Al Osp Op Al s cccc 333 3 114 77 12 80 10 29 964 19 10 2 20 67 12 39 10 2 TTT 28 49 18 265 3 10 T 28 49a 3 18 265 10b0c 0c 23 1 0 23 T bc HHa TTTcT 32 2980 28 49 298 18 265 10 2 2981673600HH 0 1681280H 232 298298 298 298 3 2 2 Al OAlO SSSS 51 0428 33 2 105 13 1 5 313 315 298298298 GHT S 1673600 313 315298 1580232 231 0 ln 232 T bcc GHaTTTTTIT 3 2 298 18 265 10 168128028 49 298 ln298 298298 2 GI 333333 114 77 12 80 10 29 964 19 10 2 20 67 12 39 10 114 77 12 80 10 29 964 19 10 2 20 67 12 39 10 333333333333333333333333333 114 77 12 80 10 29 964 19 10 2 20 67 12 39 10 114 77 12 80 10 29 964 19 10 2 20 67 12 39 10 114 77 12 80 10 29 964 19 10 2 20 67 12 39 10 333333333 3 18 265 1018 265 1018 265 1018 265 1018 265 10 bcbcbcbc 23 123 1 HHa TTTcT 23 1 bc 23 1 bc 23 1 bc 23 1 333333 114 77 12 80 10 29 964 19 10 2 20 67 12 39 10 114 77 12 80 10 29 964 19 10 2 20 67 12 39 10 333333333333333333333333 114 77 12 80 10 29 964 19 10 2 20 67 12 39 10 114 77 12 80 10 29 964 19 10 2 20 67 12 39 10 333333333 0 0c c 23 123 1 2323 bc 23 1 HHa TTTcTHHa TTTcT 23 123 123 123 1 HHa TTTcTHHa TTTcTHHa TTTcT 23 123 123 123 123 123 1 28 49 298 18 265 10 2 298167360028 49 298 18 265 10 2 298167360028 49 298 18 265 10 2 298167360028 49 298 18 265 10 2 298167360028 49 298 18 265 10 2 2981673600 298298 298 298 298298 298 298 298298 298 298 298298 298 298 SSSSSSSSSSSS 298298 298 298 298298 298 298 2 2 298298 298 298 298298 298 298 298298 298 298 SSSSSSSS2 2 1580232 498 7I 23 32 168128028 49ln9 13 10498 7 fAl O GTTTT p cab 0cc 2982982980122 GHT STaMbMcMc M 0 298298 ln1ln4 7 298 T MT TT 2 1 298 1 29844402 22 TT M TT 298 1673600313 315 28 49 ln4 7 T GTTT T 3 1 18 265 10 29844402 2 T T 32 168127928 49 ln498 759 13 10 TTTT J mol 298298 298298 TT p Tp c GHT Sc dTTdT T p c 1 61273KFeO x fFe O G 22Sgsg FeOHFeH O1273K0 668K 222 1 2 ggg HOH O 2 24958051 11 fH O GTJ mol Fe 1 2 O2 FeO S fFeO G H2 1 2 O2 H2O g 2 fH O G FeO s H2 g Fe s H2O g 1 G 2 1 fH OfFeO GGG T 1273K 1 K 0 668 1 ln4270 GRTKJ mol 2 1 fFeOfH O GGG24958051 11 12734270 168127928 49 ln498 759 13 10 168127928 49 ln498 759 13 10 168127928 49 ln498 759 13 10 168127928 49 ln498 759 13 10 168127928 49 ln498 759 13 10 168127928 49 ln498 759 13 10 TTTT TpTp298298TpTpTp298298 GHT Sc dTTdTGHT Sc dTTdTGHT Sc dTTdTGHT Sc dTTdTGHT Sc dTTdTGHT Sc dTTdTGHT Sc dTTdTGHT Sc dTTdT 298298TpTpTpTp298298 GHT