氯化橡胶漆化 学 品 安 全 技 术 说 明 书 中英 revised.docx

化 学 品 安 全 技 术 说 明 书Chemical Safety Technical Specifications第一部分化学品及企业标识 Part One Chemical products and company profiles化学品中文名：氯化橡胶面漆化学品英文名Chemical English name：Chlorinated rubber topcoat企业名称：武汉市吴桥化工涂料有限公司Enterprise name:Wuhan Wu Qiao Chemical Paint Co., Ltd.生产企业地址：武汉市化学工业区清潭湖吴桥Wuhan chemical industry district, Wuqiao Village技术说明书编码Technical specification code:邮 编Zip code:430076传 真Fax业应急电话Enterprise emergency telephone子邮件地址e-mail address：第二部分成分/组成信息 Part Two: Composition / information纯品 of the purest quality 混合物 mixture 有害物成分Harmful ingredients浓度concentrationCAS No.氯化橡胶Chlorinated rubber60%二甲苯xylene10%108-38-3正丁醇Butyl alcohol10%71-36-3第三部分危险性概述 Part Three Haxards summarizing危险性类别：第3.3类 高闪点液体The 3.3 risk categories: high flash point liquid侵入途径：吸入、食入Invasion way: inhalation and ingestion健康危害：制备和使用环氧树脂的工人，可有头痛、恶心、食欲不振、眼灼痛、眼睑水肿、上呼吸道刺激、皮肤病症等。本品的主要危害为引起过敏性皮肤病，其表现形式为瘙痒性红斑、丘疹、疱疹、湿疹性皮炎等。Health hazard: Epoxy can cause headache, nausea, loss of appetite, burning eyes, eyelid edema, irritate the upper respiratory tract, skin disorders and so on. The main harm is to cause allergic skin disease, its expression form is the itching erythema, rash, herpes, eczema, dermatitis, etc.环境危害：对环境有害。Environmental hazards: Environmentally harmful燃爆危险：易燃，其蒸气与空气混合，能形成爆炸性混合物。Explosive danger: It is flammable, it will cause explosive compound when it mixed with air.第四部分急救措施 Part Four Emergency measures皮肤接触：脱去污染的衣着，用肥皂水和清水彻底冲洗皮肤。如有不适感，就医。Skin contact: Wash skin with soap and water thoroughly. Any discomfort, medical treatment.眼睛接触：提起眼睑，用流动清水或生理盐水冲洗。如有不适感，就医。Eye contact: Rinse eyes with flowing water or saline. Any discomfort, medical treatment.吸入：脱离现场至空气新鲜处。就医。Inhalation: Separated from the scene freshly rapidly to the air place. Medical treatment.食入：用水漱口，如有不适感，就医。Ingestion: Rinse with water,.Any discomfort, medical treatment.第五部分消防措施 Part Five Fire protection measures危险特性：易燃，遇明火、高热能燃烧。受高热分解放出有毒的气体。粉体与空气可形成爆炸性混合物, 当达到一定浓度时, 遇火星会发生爆炸。Hazard Property: flammable, high temperature will cause fire. Emits poisonous gas by high temperature. Powder mix with air will explode when it comes to a certain concentration.有害燃烧产物：一氧化碳、二氧化碳。Hazardous Combustion Products: Carbon monoxide, carbon dioxide灭火方法：用雾状水、泡沫、二氧化碳、干粉、砂土灭火。Extinguishing methods: using fog water, foam, carbon dioxide, dry powder and sand.灭火注意事项及措施：消防人员必须佩戴空气呼吸器、穿全身防火防毒服，在上风向灭火。喷水冷却容器，可能的话将容器从火场移至空旷处。处在火场中的容器若已变色或从安全泄压装置中产生声音，必须马上撤离。Measures and precautions for extinguishing : Fire-fighter must wear the anti-poisonous mask, wear the uniform and put on a fire. if possible, move spray cooling water machine to open space. Any containers in the fire place have discoloration or any sound from the safety relief devices, all personnel must be evacuated immediately第六部分泄漏应急处理 Part Six Accidental release measures应急行动：消除所有点火源。根据液体流动和蒸气扩散的影响区域划定警戒区，无关人员从侧风、上风向撤离至安全区。建议应急处理人员戴正压自给式呼吸器，穿一般作业工作服。穿上适当的防护服前严禁接触破裂的容器和泄漏物。尽可能切断泄漏源。用塑料布覆盖泄漏物，减少飞散。勿使水进入包装容器内。用洁净的铲子收集泄漏物，置于干净、干燥、盖子较松的容器中，将容器移离泄漏区。