Global Metal-organic Frameworks Market Research Report 全球金属有机骨架市场研究报告.docx

Global Metal-organic Frameworks Market Research Report 2016Chapters1 Metal-organic Frameworks Market Overview1.1 Product Overview and Scope of Metal-organic FrameworksFigure Picture of Metal-organic Frameworks Source: QYR Chemical & Materials Research Center, Nov 2016Metal Organic Frameworks (MOFs), also called as Porous Coordination Polymers (PCPs) or coordination networks, are crystalline materials which can be readily self-assembled from metal ions or metal clusters with organic ligands They display permanent porosity with the enormous internal surface area and large structural diversity, and thus lead to a wide spectrum of applications including gas capture and storage , molecule separations , ion-exchange , drug delivery , sensing, catalysis , luminescence.Table Feature of Metal Organic FrameworksFeatureDescriptionAn Industrial RevolutionMOFs are crystalline, sponge-like materials that have broad industrial applications because of two key attributes:Extremely large surface areaVaried and flexible structureMore Capacity.Less Volume.MOFs have the highest surface-area of any known material, with one gram of MOF, about the size of a pea, possibly having the same surface area as forty tennis courts. This means that MOFs structure and adsorbent characteristics make them excellent for storing a range of gases such as methane, in a significantly reduced volumeExtremely large surface area;Varied and flexible structure.MOFs can also be used to filter and separate gases and can be designed to capture selected elements, while letting others pass through. MOFs have very low bulk volumes which makes them extremely light.Source: QYR Chemical & Materials Research Center, Nov 20161.2 Metal-organic Frameworks Segment by Types1.2.1 Global Production Market Share of Metal-organic Frameworks by Types in 2015Table Classification of Metal-organic FrameworksTypesProductsDescription1zinc-based organic frameworkBasolite Z1200;Basolite Z377a very hydrophobicmaterial;particle size 4.9 m (D50)surface area 1300-1800m2/g (Langmuir surf. area)bulk density 0.35 g/cm32copper-based organic frameworkBasolite C 300Used for gas adsorption (carbon dioxide, nitrogen, oxygen, hydrogen gas), catalysis, and separationsOther Notescan be reactivated at 200C3iron-based organic frameworkBasolite F300surface area BET surf. area 1300-1600 m2/gbulk density 0.160.35 g/cm34aluminum-based organic frameworBasolite A100extremely stable under water vapor conditions;Used for gas adsorption (hydrogen gas).can be reactivated at 200C (vacuum)5magnesium-based organic frameworkBasosiv M050Lightweight;surface area BET surf. area 400-600 m2/gBulk density 0.300.40 g/cm36Other typesEthane diamine cycloimine organic cageZirconium 1,4dicarboxybenzeneBiphenyl-3,4,5-tricarboxylic acid1,1:4,1Terphenyl- 3,3,5,5-tetracarboxylic acid1,3,5-Tris(4-carboxyphenyl)benzeneSource: QYR Chemical & Materials Research Center, Aug 20161.3 Metal-organic Frameworks Segment by Applications1.3.1 Metal-organic Frameworks Consumption Market Share by Applications in 2015Metal-organic frameworks are porous materials that can exhibit very high surface areas that have potential for applications such as gas storage and separation, as well as catalysis. MOFs that have magnetic or luminescence properties can be potentially utilized in sensor devicesFigure Development and Applications of Metal-organic FrameworksSource: QYR Chemical & Materials Research Center, Nov 2016 Table Applications of Metal-organic FrameworksApplicationsFeatureDescription1Gas storageHigh-specific surface areas, tunable pore sizes, functionalizable pore walls, and well-defined frameworkhydrogen interaction sites.MOF materials consist of metal atoms or metal/oxygen-clusters, which are connected by organic linkers. By choosing the linkers and also metal-clusters hundreds of different porous materials with large specific surface areas and well-defined pore sizes in the nm-range can be synthesized.2Adsorption separationvery low bulk volumes，The structural tunabilityMOfs can be used to filter and separate gases and can be designed to capture selected elements, while letting others pass through. MOFs have very low bulk volumes which makes them extremely light.3CatalyticRecord-breaking surface areas, exceptionalpore