Sc dTTdTGHT Sc dTTdT Tp 298 TTTT GHT Sc dTTdT Tp GHT Sc dTTdTGHT Sc dTTdTGHT Sc dTTdT TpTpTp T J molT J mol168127928 49 ln498 759 13 10 298 TTTTc GHT Sc dTTdTGHT Sc dTTdT 298 Tp TTTT GHT Sc dTTdTGHT Sc dTTdTGHT Sc dTTdT Tp GHT Sc dTTdTGHT Sc dTTdTGHT Sc dTTdT Tp 1273K1273KFeOFeO FeOHFeH OFeOHFeH OFeOHFeH O 2 2gggggg2 222 HOH OHOH O 2 2 HOH OHOH OHOH O 188787 J mol 1 7 Pt Rh Fe s FeOAl2O3 Al2O3 S ZrO2 CaO s MoO2 s Mo s Pt Rh 2 2323 1 2 sg FeOAl OFeOAl O s 1373 1700K 2 4 3 128 10 lg 12 895 Oa pp T Mo O2 MoO2 S 578200 166 5 fG T J mol 223 3 2 2 Sl AlOAl O 1687200326 8 fG T J mol 1FeAl2O4 fG T 21600K 1 2 2323 1 2 sg FeOAl OFeOAl O s 2 2 1 lnln rO O GRTPRT P 2 5 ln 1 0315 10 Oa PP RT 2 5 2 3lg ln1 0315 10 Oa RTPPRT 4 29 91 1075 3T 2 2323 1 2 gSs FeOAl OFeOAl O rG 2 23 3 2 2 gSs AlOAl O 23 fAl O G FeAl2O4 4 29 91 1075 3 1687200326 8 TT 1986300402 1T J mol 2 GzFE F96487 C mol 2 2323 2FeOAl OFeOAl Oe 2 2 42MoOeMoO 2423 fFeAl OrfAl O GGG 2 2 O O2 2 5 5 1 0315 101 0315 10 OaOa PP Oa 1 0315 10 2 2 2 3lg ln1 0315 102 3lg ln1 0315 10 OaOa 2 2 2 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 10 2 2 2 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 102 3lg ln1 0315 10 29 91 1075 329 91 1075 3T T29 91 1075 329 91 1075 329 91 1075 3 gSgS2 232 23 FeOAl OFeOAl O gS2 232 23 FeOAl OFeOAl OFeOAl OFeOAl O 2 232 23gS2 232 232 23 2 23 2 23 2 gSgS2 23 2 23 2 23 AlOAl OAlOAl O 2 23 2 23 2 23 2 23 AlOAl OAlOAl OAlOAl O 2 23 2 23 2 23 2 23 22323 222FeMoOAl OMoFeOAl O 24232 22 rfFeAl OfAl OfMoO GGGG 2 1986300402 1 2 1687200326 8 578200 166 5 TTT 20000 15 9T T 1600K 45440 rG J mol z 4GzFEE 0 12V 1 81000K fG 2 1 2 lS MgOMgO 1000K 298 T GH J mol k T 298 HkJ mol Mg l 47 20 MgO s 48 1 601 8 0 T GH J mol k T 2980 HHkJ mol O2 212 128656 7 O2fef298Kfef 222 29802980 TT OOO GHGHHH TTT 212 12 8656 7 1000 220 78 J mol k 2 1 2 lS MgOMgO 2 1 2 MgOOMg feffeffeffef 1 48 1 220 78 47 2 2 109 49 1000K 298fG HT fef 601 8 1000 1000 109 49 J mol kJ mol k 48 1 0 0 T GHGH0 0 T T T T GHGHGHGH GHGHHHGHGHHH TTTTTT TTTTTT 222222222222 222222 GHGHHHGHGHHH 298298 HkJ molHkJ mol 298 HkJ mol 0 0 601 8601 8 J mol kJ mol k J mol k 212 12 298K GHGHHHGHGHHHGHGHHHGHGHHHGHGHHHGHGHHH 492310 J mol 1 9SiMgOSi 2MgO2 2Mg s SiO2 s0 523000211 71 rG TJ mol 1 21473K 1 0 rG 523000 211 71T 0 T 2470K T 2470K 2 2 ln rMg GGRTP 2 523000211 71ln Mg TRTP 1473K T 1473K G0 