Emergency action: Eliminate all ignition sources. delimit warning zone according to the liquid flow and vapor diffusion influence, personnel evacuate to safe areas. Fire-fighter must wear breathing machined and uniform. Keep distance as far as possible with all the container and leakage, cut off the leakage source. Cover leakage with plastic sheeting, reduce dispersion. Do not allow water into the container. Collect the leakage with dry and clean shove, store them in dry and clean container and move out to safe place.第七部分操作处置与储存 Part Seven Operation and storage操作注意事项：密闭操作，提供良好的自然通风条件。操作人员必须经过专门培训，严格遵守操作规程。建议操作人员佩戴自吸过滤式防尘口罩，戴化学安全防护眼镜。远离火种、热源，工作场所严禁吸烟。使用防爆型的通风系统和设备。防止蒸气泄漏到工作场所空气中。避免与氧化剂接触。搬运时要轻装轻卸，防止包装及容器损坏。配备相应品种和数量的消防器材及泄漏应急处理设备。倒空的容器可能残留有害物。Operation Cautions: Enclosed operation , good natural ventilation conditions. Operator must be trained, strictly comply with the operating procedures. Suggested that the operator wear self - absorption filter dust masks, wear chemical safety glasses. Away from the fire, heat, smoking is strictly prohibited in the workplace. Ventilation systems and equipment using explosion proof type. To prevent steam from leaking into the air in the workplace. Avoid contact with oxidizing agents. When moving to light light unloading, prevent damage to packaging and containers. Fire fighting equipment and leakage emergency treatment equipment equipped with corresponding variety and quantity. Empty containers may contain harmful substances.储存注意事项：储存于阴凉、通风的库房。远离火种、热源。保持容器密封。应与氧化剂分开存放，切忌混储。采用防爆型照明、通风设施。禁止使用易产生火花的机械设备和工具。储区应备有泄漏应急处理设备和合适的收容材料。Storage note: Store in a cool, ventilated warehouse. Away from the fire, heat source. Keep container seal. Should be stored separately with the oxidant, avoid mixing. Explosion proof lighting and ventilation facilities. Mechanical equipment and tools for the prohibition of the use of easy to produce sparks. The storage area should be equipped with a leak emergency treatment equipment and a suitable shelter material.第八部分接触控制/个体防护 Part Eight Exposure controls/personal protection接触限值Contact limit：MAC(mg/m3):未制定标准Not set standardPC-TWA（mg/m3）:未制定标准Not set standardPC-STEL（mg/m3）:未制定标准Not set standardTLV-C(mg/m3):未制定标准Not set standardTLV-TWA(mg/m3):TLV-STEL(mg/m3):监测方法：无资料。Monitoring method: no data.工程控制：密闭操作。提供良好的自然通风条件。Engineering control: closed operation. Provide good natural ventilation conditions.呼吸系统防护：空气中浓度超标时，佩戴过滤式防尘呼吸器。Respiratory system protection: when the concentration exceeds the standard in the air, wear filter type dust respirator.眼睛防护：一般不需要特殊防护，高浓度接触时可戴化学安全防护眼镜。Eye protection: generally do not need special protection, high concentration contact can wear chemical safety glasses.身体防护：穿一般作业防护服。Body protection: wear general protective clothing.手 防 护：戴一般作业防护手套。Hand protection: wear general protective gloves.其他防护：工作现场严禁吸烟。保持良好的卫生习惯。Other protection: the work site is strictly prohibited smoking. Maintain good hygiene practices.