sizes, and cavernous internal channelsThe high surface areas, tunable pore metrics, and high density of active sites within the very open structures of MOFs offer many advantages to their use in catalysisSource: QYR Chemical & Materials Research Center, Aug 20161.3.2 Gas storageFigure Gas storage ExamplesSource: QYR Chemical & Materials Research Center, Nov 2016 Hydrogen storageHydrogen storage tanks are an issue for hydrogen cars or for hydrogen transportation. Unlike gasoline tanks, hydrogen storage tanks need to be cooled down. The relatively low enthalpy of adsorption for hydrogen, which is in the range 48 kJ/mol indicating physical adsorption, makes hydrogen uptake in MOFs significant at low temperatures (77 K). Hydrogen storage tanks are characterized by two popular types, compressed hydrogen and liquid hydrogen tanks.Compressed hydrogen storage tanks are the most popular now since they do not require the super-cooling and super-insulation that liquid hydrogen does. Unlike pressurizing natural gas, hydrogen is less dense and requires better seals. In addition, hydrogen storage tanks need to be made from lighter materials such as aluminum or carbon/graphite compounds. Safety becomes an issue with the handling of compressed hydrogen at high pressures.Storing liquid hydrogen in tanks requires special handling and materials to contain and keep the fuel cool. Approximately 30 to 40 percent of the energy content of hydrogen can be lost to liquefy and store hydrogen at 20 K. The filling of the tank with MOFs can moderate the storage conditions, for example, the pressure could be decreased or the temperature could be increased.Figure Progress in Hydrogen Storage Application Made by BASF Based on Different MOF MaterialsSource: QYR Chemical & Materials Research Center, Nov 2016 Methane storageFigure Working Capacity for Methane storageSource: QYR Chemical & Materials Research Center, Nov 2016Methane is the main component of natural gas and represents about two-thirds of the fossil fuels on earth, yet it remains the least utilized fuel. Currently there is a great interest in expanding the use of methane for fueling automobiles because of its wide availability and its lower carbon emission compared to petroleum. A current challenge for the implementation of this technology is to find materials that are able to store and deliver large amounts of methane near room temperature and at low pressures.1.3.3 Adsorption separationFigure Adsorption separation ExamplesSource: QYR Chemical & Materials Research Center, Nov 2016Figure CO2 Capture Using Metal Organic Frameworks (MOFs)Source: QYR Chemical & Materials Research Center, Nov 2016MOFs offer reversible carbon dioxide adsorption and are promising materials for the selective capture of carbon from the atmosphere and flue gas. Carbon dioxide adsorption in MOFs was first reported in 1998 for MOF-2 Zn(BDC).1.3.4 Catalytic Figure Catalytic ExamplesSource: QYR Chemical & Materials Research Center, Nov 2016Catalysts speed up chemical reactions without themselves being used up. Zeolites play a major role in a range of catalytic applications, most prominently in gas and petroleum refining. The MOFs performance is impressive. The Researchers compared an identical sample reaction with standard zeolites and the new MOF material. For one thing, zeolites start to lose their efficiency after an hour, and are generally completely useless after five hours. The MOF not only kept working after six hours, but it actually increased in efficiency, peaking at more than 99 per cent yields after two hours.The exceptionally high efficiency observed in the MOF catalyst is mainly because of the mutual promotion between the organic Brnsted acid site and the aluminum Lewis acid center when combined within the MOF. The coordination environment of the aluminum in the MOF catalyst was studied using the spectroscopy capabilities of the Canadian Light Source, providing key insight into the interactions between the two acids.In addition, the pores which allow molecules to enter and exit MOFs during the catalysis process are much larger than those of zeolite materials. Larger pores prevent the reaction from stalling or overheating, which likely helps give MOFs their long effective life. In principle, MOFs could combine inorganic chemistry and organi