523000211 71 14738 314 1473 2ln Mg P0 5 1 0135 10 Mg pPa 4 1 80 10 pMg18 56 Pa 1 10 460 1200KGT 3 3 sss FeCFe C 2667024 33 fG T J mol 2 2 s CCOCO 162600 167 62 fG T J mol CO220 CO75 202 65kPa 900Fe3CFe3C 23 32FeCOCOFe C 2 523000211 71ln523000211 71ln MgMg TRTPTRTP523000211 71ln523000211 71ln523000211 71ln MgMg T 1473KT 1473K 523000211 71 14738 314 1473 2ln523000211 71 14738 314 1473 2ln523000211 71 14738 314 1473 2ln523000211 71 14738 314 1473 2ln G G 523000211 71 14738 314 1473 2ln523000211 71 14738 314 1473 2ln523000211 71 14738 314 1473 2ln523000211 71 14738 314 1473 2ln523000211 71 14738 314 1473 2ln 4 4 1 80 101 80 101 80 10 18 56 Pa18 56 Pa 1200K 2667024 33162600 167 62 rG TT 135930 143 29T T 900 1173K 2 2 ln CO rr CO P GGRT P 135930 143 29 11738 314 1173 5 2 5 0 20 1 01325 10 ln 0 75 1 01325 10 zong zong p p 5 0 367 10 32149 17 9752 3 ln zong p pzong 202 65kPa rG 15485 4 0 3 Fe C 3 Fe C rG 0 900 5 0 367 10 32149 17 9752 3 ln r zong G p 0 pzong984 6kPa 1 11 2 2Ss ZrOZrO1727 1727ZrO2 3 1 3 10Pa21 O2 2 2Ss ZrOZrO1087600 18 12 lg247 36 rG TTT J mol T 1727 2000k 1087600 18 12 2000 lg2000247 36 2000 rG 712509 3 J mol 15485 4 15485 40 0 rG G 5 5 0 367 100 367 100 367 100 367 100 367 100 367 100 367 100 367 100 367 100 367 10 zongzong p p Fe C 32149 17 9752 3 ln32149 17 9752 3 ln32149 17 9752 3 ln32149 17 9752 3 ln32149 17 9752 3 ln 984 6kPa984 6kPa 2 2 ZrOZrOZrOZrO 2 22 2 ln rG RTK 712509 3 ln 8 314 2000 K 42 85 19 2 49 10K 2 5 1 01325 10 O pPa K 2 14 2 53 10 eq O pPa 3 1 3 10Pa21 O2 2 34 1 3 100 212 73 10 O pPa 2 O eq p ZrO2 1 12 600FeO 2 1 2 ssg FeOFeO 25960062 55 rG TJ mol 2 2 sgg COCO 3941000 84 rG T J mol 2 22 sgg COCO 223400 175 30 rG TJ mol 2 1Fe Cac Txc 11803400 lglg0 870 72 1 21 cc c cc xx a xTTx 1 lg c rT 3434 1 3 100 212 73 101 3 100 212 73 10 3434 1 3 100 212 73 101 3 100 212 73 101 3 100 212 73 10 3434 1 3 100 212 73 101 3 100 212 73 101 3 100 212 73 10 34343434 1 3 100 212 73 101 3 100 212 73 10 343434Pa Pa 3434343434 1 3 100 212 73 10 34 r rG TGTGTGTGT25960062 55GTGTGT 2 2 2 2 2 COCOCOCO 2 2 2 22 2 2 2 2 0 lg c rT1600 0 c r 3 C 1 C solG T 4 1600w C 0 24 w C 1 1 ccc ar xlglglg ccc rax lg c a 11803400 lglg 1 20 870 72 1 c cc c x rx TTx 20 c X cc rr 1180 lg0 87 c r T 16000 575 c r 3C C 1 55 85 lnlnln 100 c sccc R cc a GRTRTx rRTr aM 55 85 2 303 8 314lglg 100 12 c Tr 1180 19 1471 330 87T T 2259342 