第九部分理化特性 Part Nine Physical and chemical properties外观与性状：根据分子结构和分子量大小的不同, 其物态可从无臭、无味的混合有色液体至固体。With the appearance of the characters: depending on the size of the molecular structure and molecular weight, the state can be no odor of mixed colored liquid to solidpH值:无资料熔点():145155沸点():无资料相对密度(水=1):无资料相对蒸气密度(空气=1):无资料饱和蒸气压(kPa):无资料燃烧热(kJ/mol):无资料临界温度():无资料临界压力(Mpa):无资料辛醇/水分配系数:无资料闪点():无资料引燃温度():无资料爆炸下限(V/V):无资料爆炸上限(V/V):无资料PH: (c): no data point 145 155The boiling point (c): no data relative density (=1 water): no dataRelative vapour density (air =1): no data saturated vapor pressure (kPa): no dataThe heat of combustion (kJ/mol): no data critical temperature (DEG C): no dataThe critical pressure (Mpa): ungaged: octanol / water partition coefficient dataFlash point (c): no data ignition temperature (DEG C): no dataThe explosion limit % (V/V): no data explosion limit % (V/V): no data溶解性：溶于丙酮、乙二醇、甲苯。Solubility: soluble in acetone, ethylene glycol, toluene.主要用途：用作金属涂料、金属粘合剂、玻璃纤维增强结构材料、防腐材料、金属加工用模具等, 在电器工业中用作绝缘材料。Main use: used as metal coatings, metal adhesives, glass fiber reinforced structural materials, anti-corrosion materials, metal processing, etc., in the electrical industry as an insulating material.第十部分稳定性和反应性Part Ten Stability and reaction稳定性：稳定 Stability: stability禁配物：强氧化剂。 Forbidden complex: strong oxidizing agent.避免接触的条件：潮湿空气。 Conditions to avoid contact: moist air.聚合危害：不聚合。 Polymerization hazard: no polymerization分解产物：氧化硫。 Decomposition products: sulfur dioxide.第十一部分毒理学资料 Part Eleven Toxicological data急性毒性：大鼠经口的MLD为5.0g/kg。给0.25mg/kg，未见毒性反应；给予2.5mg/kg，可使肾上腺重量减轻。Acute toxicity: the MLD of the rats mouth is 5.0g/kg. To 0.25mg/kg, no toxic reaction; to give 2.5mg/kg, can reduce the weight of adrenal.LD50：大鼠经口LD50(mg/kg):11400小鼠经口LD50(mg/kg):7300 mg/kg 小鼠静脉LD50(mg/kg):1364兔经口LD50(mg/kg):7060兔经皮LD50(mg/kg):5900其它动物LD50:二甲苯，人经口LDL0：50mg/kgLD50:Rat oral LD50 (mg/kg): 11400 mice by oral LD50 (mg/kg): 7300 mg/kgMouse LD50 (mg/kg) vein: 1364 rabbits by LD50 (mg/kg): 7060Rabbit percutaneous LD50 (mg/kg): 5900 other animal LD50: xylene, by LDL0:50mg/kgLC50：大鼠吸入LC50(mg/m3):710 ppm/4H 大鼠吸入LCL0(mg/m3):2000ppm/4h小鼠吸入LC50(mg/m3):320mg/m3，2小时小鼠吸入TCL0(mg/m3):259ppm/7h人吸入LCL0(mg/m3):10pph/1m(10%),9pph/5m(9%)人吸入TCL0(mg/m3):2000ppmIDLH:50000ppmLC50:The rats inhaled LC50 (mg/m3): 710 ppm/4H rats inhaled LCL0 (mg/m3): 2000ppm/4hInhalation of LC50 mice (mg/m3): 320mg/m3, 2 hours of mice inhaled TCL0 (mg/m3): 259ppm/7hInhalation of LCL0 (mg/m3): 10pph/1m (10%), 9pph/5m (9%) TCL0 (mg/m3) inhalation: 2000ppmIDLH: 50000ppm其它动物吸入LC50：二甲苯，人吸入TCL0：200ppm,LCL0:10000ppm/6h其它动物吸入LC100：大鼠吸入LC100:335360mg/m3/4h其它动物吸入LCL0：狗吸入LCL0：40ppm/1h；豚鼠吸入LCL0：92ppm/1h其它动物吸入TCL0：女人吸入TCL0:500ppm/2minOther animals inhaled LC50: xylene, inhaled TCL0:200ppm, LCL0:10000ppm/6hOther animals inhaled LC100: rats inhaled LC100:335360mg/m3/4hOther animals inhaled LCL0: dogs inhaled LCL0:40ppm/1h; guinea pigs inhaled LCL0:92ppm/1hOther animals breathe in TCL0: Women breathe TCL0:500ppm/2min刺激性Irritation：家兔经皮：二甲苯，500mg/24h,中度刺激Rabbit percutaneous: xylene, 500mg/24h, moderate stimulation家兔经眼：1380g ，重度刺激 Rabbit eyes: 1380 g, severe stimulation人经眼：二甲苯，200ppm刺激。 