12T 4 1873k 55 85 0 240 011 100100 12 Fe c c M xC M 0 011118034000 011 lglg0 870 72 1 2 0 01118731873 1 0 011 c a 2 16 ac 0 0069 0 0069 0 627 0 011 c c c a r x 1 ccc rr f 0 627 1 09 0 575 c c c r f r 1 09 0 240 26 cc afC 55 8555 85 lnlnlnlnlnln 100100 GRTRTx rRTrGRTRTx rRTrGRTRTx rRTr 55 8555 85 lnlnlnlnlnlnlnlnln aMaM100100 55 8555 85 2 303 8 314lglg2 303 8 314lglg 55 8555 85 TrTr2 303 8 314lglg2 303 8 314lglg 55 8555 85 TrTr2 303 8 314lglg2 303 8 314lglgTrTr2 303 8 314lglg2 303 8 314lglg2 303 8 314lglg2 303 8 314lglg2 303 8 314lglg2 303 8 314lglg2 303 8 314lglg2 303 8 314lglg2 303 8 314lglg 100 12100 12 2 303 8 314lglg2 303 8 314lglg 100 12100 12 2 303 8 314lglg2 303 8 314lglg2 303 8 314lglg2 303 8 314lglg2 303 8 314lglg2 303 8 314lglg2 303 8 314lglg 100 12100 12100 12100 12100 12100 12 1180 19 1471 330 8719 1471 330 8719 1471 330 8719 1471 330 8719 1471 330 8719 1471 330 87 1873k1873k 55 8555 85 100100 12100100 12 xCxC 100100 12 2 2 Fe SiSiO2 2 9 8 26 10 O PPa 1600 Si 1234w Si 1 22sgs SiOSiO 902070 173 64 fG T J mol f Si T 141050626 fusSi HJ mol 0 Si r 0 00116 MFe 55 85kg mol MSi 28 09kg mol 1Si 22sgs SiOSiOSi s Si 2 1 902070 173 04ln SiO GTRT a P 2 9 14 8 26 10 8 26 10 101325 O P 1873k576842G 3 1 0 10 Si R a 2Si 22sgs SiOSiO 1 902070 173 64GT sl SiSi 2 50626 506265062630 1 fus GHT STT T 1 2 22lgs SiOSiO 2 952696203 74GT 1873K 2 1 571091ln SiO GRT a P SiO 1414 8 26 108 26 10 576842576842 22 SiOSiO 3 1 44 10 Si R a 3 1873k R Si Si H Si a r a 0 00145 1 25 0 0016 R Si H Si Si a a r 4 R Si Si Si Si a x r a 0 00145 62 87 55 85 0 0016 100 28 09 R Si Si Si Si a a x r 2 4500 23 2 3 s AgZnAg Zn AgZn500 rG 128kJ mol 0 Zn r 11 0 Ag r 2 3w Zn 0 32 3 207 2 10 Pb Mkg mol 3 65 38 10 Zn Mkg mol 3 107 87 10 Ag Mkg molw Ag T 500 23 2 3 s AgZnAg Zn 23 ln rR AgR Zn GRTaa 128000J mol 239 2 28 10 R AgR Zn aa 0 R AgAgAgAg aaxr 0 R ZnZnZnZn aaxr Zn a w Zn Ag a w Ag 207 2 0 019 100100 107 87 Pb Ag Ag M x M 2 3 2 3 AgZnAg ZnAgZnAg Zn2 3 2 3 2 3 2 3 2 3 2 3 0 0 Zn rZn 11 23 AgZnAg ZnAgZnAg Zn 2 AgZnAg Zn 500 0 AgAg rAg 2 3 2 3 207 2 10 207 2 10 Pb 207 2 10 207 2 10 kg mol 2 3 AgZnAg Zn2 3 2 3 2 3 2 3 207 2 0 032 100100 65 38 Pb Zn Zn M x M 239 2 28 10 R AgR Zn aa 32 9 0 32 0 032 11 0 019 2 32 28 10w Ag w Ag 0 029 2 5SiO2 Si SiO2 Si 2SiO g 1800KSiOPa SiO20 09w C 4 1 w Si 0 9 0 109 Si Si e0 18 C Si e Si l SiO2 s 2SiO g 633000299 