People by the eye: xylene, 200ppm stimulation.亚急性与慢性毒性：大鼠、豚鼠、兔和猴吸入2.61g/m39.5g/m3，每天7h，共103138天，发现肝脏、肾脏和睪丸发生轻度病理改变。Subacute and chronic toxicity: rats, guinea pigs, rabbits and monkeys inhaled 2.61g/m3 9.5g/m3, 7h every day, a total of 103 to 138 days, found that the liver, kidney and testicular pathological changes.致突变性：微生物致突变：鼠伤寒沙门(氏)菌11 pph。显性致死试验：小鼠经口11.5g/kg/天，2周，阳性。细胞遗传学分析：人淋巴细胞2.5pph/24h。姐妹染色单体交换：人淋巴细胞500ppm/72h。DNA抑制：人淋巴细胞220mmol/l。微核试验：狗淋巴细胞，400umol/l。Mutagenicity: microbial mutagenicity: Salmonella (Salmonella) 11 pph. Dominant lethal test: mice were positive for 1 to 1.5g/kg/ days, 2 weeks. Cytogenetic analysis: human lymphocytes 2.5pph/24h. Sister chromatin exchange: human lymphocytes 500ppm/72h. DNA inhibition: human lymphocytes 220mmol/l. Micronucleus test: dog lymphocytes, 400umol/l.致畸性：猴孕后2-17周经口给予最低中毒剂量（TDL0）32400mg/kg，致中枢神经系统和颅面部（包括鼻、舌）发育畸形。大鼠、小鼠、豚鼠、家畜孕后不同时间经口、静脉内、腹腔内途径给予不同剂量，致中枢神经系统、泌尿生殖系统、内分泌系统、肝胆管系统、呼吸系统、颅面部（包括鼻、舌）、眼、耳发育畸形。雄性大鼠交配前30天经口给予240g/kg，致泌尿生殖系统发育畸形。2-17 weeks after pregnancy, the minimum toxic dose (TDL0) 32400mg/kg was given to the central nervous system and the craniofacial (including the nose and tongue) development of the central nervous system and the craniofacial region. Rats, mice, guinea pigs, cattle pregnant after different time by oral, intravenous, intraperitoneal route given different dose and tube system, respiratory system, craniofacial (includes the nose, tongue, eyes, ears development malformation of central nervous system, urinary and reproductive system, endocrine system, hepatobiliary induced by. Male rats 30 days before mating induced by oral administration of 240g/kg, genitourinary system malformation.致癌性：IARC致癌性评论：对动物致癌性证据有限。Carcinogenic: IARC carcinogenic review: limited evidence of animal carcinogenesis.其 他：小鼠腹腔最低中毒剂量(TDL0)：7.5g/kg(孕9天)，致畸阳性。Other: the mice abdominal minimum toxic dose (TDL0):7.5g/kg (9 days of pregnancy), positive.第十二部分生态学资料 Part Twelve ecological information生态毒性Ecological toxicity：生物降解性Bio degradation：非生物降解性Non biological degradation：其他有害作用Other harmful effects：无资料No data。第十三部分废弃处置 Part Thirteen Disposal Information废弃物性质：危险废物 Nature of waste: hazardous waste废弃处置方法：建议用焚烧法处置。 Waste disposal methods: Disposal by incineration.废弃注意事项：处置前应参阅国家和地方有关法规。Waste matters needing attention: prior to the disposal of the state and local regulations should be referred to the relevant regulations.第十四部分运输信息 Part fourteen Transportation information危险货物编号Dangerous goods number：33646UN编号：无资料 UN number: no data包装类别：类包装 Packaging categories: Category II packaging包装标志：易燃液体 Packing mark: flammable liquid包装方法：无资料。 Packing method: no data.运输注意事项：运输时运输车辆应配备相应品种和数量的消防器材及泄漏应急处理设备。严禁与氧化剂、食用化学品、混装混运。运输途中应防曝晒、雨淋，防高温。按规定路线行驶，勿在居民区和人口稠密区停留。Transport matters: the transport vehicles should be equipped with the appropriate variety and quantity of fire equipment an