8 rG T J mol Si l Si 131500 17 24 solG T J mol SiO2 Si 2SiO g SiO2 2 2 ln SiO rryizhisol SiOSi pp GRTGG aa 633000299 8T131500 17 24T 764500 282 56T Si 1 lg 0 109 0 90 18 4 10 8361 SiC SiSiSi feSieC 6 86 Si f 2 2 ln SiO r SiOSi pp GRT aa 764500 282 56T 633000299 8 633000299 8 rG G 633000299 8 633000299 8 G G Si Si solsolGsolG Si 2SiO 633000299 8 633000299 8 633000299 8 633000299 8 633000299 8 633000299 8 131500 17 24 131500 17 24 131500 17 24 131500 17 24 Si 2SiO Si 2SiO g g ryizhisol SiOSi ryizhisol aa SiOSi ryizhisol GG ryizhisol GG 633000299 8633000299 8T 2 8 314 1800 ln764500282 56 1800 0 09 6 86 0 9 SiO pp pSiO 14 88Pa 2 7Fe Al0 xAl0 25 1600ln1 200 65 AlAl rxxFe 0 851600 G D 1122 lnln0 x drx dr 12 2 12 11 1 lnln xx xx x drdr x x1 1 r1 1 lnr1 0 0 15 0 ln1 200 65 1 Al FeAl Al x rdx x 0 15 0 1 20 1 Al Al Al x dx x 0 15 0 11 1 20 1 1 Al Al Al x dx x 0 150 15 00 1 1 20 1 1 Al Al Al dx dx x 1 20 0 15 0 16 0 012 rFe 0 988 0 988 0 850 84 FeFeFe ar x 2 9w C 3 8 w Si 1 0 1250 100kPa SiO2 C Si 1 1 200 651 200 65 AlAl 1 200 651 200 651 200 65rdxrdx1 200 651 200 651 200 651 200 651 200 651 200 651 200 651 200 65 1 201 20 1 AlAl AlAl x x dxdx x x Al 0 15 0 1111 1 AlAl 111111x11 x 11111111 0 1 20 1 1 20 1 1 20 1 1 20 1 0 14 C C e0 08 Si C e0 11 Si Si e0 18 C Si e 2 1 2 sg COCO 11799084 35 fG T J mol 22lgs SiOSiO 947676 196 86 fG T J mol 1 S CC 2259442 26 solG T J mol 1 l SiSi 131500 17 24 solG T J mol 1 2 1 2 sg COCO 1fG 2 22lgs SiOSiO 2fG 3 1 S CC 3solG 4 1 l SiSi 4solG 5 1 1 2 2 2 s CSiOCOSi 51234 22 fffsolsol GGGGG 798008 298 28T lg 0 14 3 80 08 1 00 612 CSi CCC feCeSi 4 09 C f lg 0 11 1 00 18 3 80 794 CSi SiSiSi feCeSi 6 22 Si f 2 2 5 2 ln SiCO r SiOC aP GRTG aa f 3solsolG G3 1 4 4solG G4 4 1 2 2 2 2 2 2 2 2 2 5123451234f51234f512345123451234512345123451234 222222 512345123451234 22 5123451234 22 51234 2222 C CCC lg 0 14 3 80 08 1 00 612lg 0 14 3 80 08 1 00 612lg 0 14 3 80 08 1 00 612lg 0 14 3 80 08 1 00 612lg 0 14 3 80 08 1 00 612lg 0 14 3 80 08 1 00 612 2 6 22 1 0 8 3141250273ln798008298 281250273 4 09 3 8 297392 41J mol0 SiC 2 11 Zn Cd527 xCd 0 2 0 3 0 4 0 5 rCd 2 153 1 817 1 544 1 352 1 Zn Cd 2 xCd 0 5Zn CdZnCd ZnCd 1a 2 ln 1 Cd Cd Cd r a x a1 a2 a3 a4 2xCd 0 5rCd 1 352 a 1 2 22 ln1 2 0 50 3 ZnCd ra x rZn 1 350 ln8 314527273ln1 350 mixCd mCd HRTr 1996 J mol ln8 314527273ln1 352 mixZn mZn HRTr 2006 J mol mixmCdmixCd mZnmixZn m HxHxH2001 J mol mixmZnmixZn mCdmixCd m SxSxS 0 58 314ln0 58 314ln ZnCd xx CdCd a a a a1 a a 2 ln Cd rCd a3 a a4 4 2222 1 2 0 50 3 222222 ZnCdZnCdZnCdZnCdZnCd 2222 1 2 0 50 31 2 0 50 3 222222 ZnCdZnCd ra xra x ZnCdZnCdZnCd rZn Zn 1 350 1 350 ln8 314527273ln1 350ln8 314527273ln1 350 Cd ln8 314527273ln1 350ln8 314527273ln1 350ln8 314527273ln1 350ln8 314527273ln1 350ln8 314527273ln1 350ln8 314527273ln1 350ln8 314527273ln1 350ln8 314527273ln1 350ln8 314527273ln1 350ln8 314527273ln1 350 5 763 J mol k lnln2604 4 mixmZnZnZnCdCdCd GRT xr xxr xJ mol ln2064 4 mixZn mZnZnZn GRTxr xJ mol ln2064 4 mixCd mCdCdCd GRTxr xJ mol 2 12Fe Al1600 5397493094 E mixAl mAl Gx J mol 2015 ln 1 27lg13 98lg760ppT T 1600 xFe 0 6 T 1600 1873KxFe 0 6xAl 1 0 6 0 4 ln E mixAl mAl GRTr 5397493094 0 4 ln1 1 8 314 1873 E mixAl m Al G r RT ln1 1 3 056 0 36 Al Fe r a x 22 ln3 056 0 40 489 FeAl ra x 0 61 Fe r T 1600 1873K 2015 ln 1 27lg13 98lg760ppT T 15 51 Fe pPa xAlAl 1 1 0 6 0 40 6 0 4 1 27lg13 98lg760 5397493094 0 45397493094 0 4 8 314 18738 314 1873 5397493094 0 45397493094 0 45397493094 0 4 8 314 18738 314 18738 314 1873 1 1 3 0563 056 0 360 36 15 51 0 61 0 65 77 FeFeFe ppaPa 2 13 CaO SiO2 Al2O3 MnO MgO FeO P2O5 W i 46 89 10 22 2 47 3 34 6 88 29 00 1 20 1 1600CaO a O 2 24 24 2SiOOSiO 23 2524 32POOPO 23 233 32Al OOAlO bO2 2CaO 2 2CaO SiO 25 4CaO PO 23 3CaO Al O CaOMgOMnO FeO 1 46 89 0 837 56 CaO n 2 10 22 0 17 60 SiO n 0 403 FeO n 23 0 024 Al O n 0 047 MnO n 0 172 MgO n 25 0 008 P O n 2222 CaFeMnMg nnnnn 0 837 0 403 0 172 0 047 1 459mol 2 22325 221 257 SiOAl OP O O nnnnnmol Al OOAlOAl OOAlO 23 32 23 CaOCaO 25 CaO POCaO PO 25 3 3CaO Al OCaO Al O MgOMgOMnO FeO 0 8370 837 2 2 1 023 0 814 1 257 O O n x n 2 2 0 837 0 574 1 459 Ca Ca n x n 22 0 467 CaO CaO axx 2 2 2 2 0 17 SiO CaOSiO nn 2 5 25 4 0 008 P O CaOP O nn 2 3 23 3 0 024 Al O CaOAl O nn 22523 243 ROCaOFeOMnOMgOSiOP OAl O nnnnnnnn 1 015 2 322 5324 Al OSiOP O ROCaOCaOCaO nnnnn 1 217 0 8370 17 20 008 40 024 3 1 217 CaO ZI CaO n a n 0 323 2 14 CaO SiO2 MgO FeO P2O5 w i 40 62 10 96 4 56 33 62 10 24 FeOCa2 Mg2 Fe2 SiO44 Fe2O54 O2 w SiO2 11 SiO2 22 4 4 lg 1 53 0 17 FeO rrx SiO 4 3 424 4 4 0 323 SiO P O SiO nn x n 2222 2 10 0 0790 166 FeO FeFeOO arxrx 2 17 CaO SiO2 MnO MgO FeO Al2O3CaF2 W i 47 18 0 2 14 1 8 5 14 1873K CaOSiO2MnOMgO FeO Al2O3CaF2 W i 47 18 0 2 14 1 8 5 14 ni0 8390 3 0 0030 350 025 0 0490 179 xi 0 480 170 0020 20 01430 028 0 1 oi i oi nx x nx 0 390 280 160 0020 0690 0120 082 1 745nmol 0 480 17 20 20 0020 028 30 01430 1 oi n x 1 228 i 0 718 ii x MnOMnOMgO 18 18 0 3 0 3 2269054640 lg43 625 2 s C T T 1873k 3 1 8 10 s C 2 18 CaO SiO2 MgO Al2O3 W i 43 46 35 32 2 76 18 48 1673k 1 79 0 4346 1 24 0 02766911 lg1 351 649 1 66 0 35320 33 0 18481673 s C 4 09 5 8 2 10 s C CaOSiO2MgO Al2O3 W i 43 46 35 32 2 76 18 48 ni0 7660 5890 0690 181 xi 0 480 3650 0430 112 oi i oi nx x nx 0 30 460 0270 21 0 67 ii x 2269054640 lg43 625 2 s C T 4 3 5 5 0 10 s C SiOSiO2 2 43 46 43 46 0 766 2 19 CaO SiO2 MnO MgO FeO Al2O3 P2O5 W i 45 20 7 7 16 3 2 1873k CaOSiO2MnOMgO FeO Al2O3P2O5 W i 45 20 7 7 16 3 2 ni0 8040 3330 0990 7750 2220 0290 014 xi 0 480 200 0590 100 130 0170 008 oi i oi nx x nx 0 380 320 0470 0790 100 040 032 0 71 ii x 3 4 29990 lg23 74 17 55 0 71 1873 PO C 4 73 3 4 4 5 4 10 PO C 3 1 Ni Cu WCu 1008060402010 k135514671554162716831724 k135514071467154316291724 1w Ni 30 1600K Ni Cu 0 100 10 047 0470 0790 079 0 0290 029 0 130 0170 017 0 100 10 23 74 17 55 0 7123 74 17 55 0 7123 74 17 55 0 71 4 73 4 73 1 Ni 30 a1600K aT1Ni 30 Ni C3 a T2Ni 30 Ni 14 T1 1511KC3 53 T2 1436K C4 14 2 Ni 50 1550KM 3 Wl Ws mm2 mm1 Wl W mm2 m1m2Ws W mm1 m1m2 W 0 24Kg Wl Ws C Wl Ni C1 C Ws Ni C2 Wl Ni Wl C1 Ws Ni Ws C2 Wl Ni 0 073Kg Ws Ni 0 047Kg 3 21aS1 2MgSO4 H2ObMgSO4 MgSO46H2OS1 MgSO412H2OS2 MgSO47H2O S3 MgSO46H2O WWl Ni 1 Ws Ws Ni Ni W 0 073Kg Ws 0 073Kg Ws S S1 1 1GA 2 TC TCT 3 4w CaO 60 w FeO 20 w SiO2 20 M1600 C C T T w CaO 60 w CaO 60 1601600 c S DMF SEDF E 20 50 40 mm mm C2S FME SEDF 423 25 1242 mmmm mmmm C3S S DME SDFE 423 25 1242 mmmm mmmm M SiO2 40 FeO 10 CaO 50 EDFEDF E FMEFME S SEDF 4 3 23 21 2 33 g CrCOCr OC 1 w Cr 10 w Ni 9 w C 0 05 pCO 101325Pa 2 w Cr 18 w Ni 9 w C 0 05 pCO 101325Pa 1 Cr C 3 23 42 22 33 g CrCOCr OC 4 4 1 2 22 ssgS SiMgOMgSiO 522500211 71 rG TJ mol 2 CaO1473k 1 2 22 ssgS SiMgOMgSiO 522500211 71 rG TJ mol 0 rG T 2470k 3 CaO 224 2 SS CaOSiOCa SiO 24 222 ssgS SiMgOCaOMgCa SiO 522500211 711262365 02 rG TT 396264 216 73K T 1830k SiMgOMgSiO 522500211 71 522500211 71 522500211 71 522500211 71 ssgSssgS SiMgOMgSiOSiMgOMgSiO22 ssgSssgSssgS SiMgOMgSiOSiMgOMgSiO2222 ssgSssgSssgS 2222 3 2 ln Mg GGRTP 396264216 732ln Mg TRTP 0GT 1473kln3 14 Mg P 0 0431 Mg P 0 0431 1013254365 Mg pPa 4365 Mg pP